Enabling alternative ethylene production through its selective adsorption in the metal–organic framework Mn 2 ( m -dobdc)
Abstract
The unique adsorptive properties of metal–organic frameworks open the door to new processes for energy and raw materials production.
- Authors:
-
[1];
[4]
- Department of Materials Science and Engineering, Stanford University, Stanford, USA, Department of Chemical and Biomolecular Engineering
- Department of Chemistry, University of California, Berkeley, Berkeley, USA
- Siluria Technologies Inc., San Francisco, USA
- Department of Chemical and Biomolecular Engineering, University of California, Berkeley, Berkeley, USA, Department of Chemistry
- Publication Date:
- Sponsoring Org.:
- USDOE Office of Energy Efficiency and Renewable Energy (EERE)
- OSTI Identifier:
- 1454635
- Grant/Contract Number:
- EE0005769
- Resource Type:
- Publisher's Accepted Manuscript
- Journal Name:
- Energy & Environmental Science
- Additional Journal Information:
- Journal Name: Energy & Environmental Science Journal Volume: 11 Journal Issue: 9; Journal ID: ISSN 1754-5692
- Publisher:
- Royal Society of Chemistry (RSC)
- Country of Publication:
- United Kingdom
- Language:
- English
Citation Formats
Bachman, Jonathan E., Reed, Douglas A., Kapelewski, Matthew T., Chachra, Gaurav, Jonnavittula, Divya, Radaelli, Guido, and Long, Jeffrey R. Enabling alternative ethylene production through its selective adsorption in the metal–organic framework Mn 2 ( m -dobdc). United Kingdom: N. p., 2018.
Web. doi:10.1039/C8EE01332B.
Bachman, Jonathan E., Reed, Douglas A., Kapelewski, Matthew T., Chachra, Gaurav, Jonnavittula, Divya, Radaelli, Guido, & Long, Jeffrey R. Enabling alternative ethylene production through its selective adsorption in the metal–organic framework Mn 2 ( m -dobdc). United Kingdom. https://doi.org/10.1039/C8EE01332B
Bachman, Jonathan E., Reed, Douglas A., Kapelewski, Matthew T., Chachra, Gaurav, Jonnavittula, Divya, Radaelli, Guido, and Long, Jeffrey R. Mon .
"Enabling alternative ethylene production through its selective adsorption in the metal–organic framework Mn 2 ( m -dobdc)". United Kingdom. https://doi.org/10.1039/C8EE01332B.
@article{osti_1454635,
title = {Enabling alternative ethylene production through its selective adsorption in the metal–organic framework Mn 2 ( m -dobdc)},
author = {Bachman, Jonathan E. and Reed, Douglas A. and Kapelewski, Matthew T. and Chachra, Gaurav and Jonnavittula, Divya and Radaelli, Guido and Long, Jeffrey R.},
abstractNote = {The unique adsorptive properties of metal–organic frameworks open the door to new processes for energy and raw materials production.},
doi = {10.1039/C8EE01332B},
journal = {Energy & Environmental Science},
number = 9,
volume = 11,
place = {United Kingdom},
year = {Mon Jan 01 00:00:00 EST 2018},
month = {Mon Jan 01 00:00:00 EST 2018}
}
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https://doi.org/10.1039/C8EE01332B
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Works referenced in this record:
Upper bound on the yield for oxidative coupling of methane
journal, September 2003
- Su, Y.
- Journal of Catalysis, Vol. 218, Issue 2
Thermodynamics of mixed-gas adsorption
journal, January 1965
- Myers, A. L.; Prausnitz, J. M.
- AIChE Journal, Vol. 11, Issue 1, p. 121-127
Oxidative coupling of methane (OCM) in a catalytic membrane reactor and comparison of its performance with other catalytic reactors
journal, May 2009
- Bhatia, Subhash; Thien, Chua Yen; Mohamed, Abdul Rahman
- Chemical Engineering Journal, Vol. 148, Issue 2-3
The catalytic conversion of methane to higher hydrocarbons
journal, January 1990
- Lunsford, J. H.
