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Title: Non-stoichiometric compositions arising from synergistic electronic and size effects. Synthesis, crystal chemistry and electronic properties of A14Cd1+xPn11 compounds (0 ≤ x ≤ 0.3; A = Sr, Eu; Pn = As, Sb)

Abstract

Synthesis and structural characterization of four compounds, isostructural, but not isoelectronic, with the thermoelectric material Yb14MnSb11.

Authors:
 [1];  [1];  [1];  [1]
  1. Univ. of Delaware, Newark, DE (United States)
Publication Date:
Research Org.:
Univ. of Delaware, Newark, DE (United States)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
OSTI Identifier:
1455022
Grant/Contract Number:  
SC0008885
Resource Type:
Accepted Manuscript
Journal Name:
Journal of Materials Chemistry C
Additional Journal Information:
Journal Volume: 3; Journal Issue: 40; Journal ID: ISSN 2050-7526
Publisher:
Royal Society of Chemistry
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Citation Formats

Makongo, Julien P. A., Darone, Gregory M., Xia, Sheng -Qing, and Bobev, Svilen. Non-stoichiometric compositions arising from synergistic electronic and size effects. Synthesis, crystal chemistry and electronic properties of A14Cd1+xPn11 compounds (0 ≤ x ≤ 0.3; A = Sr, Eu; Pn = As, Sb). United States: N. p., 2015. Web. doi:10.1039/c5tc01605c.
Makongo, Julien P. A., Darone, Gregory M., Xia, Sheng -Qing, & Bobev, Svilen. Non-stoichiometric compositions arising from synergistic electronic and size effects. Synthesis, crystal chemistry and electronic properties of A14Cd1+xPn11 compounds (0 ≤ x ≤ 0.3; A = Sr, Eu; Pn = As, Sb). United States. doi:10.1039/c5tc01605c.
Makongo, Julien P. A., Darone, Gregory M., Xia, Sheng -Qing, and Bobev, Svilen. Wed . "Non-stoichiometric compositions arising from synergistic electronic and size effects. Synthesis, crystal chemistry and electronic properties of A14Cd1+xPn11 compounds (0 ≤ x ≤ 0.3; A = Sr, Eu; Pn = As, Sb)". United States. doi:10.1039/c5tc01605c. https://www.osti.gov/servlets/purl/1455022.
@article{osti_1455022,
title = {Non-stoichiometric compositions arising from synergistic electronic and size effects. Synthesis, crystal chemistry and electronic properties of A14Cd1+xPn11 compounds (0 ≤ x ≤ 0.3; A = Sr, Eu; Pn = As, Sb)},
author = {Makongo, Julien P. A. and Darone, Gregory M. and Xia, Sheng -Qing and Bobev, Svilen},
abstractNote = {Synthesis and structural characterization of four compounds, isostructural, but not isoelectronic, with the thermoelectric material Yb14MnSb11.},
doi = {10.1039/c5tc01605c},
journal = {Journal of Materials Chemistry C},
number = 40,
volume = 3,
place = {United States},
year = {2015},
month = {7}
}

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Cited by: 6 works
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    Works referencing / citing this record:

    On the Extended Series of Quaternary Zintl Phases Ca13REMnSb11 (RE = La-Nd, Sm, Gd-Dy): On the Extended Series of Quaternary Zintl Phases Ca13REMnSb11 (RE = La-Nd, Sm, Gd-Dy)
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    Synthesis, crystal structure and physical properties of the solid solutions Ca 14– x RE x CdSb 11 ( RE  = La–Nd, Sm, Gd–Yb, x  ≈ 0.85 ± 0.15)
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    • Baranets, Sviatoslav; Voss, Leonard; Stoyko, Stanislav
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