Highly Permeable Oligo(ethylene oxide)-co-poly(dimethylsiloxane) Membranes for Carbon Dioxide Separation

Hong, Tao; Lai, Sophia C.; Mahurin, Shannon Mark; Cao, Peng -Fei; Voylov, Dmitry N.; Meyer, III, Harry M.; Jacobs, Christopher B.; Carrillo, Jan-Michael Y.; Kisliuk, Alexander; Ivanov, Ilia N.; Jiang, De-en; Long, Brian K.; Mays, Jimmy W.; Sokolov, Alexei P.; Saito, Tomonori

doi:10.1002/adsu.201700113

Title: Highly Permeable Oligo(ethylene oxide)-co-poly(dimethylsiloxane) Membranes for Carbon Dioxide Separation

Journal Article · 27 December 2017 · Advanced Sustainable Systems

DOI: https://doi.org/10.1002/adsu.201700113 · OSTI ID:1456782

^[1]; Lai, Sophia C. ^[2];

^[2];

^[2]; Voylov, Dmitry N. ^[1];

^[2];

^[2]; Kisliuk, Alexander ^[2];

^[2]; Jiang, De-en ^[3]; Long, Brian K. ^[1]; Mays, Jimmy W. ^[4];

^[1];

^[2]

Univ. of Tennessee, Knoxville, TN (United States)
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
Univ. of California, Riverside, CA (United States)
Univ. of Tennessee, Knoxville, TN (United States); Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

Abstract A series of cross‐linked, freestanding oligo(ethylene oxide)‐ co ‐(polydimethylsiloxane‐norbornene) membranes with varied composition is synthesized via in situ ring‐opening metathesis polymerization. These membranes show remarkably high CO ₂ permeabilities (3400 Barrer) and their separation performance approaches the Robeson upper bound. The excellent permeability of these copolymer membranes provides great potential for real‐world applications where enormous volumes of gases must be separated. The gas transport properties of these films are found to be directly proportional to oligo(ethylene oxide) content incorporation, which stems from the increased solubility selectivity change within the copolymer matrix. This work provides a systematic study of how gas separation performance in rubbery membranes can be enhanced by tuning the CO ₂ ‐philicity of their constituent monomeric subunits.

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Research Organization:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)

Sponsoring Organization:: USDOE Office of Fossil Energy (FE); USDOE

Grant/Contract Number:: AC05-00OR22725; DE‐AC05‐00OR22725

OSTI ID:: 1456782

Alternate ID(s):: OSTI ID: 1414957

Journal Information:: Advanced Sustainable Systems, Vol. 2, Issue 4; ISSN 2366-7486

Publisher:: WileyCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 10 works

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Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
CO2-philic
high permeability
membrane gas separation
oligo(ethylene oxide)
polydimethylsiloxane

Title: Highly Permeable Oligo(ethylene oxide)-co-poly(dimethylsiloxane) Membranes for Carbon Dioxide Separation

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