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Title: 3D-Printed, Superelastic Polypyrrole-Graphene Electrodes with Ultrahigh Areal Capacitance for Electrochemical Energy Storage

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  1. Lawrence Livermore National Laboratory, Livermore CA 94550 USA
Publication Date:
Sponsoring Org.:
OSTI Identifier:
Grant/Contract Number:  
AC52-07NA27344; 16-ERD-051; 14-SI-004; 13-LW-099
Resource Type:
Publisher's Accepted Manuscript
Journal Name:
Advanced Materials Technologies
Additional Journal Information:
Journal Name: Advanced Materials Technologies Journal Volume: 3 Journal Issue: 7; Journal ID: ISSN 2365-709X
Wiley Blackwell (John Wiley & Sons)
Country of Publication:
United States

Citation Formats

Qi, Zhen, Ye, Jianchao, Chen, Wen, Biener, Juergen, Duoss, Eric B., Spadaccini, Christopher M., Worsley, Marcus A., and Zhu, Cheng. 3D-Printed, Superelastic Polypyrrole-Graphene Electrodes with Ultrahigh Areal Capacitance for Electrochemical Energy Storage. United States: N. p., 2018. Web. doi:10.1002/admt.201800053.
Qi, Zhen, Ye, Jianchao, Chen, Wen, Biener, Juergen, Duoss, Eric B., Spadaccini, Christopher M., Worsley, Marcus A., & Zhu, Cheng. 3D-Printed, Superelastic Polypyrrole-Graphene Electrodes with Ultrahigh Areal Capacitance for Electrochemical Energy Storage. United States. doi:
Qi, Zhen, Ye, Jianchao, Chen, Wen, Biener, Juergen, Duoss, Eric B., Spadaccini, Christopher M., Worsley, Marcus A., and Zhu, Cheng. Thu . "3D-Printed, Superelastic Polypyrrole-Graphene Electrodes with Ultrahigh Areal Capacitance for Electrochemical Energy Storage". United States. doi:
title = {3D-Printed, Superelastic Polypyrrole-Graphene Electrodes with Ultrahigh Areal Capacitance for Electrochemical Energy Storage},
author = {Qi, Zhen and Ye, Jianchao and Chen, Wen and Biener, Juergen and Duoss, Eric B. and Spadaccini, Christopher M. and Worsley, Marcus A. and Zhu, Cheng},
abstractNote = {},
doi = {10.1002/admt.201800053},
journal = {Advanced Materials Technologies},
number = 7,
volume = 3,
place = {United States},
year = {2018},
month = {6}

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Free Publicly Available Full Text
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Works referenced in this record:

Shape-morphing composites with designed micro-architectures
journal, June 2016

  • Rodriguez, Jennifer N.; Zhu, Cheng; Duoss, Eric B.
  • Scientific Reports, Vol. 6, Issue 1
  • DOI: 10.1038/srep27933

Self-assembled three-dimensional and compressible interdigitated thin-film supercapacitors and batteries
journal, May 2015

  • Nyström, Gustav; Marais, Andrew; Karabulut, Erdem
  • Nature Communications, Vol. 6, Issue 1
  • DOI: 10.1038/ncomms8259

A comprehensive understanding of electrode thickness effects on the electrochemical performances of Li-ion battery cathodes
journal, June 2012

Preparation of Novel 3D Graphene Networks for Supercapacitor Applications
journal, September 2011

Noble-Metal-Promoted Three-Dimensional Macroassembly of Single-Layered Graphene Oxide
journal, May 2010

  • Tang, Zhihong; Shen, Shuling; Zhuang, Jing
  • Angewandte Chemie, Vol. 122, Issue 27
  • DOI: 10.1002/ange.201000270

TiO 2 @C core–shell nanowires for high-performance and flexible solid-state supercapacitors
journal, January 2013

  • Zheng, Huimin; Zhai, Teng; Yu, Minghao
  • J. Mater. Chem. C, Vol. 1, Issue 2
  • DOI: 10.1039/C2TC00047D

Engineering three-dimensional hybrid supercapacitors and microsupercapacitors for high-performance integrated energy storage
journal, March 2015