- Catalysis Today, Vol. 6, Issue 3
Hydrocarbon Separations in a Metal-Organic Framework with Open Iron(II) Coordination Sites
journal, March 2012
- Bloch, E. D.; Queen, W. L.; Krishna, R.
- Science, Vol. 335, Issue 6076, p. 1606-1610
Metal−Organic Frameworks with Functional Pores for Recognition of Small Molecules
journal, August 2010
- Chen, Banglin; Xiang, Shengchang; Qian, Guodong
- Accounts of Chemical Research, Vol. 43, Issue 8
M2(m-dobdc) (M = Mg, Mn, Fe, Co, Ni) Metal–Organic Frameworks Exhibiting Increased Charge Density and Enhanced H2 Binding at the Open Metal Sites
journal, August 2014
- Kapelewski, Matthew T.; Geier, Stephen J.; Hudson, Matthew R.
- Journal of the American Chemical Society, Vol. 136, Issue 34, p. 12119-12129
Reversible CO Binding Enables Tunable CO/H 2 and CO/N 2 Separations in Metal–Organic Frameworks with Exposed Divalent Metal Cations
journal, July 2014
- Bloch, Eric D.; Hudson, Matthew R.; Mason, Jarad A.
- Journal of the American Chemical Society, Vol. 136, Issue 30
Highly selective separation of small hydrocarbons and carbon dioxide in a metal–organic framework with open copper(ii) coordination sites
journal, January 2014
- Duan, Xing; He, Yabing; Cui, Yuanjing
- RSC Advances, Vol. 4, Issue 44
Absolute Molecular Sieve Separation of Ethylene/Ethane Mixtures with Silver Zeolite A
journal, August 2012
- Aguado, Sonia; Bergeret, Gérard; Daniel, Cecile
- Journal of the American Chemical Society, Vol. 134, Issue 36
Selective Binding of O 2 over N 2 in a Redox–Active Metal–Organic Framework with Open Iron(II) Coordination Sites
journal, September 2011
- Bloch, Eric D.; Murray, Leslie J.; Queen, Wendy L.
- Journal of the American Chemical Society, Vol. 133, Issue 37
Highly controlled acetylene accommodation in a metal–organic microporous material
journal, July 2005
- Matsuda, Ryotaro; Kitaura, Ryo; Kitagawa, Susumu
- Nature, Vol. 436, Issue 7048
Product shape selectivity dominates the Methanol-to-Olefins (MTO) reaction over H-SAPO-34 catalysts
journal, May 2009
- Hereijgers, Bart P. C.; Bleken, Francesca; Nilsen, Merete H.
- Journal of Catalysis, Vol. 264, Issue 1
Introduction to Metal–Organic Frameworks
journal, September 2011
- Zhou, Hong-Cai; Long, Jeffrey R.; Yaghi, Omar M.
- Chemical Reviews, Vol. 112, Issue 2, p. 673-674
Separation of Hexane Isomers in a Metal-Organic Framework with Triangular Channels
journal, May 2013
- Herm, Z. R.; Wiers, B. M.; Mason, J. A.
- Science, Vol. 340, Issue 6135, p. 960-964
Control of zeolite framework flexibility and pore topology for separation of ethane and ethylene
journal, November 2017
- Bereciartua, Pablo J.; Cantín, Ángel; Corma, Avelino
- Science, Vol. 358, Issue 6366
Metal−Organic Frameworks as Adsorbents for Hydrogen Purification and Precombustion Carbon Dioxide Capture
journal, April 2011
- Herm, Zoey R.; Swisher, Joseph A.; Smit, Berend
- Journal of the American Chemical Society, Vol. 133, Issue 15
Hydrogen Storage in Microporous Metal-Organic Frameworks with Exposed Metal Sites
journal, August 2008
- Dincă, Mircea; Long, Jeffrey R.
- Angewandte Chemie International Edition, Vol. 47, Issue 36, p. 6766-6779
Catalytic oxidative coupling of methane—reaction engineering aspects and process schemes
journal, April 1995
- Mleczko, L.; Baerns, M.
