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Title: The balance of electric field and interfacial catalysis in promoting water dissociation in bipolar membranes

Abstract

Bipolar membranes maintain a steady pH in electrolytic cells through water autodissociation at the interface between their cation- and anion-exchange layers. We analyze the balance of electric field and catalysis in accelerating this reaction.

Authors:
 [1]; ORCiD logo [2]; ORCiD logo [1]; ORCiD logo [3]; ORCiD logo [3]; ORCiD logo [2]; ORCiD logo [1]
  1. Departments of Chemistry, Biochemistry and Molecular Biology, and Physics, The Pennsylvania State University, University Park, USA
  2. Department of Materials Science and Engineering, The Pennsylvania State University, University Park, USA
  3. Department of Chemical and Biomolecular Engineering, Vanderbilt University, Nashville, USA
Publication Date:
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
OSTI Identifier:
1441230
Grant/Contract Number:  
FG02- 07ER15911
Resource Type:
Publisher's Accepted Manuscript
Journal Name:
Energy & Environmental Science
Additional Journal Information:
Journal Name: Energy & Environmental Science Journal Volume: 11 Journal Issue: 8; Journal ID: ISSN 1754-5692
Publisher:
Royal Society of Chemistry (RSC)
Country of Publication:
United Kingdom
Language:
English

Citation Formats

Yan, Zhifei, Zhu, Liang, Li, Yuguang C., Wycisk, Ryszard J., Pintauro, Peter N., Hickner, Michael A., and Mallouk, Thomas E. The balance of electric field and interfacial catalysis in promoting water dissociation in bipolar membranes. United Kingdom: N. p., 2018. Web. doi:10.1039/C8EE01192C.
Yan, Zhifei, Zhu, Liang, Li, Yuguang C., Wycisk, Ryszard J., Pintauro, Peter N., Hickner, Michael A., & Mallouk, Thomas E. The balance of electric field and interfacial catalysis in promoting water dissociation in bipolar membranes. United Kingdom. doi:10.1039/C8EE01192C.
Yan, Zhifei, Zhu, Liang, Li, Yuguang C., Wycisk, Ryszard J., Pintauro, Peter N., Hickner, Michael A., and Mallouk, Thomas E. Mon . "The balance of electric field and interfacial catalysis in promoting water dissociation in bipolar membranes". United Kingdom. doi:10.1039/C8EE01192C.
@article{osti_1441230,
title = {The balance of electric field and interfacial catalysis in promoting water dissociation in bipolar membranes},
author = {Yan, Zhifei and Zhu, Liang and Li, Yuguang C. and Wycisk, Ryszard J. and Pintauro, Peter N. and Hickner, Michael A. and Mallouk, Thomas E.},
abstractNote = {Bipolar membranes maintain a steady pH in electrolytic cells through water autodissociation at the interface between their cation- and anion-exchange layers. We analyze the balance of electric field and catalysis in accelerating this reaction.},
doi = {10.1039/C8EE01192C},
journal = {Energy & Environmental Science},
number = 8,
volume = 11,
place = {United Kingdom},
year = {2018},
month = {1}
}

Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record
DOI: 10.1039/C8EE01192C

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Cited by: 4 works
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Works referenced in this record:

CO2 Reduction at Low Overpotential on Cu Electrodes Resulting from the Reduction of Thick Cu2O Films
journal, April 2012

  • Li, Christina W.; Kanan, Matthew W.
  • Journal of the American Chemical Society, Vol. 134, Issue 17, p. 7231-7234
  • DOI: 10.1021/ja3010978

Communication—Electrochemical Characterization of Commercial Bipolar Membranes under Electrolyte Conditions Relevant to Solar Fuels Technologies
journal, December 2015

  • Reiter, Ronald S.; White, William; Ardo, Shane
  • Journal of The Electrochemical Society, Vol. 163, Issue 4
  • DOI: 10.1149/2.0201604jes

Benchmarking Hydrogen Evolving Reaction and Oxygen Evolving Reaction Electrocatalysts for Solar Water Splitting Devices
journal, March 2015

