From Metal–Organic Frameworks to Single‐Atom Fe Implanted N‐doped Porous Carbons: Efficient Oxygen Reduction in Both Alkaline and Acidic Media
Abstract
Abstract It remains highly desired but a great challenge to achieve atomically dispersed metals in high loadings for efficient catalysis. Now porphyrinic metal–organic frameworks (MOFs) have been synthesized based on a novel mixed‐ligand strategy to afford high‐content (1.76 wt %) single‐atom (SA) iron‐implanted N‐doped porous carbon (Fe SA ‐N‐C) via pyrolysis. Thanks to the single‐atom Fe sites, hierarchical pores, oriented mesochannels and high conductivity, the optimized Fe SA ‐N‐C exhibits excellent oxygen reduction activity and stability, surpassing almost all non‐noble‐metal catalysts and state‐of‐the‐art Pt/C, in both alkaline and more challenging acidic media. More far‐reaching, this MOF‐based mixed‐ligand strategy opens a novel avenue to the precise fabrication of efficient single‐atom catalysts.
- Authors:
-
[1]
- Hefei National Laboratory for Physical Sciences at the Microscale CAS Key Laboratory of Soft Matter Chemistry Collaborative Innovation Center of Suzhou Nano Science and Technology Department of Chemistry University of Science and Technology of China Hefei Anhui 230026 P. R. China
- Materials Science Division Advanced Photon Source Argonne National Laboratory Lemont IL 60439 USA, University of Chinese Academy of Sciences Beijing 100049 P. R. China, X-ray Science Division Advanced Photon Source Argonne National Laboratory Lemont IL 60439 USA
- X-ray Science Division Advanced Photon Source Argonne National Laboratory Lemont IL 60439 USA
- Publication Date:
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1441233
- Resource Type:
- Publisher's Accepted Manuscript
- Journal Name:
- Angewandte Chemie
- Additional Journal Information:
- Journal Name: Angewandte Chemie Journal Volume: 130 Journal Issue: 28; Journal ID: ISSN 0044-8249
- Publisher:
- Wiley Blackwell (John Wiley & Sons)
- Country of Publication:
- Germany
- Language:
- English
Citation Formats
Jiao, Long, Wan, Gang, Zhang, Rui, Zhou, Hua, Yu, Shu‐Hong, and Jiang, Hai‐Long. From Metal–Organic Frameworks to Single‐Atom Fe Implanted N‐doped Porous Carbons: Efficient Oxygen Reduction in Both Alkaline and Acidic Media. Germany: N. p., 2018.
Web. doi:10.1002/ange.201803262.
Jiao, Long, Wan, Gang, Zhang, Rui, Zhou, Hua, Yu, Shu‐Hong, & Jiang, Hai‐Long. From Metal–Organic Frameworks to Single‐Atom Fe Implanted N‐doped Porous Carbons: Efficient Oxygen Reduction in Both Alkaline and Acidic Media. Germany. https://doi.org/10.1002/ange.201803262
Jiao, Long, Wan, Gang, Zhang, Rui, Zhou, Hua, Yu, Shu‐Hong, and Jiang, Hai‐Long. Tue .
"From Metal–Organic Frameworks to Single‐Atom Fe Implanted N‐doped Porous Carbons: Efficient Oxygen Reduction in Both Alkaline and Acidic Media". Germany. https://doi.org/10.1002/ange.201803262.
@article{osti_1441233,
title = {From Metal–Organic Frameworks to Single‐Atom Fe Implanted N‐doped Porous Carbons: Efficient Oxygen Reduction in Both Alkaline and Acidic Media},
author = {Jiao, Long and Wan, Gang and Zhang, Rui and Zhou, Hua and Yu, Shu‐Hong and Jiang, Hai‐Long},
abstractNote = {Abstract It remains highly desired but a great challenge to achieve atomically dispersed metals in high loadings for efficient catalysis. Now porphyrinic metal–organic frameworks (MOFs) have been synthesized based on a novel mixed‐ligand strategy to afford high‐content (1.76 wt %) single‐atom (SA) iron‐implanted N‐doped porous carbon (Fe SA ‐N‐C) via pyrolysis. Thanks to the single‐atom Fe sites, hierarchical pores, oriented mesochannels and high conductivity, the optimized Fe SA ‐N‐C exhibits excellent oxygen reduction activity and stability, surpassing almost all non‐noble‐metal catalysts and state‐of‐the‐art Pt/C, in both alkaline and more challenging acidic media. More far‐reaching, this MOF‐based mixed‐ligand strategy opens a novel avenue to the precise fabrication of efficient single‐atom catalysts.},
doi = {10.1002/ange.201803262},
journal = {Angewandte Chemie},
number = 28,
volume = 130,
place = {Germany},
year = {Tue Jun 12 00:00:00 EDT 2018},
month = {Tue Jun 12 00:00:00 EDT 2018}
}
Free Publicly Available Full Text
Publisher's Version of Record
https://doi.org/10.1002/ange.201803262
https://doi.org/10.1002/ange.201803262
Other availability
Search WorldCat to find libraries that may hold this journal
Save to My Library
You must Sign In or Create an Account in order to save documents to your library.
