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Title: Enabling multi-electron reaction of ε-VOPO 4 to reach theoretical capacity for lithium-ion batteries

Synthesizing highly crystalline nano-sized ε-VOPO 4 particles is the key to achieve theoretical capacity of 2 Li + intercalation in lithium-ion batteries.
Authors:
 [1] ;  [2] ;  [2] ;  [1] ;  [1] ;  [1] ;  [1] ;  [1] ;  [1] ; ORCiD logo [1] ;  [2] ; ORCiD logo [1] ; ORCiD logo [1]
  1. NorthEast Center for Chemical Energy Storage (NECCES) at Binghamton University in Binghamton, USA
  2. Department of Chemistry at University of Cambridge, Cambridge, UK
Publication Date:
Grant/Contract Number:
SC0012583; AC02-06CH11357
Type:
Publisher's Accepted Manuscript
Journal Name:
Chemical Communications
Additional Journal Information:
Journal Name: Chemical Communications Journal Volume: 54 Journal Issue: 56; Journal ID: ISSN 1359-7345
Publisher:
Royal Society of Chemistry (RSC)
Sponsoring Org:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
Country of Publication:
United Kingdom
Language:
English
OSTI Identifier:
1457464

Siu, Carrie, Seymour, Ieuan D., Britto, Sylvia, Zhang, Hanlei, Rana, Jatinkumar, Feng, Jun, Omenya, Fredrick O., Zhou, Hui, Chernova, Natasha A., Zhou, Guangwen, Grey, Clare P., Piper, Louis F. J., and Whittingham, M. Stanley. Enabling multi-electron reaction of ε-VOPO 4 to reach theoretical capacity for lithium-ion batteries. United Kingdom: N. p., Web. doi:10.1039/C8CC02386G.
Siu, Carrie, Seymour, Ieuan D., Britto, Sylvia, Zhang, Hanlei, Rana, Jatinkumar, Feng, Jun, Omenya, Fredrick O., Zhou, Hui, Chernova, Natasha A., Zhou, Guangwen, Grey, Clare P., Piper, Louis F. J., & Whittingham, M. Stanley. Enabling multi-electron reaction of ε-VOPO 4 to reach theoretical capacity for lithium-ion batteries. United Kingdom. doi:10.1039/C8CC02386G.
Siu, Carrie, Seymour, Ieuan D., Britto, Sylvia, Zhang, Hanlei, Rana, Jatinkumar, Feng, Jun, Omenya, Fredrick O., Zhou, Hui, Chernova, Natasha A., Zhou, Guangwen, Grey, Clare P., Piper, Louis F. J., and Whittingham, M. Stanley. 2018. "Enabling multi-electron reaction of ε-VOPO 4 to reach theoretical capacity for lithium-ion batteries". United Kingdom. doi:10.1039/C8CC02386G.
@article{osti_1457464,
title = {Enabling multi-electron reaction of ε-VOPO 4 to reach theoretical capacity for lithium-ion batteries},
author = {Siu, Carrie and Seymour, Ieuan D. and Britto, Sylvia and Zhang, Hanlei and Rana, Jatinkumar and Feng, Jun and Omenya, Fredrick O. and Zhou, Hui and Chernova, Natasha A. and Zhou, Guangwen and Grey, Clare P. and Piper, Louis F. J. and Whittingham, M. Stanley},
abstractNote = {Synthesizing highly crystalline nano-sized ε-VOPO 4 particles is the key to achieve theoretical capacity of 2 Li + intercalation in lithium-ion batteries.},
doi = {10.1039/C8CC02386G},
journal = {Chemical Communications},
number = 56,
volume = 54,
place = {United Kingdom},
year = {2018},
month = {1}
}

Works referenced in this record:

Lithium Batteries and Cathode Materials
journal, October 2004
  • Whittingham, M. Stanley
  • Chemical Reviews, Vol. 104, Issue 10, p. 4271-4302
  • DOI: 10.1021/cr020731c

Electrochemical Behavior of Nanostructured ɛ-VOPO4 over Two Redox Plateaus
journal, January 2013
  • Chen, Z.; Chen, Q.; Chen, L.
  • Journal of the Electrochemical Society, Vol. 160, Issue 10, p. A1777-A1780
  • DOI: 10.1149/2.064310jes