  • McCrory, Charles C. L.; Jung, Suho; Ferrer, Ivonne M.
  • Journal of the American Chemical Society, Vol. 137, Issue 13
  • DOI: 10.1021/ja510442p

Resistance and polarization losses in aqueous buffer–membrane electrolytes for water-splitting photoelectrochemical cells
journal, January 2012

  • Hernández-Pagán, Emil A.; Vargas-Barbosa, Nella M.; Wang, TsingHai
  • Energy & Environmental Science, Vol. 5, Issue 6
  • DOI: 10.1039/c2ee03422k

Graphene Oxide as a Water Dissociation Catalyst in the Bipolar Membrane Interfacial Layer
journal, July 2014

  • McDonald, Michael B.; Freund, Michael S.
  • ACS Applied Materials & Interfaces, Vol. 6, Issue 16
  • DOI: 10.1021/am503242v

Mass transport aspects of electrochemical solar-hydrogen generation
journal, January 2016

  • Modestino, Miguel A.; Hashemi, S. Mohammad H.; Haussener, Sophia
  • Energy & Environmental Science, Vol. 9, Issue 5
  • DOI: 10.1039/C5EE03698D

PEM/AEM Junction Design for Bipolar Membrane Fuel Cells
journal, January 2017

  • Ahlfield, John M.; Liu, Lisha; Kohl, Paul A.
  • Journal of The Electrochemical Society, Vol. 164, Issue 12
  • DOI: 10.1149/2.1041712jes

Assessing the Utility of Bipolar Membranes for use in Photoelectrochemical Water-Splitting Cells
journal, September 2014

  • Vargas-Barbosa, Nella M.; Geise, Geoffrey M.; Hickner, Michael A.
  • ChemSusChem, Vol. 7, Issue 11
  • DOI: 10.1002/cssc.201402535

Synergistic Enhancement of Electrocatalytic CO 2 Reduction with Gold Nanoparticles Embedded in Functional Graphene Nanoribbon Composite Electrodes
journal, March 2017

  • Rogers, Cameron; Perkins, Wade S.; Veber, Gregory
  • Journal of the American Chemical Society, Vol. 139, Issue 11
  • DOI: 10.1021/jacs.6b12217

Multication Side Chain Anion Exchange Membranes
journal, January 2016


Developing a scalable artificial photosynthesis technology through nanomaterials by design
journal, December 2016


Nonequilibrium hysteresis and Wien effect water dissociation at a bipolar membrane
journal, November 2012


Electric field-assisted proton transfer and water dissociation at the junction of a fixed-charge bipolar membrane
journal, September 1998


Ag–Sn Bimetallic Catalyst with a Core–Shell Structure for CO 2 Reduction
journal, January 2017

  • Luc, Wesley; Collins, Charles; Wang, Siwen
  • Journal of the American Chemical Society, Vol. 139, Issue 5
  • DOI: 10.1021/jacs.6b10435

Solar conversion of CO2 to CO using Earth-abundant electrocatalysts prepared by atomic layer modification of CuO
journal, June 2017

  • Schreier, Marcel; Héroguel, Florent; Steier, Ludmilla
  • Nature Energy, Vol. 2, Issue 7
  • DOI: 10.1038/nenergy.2017.87

Modeling, simulation, and design criteria for photoelectrochemical water-splitting systems
journal, January 2012

  • Haussener, Sophia; Xiang, Chengxiang; Spurgeon, Joshua M.
  • Energy & Environmental Science, Vol. 5, Issue 12
  • DOI: 10.1039/c2ee23187e

PEG–catalytic water splitting in the interface of a bipolar membrane
journal, July 2003


Numerical Solution of the Coupled Nernst−Planck and Poisson Equations for Liquid Junction and Ion Selective Membrane Potentials
journal, March 2003

  • Sokalski, Tomasz; Lingenfelter, Peter; Lewenstam, Andrzej
  • The Journal of Physical Chemistry B, Vol. 107, Issue 11
  • DOI: 10.1021/jp026406a