Works referenced in this record:
Heat-treated polyacrylonitrile-based catalysts for oxygen electroreduction
journal, January 1989
- Gupta, S.; Tryk, D.; Bae, I.
- Journal of Applied Electrochemistry, Vol. 19, Issue 1, p. 19-27
Nanoarchitectured Design of Porous Materials and Nanocomposites from Metal-Organic Frameworks
journal, December 2016
- Kaneti, Yusuf Valentino; Tang, Jing; Salunkhe, Rahul R.
- Advanced Materials, Vol. 29, Issue 12
Atomic cobalt on nitrogen-doped graphene for hydrogen generation
journal, October 2015
- Fei, Huilong; Dong, Juncai; Arellano-Jiménez, M. Josefina
- Nature Communications, Vol. 6, Issue 1
Single cobalt sites in mesoporous N-doped carbon matrix for selective catalytic hydrogenation of nitroarenes
journal, January 2018
- Sun, Xiaohui; Olivos-Suarez, Alma I.; Osadchii, Dmitrii
- Journal of Catalysis, Vol. 357
Synthesis, Structure, and Metalation of Two New Highly Porous Zirconium Metal–Organic Frameworks
journal, June 2012
- Morris, William; Volosskiy, Boris; Demir, Selcuk
- Inorganic Chemistry, Vol. 51, Issue 12, p. 6443-6445
A metal–organic framework-derived bifunctional oxygen electrocatalyst
journal, January 2016
- Xia, Bao Yu; Yan, Ya; Li, Nan
- Nature Energy, Vol. 1, Issue 1
Catalysis by Supported Single Metal Atoms
journal, November 2016
- Liu, Jingyue
- ACS Catalysis, Vol. 7, Issue 1
Molecule-Level g-C 3 N 4 Coordinated Transition Metals as a New Class of Electrocatalysts for Oxygen Electrode Reactions
journal, February 2017
- Zheng, Yao; Jiao, Yan; Zhu, Yihan
- Journal of the American Chemical Society, Vol. 139, Issue 9
Development of MOF-Derived Carbon-Based Nanomaterials for Efficient Catalysis
journal, August 2016
- Shen, Kui; Chen, Xiaodong; Chen, Junying
- ACS Catalysis, Vol. 6, Issue 9
A General Approach to Preferential Formation of Active Fe–N x Sites in Fe–N/C Electrocatalysts for Efficient Oxygen Reduction Reaction
journal, November 2016
- Sa, Young Jin; Seo, Dong-Jun; Woo, Jinwoo
- Journal of the American Chemical Society, Vol. 138, Issue 45
Hierarchically porous carbons with optimized nitrogen doping as highly active electrocatalysts for oxygen reduction
journal, September 2014
- Liang, Hai-Wei; Zhuang, Xiaodong; Brüller, Sebastian
- Nature Communications, Vol. 5, Issue 1
Isolated Single Iron Atoms Anchored on N-Doped Porous Carbon as an Efficient Electrocatalyst for the Oxygen Reduction Reaction
journal, April 2017
- Chen, Yuanjun; Ji, Shufang; Wang, Yanggang
- Angewandte Chemie International Edition, Vol. 56, Issue 24
Metal–Organic Frameworks (MOFs)
journal, January 2014
- Zhou, Hong-Cai “Joe”; Kitagawa, Susumu
- Chem. Soc. Rev., Vol. 43, Issue 16
Thermally stable single atom Pt/m-Al2O3 for selective hydrogenation and CO oxidation
journal, July 2017
- Zhang, Zailei; Zhu, Yihan; Asakura, Hiroyuki
- Nature Communications, Vol. 8, Issue 1
Introduction to Metal–Organic Frameworks
journal, September 2011
- Zhou, Hong-Cai; Long, Jeffrey R.; Yaghi, Omar M.
- Chemical Reviews, Vol. 112, Issue 2, p. 673-674
Transformation of Metal–Organic Frameworks/Coordination Polymers into Functional Nanostructured Materials: Experimental Approaches Based on Mechanistic Insights
journal, October 2017
- Lee, Kyung Joo; Lee, Jae Hwa; Jeoung, Sungeun
- Accounts of Chemical Research, Vol. 50, Issue 11
Single-atom catalysis of CO oxidation using Pt1/FeOx
journal, July 2011
- Qiao, Botao; Wang, Aiqin; Yang, Xiaofeng
- Nature Chemistry, Vol. 3, Issue 8
Surface functionalization of ZIF-8 with ammonium ferric citrate toward high exposure of Fe-N active sites for efficient oxygen and carbon dioxide electroreduction
journal, August 2017
- Ye, Yifan; Cai, Fan; Li, Haobo
- Nano Energy, Vol. 38
Photochemical route for synthesizing atomically dispersed palladium catalysts
journal, May 2016
- Liu, P.; Zhao, Y.; Qin, R.
