Superior Performance of a Lithium-Sulfur Battery Enabled by a Dimethyl Trisulfide Containing Electrolyte
Abstract
Abstract The lithium–sulfur (Li‐S) battery offers a high theoretical energy density of ≈2600 Wh kg −1 and low cost, positioning it as a promising candidate for next‐generation battery technology. However, problems including disastrous Li polysulfides dissolution and irreversible Li 2 S deposition have severely retarded the development of Li‐S batteries. To solve these issues, a functional dimethyl disulfide (DMDS)‐containing electrolyte was recently reported that promotes an alternate electrochemical reaction pathway for sulfur cathodes by the formation of dimethyl polysulfides and Li organosulfides as intermediates and reduction products, leading to significantly boosted Li‐S cell capacity with improved cycling reversibility and stability. Here, dimethyl trisulfide (DMTS), a primary discharge–charge intermediate in the DMDS‐containing electrolyte, which is also a commercially available reagent, is further investigated as a cosolvent in functional electrolytes for Li‐S batteries. Due to the higher theoretical capacity of DMTS and its better reactivity with Li 2 S than DMDS, a 25 vol% DMTS‐containing electrolyte enables Li‐S batteries with even higher cell capacity and improved cycling performance than using previous optimal 50 vol% DMDS‐containing electrolyte.
- Authors:
-
[1];
[1]
- Pennsylvania State Univ., University Park, PA (United States). Dept of Mechanical and Nuclear Engineering
- Publication Date:
- Research Org.:
- Pennsylvania State Univ., University Park, PA (United States). Dept of Mechanical and Nuclear Engineering
- Sponsoring Org.:
- USDOE Office of Energy Efficiency and Renewable Energy (EERE), Vehicle Technologies Office (EE-3V); USDOE
- OSTI Identifier:
- 1435969
- Alternate Identifier(s):
- OSTI ID: 1441117
- Report Number(s):
- DOE-PENNSTATE-0007795
Journal ID: ISSN 2366-9608; PII:974
- Grant/Contract Number:
- EE0007795; DE‐EE0007795
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Small Methods
- Additional Journal Information:
- Journal Volume: 2; Journal Issue: 6; Journal ID: ISSN 2366-9608
- Publisher:
- Wiley
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 25 ENERGY STORAGE; 36 MATERIALS SCIENCE; 77 NANOSCIENCE AND NANOTECHNOLOGY; 42 ENGINEERING; lithium-sulfur battery; lithium organosulfides; dimethyl trisulfide; dimethyl disulfide; lithium-sulfur; batteries; electrolyte
Citation Formats
Chen, Shuru, Wang, Daiwei, Zhao, Yuming, and Wang, Donghai. Superior Performance of a Lithium-Sulfur Battery Enabled by a Dimethyl Trisulfide Containing Electrolyte. United States: N. p., 2018.
Web. doi:10.1002/smtd.201800038.
Chen, Shuru, Wang, Daiwei, Zhao, Yuming, & Wang, Donghai. Superior Performance of a Lithium-Sulfur Battery Enabled by a Dimethyl Trisulfide Containing Electrolyte. United States. https://doi.org/10.1002/smtd.201800038
Chen, Shuru, Wang, Daiwei, Zhao, Yuming, and Wang, Donghai. Thu .
"Superior Performance of a Lithium-Sulfur Battery Enabled by a Dimethyl Trisulfide Containing Electrolyte". United States. https://doi.org/10.1002/smtd.201800038. https://www.osti.gov/servlets/purl/1435969.
@article{osti_1435969,
title = {Superior Performance of a Lithium-Sulfur Battery Enabled by a Dimethyl Trisulfide Containing Electrolyte},
author = {Chen, Shuru and Wang, Daiwei and Zhao, Yuming and Wang, Donghai},
abstractNote = {Abstract The lithium–sulfur (Li‐S) battery offers a high theoretical energy density of ≈2600 Wh kg −1 and low cost, positioning it as a promising candidate for next‐generation battery technology. However, problems including disastrous Li polysulfides dissolution and irreversible Li 2 S deposition have severely retarded the development of Li‐S batteries. To solve these issues, a functional dimethyl disulfide (DMDS)‐containing electrolyte was recently reported that promotes an alternate electrochemical reaction pathway for sulfur cathodes by the formation of dimethyl polysulfides and Li organosulfides as intermediates and reduction products, leading to significantly boosted Li‐S cell capacity with improved cycling reversibility and stability. Here, dimethyl trisulfide (DMTS), a primary discharge–charge intermediate in the DMDS‐containing electrolyte, which is also a commercially available reagent, is further investigated as a cosolvent in functional electrolytes for Li‐S batteries. Due to the higher theoretical capacity of DMTS and its better reactivity with Li 2 S than DMDS, a 25 vol% DMTS‐containing electrolyte enables Li‐S batteries with even higher cell capacity and improved cycling performance than using previous optimal 50 vol% DMDS‐containing electrolyte.},
doi = {10.1002/smtd.201800038},
journal = {Small Methods},
number = 6,
volume = 2,
place = {United States},
year = {Thu Apr 26 00:00:00 EDT 2018},
month = {Thu Apr 26 00:00:00 EDT 2018}
}
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