Syntheses, Raman spectroscopy and crystal structures of alkali hexafluoridorhenates(IV) revisited

Louis-Jean, James; Mariappan Balasekaran, Samundeeswari; Smith, Dean; Salamat, Ashkan; Pham, Chien Thang; Poineau, Frederic

doi:10.1107/S2056989018005297

Title: Syntheses, Raman spectroscopy and crystal structures of alkali hexafluoridorhenates(IV) revisited

Journal Article · 05 April 2018 · Acta Crystallographica. Section E, Crystallographic Communications

DOI: https://doi.org/10.1107/S2056989018005297 · OSTI ID:1455235

Louis-Jean, James ^[1];

^[2];

^[3]; Salamat, Ashkan ^[3]; Pham, Chien Thang ^[4]; Poineau, Frederic ^[2]

Univ. of Nevada, Las Vegas, NV (United States). Dept. of Chemistry; UC Berkeley
Univ. of Nevada, Las Vegas, NV (United States). Dept. of Chemistry
Univ. of Nevada, Las Vegas, NV (United States). Dept. of Physics and Astronomy and High Pressure Science and Engineering Center (HiPSEC)
Hanoi Univ. of Science (Vietnam). Dept. of Chemistry

The A₂[ReF₆] (A = K, Rb and Cs) salts are isotypic and crystallize in the trigonal space group type P$$\bar{3}$$m1, adopting the K₂[GeF₆] structure type. Common to all A₂[ReF₆] structures are slightly distorted octahedral [ReF₆]^2- anions with an average Re—F bond length of 1.951 (8) Å. In these salts, symmetry lowering on the local [ReF₆]^2- anions from O_h (free anion) to D_3d (solid-state structure) occur. The distortions of the [ReF₆]^2- anions, as observed in their Raman spectra, are correlated to the size of the counter-cations.

View Accepted Manuscript (DOE)

Cite

Export

Save

Research Organization:: Univ. of Nevada, Las Vegas, NV (United States)

Sponsoring Organization:: USDOE National Nuclear Security Administration (NNSA). Nuclear Science and Security Consortium (NSSC)

Grant/Contract Number:: NA0003180

OSTI ID:: 1455235

Journal Information:: Acta Crystallographica. Section E, Crystallographic Communications, Journal Name: Acta Crystallographica. Section E, Crystallographic Communications Journal Issue: 5 Vol. 74; ISSN ACSECI; ISSN 2056-9890

Publisher:: International Union of CrystallographyCopyright Statement

Country of Publication:: United States

Language:: English

References (13)

