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Title: Ultrafast shock compression of PDMS-based polymers

Journal Article · · Journal of Polymer Science. Part B, Polymer Physics
DOI: https://doi.org/10.1002/polb.24589 · OSTI ID:1458706
ORCiD logo [1];  [1];  [1];  [1];  [1];  [1];  [1];  [1];  [1];  [1];  [1]
  1. Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States)
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The shock response of polymers is important for a number of commercial and defense–related applications, but it is difficult to obtain empirical shock response data over the wide range of preparations and aging conditions typically found in such applications. Ultrafast compression is useful to characterize polymer shock response over a wide range of polymer initial conditions due to the high throughput of this method. To establish greater confidence in ultrafast compression experiments and to characterize the detailed shock response of several variations in a single base polymer, the results of sub–nanosecond shock compression experiments in ~5 μm thick layers of the polydimethylsiloxane (PDMS)–based elastomeric rubbers Sylgard–184, SE1700, and an unfilled, end–linked model PDMS network are presented. The results of conventional ultrafast shock etalon measurements to time–of–flight measurements for similar thickness layers of irradiated and unirradiated SE1700 are compared. Here, good agreement between the shock response measured by these two ultrafast shock methods, as well as consistency between ultrafast data and long time scale gas gun data is found.

Research Organization:
Lawrence Livermore National Laboratory (LLNL), Livermore, CA (United States)
Sponsoring Organization:
USDOE National Nuclear Security Administration (NNSA)
Grant/Contract Number:
AC52-07NA27344
OSTI ID:
1458706
Alternate ID(s):
OSTI ID: 1421566
Report Number(s):
LLNL-JRNL--741919; 895994
Journal Information:
Journal of Polymer Science. Part B, Polymer Physics, Journal Name: Journal of Polymer Science. Part B, Polymer Physics Journal Issue: 11 Vol. 56; ISSN 0887-6266
Publisher:
WileyCopyright Statement
Country of Publication:
United States
Language:
English

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Cited By (4)

A benchtop shock physics laboratory: Ultrafast laser driven shock spectroscopy and interferometry methods journal June 2019
Ultrafast shock synthesis of nanocarbon from a liquid precursor journal January 2020
Canonical dynamics: Equilibrium phase-space distributions journal March 1985
Ultrafast shock synthesis of nanocarbon from a liquid precursor journal January 2020

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Related Subjects

36 MATERIALS SCIENCE
75 CONDENSED MATTER PHYSICS
SUPERCONDUCTIVITY AND SUPERFLUIDITY
compression
dynamic mechanical properties
elastomers
irradiation
polydimethylsiloxane
response
shock
strain
strength
ultrafast