The balance of electric field and interfacial catalysis in promoting water dissociation in bipolar membranes
Abstract
Bipolar membranes maintain a steady pH in electrolytic cells through water autodissociation at the interface between their cation- and anion-exchange layers. We analyze the balance of electric field and catalysis in accelerating this reaction.
- Authors:
-
[2];
[1];
[3];
[3];
[2];
[1]
- Departments of Chemistry, Biochemistry and Molecular Biology, and Physics, The Pennsylvania State University, University Park, USA
- Department of Materials Science and Engineering, The Pennsylvania State University, University Park, USA
- Department of Chemical and Biomolecular Engineering, Vanderbilt University, Nashville, USA
- Publication Date:
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1441230
- Grant/Contract Number:
- FG02- 07ER15911
- Resource Type:
- Publisher's Accepted Manuscript
- Journal Name:
- Energy & Environmental Science
- Additional Journal Information:
- Journal Name: Energy & Environmental Science Journal Volume: 11 Journal Issue: 8; Journal ID: ISSN 1754-5692
- Publisher:
- Royal Society of Chemistry (RSC)
- Country of Publication:
- United Kingdom
- Language:
- English
Citation Formats
Yan, Zhifei, Zhu, Liang, Li, Yuguang C., Wycisk, Ryszard J., Pintauro, Peter N., Hickner, Michael A., and Mallouk, Thomas E. The balance of electric field and interfacial catalysis in promoting water dissociation in bipolar membranes. United Kingdom: N. p., 2018.
Web. doi:10.1039/C8EE01192C.
Yan, Zhifei, Zhu, Liang, Li, Yuguang C., Wycisk, Ryszard J., Pintauro, Peter N., Hickner, Michael A., & Mallouk, Thomas E. The balance of electric field and interfacial catalysis in promoting water dissociation in bipolar membranes. United Kingdom. https://doi.org/10.1039/C8EE01192C
Yan, Zhifei, Zhu, Liang, Li, Yuguang C., Wycisk, Ryszard J., Pintauro, Peter N., Hickner, Michael A., and Mallouk, Thomas E. Mon .
"The balance of electric field and interfacial catalysis in promoting water dissociation in bipolar membranes". United Kingdom. https://doi.org/10.1039/C8EE01192C.
@article{osti_1441230,
title = {The balance of electric field and interfacial catalysis in promoting water dissociation in bipolar membranes},
author = {Yan, Zhifei and Zhu, Liang and Li, Yuguang C. and Wycisk, Ryszard J. and Pintauro, Peter N. and Hickner, Michael A. and Mallouk, Thomas E.},
abstractNote = {Bipolar membranes maintain a steady pH in electrolytic cells through water autodissociation at the interface between their cation- and anion-exchange layers. We analyze the balance of electric field and catalysis in accelerating this reaction.},
doi = {10.1039/C8EE01192C},
journal = {Energy & Environmental Science},
number = 8,
volume = 11,
place = {United Kingdom},
year = {Mon Jan 01 00:00:00 EST 2018},
month = {Mon Jan 01 00:00:00 EST 2018}
}
Free Publicly Available Full Text
Publisher's Version of Record
https://doi.org/10.1039/C8EE01192C
https://doi.org/10.1039/C8EE01192C
Other availability
Search WorldCat to find libraries that may hold this journal
Cited by: 67 works
Citation information provided by
Web of Science
Web of Science
Save to My Library
You must Sign In or Create an Account in order to save documents to your library.
Works referenced in this record:
CO2 Reduction at Low Overpotential on Cu Electrodes Resulting from the Reduction of Thick Cu2O Films
journal, April 2012
- Li, Christina W.; Kanan, Matthew W.
- Journal of the American Chemical Society, Vol. 134, Issue 17, p. 7231-7234
Communication—Electrochemical Characterization of Commercial Bipolar Membranes under Electrolyte Conditions Relevant to Solar Fuels Technologies
journal, December 2015
- Reiter, Ronald S.; White, William; Ardo, Shane
- Journal of The Electrochemical Society, Vol. 163, Issue 4
Benchmarking Hydrogen Evolving Reaction and Oxygen Evolving Reaction Electrocatalysts for Solar Water Splitting Devices
journal, March 2015
- McCrory, Charles C. L.; Jung, Suho; Ferrer, Ivonne M.
