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Title: Synthesis, structure, and reactivity of crystalline molecular complexes of the {[C 5H 3(SiMe 3) 2] 3Th} 1– anion containing thorium in the formal +2 oxidation state

Abstract

Structural, spectroscopic, and DFT analysis of the first molecular complexes of Th 2+indicate they have a 6d 2electron configuration of the type expected for the transactinide ions Rf 2+and Db 3+.

Authors:
 [1];  [1];  [1];  [1];  [1]
  1. Univ. of California, Irvine, CA (United States)
Publication Date:
Research Org.:
Univ. of California, Irvine, CA (United States)
Sponsoring Org.:
USDOE
OSTI Identifier:
1455191
Grant/Contract Number:  
SC0004739
Resource Type:
Accepted Manuscript
Journal Name:
Chemical Science
Additional Journal Information:
Journal Volume: 6; Journal Issue: 1; Journal ID: ISSN 2041-6520
Publisher:
Royal Society of Chemistry
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Citation Formats

Langeslay, Ryan R., Fieser, Megan E., Ziller, Joseph W., Furche, Filipp, and Evans, William J. Synthesis, structure, and reactivity of crystalline molecular complexes of the {[C5H3(SiMe3)2]3Th} 1– anion containing thorium in the formal +2 oxidation state. United States: N. p., 2014. Web. doi:10.1039/c4sc03033h.
Langeslay, Ryan R., Fieser, Megan E., Ziller, Joseph W., Furche, Filipp, & Evans, William J. Synthesis, structure, and reactivity of crystalline molecular complexes of the {[C5H3(SiMe3)2]3Th} 1– anion containing thorium in the formal +2 oxidation state. United States. doi:10.1039/c4sc03033h.
Langeslay, Ryan R., Fieser, Megan E., Ziller, Joseph W., Furche, Filipp, and Evans, William J. Mon . "Synthesis, structure, and reactivity of crystalline molecular complexes of the {[C5H3(SiMe3)2]3Th} 1– anion containing thorium in the formal +2 oxidation state". United States. doi:10.1039/c4sc03033h. https://www.osti.gov/servlets/purl/1455191.
@article{osti_1455191,
title = {Synthesis, structure, and reactivity of crystalline molecular complexes of the {[C5H3(SiMe3)2]3Th} 1– anion containing thorium in the formal +2 oxidation state},
author = {Langeslay, Ryan R. and Fieser, Megan E. and Ziller, Joseph W. and Furche, Filipp and Evans, William J.},
abstractNote = {Structural, spectroscopic, and DFT analysis of the first molecular complexes of Th2+indicate they have a 6d2electron configuration of the type expected for the transactinide ions Rf2+and Db3+.},
doi = {10.1039/c4sc03033h},
journal = {Chemical Science},
number = 1,
volume = 6,
place = {United States},
year = {2014},
month = {11}
}

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Cited by: 47 works
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Works referenced in this record:

Revised effective ionic radii and systematic studies of interatomic distances in halides and chalcogenides
journal, September 1976


    Works referencing / citing this record:

    CCDC 1018013: Experimental Crystal Structure Determination: DULCOC01 : tris(η5-1,3-bis(trimethylsilyl)cyclopentadienyl)-thorium(iii)
    dataset, August 2014

    • Langeslay, Ryan; Fieser, Megan; Ziller, Joseph
    • Cambridge Structural Database (CSD)
    • DOI: 10.5517/cc135b4r

    CCDC 1018014: Experimental Crystal Structure Determination
    dataset, April 2014

    • Langeslay, Ryan R.; Fieser, Megan E.; Ziller, Joseph W.
    • Cambridge Crystallographic Data Centre, Issue vp
    • DOI: 10.5517/cc135b5s