The frequency-dependent response of single aerosol particles to vapour phase oscillations and its application in measuring diffusion coefficients
Abstract
A new method for measuring diffusion in the condensed phase of single aerosol particles is proposed and demonstrated. The technique is based on the frequency-dependent response of a binary particle to oscillations in the vapour phase of one of its chemical components. Here, we discuss how this physical situation allows for what would typically be a non-linear boundary value problem to be approximately reduced to a linear boundary value problem. For the case of aqueous aerosol particles, we investigate the accuracy of the closed-form analytical solution to this linear problem through a comparison with the numerical solution of the full problem. Then, using experimentally measured whispering gallery modes to track the frequency-dependent response of aqueous particles to relative humidity oscillations, we determine diffusion coefficients as a function of water activity. The measured diffusion coefficients are compared to previously reported values found using the two common experiments: (i) the analysis of the sorption/desorption of water from a particle after a step-wise change to the surrounding relative humidity and (ii) the isotopic exchange of water between a particle and the vapour phase. The technique presented here has two main strengths: first, when compared to the sorption/desorption experiment, it does not require themore »
- Authors:
-
- McGill Univ., Montreal, QC (Canada). Dept. of Atmospheric and Oceanic Sciences and Dept. of Chemistry
- Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Chemical Sciences Division
- Publication Date:
- Research Org.:
- Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES). Chemical Sciences, Geosciences, and Biosciences Division; Natural Sciences and Engineering Research Council of Canada (NSERC)
- OSTI Identifier:
- 1454491
- Grant/Contract Number:
- AC02-05CH11231
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Physical Chemistry Chemical Physics. PCCP
- Additional Journal Information:
- Journal Volume: 19; Journal Issue: 5; Related Information: © 2017 the Owner Societies.; Journal ID: ISSN 1463-9076
- Publisher:
- Royal Society of Chemistry
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; 54 ENVIRONMENTAL SCIENCES
Citation Formats
Preston, Thomas C., Davies, James F., and Wilson, Kevin R. The frequency-dependent response of single aerosol particles to vapour phase oscillations and its application in measuring diffusion coefficients. United States: N. p., 2017.
Web. doi:10.1039/c6cp07711k.
Preston, Thomas C., Davies, James F., & Wilson, Kevin R. The frequency-dependent response of single aerosol particles to vapour phase oscillations and its application in measuring diffusion coefficients. United States. https://doi.org/10.1039/c6cp07711k
Preston, Thomas C., Davies, James F., and Wilson, Kevin R. Fri .
"The frequency-dependent response of single aerosol particles to vapour phase oscillations and its application in measuring diffusion coefficients". United States. https://doi.org/10.1039/c6cp07711k. https://www.osti.gov/servlets/purl/1454491.
@article{osti_1454491,
title = {The frequency-dependent response of single aerosol particles to vapour phase oscillations and its application in measuring diffusion coefficients},
author = {Preston, Thomas C. and Davies, James F. and Wilson, Kevin R.},
abstractNote = {A new method for measuring diffusion in the condensed phase of single aerosol particles is proposed and demonstrated. The technique is based on the frequency-dependent response of a binary particle to oscillations in the vapour phase of one of its chemical components. Here, we discuss how this physical situation allows for what would typically be a non-linear boundary value problem to be approximately reduced to a linear boundary value problem. For the case of aqueous aerosol particles, we investigate the accuracy of the closed-form analytical solution to this linear problem through a comparison with the numerical solution of the full problem. Then, using experimentally measured whispering gallery modes to track the frequency-dependent response of aqueous particles to relative humidity oscillations, we determine diffusion coefficients as a function of water activity. The measured diffusion coefficients are compared to previously reported values found using the two common experiments: (i) the analysis of the sorption/desorption of water from a particle after a step-wise change to the surrounding relative humidity and (ii) the isotopic exchange of water between a particle and the vapour phase. The technique presented here has two main strengths: first, when compared to the sorption/desorption experiment, it does not require the numerical evaluation of a boundary value problem during the fitting process as a closed-form expression is available. Second, when compared to the isotope exchange experiment, it does not require the use of labeled molecules. Therefore, the frequency-dependent experiment retains the advantages of these two commonly used methods but does not suffer from their drawbacks.},
doi = {10.1039/c6cp07711k},
journal = {Physical Chemistry Chemical Physics. PCCP},
number = 5,
volume = 19,
place = {United States},
year = {Fri Jan 13 00:00:00 EST 2017},
month = {Fri Jan 13 00:00:00 EST 2017}
}
Web of Science
Works referenced in this record:
Secondary organic aerosol formation and transport
journal, September 1992
- Pandis, Spyros N.; Harley, Robert A.; Cass, Glen R.
