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Title: Heating rate dependent ignition of Al/Pt nanolaminates through pulsed laser irradiation

Abstract

Direct laser irradiation of sputter deposited Al/Pt nanolaminate multilayers results in rapid local heating and exothermic mixing of reactant layers. Milli- and microsecond pulsed laser irradiation under certain test conditions leads to single-point ignition of rapid, self-propagating, formation reactions. Multilayers having bilayer thicknesses of 328 nm, 164 nm, and 65 nm are characterized by their ignition onset times and temperatures. Smaller bilayer thickness multilayers require less laser intensity for ignition compared with larger bilayer designs (when utilizing a particular pulse duration). The relationship between laser intensity and ignition onset time is used to calibrate an activation energy for ignition within a finite element reactive heat transport model. The local heating rate is varied from 104 K/s to 106 K/s by selecting a laser intensity. Kissinger analysis was performed on the heating rate-dependent ignition temperatures measured with high speed pyrometry to experimentally determine an activation energy in the foils of (6.2 ± 1.6 × 104 J/mole atoms). Furthermore, this value is then compared to an activation energy produced from model fits to an ignition onset time of 7.2 × 104 J/mole atoms.

Authors:
 [1];  [1];  [1]
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  1. Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)
Publication Date:
Research Org.:
Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)
Sponsoring Org.:
USDOE National Nuclear Security Administration (NNSA)
OSTI Identifier:
1457521
Alternate Identifier(s):
OSTI ID: 1456261
Report Number(s):
SAND-2018-6578J
Journal ID: ISSN 0021-8979; 664565; TRN: US1901380
Grant/Contract Number:  
AC04-94AL85000
Resource Type:
Accepted Manuscript
Journal Name:
Journal of Applied Physics
Additional Journal Information:
Journal Volume: 123; Journal Issue: 23; Journal ID: ISSN 0021-8979
Publisher:
American Institute of Physics (AIP)
Country of Publication:
United States
Language:
English
Subject:
36 MATERIALS SCIENCE; 71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSICS

Citation Formats

Abere, Michael J., Yarrington, Cole D., and Adams, David P. Heating rate dependent ignition of Al/Pt nanolaminates through pulsed laser irradiation. United States: N. p., 2018. Web. doi:10.1063/1.5026507.
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Abere, Michael J., Yarrington, Cole D., & Adams, David P. Heating rate dependent ignition of Al/Pt nanolaminates through pulsed laser irradiation. United States. https://doi.org/10.1063/1.5026507
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Abere, Michael J., Yarrington, Cole D., and Adams, David P. Thu . "Heating rate dependent ignition of Al/Pt nanolaminates through pulsed laser irradiation". United States. https://doi.org/10.1063/1.5026507. https://www.osti.gov/servlets/purl/1457521.
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@article{osti_1457521,
title = {Heating rate dependent ignition of Al/Pt nanolaminates through pulsed laser irradiation},
author = {Abere, Michael J. and Yarrington, Cole D. and Adams, David P.},
abstractNote = {Direct laser irradiation of sputter deposited Al/Pt nanolaminate multilayers results in rapid local heating and exothermic mixing of reactant layers. Milli- and microsecond pulsed laser irradiation under certain test conditions leads to single-point ignition of rapid, self-propagating, formation reactions. Multilayers having bilayer thicknesses of 328 nm, 164 nm, and 65 nm are characterized by their ignition onset times and temperatures. Smaller bilayer thickness multilayers require less laser intensity for ignition compared with larger bilayer designs (when utilizing a particular pulse duration). The relationship between laser intensity and ignition onset time is used to calibrate an activation energy for ignition within a finite element reactive heat transport model. The local heating rate is varied from 104 K/s to 106 K/s by selecting a laser intensity. Kissinger analysis was performed on the heating rate-dependent ignition temperatures measured with high speed pyrometry to experimentally determine an activation energy in the foils of (6.2 ± 1.6 × 104 J/mole atoms). Furthermore, this value is then compared to an activation energy produced from model fits to an ignition onset time of 7.2 × 104 J/mole atoms.},
doi = {10.1063/1.5026507},
journal = {Journal of Applied Physics},
number = 23,
volume = 123,
place = {United States},
year = {Thu Jun 21 00:00:00 EDT 2018},
month = {Thu Jun 21 00:00:00 EDT 2018}
}
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Journal Article:
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Publisher's Version of Record
https://doi.org/10.1063/1.5026507
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Cited by: 11 works
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Figures / Tables:

FIG. 1 FIG. 1: This diagram shows the Al/Pt multilayer notation with bilayer thickness $Δ$ for the reaction model and depicts the progression from pristine A1/Pt to the growth of a product layer of thickness s(t) with composition AlxPty upon laser irradiation. Here, a(t) and b(t) are the half thicknesses of themore » Pt and Al layers at time t, respectively. A thermal circuit model for calculating the foil thermal conductivity, k, in the longitudinal and transverse directions is shown schematically on the left. Individual material layer widths are not drawn to scale. Within the simulation, s(0) = 10 nm to account for the premixing in the as deposited nanolaminate.« less
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    Works referencing / citing this record:

    Ignition and self-propagating reactions in Al/Pt multilayers of varied design
    journal, September 2018

    • Adams, D. P.; Reeves, R. V.; Abere, M. J.
    • Journal of Applied Physics, Vol. 124, Issue 9
    • DOI: 10.1063/1.5026293

    Influence of interface with mismatch dislocations on mechanical properties of Ti/Al nanolaminate
    journal, April 2019

    • An, M. R.; Song, H. Y.; Deng, Q.
    • Journal of Applied Physics, Vol. 125, Issue 16
    • DOI: 10.1063/1.5085455
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      FIG. 1 (p. 3)figure
      FIG. 3 (p. 5)figure
      FIG.2 (p. 5)figure
      FIG. 4 (p. 6)figure
      FIG. 5 (p. 6)figure
      TABLE I (p. 8)table
      TABLE II (p. 8)table
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