- Journal of the American Chemical Society, Vol. 137, Issue 13
Resistance and polarization losses in aqueous buffer–membrane electrolytes for water-splitting photoelectrochemical cells
journal, January 2012
- Hernández-Pagán, Emil A.; Vargas-Barbosa, Nella M.; Wang, TsingHai
- Energy & Environmental Science, Vol. 5, Issue 6
Graphene Oxide as a Water Dissociation Catalyst in the Bipolar Membrane Interfacial Layer
journal, July 2014
- McDonald, Michael B.; Freund, Michael S.
- ACS Applied Materials & Interfaces, Vol. 6, Issue 16
Mass transport aspects of electrochemical solar-hydrogen generation
journal, January 2016
- Modestino, Miguel A.; Hashemi, S. Mohammad H.; Haussener, Sophia
- Energy & Environmental Science, Vol. 9, Issue 5
PEM/AEM Junction Design for Bipolar Membrane Fuel Cells
journal, January 2017
- Ahlfield, John M.; Liu, Lisha; Kohl, Paul A.
- Journal of The Electrochemical Society, Vol. 164, Issue 12
Assessing the Utility of Bipolar Membranes for use in Photoelectrochemical Water-Splitting Cells
journal, September 2014
- Vargas-Barbosa, Nella M.; Geise, Geoffrey M.; Hickner, Michael A.
- ChemSusChem, Vol. 7, Issue 11
Synergistic Enhancement of Electrocatalytic CO 2 Reduction with Gold Nanoparticles Embedded in Functional Graphene Nanoribbon Composite Electrodes
journal, March 2017
- Rogers, Cameron; Perkins, Wade S.; Veber, Gregory
- Journal of the American Chemical Society, Vol. 139, Issue 11
Multication Side Chain Anion Exchange Membranes
journal, January 2016
- Zhu, Liang; Pan, Jing; Wang, Ying
- Macromolecules, Vol. 49, Issue 3
An experimental and modeling/simulation-based evaluation of the efficiency and operational performance characteristics of an integrated, membrane-free, neutral pH solar-driven water-splitting system
journal, January 2014
- Jin, Jian; Walczak, Karl; Singh, Meenesh R.
- Energy Environ. Sci., Vol. 7, Issue 10
Developing a scalable artificial photosynthesis technology through nanomaterials by design
journal, December 2016
- Lewis, Nathan S.
- Nature Nanotechnology, Vol. 11, Issue 12
Nonequilibrium hysteresis and Wien effect water dissociation at a bipolar membrane
journal, November 2012
- Conroy, D. T.; Craster, R. V.; Matar, O. K.
- Physical Review E, Vol. 86, Issue 5
Electric field-assisted proton transfer and water dissociation at the junction of a fixed-charge bipolar membrane
journal, September 1998
- Mafé, Salvador; Ramı́rez, Patricio; Alcaraz, Antonio
- Chemical Physics Letters, Vol. 294, Issue 4-5
Ag–Sn Bimetallic Catalyst with a Core–Shell Structure for CO 2 Reduction
journal, January 2017
- Luc, Wesley; Collins, Charles; Wang, Siwen
- Journal of the American Chemical Society, Vol. 139, Issue 5
Solar conversion of CO2 to CO using Earth-abundant electrocatalysts prepared by atomic layer modification of CuO
journal, June 2017
- Schreier, Marcel; Héroguel, Florent; Steier, Ludmilla
- Nature Energy, Vol. 2, Issue 7
Modeling, simulation, and design criteria for photoelectrochemical water-splitting systems
journal, January 2012
- Haussener, Sophia; Xiang, Chengxiang; Spurgeon, Joshua M.