Ni 2 P as a Janus catalyst for water splitting: the oxygen evolution activity of Ni 2 P nanoparticles
journal, January 2015

  • Stern, Lucas-Alexandre; Feng, Ligang; Song, Fang
  • Energy & Environmental Science, Vol. 8, Issue 8
  • DOI: 10.1039/C5EE01155H

Material requirements for membrane separators in a water-splitting photoelectrochemical cell
journal, January 2014

  • Berger, Alan; Segalman, R. A.; Newman, J.
  • Energy Environ. Sci., Vol. 7, Issue 4
  • DOI: 10.1039/C3EE43807D

High performance electrospun bipolar membrane with a 3D junction
journal, January 2017

  • Shen, Chunhui; Wycisk, Ryszard; Pintauro, Peter N.
  • Energy & Environmental Science, Vol. 10, Issue 6
  • DOI: 10.1039/C7EE00345E

Experimental and theoretical investigations of steady and transient states in systems of ion exchange bipolar membranes
journal, January 2004


Effects of inorganic substances on water splitting in ion-exchange membranes
journal, May 2004

  • Kang, Moon-Sung; Choi, Yong-Jin; Moon, Seung-Hyeon
  • Journal of Colloid and Interface Science, Vol. 273, Issue 2
  • DOI: 10.1016/j.jcis.2004.01.051

Hybrid Anion and Proton Exchange Membrane Fuel Cells
journal, June 2009

  • Ünlü, Murat; Zhou, Junfeng; Kohl, Paul A.
  • The Journal of Physical Chemistry C, Vol. 113, Issue 26
  • DOI: 10.1021/jp903252u

Mechanically Robust Anion Exchange Membranes via Long Hydrophilic Cross-Linkers
journal, March 2017


Ionic transport through ion-exchange and bipolar membranes
journal, August 2005


Theorems of Electrochemical Mass Transport in Dilute Solutions of Mixtures of Electrolytes, Including Weak Electrolytes and Hydrolysis Reactions
journal, January 2005

  • Leibovitz, Jacques
  • Journal of The Electrochemical Society, Vol. 152, Issue 9
  • DOI: 10.1149/1.1997047

Acid/Base Multi-Ion Exchange Membrane-Based Electrolysis System for Water Splitting
journal, January 2017

  • Nazemi, Mohammadreza; Padgett, James; Hatzell, Marta C.
  • Energy Technology, Vol. 5, Issue 8
  • DOI: 10.1002/ente.201600629

Synergistic Electrochemical CO 2 Reduction and Water Oxidation with a Bipolar Membrane
journal, November 2016


Transparent Bipolar Membrane for Water Splitting Applications
journal, August 2017

  • Chabi, Sakineh; Wright, Andrew G.; Holdcroft, Steven
  • ACS Applied Materials & Interfaces, Vol. 9, Issue 32
  • DOI: 10.1021/acsami.7b04402

Modeling, Simulation, and Implementation of Solar-Driven Water-Splitting Devices
journal, October 2016

  • Xiang, Chengxiang; Weber, Adam Z.; Ardo, Shane
  • Angewandte Chemie International Edition, Vol. 55, Issue 42
  • DOI: 10.1002/anie.201510463

Functionalization of Poly(2,6-dimethyl-1,4-phenylene oxide)s with Hindered Fluorene Side Chains for Anion Exchange Membranes
journal, April 2016


Catalytic, Conductive Bipolar Membrane Interfaces through Layer-by-Layer Deposition for the Design of Membrane-Integrated Artificial Photosynthesis Systems
journal, November 2017

  • McDonald, Michael B.; Freund, Michael S.; Hammond, Paula T.
  • ChemSusChem, Vol. 10, Issue 22
  • DOI: 10.1002/cssc.201701397