- Science, Vol. 352, Issue 6287
Metal–organic frameworks as selectivity regulators for hydrogenation reactions
journal, October 2016
- Zhao, Meiting; Yuan, Kuo; Wang, Yun
- Nature, Vol. 539, Issue 7627
Towards high-efficiency nanoelectrocatalysts for oxygen reduction through engineering advanced carbon nanomaterials
journal, January 2016
- Zhou, Ming; Wang, Hsing-Lin; Guo, Shaojun
- Chemical Society Reviews, Vol. 45, Issue 5
Isolated Single Iron Atoms Anchored on N-Doped Porous Carbon as an Efficient Electrocatalyst for the Oxygen Reduction Reaction
journal, April 2017
- Chen, Yuanjun; Ji, Shufang; Wang, Yanggang
- Angewandte Chemie, Vol. 129, Issue 24
Biomimetic Catalysis of a Porous Iron-Based Metal–Metalloporphyrin Framework
journal, November 2012
- Chen, Yao; Hoang, Tran; Ma, Shengqian
- Inorganic Chemistry, Vol. 51, Issue 23
From Bimetallic Metal-Organic Framework to Porous Carbon: High Surface Area and Multicomponent Active Dopants for Excellent Electrocatalysis
journal, July 2015
- Chen, Yu-Zhen; Wang, Chengming; Wu, Zhen-Yu
- Advanced Materials, Vol. 27, Issue 34
N-doped carbon nanotubes containing a high concentration of single iron atoms for efficient oxygen reduction
journal, January 2018
- Li, Jin-Cheng; Yang, Zhi-Qing; Tang, Dai-Ming
- NPG Asia Materials, Vol. 10, Issue 1
Single-Atom Catalysts: Emerging Multifunctional Materials in Heterogeneous Catalysis
journal, September 2017
- Zhang, Huabin; Liu, Guigao; Shi, Li
- Advanced Energy Materials, Vol. 8, Issue 1
In Situ Coupling of Strung Co 4 N and Intertwined N–C Fibers toward Free-Standing Bifunctional Cathode for Robust, Efficient, and Flexible Zn–Air Batteries
journal, August 2016
- Meng, Fanlu; Zhong, Haixia; Bao, Di
- Journal of the American Chemical Society, Vol. 138, Issue 32
Heteroatom-Doped Graphitic Carbon Catalysts for Efficient Electrocatalysis of Oxygen Reduction Reaction
journal, November 2015
- Zhang, Jintao; Dai, Liming
- ACS Catalysis, Vol. 5, Issue 12
Identification of catalytic sites for oxygen reduction in iron- and nitrogen-doped graphene materials
journal, August 2015
- Zitolo, Andrea; Goellner, Vincent; Armel, Vanessa
- Nature Materials, Vol. 14, Issue 9
Postsynthetic Tuning of Metal–Organic Frameworks for Targeted Applications
journal, February 2017
- Islamoglu, Timur; Goswami, Subhadip; Li, Zhanyong
- Accounts of Chemical Research, Vol. 50, Issue 4
Metal–organic framework-based CoP/reduced graphene oxide: high-performance bifunctional electrocatalyst for overall water splitting
journal, January 2016
- Jiao, Long; Zhou, Yu-Xiao; Jiang, Hai-Long
- Chemical Science, Vol. 7, Issue 3
A metal–organic framework route to in situ encapsulation of Co@Co 3 O 4 @C core@bishell nanoparticles into a highly ordered porous carbon matrix for oxygen reduction
journal, January 2015
- Xia, Wei; Zou, Ruqiang; An, Li
- Energy & Environmental Science, Vol. 8, Issue 2
Enhanced oxygen reduction performance by novel pyridine substituent groups of iron (II) phthalocyanine with graphene composite
journal, May 2015
- Cui, Lili; Lv, Guojun; He, Xingquan
- Journal of Power Sources, Vol. 282
Single Atomic Iron Catalysts for Oxygen Reduction in Acidic Media: Particle Size Control and Thermal Activation
journal, September 2017
- Zhang, Hanguang; Hwang, Sooyeon; Wang, Maoyu
- Journal of the American Chemical Society, Vol. 139, Issue 40
Metal–Organic-Framework-Derived Fe-N/C Electrocatalyst with Five-Coordinated Fe-N x Sites for Advanced Oxygen Reduction in Acid Media
journal, February 2017
- Lai, Qingxue; Zheng, Lirong; Liang, Yanyu
- ACS Catalysis, Vol. 7, Issue 3
Single-Atom Electrocatalysts