- Energy & Environmental Science, Vol. 5, Issue 12
PEG–catalytic water splitting in the interface of a bipolar membrane
journal, July 2003
- Fu, RongQiang; Xu, TongWen; Wang, Gang
- Journal of Colloid and Interface Science, Vol. 263, Issue 2
Numerical Solution of the Coupled Nernst−Planck and Poisson Equations for Liquid Junction and Ion Selective Membrane Potentials
journal, March 2003
- Sokalski, Tomasz; Lingenfelter, Peter; Lewenstam, Andrzej
- The Journal of Physical Chemistry B, Vol. 107, Issue 11
Ni 2 P as a Janus catalyst for water splitting: the oxygen evolution activity of Ni 2 P nanoparticles
journal, January 2015
- Stern, Lucas-Alexandre; Feng, Ligang; Song, Fang
- Energy & Environmental Science, Vol. 8, Issue 8
High performance electrospun bipolar membrane with a 3D junction
journal, January 2017
- Shen, Chunhui; Wycisk, Ryszard; Pintauro, Peter N.
- Energy & Environmental Science, Vol. 10, Issue 6
Experimental and theoretical investigations of steady and transient states in systems of ion exchange bipolar membranes
journal, January 2004
- Hurwitz, H. D.; Dibiani, R.
- Journal of Membrane Science, Vol. 228, Issue 1
Effects of inorganic substances on water splitting in ion-exchange membranes
journal, May 2004
- Kang, Moon-Sung; Choi, Yong-Jin; Moon, Seung-Hyeon
- Journal of Colloid and Interface Science, Vol. 273, Issue 2
Hybrid Anion and Proton Exchange Membrane Fuel Cells
journal, June 2009
- Ünlü, Murat; Zhou, Junfeng; Kohl, Paul A.
- The Journal of Physical Chemistry C, Vol. 113, Issue 26
Mechanically Robust Anion Exchange Membranes via Long Hydrophilic Cross-Linkers
journal, March 2017
- Zhu, Liang; Zimudzi, Tawanda J.; Wang, Ying
- Macromolecules, Vol. 50, Issue 6
Ionic transport through ion-exchange and bipolar membranes
journal, August 2005
- Volgin, V. M.; Davydov, A. D.
- Journal of Membrane Science, Vol. 259, Issue 1-2
Theorems of Electrochemical Mass Transport in Dilute Solutions of Mixtures of Electrolytes, Including Weak Electrolytes and Hydrolysis Reactions
journal, January 2005
- Leibovitz, Jacques
- Journal of The Electrochemical Society, Vol. 152, Issue 9
Solar-Driven Reduction of 1 atm of CO 2 to Formate at 10% Energy-Conversion Efficiency by Use of a TiO 2 -Protected III–V Tandem Photoanode in Conjunction with a Bipolar Membrane and a Pd/C Cathode
journal, September 2016
- Zhou, Xinghao; Liu, Rui; Sun, Ke
- ACS Energy Letters, Vol. 1, Issue 4
Acid/Base Multi-Ion Exchange Membrane-Based Electrolysis System for Water Splitting
journal, January 2017
- Nazemi, Mohammadreza; Padgett, James; Hatzell, Marta C.
- Energy Technology, Vol. 5, Issue 8
Synergistic Electrochemical CO 2 Reduction and Water Oxidation with a Bipolar Membrane
journal, November 2016
- Vermaas, David A.; Smith, Wilson A.
- ACS Energy Letters, Vol. 1, Issue 6
Transparent Bipolar Membrane for Water Splitting Applications
journal, August 2017
- Chabi, Sakineh; Wright, Andrew G.; Holdcroft, Steven
- ACS Applied Materials & Interfaces, Vol. 9, Issue 32
Modeling, Simulation, and Implementation of Solar-Driven Water-Splitting Devices
journal, October 2016
- Xiang, Chengxiang; Weber, Adam Z.; Ardo, Shane
- Angewandte Chemie International Edition, Vol. 55, Issue 42
Functionalization of Poly(2,6-dimethyl-1,4-phenylene oxide)s with Hindered Fluorene Side Chains for Anion Exchange Membranes
journal, April 2016
- Zhu, Liang; Pan, Jing; Christensen, Caroline M.