- Fuel Processing Technology, Vol. 42, Issue 2-3
Synthesis of ethylene via oxidative coupling of methane I. Determination of active catalysts
journal, January 1982
- Keller, G.
- Journal of Catalysis, Vol. 73, Issue 1
Selective adsorption of ethylene over ethane and propylene over propane in the metal–organic frameworks M2(dobdc) (M = Mg, Mn, Fe, Co, Ni, Zn)
journal, January 2013
- Geier, Stephen J.; Mason, Jarad A.; Bloch, Eric D.
- Chemical Science, Vol. 4, Issue 5
Dramatic Tuning of Carbon Dioxide Uptake via Metal Substitution in a Coordination Polymer with Cylindrical Pores
journal, August 2008
- Caskey, Stephen R.; Wong-Foy, Antek G.; Matzger, Adam J.
- Journal of the American Chemical Society, Vol. 130, Issue 33, p. 10870-10871
Targeted Manipulation of Metal-Organic Frameworks To Direct Sorption Properties
journal, March 2014
- Schneemann, Andreas; Henke, Sebastian; Schwedler, Inke
- ChemPhysChem, Vol. 15, Issue 5
Methane Storage in Metal–Organic Frameworks: Current Records, Surprise Findings, and Challenges
journal, July 2013
- Peng, Yang; Krungleviciute, Vaiva; Eryazici, Ibrahim
- Journal of the American Chemical Society, Vol. 135, Issue 32, p. 11887-11894
Binary Langmuir and Freundlich isotherms for ideal adsorbed solutions
journal, October 1981
- LeVan, M. Douglas; Vermeulen, Theodore
- The Journal of Physical Chemistry, Vol. 85, Issue 22
Covalent organic frameworks comprising cobalt porphyrins for catalytic CO 2 reduction in water
journal, August 2015
- Lin, Song; Diercks, Christian S.; Zhang, Yue-Biao
- Science, Vol. 349, Issue 6253
Oxidative coupling of methane over mixed oxide catalysts designed for solid oxide membrane reactors
journal, January 2016
- Farrell, Brittany L.; Linic, Suljo
- Catalysis Science & Technology, Vol. 6, Issue 12
Oxidative coupling of methane—A complex surface/gas phase mechanism with strong impact on the reaction engineering
journal, June 2014
- Beck, Benjamin; Fleischer, Vinzenz; Arndt, Sebastian
- Catalysis Today, Vol. 228
Methanol conversion to olefins over ZSM-5 I. Effect of temperature and zeolite SiO2/Al2O3
journal, April 1984
- Chang, C.
- Journal of Catalysis, Vol. 86, Issue 2
Catalytic conversion of methane to more useful chemicals and fuels: a challenge for the 21st century
journal, December 2000
- Lunsford, Jack H.
- Catalysis Today, Vol. 63, Issue 2-4, p. 165-174
Oxidative coupling of methane in a mixed-conducting perovskite membrane reactor
journal, September 1995
- ten Elshof, J. E.; Bouwmeester, H. J. M.; Verweij, H.
- Applied Catalysis A: General, Vol. 130, Issue 2
Selective increase in CO 2 electroreduction activity at grain-boundary surface terminations
journal, November 2017
- Mariano, Ruperto G.; McKelvey, Kim; White, Henry S.
- Science, Vol. 358, Issue 6367
Reversible CO Scavenging via Adsorbate-Dependent Spin State Transitions in an Iron(II)–Triazolate Metal–Organic Framework
journal, April 2016
- Reed, Douglas A.; Xiao, Dianne J.; Gonzalez, Miguel I.
- Journal of the American Chemical Society, Vol. 138, Issue 17
Effect of adsorption equation on prediction of multicomponent adsorption equilibria by the ideal adsorbed solution theory
journal, January 1989
- Richter, Ekkehard; Wilfried, Schütz; Myers, Alan L.
