Heterogeneous chemistry: a mechanism missing in current models to explain secondary inorganic aerosol formation during the January 2013 haze episode in North China
Abstract
Severe regional haze pollution events occurred in eastern and central China in January 2013, which had adverse effects on the environment and public health. Extremely high levels of particulate matter with aerodynamic diameter of 2.5 μm or less (PM2.5) with dominant components of sulfate and nitrate are responsible for the haze pollution. Although heterogeneous chemistry is thought to play an important role in the production of sulfate and nitrate during haze episodes, few studies have comprehensively evaluated the effect of heterogeneous chemistry on haze formation in China by using the 3-D models due to of a lack of treatments for heterogeneous reactions in most climate and chemical transport models. In this work, the WRF-CMAQ model with newly added heterogeneous reactions is applied to East Asia to evaluate the impacts of heterogeneous chemistry and the meteorological anomaly during January 2013 on regional haze formation. As the parameterization of heterogeneous reactions on different types of particles is not well established yet, we arbitrarily selected the uptake coefficients from reactions on dust particles and then conducted several sensitivity runs to find the value that can best match observations. The revised CMAQ with heterogeneous chemistry not only captures the magnitude and temporal variation ofmore »
- Authors:
-
[6]
- Tsinghua Univ., Beijing (China)
- Collaborative Innovation Center for Regional Environmental Quality, Beijing (China); Tsinghua Univ., Beijing (China)
- Collaborative Innovation Center for Regional Environmental Quality, Beijing (China); North Carolina State Univ., Raleigh, NC (United States); Tsinghua Univ., Beijing (China)
- Collaborative Innovation Center for Regional Environmental Quality, Beijing (China); State Environmental Protection Key Laboratory of Sources and Control of Air Pollution Complex, Beijing (China); Tsinghua Univ., Beijing (China)
- North Carolina State Univ., Raleigh, NC (United States)
- Kimoto Electric Co., Ltd., Osaka (Japan)
- Publication Date:
- Research Org.:
- North Carolina State University, Raleigh, NC (United States)
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1452792
- Grant/Contract Number:
- SC0006695
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Atmospheric Chemistry and Physics (Online)
- Additional Journal Information:
- Journal Name: Atmospheric Chemistry and Physics (Online); Journal Volume: 15; Journal Issue: 4; Journal ID: ISSN 1680-7324
- Publisher:
- European Geosciences Union
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Citation Formats
Zheng, B., Zhang, Q., Zhang, Y., He, K. B., Wang, K., Zheng, G. J., Duan, F. K., Ma, Y. L., and Kimoto, T. Heterogeneous chemistry: a mechanism missing in current models to explain secondary inorganic aerosol formation during the January 2013 haze episode in North China. United States: N. p., 2015.
Web. doi:10.5194/acp-15-2031-2015.
Zheng, B., Zhang, Q., Zhang, Y., He, K. B., Wang, K., Zheng, G. J., Duan, F. K., Ma, Y. L., & Kimoto, T. Heterogeneous chemistry: a mechanism missing in current models to explain secondary inorganic aerosol formation during the January 2013 haze episode in North China. United States. https://doi.org/10.5194/acp-15-2031-2015
Zheng, B., Zhang, Q., Zhang, Y., He, K. B., Wang, K., Zheng, G. J., Duan, F. K., Ma, Y. L., and Kimoto, T. Wed .
"Heterogeneous chemistry: a mechanism missing in current models to explain secondary inorganic aerosol formation during the January 2013 haze episode in North China". United States. https://doi.org/10.5194/acp-15-2031-2015. https://www.osti.gov/servlets/purl/1452792.