Nafion in Dilute Solvent Systems: Dispersion or Solution?
journal, November 2012

  • Welch, Cynthia; Labouriau, Andrea; Hjelm, Rex
  • ACS Macro Letters, Vol. 1, Issue 12
  • DOI: 10.1021/mz3005204

The Central Role of Bicarbonate in the Electrochemical Reduction of Carbon Dioxide on Gold
journal, March 2017

  • Dunwell, Marco; Lu, Qi; Heyes, Jeffrey M.
  • Journal of the American Chemical Society, Vol. 139, Issue 10
  • DOI: 10.1021/jacs.6b13287

Photo-assisted water splitting with bipolar membrane induced pH gradients for practical solar fuel devices
journal, January 2015

  • Vermaas, David A.; Sassenburg, Mark; Smith, Wilson A.
  • Journal of Materials Chemistry A, Vol. 3, Issue 38
  • DOI: 10.1039/C5TA06315A

Insights into the electrocatalytic reduction of CO 2 on metallic silver surfaces
journal, January 2014

  • Hatsukade, Toru; Kuhl, Kendra P.; Cave, Etosha R.
  • Phys. Chem. Chem. Phys., Vol. 16, Issue 27
  • DOI: 10.1039/C4CP00692E

Deviations from Ohm's Law in Weak Electrolytes
journal, September 1934

  • Onsager, Lars
  • The Journal of Chemical Physics, Vol. 2, Issue 9
  • DOI: 10.1063/1.1749541

Model for ion transport in bipolar membranes
journal, November 1990


A Simple Model for Ac Impedance Spectra in Bipolar Membranes
journal, January 1996

  • Alcaraz, A.; Ramírez, P.; Mafé, S.
  • The Journal of Physical Chemistry, Vol. 100, Issue 38
  • DOI: 10.1021/jp961187c

Water dissociation in bipolar membranes: Experiments and theory
journal, March 1978

  • Simons, R.; Khanarian, G.
  • The Journal of Membrane Biology, Vol. 38, Issue 1-2
  • DOI: 10.1007/BF01875160

Benchmarking Heterogeneous Electrocatalysts for the Oxygen Evolution Reaction
journal, October 2013

  • McCrory, Charles C. L.; Jung, Suho; Peters, Jonas C.
  • Journal of the American Chemical Society, Vol. 135, Issue 45
  • DOI: 10.1021/ja407115p

Morphology study of Nafion membranes prepared by solutions casting
journal, January 2005

  • Lin, Hsiu-Li; Yu, T. Leon; Huang, Cheng-Hung
  • Journal of Polymer Science Part B: Polymer Physics, Vol. 43, Issue 21
  • DOI: 10.1002/polb.20599

How copper catalyzes the electroreduction of carbon dioxide into hydrocarbon fuels
journal, January 2010

  • Peterson, Andrew A.; Abild-Pedersen, Frank; Studt, Felix
  • Energy & Environmental Science, Vol. 3, Issue 9
  • DOI: 10.1039/c0ee00071j

Strong electric field effects on proton transfer between membrane-bound amines and water
journal, August 1979


Ion transport through electrolyte/polyelectrolyte multi-layers
journal, June 2015

  • Femmer, Robert; Mani, Ali; Wessling, Matthias
  • Scientific Reports, Vol. 5, Issue 1
  • DOI: 10.1038/srep11583

Core–Shell Au@Metal-Oxide Nanoparticle Electrocatalysts for Enhanced Oxygen Evolution
journal, September 2017

  • Strickler, Alaina L.; Escudero-Escribano, Marı́a; Jaramillo, Thomas F.
  • Nano Letters, Vol. 17, Issue 10
  • DOI: 10.1021/acs.nanolett.7b02357

Conductive and Capacitive Properties of the Bipolar Membrane Junction Studied by AC Impedance Spectroscopy
journal, November 2001

  • Alcaraz, Antonio; Ramírez, Patricio; Manzanares, José A.
  • The Journal of Physical Chemistry B, Vol. 105, Issue 47
  • DOI: 10.1021/jp011581x

