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Title: Oxygen activation at a dicobalt centre of a dipyridylethane naphthyridine complex

The mechanism of oxygen activation at a dicobalt bis-μ-hydroxo core is probed by the implementation of synthetic methods to isolate reaction intermediates.
Authors:
 [1] ;  [1] ;  [1] ;  [1] ; ORCiD logo [1] ;  [1] ;  [1] ; ORCiD logo [2] ; ORCiD logo [1]
  1. Department of Chemistry and Chemical Biology, Harvard University, Cambridge, USA
  2. Laboratoire d'Electrochimie Moléculaire, Unité Mixte de Recherche Université – CNRS N° 7591, Bâtiment Lavoisier, Université Paris Diderot, Sorbonne Paris Cité
Publication Date:
Grant/Contract Number:
SC0017619
Type:
Publisher's Accepted Manuscript
Journal Name:
Dalton Transactions
Additional Journal Information:
Journal Name: Dalton Transactions Journal Volume: 47 Journal Issue: 34; Journal ID: ISSN 1477-9226
Publisher:
Royal Society of Chemistry (RSC)
Sponsoring Org:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
Country of Publication:
United Kingdom
Language:
English
OSTI Identifier:
1457198

Brodsky, Casey N., Passard, Guillaume, Ullman, Andrew M., Jaramillo, David E., Bloch, Eric D., Huynh, Michael, Gygi, David, Costentin, Cyrille, and Nocera, Daniel G.. Oxygen activation at a dicobalt centre of a dipyridylethane naphthyridine complex. United Kingdom: N. p., Web. doi:10.1039/C8DT01598H.
Brodsky, Casey N., Passard, Guillaume, Ullman, Andrew M., Jaramillo, David E., Bloch, Eric D., Huynh, Michael, Gygi, David, Costentin, Cyrille, & Nocera, Daniel G.. Oxygen activation at a dicobalt centre of a dipyridylethane naphthyridine complex. United Kingdom. doi:10.1039/C8DT01598H.
Brodsky, Casey N., Passard, Guillaume, Ullman, Andrew M., Jaramillo, David E., Bloch, Eric D., Huynh, Michael, Gygi, David, Costentin, Cyrille, and Nocera, Daniel G.. 2018. "Oxygen activation at a dicobalt centre of a dipyridylethane naphthyridine complex". United Kingdom. doi:10.1039/C8DT01598H.
@article{osti_1457198,
title = {Oxygen activation at a dicobalt centre of a dipyridylethane naphthyridine complex},
author = {Brodsky, Casey N. and Passard, Guillaume and Ullman, Andrew M. and Jaramillo, David E. and Bloch, Eric D. and Huynh, Michael and Gygi, David and Costentin, Cyrille and Nocera, Daniel G.},
abstractNote = {The mechanism of oxygen activation at a dicobalt bis-μ-hydroxo core is probed by the implementation of synthetic methods to isolate reaction intermediates.},
doi = {10.1039/C8DT01598H},
journal = {Dalton Transactions},
number = 34,
volume = 47,
place = {United Kingdom},
year = {2018},
month = {1}
}

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Powering the planet: Chemical challenges in solar energy utilization
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  • Lewis, N. S.; Nocera, D. G.
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  • DOI: 10.1073/pnas.0603395103

In Situ Formation of an Oxygen-Evolving Catalyst in Neutral Water Containing Phosphate and Co2+
journal, August 2008