- Macromolecules, Vol. 49, Issue 9
Catalytic, Conductive Bipolar Membrane Interfaces through Layer-by-Layer Deposition for the Design of Membrane-Integrated Artificial Photosynthesis Systems
journal, November 2017
- McDonald, Michael B.; Freund, Michael S.; Hammond, Paula T.
- ChemSusChem, Vol. 10, Issue 22
Nafion in Dilute Solvent Systems: Dispersion or Solution?
journal, November 2012
- Welch, Cynthia; Labouriau, Andrea; Hjelm, Rex
- ACS Macro Letters, Vol. 1, Issue 12
The Central Role of Bicarbonate in the Electrochemical Reduction of Carbon Dioxide on Gold
journal, March 2017
- Dunwell, Marco; Lu, Qi; Heyes, Jeffrey M.
- Journal of the American Chemical Society, Vol. 139, Issue 10
Photo-assisted water splitting with bipolar membrane induced pH gradients for practical solar fuel devices
journal, January 2015
- Vermaas, David A.; Sassenburg, Mark; Smith, Wilson A.
- Journal of Materials Chemistry A, Vol. 3, Issue 38
Insights into the electrocatalytic reduction of CO 2 on metallic silver surfaces
journal, January 2014
- Hatsukade, Toru; Kuhl, Kendra P.; Cave, Etosha R.
- Phys. Chem. Chem. Phys., Vol. 16, Issue 27
Deviations from Ohm's Law in Weak Electrolytes
journal, September 1934
- Onsager, Lars
- The Journal of Chemical Physics, Vol. 2, Issue 9
Model for ion transport in bipolar membranes
journal, November 1990
- Mafé, S.; Manzanares, J. A.; Ramrez, P.
- Physical Review A, Vol. 42, Issue 10
A Simple Model for Ac Impedance Spectra in Bipolar Membranes
journal, January 1996
- Alcaraz, A.; Ramírez, P.; Mafé, S.
- The Journal of Physical Chemistry, Vol. 100, Issue 38
Water dissociation in bipolar membranes: Experiments and theory
journal, March 1978
- Simons, R.; Khanarian, G.
- The Journal of Membrane Biology, Vol. 38, Issue 1-2
Benchmarking Heterogeneous Electrocatalysts for the Oxygen Evolution Reaction
journal, October 2013
- McCrory, Charles C. L.; Jung, Suho; Peters, Jonas C.
- Journal of the American Chemical Society, Vol. 135, Issue 45
Morphology study of Nafion membranes prepared by solutions casting
journal, January 2005
- Lin, Hsiu-Li; Yu, T. Leon; Huang, Cheng-Hung
- Journal of Polymer Science Part B: Polymer Physics, Vol. 43, Issue 21
How copper catalyzes the electroreduction of carbon dioxide into hydrocarbon fuels
journal, January 2010
- Peterson, Andrew A.; Abild-Pedersen, Frank; Studt, Felix
- Energy & Environmental Science, Vol. 3, Issue 9
Strong electric field effects on proton transfer between membrane-bound amines and water
journal, August 1979
- Simons, R.
- Nature, Vol. 280, Issue 5725
Ion transport through electrolyte/polyelectrolyte multi-layers
journal, June 2015
- Femmer, Robert; Mani, Ali; Wessling, Matthias
- Scientific Reports, Vol. 5, Issue 1
Core–Shell Au@Metal-Oxide Nanoparticle Electrocatalysts for Enhanced Oxygen Evolution
journal, September 2017
- Strickler, Alaina L.; Escudero-Escribano, Marı́a; Jaramillo, Thomas F.
- Nano Letters, Vol. 17, Issue 10
Conductive and Capacitive Properties of the Bipolar Membrane Junction Studied by AC Impedance Spectroscopy †
journal, November 2001
- Alcaraz, Antonio; Ramírez, Patricio; Manzanares, José A.
