skip to main content

DOE PAGESDOE PAGES

This content will become publicly available on June 19, 2019

Title: Compositional and structural insights into the nature of the H-cluster precursor on HydF

Spectroscopic and computational characterization of loaded HydF reveals that the 2Fe subcluster is a coordinatively saturated Fe( i )–Fe( i ) species that contains 4 CO and 2 CN ligands, and is anchored to HydF via coordination to a [4Fe–4S] cluster.
Authors:
 [1] ; ORCiD logo [1] ;  [2] ;  [2] ;  [1] ; ORCiD logo [2] ;  [1] ;  [1] ; ORCiD logo [1]
  1. Department of Chemistry and Biochemistry, Montana State University, Bozeman, USA
  2. Biosciences Center, National Renewable Energy Laboratory, Golden, USA
Publication Date:
Grant/Contract Number:
AC36-08-GO28308; SC0005404
Type:
Publisher's Accepted Manuscript
Journal Name:
Dalton Transactions
Additional Journal Information:
Journal Volume: 47; Journal Issue: 28; Related Information: CHORUS Timestamp: 2018-07-17 05:55:10; Journal ID: ISSN 1477-9226
Publisher:
Royal Society of Chemistry (RSC)
Sponsoring Org:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
Country of Publication:
United Kingdom
Language:
English
OSTI Identifier:
1458586