- Chemical Engineering Science, Vol. 44, Issue 8
Drivers of the US CO2 emissions 1997–2013
journal, July 2015
- Feng, Kuishuang; Davis, Steven J.; Sun, Laixiang
- Nature Communications, Vol. 6, Issue 1
Active and selective catalysts for the synthesis of C2H4 and C2H6 via oxidative coupling of methane
journal, August 1986
- Otsuka, K.
- Journal of Catalysis, Vol. 100, Issue 2
Screening of Metal−Organic Frameworks for Carbon Dioxide Capture from Flue Gas Using a Combined Experimental and Modeling Approach
journal, December 2009
- Yazaydın, A. Özgür; Snurr, Randall Q.; Park, Tae-Hong
- Journal of the American Chemical Society, Vol. 131, Issue 51
The oxidative conversion of methane to higher hydrocarbons
journal, February 1987
- Sofranko, J.
- Journal of Catalysis, Vol. 103, Issue 2
A metal-free electrocatalyst for carbon dioxide reduction to multi-carbon hydrocarbons and oxygenates
journal, December 2016
- Wu, Jingjie; Ma, Sichao; Sun, Jing
- Nature Communications, Vol. 7, Issue 1
The Effect of Acid Strength on the Conversion of Methanol to Olefins Over Acidic Microporous Catalysts with the CHA Topology
journal, January 2009
- Bleken, Francesca; Bjørgen, Morten; Palumbo, Luisa
- Topics in Catalysis, Vol. 52, Issue 3
Conversion of methanol to olefins over cobalt-, manganese- and nickel-incorporated SAPO-34 molecular sieves
journal, September 2003
- Dubois, Delphine R.; Obrzut, Daniel L.; Liu, Jing
- Fuel Processing Technology, Vol. 83, Issue 1-3
A Viewpoint on Direct Methane Conversion to Ethane and Ethylene Using Oxidative Coupling on Solid Catalysts
journal, June 2016
- Farrell, Brittany Lancaster; Igenegbai, Valentina Omoze; Linic, Suljo
- ACS Catalysis, Vol. 6, Issue 7
Carbon Dioxide Capture in Metal–Organic Frameworks
journal, September 2011
- Sumida, Kenji; Rogow, David L.; Mason, Jarad A.
- Chemical Reviews, Vol. 112, Issue 2, p. 724-781
M 2 ( m -dobdc) (M = Mn, Fe, Co, Ni) Metal–Organic Frameworks as Highly Selective, High-Capacity Adsorbents for Olefin/Paraffin Separations
journal, October 2017
- Bachman, Jonathan E.; Kapelewski, Matthew T.; Reed, Douglas A.
- Journal of the American Chemical Society, Vol. 139, Issue 43
Hydrocarbon Separations in Metal–Organic Frameworks
journal, September 2013
- Herm, Zoey R.; Bloch, Eric D.; Long, Jeffrey R.
- Chemistry of Materials, Vol. 26, Issue 1
Hybrid porous solids past, present, future
journal, January 2008
- Férey, Gérard
- Chem. Soc. Rev., Vol. 37, Issue 1, p. 191-214
Performance of CaX Zeolite for Separation of C 2 H 6 , C 2 H 4 , and CH 4 by Adsorption Process; Capacity, Selectivity, and Dynamic Adsorption Measurements
journal, December 2010
- Hosseinpour, S.; Fatemi, S.; Mortazavi, Y.
- Separation Science and Technology, Vol. 46, Issue 2
Enhanced CO 2 Adsorption in Metal-Organic Frameworks via Occupation of Open-Metal Sites by Coordinated Water Molecules
journal, April 2009
- Yazaydın, A. Özgür; Benin, Annabelle I.; Faheem, Syed A.
- Chemistry of Materials, Vol. 21, Issue 8
Evaluating metal–organic frameworks for post-combustion carbon dioxide capture via temperature swing adsorption
journal, January 2011
- Mason, Jarad A.; Sumida, Kenji; Herm, Zoey R.