- Atmospheric Environment. Part A. General Topics, Vol. 26, Issue 13
Water diffusion in atmospherically relevant α-pinene secondary organic material
journal, January 2015
- Price, Hannah C.; Mattsson, Johan; Zhang, Yue
- Chemical Science, Vol. 6, Issue 8
A new approach to determine vapour pressures and hygroscopicities of aqueous aerosols containing semi-volatile organic compounds
journal, January 2014
- Cai, C.; Stewart, D. J.; Preston, T. C.
- Physical Chemistry Chemical Physics, Vol. 16, Issue 7
The formation, properties and impact of secondary organic aerosol: current and emerging issues
journal, January 2009
- Hallquist, M.; Wenger, J. C.; Baltensperger, U.
- Atmospheric Chemistry and Physics, Vol. 9, Issue 14
The effect of viscosity and diffusion on the HO 2 uptake by sucrose and secondary organic aerosol particles
journal, January 2016
- Lakey, Pascale S. J.; Berkemeier, Thomas; Krapf, Manuel
- Atmospheric Chemistry and Physics, Vol. 16, Issue 20
Drop-on-demand microdroplet generation: a very stable platform for single-droplet experimentation
journal, January 2016
- Vaughn, Bartholomew S.; Tracey, Phillip J.; Trevitt, Adam J.
- RSC Advances, Vol. 6, Issue 65
Formation of Secondary Organic Aerosols Through Photooxidation of Isoprene
journal, February 2004
- Claeys, M.
- Science, Vol. 303, Issue 5661
Gas/Particle Partitioning and Secondary Organic Aerosol Yields
journal, July 1996
- Odum, Jay R.; Hoffmann, Thorsten; Bowman, Frank
- Environmental Science & Technology, Vol. 30, Issue 8
Scattering of electromagnetic radiation by a multilayered sphere
journal, November 2009
- Peña, O.; Pal, U.
- Computer Physics Communications, Vol. 180, Issue 11
Evolution of organic aerosol mass spectra upon heating: implications for OA phase and partitioning behavior
journal, January 2011
- Cappa, C. D.; Wilson, K. R.
- Atmospheric Chemistry and Physics, Vol. 11, Issue 5
Phase of atmospheric secondary organic material affects its reactivity
journal, October 2012
- Kuwata, M.; Martin, S. T.
- Proceedings of the National Academy of Sciences, Vol. 109, Issue 43
Raman Spectroscopy of Isotopic Water Diffusion in Ultraviscous, Glassy, and Gel States in Aerosol by Use of Optical Tweezers
journal, January 2016
- Davies, James F.; Wilson, Kevin R.
- Analytical Chemistry, Vol. 88, Issue 4
An amorphous solid state of biogenic secondary organic aerosol particles
journal, October 2010
- Virtanen, Annele; Joutsensaari, Jorma; Koop, Thomas
- Nature, Vol. 467, Issue 7317
Retrieving the translational diffusion coefficient of water from experiments on single levitated aerosol droplets
journal, January 2014
- Lienhard, Daniel M.; Huisman, Andrew J.; Bones, David L.
- Physical Chemistry Chemical Physics, Vol. 16, Issue 31
Variabilities and uncertainties in characterising water transport kinetics in glassy and ultraviscous aerosol
journal, January 2015
- Rickards, Andrew M. J.; Song, Young-Chul; Miles, Rachael E. H.
- Physical Chemistry Chemical Physics, Vol. 17, Issue 15
Accurate and efficient determination of the radius, refractive index, and dispersion of weakly absorbing spherical particle using whispering gallery modes
journal, January 2013
- Preston, Thomas C.; Reid, Jonathan P.
- Journal of the Optical Society of America B, Vol. 30, Issue 8
Secondary organic aerosol formation from anthropogenic air pollution: Rapid and higher than expected
journal, January 2006
- Volkamer, Rainer; Jimenez, Jose L.; San Martini, Federico
- Geophysical Research Letters, Vol. 33, Issue 17
Viscous organic aerosol particles in the upper troposphere: diffusivity-controlled water uptake and ice nucleation?
journal, January 2015
- Lienhard, D. M.; Huisman, A. J.; Krieger, U. K.
- Atmospheric Chemistry and Physics, Vol. 15, Issue 23
Laser-initiated iodine radical chemistry in single microdroplets
journal, November 2012
- Vaughn, Bartholomew S.; Tracey, Phillip J.; Trevitt, Adam J.
- Chemical Physics Letters, Vol. 551
Models of Isotopic Water Diffusion in Spherical Aerosol Particles
journal, December 2016
- Moridnejad, Ali; Preston, Thomas C.