@article{osti_1452792,
title = {Heterogeneous chemistry: a mechanism missing in current models to explain secondary inorganic aerosol formation during the January 2013 haze episode in North China},
author = {Zheng, B. and Zhang, Q. and Zhang, Y. and He, K. B. and Wang, K. and Zheng, G. J. and Duan, F. K. and Ma, Y. L. and Kimoto, T.},
abstractNote = {Severe regional haze pollution events occurred in eastern and central China in January 2013, which had adverse effects on the environment and public health. Extremely high levels of particulate matter with aerodynamic diameter of 2.5 μm or less (PM2.5) with dominant components of sulfate and nitrate are responsible for the haze pollution. Although heterogeneous chemistry is thought to play an important role in the production of sulfate and nitrate during haze episodes, few studies have comprehensively evaluated the effect of heterogeneous chemistry on haze formation in China by using the 3-D models due to of a lack of treatments for heterogeneous reactions in most climate and chemical transport models. In this work, the WRF-CMAQ model with newly added heterogeneous reactions is applied to East Asia to evaluate the impacts of heterogeneous chemistry and the meteorological anomaly during January 2013 on regional haze formation. As the parameterization of heterogeneous reactions on different types of particles is not well established yet, we arbitrarily selected the uptake coefficients from reactions on dust particles and then conducted several sensitivity runs to find the value that can best match observations. The revised CMAQ with heterogeneous chemistry not only captures the magnitude and temporal variation of sulfate and nitrate, but also reproduces the enhancement of relative contribution of sulfate and nitrate to PM2.5 mass from clean days to polluted haze days. Finally, these results indicate the significant role of heterogeneous chemistry in regional haze formation and improve the understanding of the haze formation mechanisms during the January 2013 episode.},
doi = {10.5194/acp-15-2031-2015},
journal = {Atmospheric Chemistry and Physics (Online)},
number = 4,
volume = 15,
place = {United States},
year = {Wed Feb 25 00:00:00 EST 2015},
month = {Wed Feb 25 00:00:00 EST 2015}
}
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Resolution dependence of uncertainties in gridded emission inventories: a case study in Hebei, China
journal, January 2017
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Changes in the aerosol direct radiative forcing from 2001 to 2015: observational constraints and regional mechanisms
journal, January 2018
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Emission or atmospheric processes? An attempt to attribute the source of large bias of aerosols in eastern China simulated by global climate models
journal, January 2018
- Fan, Tianyi; Liu, Xiaohong; Ma, Po-Lun
- Atmospheric Chemistry and Physics, Vol. 18, Issue 2
Atmospheric Δ17O(NO3−) reveals nocturnal chemistry dominates nitrate production in Beijing haze
journal, January 2018
- He, Pengzhen; Xie, Zhouqing; Chi, Xiyuan
- Atmospheric Chemistry and Physics, Vol. 18, Issue 19
Is there an aerosol signature of chemical cloud processing?
journal, January 2018
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- Atmospheric Chemistry and Physics, Vol. 18, Issue 21
Feedback effects of boundary-layer meteorological factors on cumulative explosive growth of PM 2.5 during winter heavy pollution episodes in Beijing from 2013 to 2016
journal, January 2018
- Zhong, Junting; Zhang, Xiaoye; Dong, Yunsheng
- Atmospheric Chemistry and Physics, Vol. 18, Issue 1
Multiphase oxidation of SO 2 by NO 2 on CaCO 3 particles
journal, January 2018
- Zhao, Defeng; Song, Xiaojuan; Zhu, Tong
- Atmospheric Chemistry and Physics, Vol. 18, Issue 4
Vertically resolved characteristics of air pollution during two severe winter haze episodes in urban Beijing, China
journal, January 2018
- Wang, Qingqing; Sun, Yele; Xu, Weiqi
- Atmospheric Chemistry and Physics, Vol. 18, Issue 4
Air quality and climate change, Topic 3 of the Model Inter-Comparison Study for Asia Phase III (MICS-Asia III) – Part 1: Overview and model evaluation
journal, January 2018
- Gao, Meng; Han, Zhiwei; Liu, Zirui
- Atmospheric Chemistry and Physics, Vol. 18, Issue 7
Isotopic constraints on heterogeneous sulfate production in Beijing haze
journal, January 2018
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- Atmospheric Chemistry and Physics, Vol. 18, Issue 8
Seasonal characteristics, formation mechanisms and source origins of PM2.5 in two megacities in Sichuan Basin, China
journal, January 2018
- Wang, Huanbo; Tian, Mi; Chen, Yang
- Atmospheric Chemistry and Physics, Vol. 18, Issue 2
Characteristics of marine shipping emissions at berth: profiles for particulate matter and volatile organic compounds
journal, January 2018
- Xiao, Qian; Li, Mei; Liu, Huan
- Atmospheric Chemistry and Physics, Vol. 18, Issue 13
Relative importance of gas uptake on aerosol and ground surfaces characterized by equivalent uptake coefficients
journal, January 2019
- Li, Meng; Su, Hang; Li, Guo
- Atmospheric Chemistry and Physics, Vol. 19, Issue 16
Atmospheric new particle formation in China
journal, January 2019
- Chu, Biwu; Kerminen, Veli-Matti; Bianchi, Federico
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Relative humidity and O3 concentration as two prerequisites for sulfate formation
journal, January 2019
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- Atmospheric Chemistry and Physics, Vol. 19, Issue 19
Possible heterogeneous chemistry of hydroxymethanesulfonate (HMS) in northern China winter haze
journal, January 2019
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Sulfate formation during heavy winter haze events and the potential contribution from heterogeneous SO2 + NO2 reactions in the Yangtze River Delta region, China
journal, January 2019
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Effects of NO2 and C3H6 on the heterogeneous oxidation of SO2 on TiO2 in the presence or absence of UV–Vis irradiation
journal, January 2019
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Unraveling the role of silicon in atmospheric aerosol secondary formation: a new conservative tracer for aerosol chemistry
journal, January 2019
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Heterogeneous sulfate aerosol formation mechanisms during wintertime Chinese haze events: air quality model assessment using observations of sulfate oxygen isotopes in Beijing
journal, January 2019
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Dominant role of emission reduction in PM 2.5 air quality improvement in Beijing during 2013–2017: a model-based decomposition analysis
journal, January 2019
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- Atmospheric Chemistry and Physics, Vol. 19, Issue 9
Significant source of secondary aerosol: formation from gasoline evaporative emissions in the presence of SO 2 and NH 3
journal, January 2019