  • El-Kady, Maher F.; Ihns, Melanie; Li, Mengping
  • Proceedings of the National Academy of Sciences, Vol. 112, Issue 14
  • DOI: 10.1073/pnas.1420398112

Energy Scavenging for Mobile and Wireless Electronics
journal, January 2005

  • Paradiso, J. A.; Starner, T.
  • IEEE Pervasive Computing, Vol. 4, Issue 1
  • DOI: 10.1109/MPRV.2005.9

Ultrahigh-power micrometre-sized supercapacitors based on onion-like carbon
journal, August 2010

  • Pech, David; Brunet, Magali; Durou, Hugo
  • Nature Nanotechnology, Vol. 5, Issue 9, p. 651-654
  • DOI: 10.1038/nnano.2010.162

Highly Compression-Tolerant Supercapacitor Based on Polypyrrole-mediated Graphene Foam Electrodes
journal, October 2012

A facile soft-template synthesis of mesoporous polymeric and carbonaceous nanospheres
journal, December 2013

  • Liu, Jian; Yang, Tianyu; Wang, Da-Wei
  • Nature Communications, Vol. 4, Issue 1
  • DOI: 10.1038/ncomms3798

Processable aqueous dispersions of graphene nanosheets
journal, January 2008

Reversibly Compressible, Highly Elastic, and Durable Graphene Aerogels for Energy Storage Devices under Limiting Conditions
journal, December 2014

  • Hong, Jin-Yong; Bak, Bo Mee; Wie, Jeong Jae
  • Advanced Functional Materials, Vol. 25, Issue 7
  • DOI: 10.1002/adfm.201403273

Supercapacitors Based on Three-Dimensional Hierarchical Graphene Aerogels with Periodic Macropores
journal, January 2016

Ion Intercalation Induced Capacitance Improvement for Graphene-Based Supercapacitor Electrodes
journal, May 2016

Controlling Material Reactivity Using Architecture
journal, December 2015

  • Sullivan, Kyle T.; Zhu, Cheng; Duoss, Eric B.
  • Advanced Materials, Vol. 28, Issue 10
  • DOI: 10.1002/adma.201504286

Highly Compressible and All-Solid-State Supercapacitors Based on Nanostructured Composite Sponge
journal, August 2015

  • Niu, Zhiqiang; Zhou, Weiya; Chen, Xiaodong
  • Advanced Materials, Vol. 27, Issue 39
  • DOI: 10.1002/adma.201502263

Solid-State Supercapacitor Based on Activated Carbon Cloths Exhibits Excellent Rate Capability
journal, February 2014

Fabrication of an arbitrary-shaped and nitrogen-doped graphene aerogel for highly compressible all solid-state supercapacitors
journal, January 2017

  • Jiang, Degang; Li, Chenwei; Yang, Wenrong
  • Journal of Materials Chemistry A, Vol. 5, Issue 35
  • DOI: 10.1039/C7TA04917J

Supercapacitor electrode materials: nanostructures from 0 to 3 dimensions
journal, January 2015

  • Yu, Zenan; Tetard, Laurene; Zhai, Lei
  • Energy & Environmental Science, Vol. 8, Issue 3
  • DOI: 10.1039/C4EE03229B

Three dimensional (3D) flexible graphene foam/polypyrrole composite: towards highly efficient supercapacitors
journal, January 2015

  • Chabi, Sakineh; Peng, Chuang; Yang, Zhuxian
  • RSC Advances, Vol. 5, Issue 6
  • DOI: 10.1039/C4RA13743D

3D carbon based nanostructures for advanced supercapacitors
journal, January 2013

  • Jiang, Hao; Lee, Pooi See; Li, Chunzhong
  • Energy Environ. Sci., Vol. 6, Issue 1
  • DOI: 10.1039/C2EE23284G

Graphene-Based Supercapacitor with an Ultrahigh Energy Density
journal, December 2010

  • Liu, Chenguang; Yu, Zhenning; Neff, David
  • Nano Letters, Vol. 10, Issue 12
  • DOI: 10.1021/nl102661q

