Restricted Speciation and Supramolecular Assembly in the 5f Block

Carter, Korey P.; Surbella, III, Robert G.; Kalaj, Mark; Cahill, Christopher L.

doi:10.1002/chem.201801044

Title: Restricted Speciation and Supramolecular Assembly in the 5f Block

Journal Article · 02 July 2018 · Chemistry - A European Journal

DOI: https://doi.org/10.1002/chem.201801044 · OSTI ID:1458583

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Department of Chemistry The George Washington University 800 22nd Street NW Washington, DC 20052 USA
Department of Chemistry The George Washington University 800 22nd Street NW Washington, DC 20052 USA, Pacific Northwest National Laboratory 902 Battelle Boulevard Richland WA 99354 USA

Abstract Hybrid materials bearing elements from the 5f block display a rich diversity of coordination geometries, connectivities, and assembly motifs. Exemplary in this regard have been uranyl coordination polymers, which feature a wide range of secondary building units resulting from hydrolysis and oligomerization of the [UO ₂ ] ²⁺ cation. An alternative approach to novel materials, however, suppresses hydrolysis and relies on non‐covalent interactions (e.g. hydrogen or halogen bonding) to direct assembly of a more limited suite of species or building units. This may be achieved through the use of high‐anion media to promote singular actinyl anions that are assembled with organic cations, or by way of functionalized chelating ligands that produce complexes suited for assembly through peripheral donor/acceptor sites. Presented in this Concept article is therefore an overview of our efforts in this arena. We highlight examples of each approach, share our thoughts regarding delineation of assembly criteria, and discuss the opportunities for exploring structure–property relationships in these systems.

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Sponsoring Organization:: USDOE

Grant/Contract Number:: NONE; FG02-05ER15736

OSTI ID:: 1458583

Journal Information:: Chemistry - A European Journal, Journal Name: Chemistry - A European Journal Journal Issue: 49 Vol. 24; ISSN 0947-6539

Publisher:: Wiley Blackwell (John Wiley & Sons)Copyright Statement

Country of Publication:: Germany

Language:: English

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