Tuning the Activity of Heterogeneous Cofacial Cobalt Porphyrins for Oxygen Reduction Electrocatalysis through Self‐Assembly
Abstract
Abstract We report a suite of coordination‐driven self‐assembled prisms for heterogeneous electrocatalytic oxygen reduction (ORR) differing in the molecular clips linking two porphyrin faces in a cofacial arrangement. ORR activities and selectivities of monomeric CoTPyP along with cofacial prisms Ox‐Co , Oxa‐Co , and Benzo‐Co were probed using cyclic voltammetry and rotating ring‐disk techniques. All species were immobilized as heterogeneous catalysts on glassy carbon electrodes using a Nafion ink method. The selectivities of Ox‐Co , Oxa‐Co , and Benzo‐Co prisms towards H 2 O as determined by RRDE were 87, 97, and 75 %, respectively. The current density of the Oxa‐Co plateaus at five times that of Pt/C when normalized per Co/Pt. The high synthetic yield (79 %), competitive overpotential ( η ≈800 mV) and high selectivity (%H 2 O ≈97 %) of the Oxa‐Co highlights how self‐assembly can be used to address multi‐electron multi‐proton transformations using polynuclear catalysts.
- Authors:
-
[1];
[1];
[2];
[1]
- Department of Chemistry University at Buffalo, The State University of New York Buffalo NY 14260 USA
- Department of Materials, Design, and Innovation University at Buffalo, The State University of New York Buffalo NY 14260 USA
- Publication Date:
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1458781
- Resource Type:
- Publisher's Accepted Manuscript
- Journal Name:
- Chemistry - A European Journal
- Additional Journal Information:
- Journal Name: Chemistry - A European Journal Journal Volume: 24 Journal Issue: 43; Journal ID: ISSN 0947-6539
- Publisher:
- Wiley Blackwell (John Wiley & Sons)
- Country of Publication:
- Germany
- Language:
- English
Citation Formats
Oldacre, Amanda N., Crawley, Matthew R., Friedman, Alan E., and Cook, Timothy R. Tuning the Activity of Heterogeneous Cofacial Cobalt Porphyrins for Oxygen Reduction Electrocatalysis through Self‐Assembly. Germany: N. p., 2018.
Web. doi:10.1002/chem.201802585.
Oldacre, Amanda N., Crawley, Matthew R., Friedman, Alan E., & Cook, Timothy R. Tuning the Activity of Heterogeneous Cofacial Cobalt Porphyrins for Oxygen Reduction Electrocatalysis through Self‐Assembly. Germany. https://doi.org/10.1002/chem.201802585
Oldacre, Amanda N., Crawley, Matthew R., Friedman, Alan E., and Cook, Timothy R. Tue .
"Tuning the Activity of Heterogeneous Cofacial Cobalt Porphyrins for Oxygen Reduction Electrocatalysis through Self‐Assembly". Germany. https://doi.org/10.1002/chem.201802585.
@article{osti_1458781,
title = {Tuning the Activity of Heterogeneous Cofacial Cobalt Porphyrins for Oxygen Reduction Electrocatalysis through Self‐Assembly},
author = {Oldacre, Amanda N. and Crawley, Matthew R. and Friedman, Alan E. and Cook, Timothy R.},
abstractNote = {Abstract We report a suite of coordination‐driven self‐assembled prisms for heterogeneous electrocatalytic oxygen reduction (ORR) differing in the molecular clips linking two porphyrin faces in a cofacial arrangement. ORR activities and selectivities of monomeric CoTPyP along with cofacial prisms Ox‐Co , Oxa‐Co , and Benzo‐Co were probed using cyclic voltammetry and rotating ring‐disk techniques. All species were immobilized as heterogeneous catalysts on glassy carbon electrodes using a Nafion ink method. The selectivities of Ox‐Co , Oxa‐Co , and Benzo‐Co prisms towards H 2 O as determined by RRDE were 87, 97, and 75 %, respectively. The current density of the Oxa‐Co plateaus at five times that of Pt/C when normalized per Co/Pt. The high synthetic yield (79 %), competitive overpotential ( η ≈800 mV) and high selectivity (%H 2 O ≈97 %) of the Oxa‐Co highlights how self‐assembly can be used to address multi‐electron multi‐proton transformations using polynuclear catalysts.},
doi = {10.1002/chem.201802585},
journal = {Chemistry - A European Journal},
number = 43,
volume = 24,
place = {Germany},
year = {Tue Jul 03 00:00:00 EDT 2018},
month = {Tue Jul 03 00:00:00 EDT 2018}
}
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