- The Journal of Physical Chemistry B, Vol. 105, Issue 47
Hydrogen Production From Water Electrolysis: Current Status and Future Trends
journal, February 2012
- Ursua, Alfredo; Gandia, Luis M.; Sanchis, Pablo
- Proceedings of the IEEE, Vol. 100, Issue 2
Bipolar Membrane-Assisted Solar Water Splitting in Optimal pH
journal, April 2016
- Luo, Jingshan; Vermaas, David A.; Bi, Dongqin
- Advanced Energy Materials, Vol. 6, Issue 13
Electrolysis of CO 2 to Syngas in Bipolar Membrane-Based Electrochemical Cells
journal, November 2016
- Li, Yuguang C.; Zhou, Dekai; Yan, Zhifei
- ACS Energy Letters, Vol. 1, Issue 6
Understanding Transport at the Acid-Alkaline Interface of Bipolar Membranes
journal, January 2016
- Grew, Kyle N.; McClure, Joshua P.; Chu, Deryn
- Journal of The Electrochemical Society, Vol. 163, Issue 14
New insights into the electrochemical reduction of carbon dioxide on metallic copper surfaces
journal, January 2012
- Kuhl, Kendra P.; Cave, Etosha R.; Abram, David N.
- Energy & Environmental Science, Vol. 5, Issue 5
Use of Bipolar Membranes for Maintaining Steady-State pH Gradients in Membrane-Supported, Solar-Driven Water Splitting
journal, September 2014
- McDonald, Michael B.; Ardo, Shane; Lewis, Nathan S.
- ChemSusChem, Vol. 7, Issue 11
Electric field enhanced water dissociation at the bipolar membrane junction from ac impedance spectra measurements
journal, January 1998
- Holdik, H.; Alcaraz, A.; Ramı́rez, P.
- Journal of Electroanalytical Chemistry, Vol. 442, Issue 1-2
Research opportunities to advance solar energy utilization
journal, January 2016
- Lewis, N. S.
- Science, Vol. 351, Issue 6271
Shape-Dependent Electrocatalytic Reduction of CO 2 to CO on Triangular Silver Nanoplates
journal, February 2017
- Liu, Subiao; Tao, Hongbiao; Zeng, Li
- Journal of the American Chemical Society, Vol. 139, Issue 6
Efficient bipolar membrane with protein interfacial layer for optimal water splitting
journal, March 2017
- Manohar, Murli; Shukla, Geetanjali; Pandey, Ravi P.
- Journal of Industrial and Engineering Chemistry, Vol. 47
Aqueous CO 2 Reduction at Very Low Overpotential on Oxide-Derived Au Nanoparticles
journal, November 2012
- Chen, Yihong; Li, Christina W.; Kanan, Matthew W.
- Journal of the American Chemical Society, Vol. 134, Issue 49
A prototype reactor for highly selective solar-driven CO 2 reduction to synthesis gas using nanosized earth-abundant catalysts and silicon photovoltaics
journal, January 2017
- Urbain, Félix; Tang, Pengyi; Carretero, Nina M.
- Energy & Environmental Science, Vol. 10, Issue 10
Limiting current density and water dissociation in bipolar membranes
journal, March 1997
- Strathmann, H.; Krol, J. J.; Rapp, H. -J
- Journal of Membrane Science, Vol. 125, Issue 1
Achieving Selective and Efficient Electrocatalytic Activity for CO 2 Reduction Using Immobilized Silver Nanoparticles
journal, October 2015
- Kim, Cheonghee; Jeon, Hyo Sang; Eom, Taedaehyeong
- Journal of the American Chemical Society, Vol. 137, Issue 43
Catalytic Polyelectrolyte Multilayers at the Bipolar Membrane Interface
journal, October 2013
- Abdu, Said; Sricharoen, Kittikun; Wong, John E.
- ACS Applied Materials & Interfaces, Vol. 5, Issue 21
Membranes for artificial photosynthesis
journal, January 2017
- Chabi, Sakineh; Papadantonakis, Kimberly M.; Lewis, Nathan S.
- Energy & Environmental Science, Vol. 10, Issue 6