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Title: Fermi resonance controlled product branching in the H + HOD reaction

Abstract

Excitation of the first overtone of bending mode results in a significant enhancement in the HD + OH channel due to the 1 : 2 Fermi resonance between the fundamental OD stretch and the first overtone of the bend.

Authors:
ORCiD logo [1]; ORCiD logo [1]; ORCiD logo [2]
  1. Theoretische Chemie, Fakultät für Chemie, Universität Bielefeld, D-33615 Bielefeld, Germany
  2. Department of Chemistry and Chemical Biology, University of New Mexico, Albuquerque, USA
Publication Date:
Sponsoring Org.:
USDOE
OSTI Identifier:
1454631
Grant/Contract Number:  
SC0015997
Resource Type:
Publisher's Accepted Manuscript
Journal Name:
Physical Chemistry Chemical Physics
Additional Journal Information:
Journal Name: Physical Chemistry Chemical Physics Journal Volume: 20 Journal Issue: 25; Journal ID: ISSN 1463-9076
Publisher:
Royal Society of Chemistry (RSC)
Country of Publication:
United Kingdom
Language:
English

Citation Formats

Zhao, Bin, Manthe, Uwe, and Guo, Hua. Fermi resonance controlled product branching in the H + HOD reaction. United Kingdom: N. p., 2018. Web. doi:10.1039/C8CP02279H.
Zhao, Bin, Manthe, Uwe, & Guo, Hua. Fermi resonance controlled product branching in the H + HOD reaction. United Kingdom. doi:10.1039/C8CP02279H.
Zhao, Bin, Manthe, Uwe, and Guo, Hua. Mon . "Fermi resonance controlled product branching in the H + HOD reaction". United Kingdom. doi:10.1039/C8CP02279H.
@article{osti_1454631,
title = {Fermi resonance controlled product branching in the H + HOD reaction},
author = {Zhao, Bin and Manthe, Uwe and Guo, Hua},
abstractNote = {Excitation of the first overtone of bending mode results in a significant enhancement in the HD + OH channel due to the 1 : 2 Fermi resonance between the fundamental OD stretch and the first overtone of the bend.},
doi = {10.1039/C8CP02279H},
journal = {Physical Chemistry Chemical Physics},
number = 25,
volume = 20,
place = {United Kingdom},
year = {2018},
month = {1}
}

Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record
DOI: 10.1039/C8CP02279H

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Cited by: 1 work
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