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Title: Amending the Structure of Renewable Carbon from Biorefinery Waste-Streams for Energy Storage Applications

Abstract

Biorefineries produce impure sugar waste streams that are being underutilized. By converting this waste to a profitable by-product, biorefineries could be safeguarded against low oil prices. We demonstrate controlled production of useful carbon materials from the waste concentrate via hydrothermal synthesis and carbonization. We devise a pathway to producing tunable, porous spherical carbon materials by modeling the gross structure formation and developing an understanding of the pore formation mechanism utilizing simple reaction principles. Compared to a simple hydrothermal synthesis from sugar concentrate, emulsion-based synthesis results in hollow spheres with abundant microporosity. In contrast, conventional hydrothermal synthesis produces solid beads with micro and mesoporosity. All the carbonaceous materials show promise in energy storage application. Using our reaction pathway, perfect hollow activated carbon spheres can be produced from waste sugar in liquid effluence of biomass steam pretreatment units. As a result, the renewable carbon product demonstrated a desirable surface area of 872 m 2/g and capacitance of up to 109 F/g when made into an electric double layer supercapacitor. The capacitor exhibited nearly ideal capacitive behavior with 90.5% capacitance retention after 5000 cycles.

Authors:
 [1]; ORCiD logo [2]; ORCiD logo [2]; ORCiD logo [2]; ORCiD logo [1]
  1. Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); The Univ. of Tennessee, Knoxville, TN (United States)
  2. Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
Publication Date:
Research Org.:
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Oak Ridge Leadership Computing Facility (OLCF)
Sponsoring Org.:
USDOE Office of Science (SC)
OSTI Identifier:
1456801
Grant/Contract Number:  
AC05-00OR22725
Resource Type:
Accepted Manuscript
Journal Name:
Scientific Reports
Additional Journal Information:
Journal Volume: 8; Journal Issue: 1; Journal ID: ISSN 2045-2322
Publisher:
Nature Publishing Group
Country of Publication:
United States
Language:
English
Subject:
25 ENERGY STORAGE

Citation Formats

Ho, Hoi Chun, Goswami, Monojoy, Chen, Jihua, Keum, Jong K., and Naskar, Amit K. Amending the Structure of Renewable Carbon from Biorefinery Waste-Streams for Energy Storage Applications. United States: N. p., 2018. Web. doi:10.1038/s41598-018-25880-0.
Ho, Hoi Chun, Goswami, Monojoy, Chen, Jihua, Keum, Jong K., & Naskar, Amit K. Amending the Structure of Renewable Carbon from Biorefinery Waste-Streams for Energy Storage Applications. United States. doi:10.1038/s41598-018-25880-0.
Ho, Hoi Chun, Goswami, Monojoy, Chen, Jihua, Keum, Jong K., and Naskar, Amit K. Tue . "Amending the Structure of Renewable Carbon from Biorefinery Waste-Streams for Energy Storage Applications". United States. doi:10.1038/s41598-018-25880-0. https://www.osti.gov/servlets/purl/1456801.
@article{osti_1456801,
title = {Amending the Structure of Renewable Carbon from Biorefinery Waste-Streams for Energy Storage Applications},
author = {Ho, Hoi Chun and Goswami, Monojoy and Chen, Jihua and Keum, Jong K. and Naskar, Amit K.},
abstractNote = {Biorefineries produce impure sugar waste streams that are being underutilized. By converting this waste to a profitable by-product, biorefineries could be safeguarded against low oil prices. We demonstrate controlled production of useful carbon materials from the waste concentrate via hydrothermal synthesis and carbonization. We devise a pathway to producing tunable, porous spherical carbon materials by modeling the gross structure formation and developing an understanding of the pore formation mechanism utilizing simple reaction principles. Compared to a simple hydrothermal synthesis from sugar concentrate, emulsion-based synthesis results in hollow spheres with abundant microporosity. In contrast, conventional hydrothermal synthesis produces solid beads with micro and mesoporosity. All the carbonaceous materials show promise in energy storage application. Using our reaction pathway, perfect hollow activated carbon spheres can be produced from waste sugar in liquid effluence of biomass steam pretreatment units. As a result, the renewable carbon product demonstrated a desirable surface area of 872 m2/g and capacitance of up to 109 F/g when made into an electric double layer supercapacitor. The capacitor exhibited nearly ideal capacitive behavior with 90.5% capacitance retention after 5000 cycles.},
doi = {10.1038/s41598-018-25880-0},
journal = {Scientific Reports},
number = 1,
volume = 8,
place = {United States},
year = {2018},
month = {5}
}

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