Flexible and Hierarchical Metal–Organic Framework Composites for High‐Performance Catalysis
Abstract
Abstract The development of porous composite materials is of great significance for their potentially improved performance over those of individual components and extensive applications in separation, energy storage, and heterogeneous catalysis. Now mesoporous metal–organic frameworks (MOFs) with macroporous melamine foam (MF) have been integrated using a one‐pot process, generating a series of MOF/MF composite materials with preserved crystallinity, hierarchical porosity, and increased stability over that of melamine foam. The MOF nanocrystals were threaded by the melamine foam networks, resembling a ball‐and‐stick model overall. The resulting MOF/MF composite materials were employed as an effective heterogeneous catalyst for the epoxidation of cholesteryl esters. Combining the advantages of interpenetrative mesoporous and macroporous structures, the MOF/melamine foam composite has higher dispersibility and more accessibility of catalytic sites, exhibiting excellent catalytic performance.
- Authors:
-
[1];
[1]
- Department of Chemistry Texas A&,M University College Station TX 77842-3012 USA
- Department of Chemistry Texas A&,M University College Station TX 77842-3012 USA, College of Chemistry Tianjin Normal University Tianjin 300387 China
- Publication Date:
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1454326
- Grant/Contract Number:
- FE0026472
- Resource Type:
- Publisher's Accepted Manuscript
- Journal Name:
- Angewandte Chemie
- Additional Journal Information:
- Journal Name: Angewandte Chemie Journal Volume: 130 Journal Issue: 29; Journal ID: ISSN 0044-8249
- Publisher:
- Wiley Blackwell (John Wiley & Sons)
- Country of Publication:
- Germany
- Language:
- English
Citation Formats
Huang, Ning, Drake, Hannah, Li, Jialuo, Pang, Jiandong, Wang, Ying, Yuan, Shuai, Wang, Qi, Cai, Peiyu, Qin, Junsheng, and Zhou, Hong‐Cai. Flexible and Hierarchical Metal–Organic Framework Composites for High‐Performance Catalysis. Germany: N. p., 2018.
Web. doi:10.1002/ange.201803096.
Huang, Ning, Drake, Hannah, Li, Jialuo, Pang, Jiandong, Wang, Ying, Yuan, Shuai, Wang, Qi, Cai, Peiyu, Qin, Junsheng, & Zhou, Hong‐Cai. Flexible and Hierarchical Metal–Organic Framework Composites for High‐Performance Catalysis. Germany. https://doi.org/10.1002/ange.201803096
Huang, Ning, Drake, Hannah, Li, Jialuo, Pang, Jiandong, Wang, Ying, Yuan, Shuai, Wang, Qi, Cai, Peiyu, Qin, Junsheng, and Zhou, Hong‐Cai. Thu .
"Flexible and Hierarchical Metal–Organic Framework Composites for High‐Performance Catalysis". Germany. https://doi.org/10.1002/ange.201803096.
@article{osti_1454326,
title = {Flexible and Hierarchical Metal–Organic Framework Composites for High‐Performance Catalysis},
author = {Huang, Ning and Drake, Hannah and Li, Jialuo and Pang, Jiandong and Wang, Ying and Yuan, Shuai and Wang, Qi and Cai, Peiyu and Qin, Junsheng and Zhou, Hong‐Cai},
abstractNote = {Abstract The development of porous composite materials is of great significance for their potentially improved performance over those of individual components and extensive applications in separation, energy storage, and heterogeneous catalysis. Now mesoporous metal–organic frameworks (MOFs) with macroporous melamine foam (MF) have been integrated using a one‐pot process, generating a series of MOF/MF composite materials with preserved crystallinity, hierarchical porosity, and increased stability over that of melamine foam. The MOF nanocrystals were threaded by the melamine foam networks, resembling a ball‐and‐stick model overall. The resulting MOF/MF composite materials were employed as an effective heterogeneous catalyst for the epoxidation of cholesteryl esters. Combining the advantages of interpenetrative mesoporous and macroporous structures, the MOF/melamine foam composite has higher dispersibility and more accessibility of catalytic sites, exhibiting excellent catalytic performance.},
doi = {10.1002/ange.201803096},
journal = {Angewandte Chemie},
number = 29,
volume = 130,
place = {Germany},
year = {Thu Jun 14 00:00:00 EDT 2018},
month = {Thu Jun 14 00:00:00 EDT 2018}
}
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