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Title: Fermi resonance controlled product branching in the H + HOD reaction

Excitation of the first overtone of bending mode results in a significant enhancement in the HD + OH channel due to the 1 : 2 Fermi resonance between the fundamental OD stretch and the first overtone of the bend.
Authors:
ORCiD logo [1] ; ORCiD logo [1] ; ORCiD logo [2]
  1. Theoretische Chemie, Fakultät für Chemie, Universität Bielefeld, D-33615 Bielefeld, Germany
  2. Department of Chemistry and Chemical Biology, University of New Mexico, Albuquerque, USA
Publication Date:
Grant/Contract Number:
SC0015997
Type:
Publisher's Accepted Manuscript
Journal Name:
Physical Chemistry Chemical Physics
Additional Journal Information:
Journal Name: Physical Chemistry Chemical Physics Journal Volume: 20 Journal Issue: 25; Journal ID: ISSN 1463-9076
Publisher:
Royal Society of Chemistry (RSC)
Sponsoring Org:
USDOE
Country of Publication:
United Kingdom
Language:
English
OSTI Identifier:
1454631

Zhao, Bin, Manthe, Uwe, and Guo, Hua. Fermi resonance controlled product branching in the H + HOD reaction. United Kingdom: N. p., Web. doi:10.1039/C8CP02279H.
Zhao, Bin, Manthe, Uwe, & Guo, Hua. Fermi resonance controlled product branching in the H + HOD reaction. United Kingdom. doi:10.1039/C8CP02279H.
Zhao, Bin, Manthe, Uwe, and Guo, Hua. 2018. "Fermi resonance controlled product branching in the H + HOD reaction". United Kingdom. doi:10.1039/C8CP02279H.
@article{osti_1454631,
title = {Fermi resonance controlled product branching in the H + HOD reaction},
author = {Zhao, Bin and Manthe, Uwe and Guo, Hua},
abstractNote = {Excitation of the first overtone of bending mode results in a significant enhancement in the HD + OH channel due to the 1 : 2 Fermi resonance between the fundamental OD stretch and the first overtone of the bend.},
doi = {10.1039/C8CP02279H},
journal = {Physical Chemistry Chemical Physics},
number = 25,
volume = 20,
place = {United Kingdom},
year = {2018},
month = {1}
}

Works referenced in this record:

Bond‐specific chemistry: OD:OH product ratios for the reactions H+HOD(100) and H+HOD(001)
journal, December 1991
  • Bronikowski, Michael J.; Simpson, William R.; Girard, Bertrand
  • The Journal of Chemical Physics, Vol. 95, Issue 11, p. 8647-8648
  • DOI: 10.1063/1.461243

Laser Control of Chemical Reactions
journal, March 1998