Hydrogen Production From Water Electrolysis: Current Status and Future Trends
journal, February 2012


Bipolar Membrane-Assisted Solar Water Splitting in Optimal pH
journal, April 2016

  • Luo, Jingshan; Vermaas, David A.; Bi, Dongqin
  • Advanced Energy Materials, Vol. 6, Issue 13
  • DOI: 10.1002/aenm.201600100

Electrolysis of CO 2 to Syngas in Bipolar Membrane-Based Electrochemical Cells
journal, November 2016


Understanding Transport at the Acid-Alkaline Interface of Bipolar Membranes
journal, January 2016

  • Grew, Kyle N.; McClure, Joshua P.; Chu, Deryn
  • Journal of The Electrochemical Society, Vol. 163, Issue 14
  • DOI: 10.1149/2.0941614jes

New insights into the electrochemical reduction of carbon dioxide on metallic copper surfaces
journal, January 2012

  • Kuhl, Kendra P.; Cave, Etosha R.; Abram, David N.
  • Energy & Environmental Science, Vol. 5, Issue 5
  • DOI: 10.1039/c2ee21234j

Use of Bipolar Membranes for Maintaining Steady-State pH Gradients in Membrane-Supported, Solar-Driven Water Splitting
journal, September 2014

  • McDonald, Michael B.; Ardo, Shane; Lewis, Nathan S.
  • ChemSusChem, Vol. 7, Issue 11
  • DOI: 10.1002/cssc.201402288

Electric field enhanced water dissociation at the bipolar membrane junction from ac impedance spectra measurements
journal, January 1998


Research opportunities to advance solar energy utilization
journal, January 2016


Shape-Dependent Electrocatalytic Reduction of CO 2 to CO on Triangular Silver Nanoplates
journal, February 2017

  • Liu, Subiao; Tao, Hongbiao; Zeng, Li
  • Journal of the American Chemical Society, Vol. 139, Issue 6
  • DOI: 10.1021/jacs.6b12103

Efficient bipolar membrane with protein interfacial layer for optimal water splitting
journal, March 2017

  • Manohar, Murli; Shukla, Geetanjali; Pandey, Ravi P.
  • Journal of Industrial and Engineering Chemistry, Vol. 47
  • DOI: 10.1016/j.jiec.2016.11.025

Aqueous CO 2 Reduction at Very Low Overpotential on Oxide-Derived Au Nanoparticles
journal, November 2012

  • Chen, Yihong; Li, Christina W.; Kanan, Matthew W.
  • Journal of the American Chemical Society, Vol. 134, Issue 49
  • DOI: 10.1021/ja309317u

A prototype reactor for highly selective solar-driven CO 2 reduction to synthesis gas using nanosized earth-abundant catalysts and silicon photovoltaics
journal, January 2017

  • Urbain, Félix; Tang, Pengyi; Carretero, Nina M.
  • Energy & Environmental Science, Vol. 10, Issue 10
  • DOI: 10.1039/C7EE01747B

Limiting current density and water dissociation in bipolar membranes
journal, March 1997


Achieving Selective and Efficient Electrocatalytic Activity for CO 2 Reduction Using Immobilized Silver Nanoparticles
journal, October 2015

  • Kim, Cheonghee; Jeon, Hyo Sang; Eom, Taedaehyeong
  • Journal of the American Chemical Society, Vol. 137, Issue 43
  • DOI: 10.1021/jacs.5b06568

Catalytic Polyelectrolyte Multilayers at the Bipolar Membrane Interface
journal, October 2013

  • Abdu, Said; Sricharoen, Kittikun; Wong, John E.
  • ACS Applied Materials & Interfaces, Vol. 5, Issue 21
  • DOI: 10.1021/am403019y

Membranes for artificial photosynthesis
journal, January 2017

  • Chabi, Sakineh; Papadantonakis, Kimberly M.; Lewis, Nathan S.
  • Energy & Environmental Science, Vol. 10, Issue 6
  • DOI: 10.1039/C7EE00294G