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Title: Compositional and structural insights into the nature of the H-cluster precursor on HydF

Abstract

Spectroscopic and computational characterization of loaded HydF reveals that the 2Fe subcluster is a coordinatively saturated Fe( i )–Fe( i ) species that contains 4 CO and 2 CN ligands, and is anchored to HydF via coordination to a [4Fe–4S] cluster.

Authors:
 [1]; ORCiD logo [1];  [2];  [2];  [1]; ORCiD logo [2];  [1];  [1]; ORCiD logo [1]
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  1. Montana State Univ., Bozeman, MT (United States)
  2. National Renewable Energy Lab. (NREL), Golden, CO (United States)
Publication Date:
Research Org.:
National Renewable Energy Lab. (NREL), Golden, CO (United States)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
OSTI Identifier:
1466185
Alternate Identifier(s):
OSTI ID: 1458586
Report Number(s):
NREL/JA-2700-71169
Journal ID: ISSN 1477-9226; ICHBD9
Grant/Contract Number:  
AC36-08GO28308; AC36-08-GO28308; SC0005404
Resource Type:
Accepted Manuscript
Journal Name:
Dalton Transactions
Additional Journal Information:
Journal Volume: 47; Journal Issue: 28; Journal ID: ISSN 1477-9226
Publisher:
Royal Society of Chemistry
Country of Publication:
United States
Language:
English
Subject:
09 BIOMASS FUELS; [FeFe]-hydrogenases; spectroscopy

Citation Formats

Scott, Anna G., Szilagyi, Robert K., Mulder, David W., Ratzloff, Michael W., Byer, Amanda S., King, Paul W., Broderick, William E., Shepard, Eric M., and Broderick, Joan B. Compositional and structural insights into the nature of the H-cluster precursor on HydF. United States: N. p., 2018. Web. doi:10.1039/C8DT01654B.
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Scott, Anna G., Szilagyi, Robert K., Mulder, David W., Ratzloff, Michael W., Byer, Amanda S., King, Paul W., Broderick, William E., Shepard, Eric M., & Broderick, Joan B. Compositional and structural insights into the nature of the H-cluster precursor on HydF. United States. https://doi.org/10.1039/C8DT01654B
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Scott, Anna G., Szilagyi, Robert K., Mulder, David W., Ratzloff, Michael W., Byer, Amanda S., King, Paul W., Broderick, William E., Shepard, Eric M., and Broderick, Joan B. Tue . "Compositional and structural insights into the nature of the H-cluster precursor on HydF". United States. https://doi.org/10.1039/C8DT01654B. https://www.osti.gov/servlets/purl/1466185.
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@article{osti_1466185,
title = {Compositional and structural insights into the nature of the H-cluster precursor on HydF},
author = {Scott, Anna G. and Szilagyi, Robert K. and Mulder, David W. and Ratzloff, Michael W. and Byer, Amanda S. and King, Paul W. and Broderick, William E. and Shepard, Eric M. and Broderick, Joan B.},
abstractNote = {Spectroscopic and computational characterization of loaded HydF reveals that the 2Fe subcluster is a coordinatively saturated Fe( i )–Fe( i ) species that contains 4 CO and 2 CN ligands, and is anchored to HydF via coordination to a [4Fe–4S] cluster.},
doi = {10.1039/C8DT01654B},
journal = {Dalton Transactions},
number = 28,
volume = 47,
place = {United States},
year = {Tue Jun 19 00:00:00 EDT 2018},
month = {Tue Jun 19 00:00:00 EDT 2018}
}
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Journal Article:
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Publisher's Version of Record
https://doi.org/10.1039/C8DT01654B
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Cited by: 11 works
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Figures / Tables:

Figure 1 Figure 1: Overview of computational models for the [2Fe]F subcluster in HydFEG considered in the given work.
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    Works referencing / citing this record:

    Overview of the Maturation Machinery of the H-Cluster of [FeFe]-Hydrogenases with a Focus on HydF
    journal, October 2018

    • Bortolus, Marco; Costantini, Paola; Doni, Davide
    • International Journal of Molecular Sciences, Vol. 19, Issue 10
    • DOI: 10.3390/ijms19103118
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