Darstellung, Eigenschaften und Kristallstruktur von Kalium-hexafluorotechnetat(IV) Schwochau, K.; Herr, W. Angewandte Chemie, Vol. 75, Issue 1 https://doi.org/10.1002/ange.19630750131	journal	January 1963
[ReF ₆ ] ²⁻ : A Robust Module for the Design of Molecule-Based Magnetic Materials Pedersen, Kasper S.; Sigrist, Marc; Sørensen, Mikkel A. Angewandte Chemie International Edition, Vol. 53, Issue 5 https://doi.org/10.1002/anie.201309981	journal	January 2014
Rheniumfluoride (insbesondere ReF6, ReOF4, ReO2F2, ReF4 und K2ReF6) Ruff, Otto; Kwasnik, Walter Zeitschrift f�r anorganische und allgemeine Chemie, Vol. 219, Issue 1 https://doi.org/10.1002/zaac.19342190107	journal	August 1934
Fluorokomplexe des vierwertigen Rheniums Weise, Eberhard Zeitschrift f�r anorganische und allgemeine Chemie, Vol. 283, Issue 1-6 https://doi.org/10.1002/zaac.19562830139	journal	January 1956
�ber einige Hexahalogenorhenate(IV) Brauer, G.; Allardt, H. -D. Zeitschrift f�r anorganische und allgemeine Chemie, Vol. 316, Issue 3-4 https://doi.org/10.1002/zaac.19623160305	journal	July 1962
Polarized Raman spectra of the trigonal crystal K2ReF6 Bettinelli, Marco; Di Sipio, Lorenzo; Ingletto, Gianluigi Inorganica Chimica Acta, Vol. 133, Issue 1 https://doi.org/10.1016/S0020-1693(00)84358-3	journal	October 1987
Hexafluoridotechnetate(IV) Revisited Balasekaran, Samundeeswari Mariappan; Molski, Matthias; Spandl, Johann Inorganic Chemistry, Vol. 52, Issue 12 https://doi.org/10.1021/ic400775e	journal	May 2013
Structures of Complex Fluorides. Potassium Hexafluogermanate and Ammonium Hexafluogermanate Hoard, J. L.; Vincent, W. B. Journal of the American Chemical Society, Vol. 61, Issue 10 https://doi.org/10.1021/ja01265a082	journal	October 1939
263. The quadrivalent fluororhenates Peacock, R. D. Journal of the Chemical Society (Resumed) https://doi.org/10.1039/jr9560001291	journal	January 1956
publCIF : software for editing, validating and formatting crystallographic information files Westrip, Simon P. Journal of Applied Crystallography, Vol. 43, Issue 4 https://doi.org/10.1107/S0021889810022120	journal	June 2010
A short history of SHELX Sheldrick, George M. Acta Crystallographica Section A Foundations of Crystallography, Vol. 64, Issue 1, p. 112-122 https://doi.org/10.1107/S0108767307043930	journal	December 2007
Potassium hexafluororhenate(IV) Clark, G. R.; Russell, D. R. Acta Crystallographica Section B Structural Crystallography and Crystal Chemistry, Vol. 34, Issue 3 https://doi.org/10.1107/S0567740878004264	journal	March 1978
Crystal structure refinement with SHELXL Sheldrick, George M. Acta Crystallographica Section C Structural Chemistry, Vol. 71, Issue 1, p. 3-8 https://doi.org/10.1107/S2053229614024218	journal	January 2015

Cited By (1)

X-ray absorption fine structure spectroscopic study of (NH4)2ReF6 Poineau, Frederic; Louis-Jean, James; Jang, Harry SN Applied Sciences, Vol. 1, Issue 11 https://doi.org/10.1007/s42452-019-1464-6	journal	October 2019

Linked Research (3)

Similar Records

Coexistence of metamagnetism and slow relaxation of magnetization in ammonium hexafluoridorhenate

Journal Article · 2021 · RSC Advances · OSTI ID:1765173

Louis-Jean, James; Balasekaran, Samundeeswari M.; Lawler, Keith V.; +6 more

Structural and spectral studies of hydrated hexaamminecobalt(III)–hexafluororhenate(IV)

Journal Article · 2021 · Journal of Fluorine Chemistry · OSTI ID:1826175

Louis-Jean, James; Forster, Paul M.; Balasekaran, Samundeeswari Mariappan; +2 more

An unexpected rhenium(IV)–rhenium(VII) salt: [Co(NH ₃ ) ₆ ] ₃ [Re ^VII O ₄ ][Re ^IV F ₆ ] ₄ ·6H ₂ O

Journal Article · 2019 · Acta Crystallographica. Section E, Crystallographic Communications · OSTI ID:1617940

Louis–Jean, James; Mariappan Balasekaran, Samundeeswari; Hagenbach, Adelheid; +1 more

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Raman spectroscopy
crystal structure
fluorine
isotypism
rhenium

CSD 1834614: Experimental Crystal Structure Determination: Non-CSD Structure Louis-Jean, J.; Balasekaran, S. Mariappan; Smith, D. https://doi.org/10.25505/fiz.icsd.cc1zl23r The current record is supplemented by this dataset	dataset	April 2018
CSD 1834615: Experimental Crystal Structure Determination: Non-CSD Structure Louis-Jean, J.; Balasekaran, S. Mariappan; Smith, D. https://doi.org/10.25505/fiz.icsd.cc1zl24s The current record is supplemented by this dataset	dataset	April 2018
CSD 1834616: Experimental Crystal Structure Determination: Non-CSD Structure Louis-Jean, J.; Balasekaran, S. Mariappan; Smith, D. https://doi.org/10.25505/fiz.icsd.cc1zl25t The current record is supplemented by this dataset	dataset	April 2018