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Effects of organic coating on the nitrate formation by suppressing the N 2 O 5 heterogeneous hydrolysis: a case study during wintertime in Beijing–Tianjin–Hebei (BTH)
journal, January 2019
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IAP-AACM v1.0: a global to regional evaluation of the atmospheric chemistry model in CAS-ESM
journal, January 2019
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The 2015 and 2016 wintertime air pollution in China: SO 2 emission changes derived from a WRF-Chem/EnKF coupled data assimilation system
journal, January 2019
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Evaluation of the effect of regional joint-control measures on changing photochemical transformation: a comprehensive study of the optimization scenario analysis
journal, January 2019
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Photochemical impacts of haze pollution in an urban environment
journal, January 2019
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- Atmospheric Chemistry and Physics, Vol. 19, Issue 15
Large contributions of biogenic and anthropogenic sources to fine organic aerosols in Tianjin, North China
journal, January 2020
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Significant contribution of organics to aerosol liquid water content in winter in Beijing, China
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Ensemble forecasts of air quality in eastern China – Part 1: Model description and implementation of the MarcoPolo–Panda prediction system, version 1
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Enhanced sulfate formation by nitrogen dioxide: Implications from in situ observations at the SORPES station: Sulfate Formation by Nitrogen Dioxide
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Secondary aerosol formation and oxidation capacity in photooxidation in the presence of Al2O3 seed particles and SO2
journal, July 2015
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Air quality and health benefits of China’s emission control policies on coal-fired power plants during 2005–2020
journal, September 2019
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Air quality and health impacts from the updated industrial emission standards in China
journal, December 2019
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A Review of Aerosol Chemical Composition and Sources in Representative Regions of China during Wintertime
journal, May 2019
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Intermittent turbulence contributes to vertical dispersion of PM2.5 in the North China Plain: cases from Tianjin
journal, January 2018
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The impact of multi-species surface chemical observation assimilation on air quality forecasts in China
journal, January 2018
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Fine particulate matter (PM 2.5 ) trends in China, 2013–2018: separating contributions from anthropogenic emissions and meteorology
journal, January 2019
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Rapid transition in winter aerosol composition in Beijing from 2014 to 2017: response to clean air actions
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Spatiotemporal variability of NO2 and PM2.5 over Eastern China: observational and model analyses with a novel statistical method
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Characterization of organic aerosols from a Chinese Mega-City during winter:
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Photochemical impacts of haze pollution in an urban environment
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Significant contribution of organics to aerosol liquid water content in winter in Beijing, China
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Organic Aerosol Processing During Winter Severe Haze Episodes in Beijing
journal, September 2019
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New positive feedback mechanism between boundary layer meteorology and secondary aerosol formation during severe haze events
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Effect of model errors in ambient air humidity on the aerosol optical depth obtained via aerosol hygroscopicity in eastern China in the Atmospheric Chemistry and Climate Model Intercomparison Project datasets
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Evidence of heterogeneous HONO formation from aerosols and the regional photochemical impact of this HONO source
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Wintertime aerosol chemistry and haze evolution in an extremely polluted city of the North China Plain: significant contribution from coal and biomass combustion
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Spatiotemporal variability of NO2 and PM2.5 over Eastern China: observational and model analyses with a novel statistical method
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MICS-Asia III: multi-model comparison and evaluation of aerosol over East Asia
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Modeling of aerosol property evolution during winter haze episodes over a megacity cluster in northern China: roles of regional transport and heterogeneous reactions of SO2
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Atmospheric Δ17O(NO3–) reveals nocturnal chemistry dominates nitrate production in Beijing haze
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Unraveling the role of silicon in atmospheric aerosol secondary formation: A new conservative tracer for aerosol chemistry
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Characterization of organic aerosols from a Chinese megacity during winter: predominance of fossil fuel combustion
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A Review of the Representation of Aerosol Mixing State in Atmospheric Models
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Modeling study of the 2010 regional haze event in the North China Plain
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Vertical Characterization of Aerosol Particle Composition in Beijing, China: Insights From 3‐Month Measurements With Two Aerosol Mass Spectrometers
journal, November 2018
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Nitrate-driven urban haze pollution during summertime over the North China Plain
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One-Year Simulation of Ozone and Particulate Matter in China Using WRF/CMAQ Modeling System
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Rapid transition in winter aerosol composition in Beijing from 2014 to 2017: response to clean air actions
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Examining the physical and chemical contributions to size spectrum evolution during the development of hazes
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Source Contributions of PM2.5in the Severe Haze Episode in Hebei Cities
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