journal, October 2017
- Zhu, Chengzhou; Fu, Shaofang; Shi, Qiurong
- Angewandte Chemie International Edition, Vol. 56, Issue 45
Single Cobalt Atoms with Precise N-Coordination as Superior Oxygen Reduction Reaction Catalysts
journal, August 2016
- Yin, Peiqun; Yao, Tao; Wu, Yuen
- Angewandte Chemie, Vol. 128, Issue 36
Out-of-plane Fe II –N 4 moiety modified Fe–N co-doped porous carbons as high-performance electrocatalysts for the oxygen reduction reaction
journal, January 2017
- Qian, Zhongjie; Hu, Zhaowen; Zhang, Zhengping
- Catalysis Science & Technology, Vol. 7, Issue 18
Metal-Organic Framework as a Template for Porous Carbon Synthesis
journal, April 2008
- Liu, Bo; Shioyama, Hiroshi; Akita, Tomoki
- Journal of the American Chemical Society, Vol. 130, Issue 16
New Heterometallic Zirconium Metalloporphyrin Frameworks and Their Heteroatom-Activated High-Surface-Area Carbon Derivatives
journal, February 2015
- Lin, Qipu; Bu, Xianhui; Kong, Aiguo
- Journal of the American Chemical Society, Vol. 137, Issue 6
Zirconium-Metalloporphyrin PCN-222: Mesoporous Metal-Organic Frameworks with Ultrahigh Stability as Biomimetic Catalysts
journal, August 2012
- Feng, Dawei; Gu, Zhi-Yuan; Li, Jian-Rong
- Angewandte Chemie, Vol. 124, Issue 41, p. 10453-10456
Cobalt Imidazolate Framework as Precursor for Oxygen Reduction Reaction Electrocatalysts
journal, January 2011
- Ma, Shengqian; Goenaga, Gabriel A.; Call, Ann V.
- Chemistry - A European Journal, Vol. 17, Issue 7
Electrocatalysts Derived from Metal-Organic Frameworks for Oxygen Reduction and Evolution Reactions in Aqueous Media
journal, July 2017
- Qian, Yuhong; Khan, Inayat Ali; Zhao, Dan
- Small, Vol. 13, Issue 37
Emerging Multifunctional Metal-Organic Framework Materials
journal, July 2016
- Li, Bin; Wen, Hui-Min; Cui, Yuanjing
- Advanced Materials, Vol. 28, Issue 40
Metal-organic frameworks and their derived materials for electrochemical energy storage and conversion: Promises and challenges
journal, December 2017
- Wu, Hao Bin; Lou, Xiong Wen (David)
- Science Advances, Vol. 3, Issue 12
Construction of a cobalt-embedded nitrogen-doped carbon material with the desired porosity derived from the confined growth of MOFs within graphene aerogels as a superior catalyst towards HER and ORR
journal, January 2016
- Zhu, Zhen; Yang, Yan; Guan, Yue
- Journal of Materials Chemistry A, Vol. 4, Issue 40
Atomically isolated nickel species anchored on graphitized carbon for efficient hydrogen evolution electrocatalysis
journal, February 2016
- Fan, Lili; Liu, Peng Fei; Yan, Xuecheng
- Nature Communications, Vol. 7, Issue 1
Einzelatom-Elektrokatalysatoren
journal, October 2017
- Zhu, Chengzhou; Fu, Shaofang; Shi, Qiurong
- Angewandte Chemie, Vol. 129, Issue 45
Iron-Based Catalysts with Improved Oxygen Reduction Activity in Polymer Electrolyte Fuel Cells
journal, April 2009
- Lefèvre, Michel; Proietti, Eric; Jaouen, Frédéric
- Science, Vol. 324, Issue 5923, p. 71-74
Single Cobalt Atoms with Precise N-Coordination as Superior Oxygen Reduction Reaction Catalysts
journal, August 2016
- Yin, Peiqun; Yao, Tao; Wu, Yuen
- Angewandte Chemie International Edition, Vol. 55, Issue 36
Zirconium-Metalloporphyrin PCN-222: Mesoporous Metal-Organic Frameworks with Ultrahigh Stability as Biomimetic Catalysts
journal, August 2012
- Feng, Dawei; Gu, Zhi-Yuan; Li, Jian-Rong
- Angewandte Chemie International Edition, Vol. 51, Issue 41
A review of Fe–N/C and Co–N/C catalysts for the oxygen reduction reaction
journal, June 2008
- Bezerra, Cicero W.B.; Zhang, Lei; Lee, Kunchan
- Electrochimica Acta, Vol. 53, Issue 15, p. 4937-4951