- The Journal of Physical Chemistry A, Vol. 120, Issue 49
Nanoscale interfacial gradients formed by the reactive uptake of OH radicals onto viscous aerosol surfaces
journal, January 2015
- Davies, James F.; Wilson, Kevin R.
- Chemical Science, Vol. 6, Issue 12
Quantifying water diffusion in high-viscosity and glassy aqueous solutions using a Raman isotope tracer method
journal, January 2014
- Price, H. C.; Murray, B. J.; Mattsson, J.
- Atmospheric Chemistry and Physics, Vol. 14, Issue 8
Do atmospheric aerosols form glasses?
journal, January 2008
- Zobrist, B.; Marcolli, C.; Pedernera, D. A.
- Atmospheric Chemistry and Physics Discussions, Vol. 8, Issue 3
Exploring the complexity of aerosol particle properties and processes using single particle techniques
journal, January 2012
- Krieger, Ulrich K.; Marcolli, Claudia; Reid, Jonathan P.
- Chemical Society Reviews, Vol. 41, Issue 19
Influence of swelling and diffusion-induced convection on polymer sorption processes
journal, September 2002
- Alsoy, Sacide; Duda, J. L.
- AIChE Journal, Vol. 48, Issue 9
Timescales of water transport in viscous aerosol: measurements on sub-micron particles and dependence on conditioning history
journal, January 2014
- Lu, Jessica W.; Rickards, Andrew M. J.; Walker, Jim S.
- Phys. Chem. Chem. Phys., Vol. 16, Issue 21
Comparing the mechanism of water condensation and evaporation in glassy aerosol
journal, July 2012
- Bones, D. L.; Reid, J. P.; Lienhard, D. M.
- Proceedings of the National Academy of Sciences, Vol. 109, Issue 29
Raman- and Mie-Spectroscopic Studies of the Cooling Behaviour of Levitated, Single Sulfuric Acid/H2O Microdroplets
journal, June 2003
- Mund, C.; Zellner, R.
- ChemPhysChem, Vol. 4, Issue 6
Ultra-slow water diffusion in aqueous sucrose glasses
journal, January 2011
- Zobrist, Bernhard; Soonsin, Vacharaporn; Luo, Bei P.
- Physical Chemistry Chemical Physics, Vol. 13, Issue 8
Sucrose diffusion in aqueous solution
journal, January 2016
- Price, Hannah C.; Mattsson, Johan; Murray, Benjamin J.
- Physical Chemistry Chemical Physics, Vol. 18, Issue 28
An absorption model of the gas/aerosol partitioning involved in the formation of secondary organic aerosol
journal, January 1994
- Pankow, James F.
- Atmospheric Environment, Vol. 28, Issue 2
Gas uptake and chemical aging of semisolid organic aerosol particles
journal, June 2011
- Shiraiwa, M.; Ammann, M.; Koop, T.
- Proceedings of the National Academy of Sciences, Vol. 108, Issue 27
Viscosity of -pinene secondary organic material and implications for particle growth and reactivity
journal, April 2013
- Renbaum-Wolff, L.; Grayson, J. W.; Bateman, A. P.
- Proceedings of the National Academy of Sciences, Vol. 110, Issue 20
Chemistry of secondary organic aerosol: Formation and evolution of low-volatility organics in the atmosphere
journal, May 2008
- Kroll, Jesse H.; Seinfeld, John H.
- Atmospheric Environment, Vol. 42, Issue 16
Determining the size and refractive index of microspheres using the mode assignments from Mie resonances
journal, January 2015
- Preston, Thomas C.; Reid, Jonathan P.
- Journal of the Optical Society of America A, Vol. 32, Issue 11
Retrieval of the complex refractive index of aerosol droplets from optical tweezers measurements
journal, January 2012
- Miles, Rachael E. H.; Walker, Jim S.; Burnham, Daniel R.
- Physical Chemistry Chemical Physics, Vol. 14, Issue 9
Assessing the accuracy of complex refractive index retrievals from single aerosol particle cavity ring-down spectroscopy
journal, August 2016
- Cotterell, Michael I.; Preston, Thomas C.; Orr-Ewing, Andrew J.
- Aerosol Science and Technology, Vol. 50, Issue 10
Works referencing / citing this record:
Time evolution of steep diffusion fronts in highly viscous aerosol particles measured with Mie resonance spectroscopy
journal, December 2018
- Bastelberger, S.; Krieger, U. K.; Luo, B. P.
- The Journal of Chemical Physics, Vol. 149, Issue 24
Time evolution of steep diffusion fronts in highly viscous aerosol particles measured with Mie resonance spectroscopy
text, January 2018
- Bastelberger, Sandra; Krieger, Ulrich; Luo, Beiping P.
- ETH Zurich