- Energy & Environmental Science, Vol. 4, Issue 8, p. 3030-3040
Metal–Organic Frameworks for Separations
journal, September 2011
- Li, Jian-Rong; Sculley, Julian; Zhou, Hong-Cai
- Chemical Reviews, Vol. 112, Issue 2, p. 869-932
Methanol to Olefins (MTO): From Fundamentals to Commercialization
journal, February 2015
- Tian, Peng; Wei, Yingxu; Ye, Mao
- ACS Catalysis, Vol. 5, Issue 3
Atomically dispersed Ni(i) as the active site for electrochemical CO2 reduction
journal, February 2018
- Yang, Hong Bin; Hung, Sung-Fu; Liu, Song
- Nature Energy, Vol. 3, Issue 2
Metal−Organic Frameworks with Exceptionally High Capacity for Storage of Carbon Dioxide at Room Temperature
journal, December 2005
- Millward, Andrew R.; Yaghi, Omar M.
- Journal of the American Chemical Society, Vol. 127, Issue 51, p. 17998-17999
Cooperative insertion of CO2 in diamine-appended metal-organic frameworks
journal, March 2015
- McDonald, Thomas M.; Mason, Jarad A.; Kong, Xueqian
- Nature, Vol. 519, Issue 7543
Anaerobic digestion technology in livestock manure treatment for biogas production: A review: Anaerobic digestion technology in livestock manure treatment for biogas production
journal, June 2012
- Nasir, Ismail M.; Mohd Ghazi, Tinia I.; Omar, Rozita
- Engineering in Life Sciences, Vol. 12, Issue 3
Adsorption separation of CO2/CH4 gas mixture on the commercial zeolites at atmospheric pressure
journal, August 2013
- Li, Yundong; Yi, Honghong; Tang, Xiaolong
- Chemical Engineering Journal, Vol. 229
The use of the anaerobic baffled reactor (ABR) for wastewater treatment: a review
journal, May 1999
- Barber, William P.; Stuckey, David C.
- Water Research, Vol. 33, Issue 7
Mechanism of the oxidative coupling of methane using C02 as an oxidant over PbO$z.sbnd;MgO
journal, April 1990
- Nishiyama, T.
- Journal of Catalysis, Vol. 122, Issue 2
Industrial applications of metal–organic frameworks
journal, January 2009
- Czaja, Alexander U.; Trukhan, Natalia; Müller, Ulrich
- Chemical Society Reviews, Vol. 38, Issue 5, p. 1284-1293
A Complete Catalytic Cycle for Supramolecular Methanol‐to‐Olefins Conversion by Linking Theory with Experiment
journal, June 2008
- McCann, David M.; Lesthaeghe, David; Kletnieks, Philip W.
- Angewandte Chemie, Vol. 120, Issue 28
Functional Porous Coordination Polymers
journal, April 2004
- Kitagawa, Susumu; Kitaura, Ryo; Noro, Shin-ichiro
- Angewandte Chemie International Edition, Vol. 43, Issue 18, p. 2334-2375
CO2/CH4, CH4/H2 and CO2/CH4/H2 separations at high pressures using Mg2(dobdc)
journal, March 2012
- Herm, Zoey R.; Krishna, Rajamani; Long, Jeffrey R.
- Microporous and Mesoporous Materials, Vol. 151
Design and synthesis of an exceptionally stable and highly porous metal-organic framework
journal, November 1999
- Li, Hailian; Eddaoudi, Mohamed; M., O'Keeffe
- Nature, Vol. 402, Issue 6759, p. 276-279
Application of metal–organic frameworks with coordinatively unsaturated metal sites in storage and separation of methane and carbon dioxide
journal, January 2009
- Dietzel, Pascal D. C.; Besikiotis, Vasileios; Blom, Richard
- Journal of Materials Chemistry, Vol. 19, Issue 39, p. 7362-7370
Olefin/paraffin separation technology: a review
journal, October 1993
- Eldridge, R. Bruce
- Industrial & Engineering Chemistry Research, Vol. 32, Issue 10
Steering post-C–C coupling selectivity enables high efficiency electroreduction of carbon dioxide to multi-carbon alcohols
journal, June 2018
- Zhuang, Tao-Tao; Liang, Zhi-Qin; Seifitokaldani, Ali
- Nature Catalysis, Vol. 1, Issue 6