Three-Dimensional Printing of Elastomeric, Cellular Architectures with Negative Stiffness
journal, May 2014

  • Duoss, Eric B.; Weisgraber, Todd H.; Hearon, Keith
  • Advanced Functional Materials, Vol. 24, Issue 31
  • DOI: 10.1002/adfm.201400451

Freestanding, Hydrophilic Nitrogen-Doped Carbon Foams for Highly Compressible All Solid-State Supercapacitors
journal, May 2016

Ultrasmall Integrated 3D Micro-Supercapacitors Solve Energy Storage for Miniature Devices
journal, December 2013

  • Meng, Chuizhou; Maeng, Jimin; John, Simon W. M.
  • Advanced Energy Materials, Vol. 4, Issue 7
  • DOI: 10.1002/aenm.201301269

Capacitive energy storage in micro-scale devices: recent advances in design and fabrication of micro-supercapacitors
journal, January 2014

  • Beidaghi, Majid; Gogotsi, Yury
  • Energy & Environmental Science, Vol. 7, Issue 3
  • DOI: 10.1039/c3ee43526a

3D printed functional nanomaterials for electrochemical energy storage
journal, August 2017

Scalable fabrication of high-power graphene micro-supercapacitors for flexible and on-chip energy storage
journal, February 2013

  • El-Kady, Maher F.; Kaner, Richard B.
  • Nature Communications, Vol. 4, Issue 1
  • DOI: 10.1038/ncomms2446

Flexible and stretchable power sources for wearable electronics
journal, June 2017

  • Zamarayeva, Alla M.; Ostfeld, Aminy E.; Wang, Michael
  • Science Advances, Vol. 3, Issue 6
  • DOI: 10.1126/sciadv.1602051

Thixotropic rheology of concentrated alumina colloidal gels for solid freeform fabrication
journal, May 2011

  • Zhu, Cheng; Smay, James E.
  • Journal of Rheology, Vol. 55, Issue 3
  • DOI: 10.1122/1.3573828

3-Dimensional Graphene Carbon Nanotube Carpet-Based Microsupercapacitors with High Electrochemical Performance
journal, December 2012

  • Lin, Jian; Zhang, Chenguang; Yan, Zheng
  • Nano Letters, Vol. 13, Issue 1
  • DOI: 10.1021/nl3034976

Electrophoretic Deposition of Thermites onto Micro-Engineered Electrodes Prepared by Direct-Ink Writing
journal, September 2012

  • Sullivan, K. T.; Zhu, C.; Tanaka, D. J.
  • The Journal of Physical Chemistry B, Vol. 117, Issue 6, p. 1686-1693
  • DOI: 10.1021/jp306440t

Optimizing supercapacitor electrode density: achieving the energy of organic electrolytes with the power of aqueous electrolytes
journal, January 2014

  • Merrill, M. D.; Montalvo, E.; Campbell, P. G.
  • RSC Advances, Vol. 4, Issue 81
  • DOI: 10.1039/C4RA08114E

Carbon nanotube-polypyrrole core-shell sponge and its application as highly compressible supercapacitor electrode
journal, December 2013

Flexible and Stretchable Energy Storage: Recent Advances and Future Perspectives
journal, November 2016

3D-Printed Transparent Glass
journal, April 2017

  • Nguyen, Du T.; Meyers, Cameron; Yee, Timothy D.
  • Advanced Materials, Vol. 29, Issue 26
  • DOI: 10.1002/adma.201701181

Three-dimensional graphene oxide/polypyrrole composite electrodes fabricated by one-step electrodeposition for high performance supercapacitors
journal, January 2015

  • Cao, Jianyun; Wang, Yaming; Chen, Junchen
  • Journal of Materials Chemistry A, Vol. 3, Issue 27
  • DOI: 10.1039/C5TA02920A

High-rate in-plane micro-supercapacitors scribed onto photo paper using in situ femtolaser-reduced graphene oxide/Au nanoparticle microelectrodes
journal, January 2016

  • Li, R. -Z.; Peng, Rui; Kihm, K. D.
  • Energy & Environmental Science, Vol. 9, Issue 4
  • DOI: 10.1039/C5EE03637B

Redox-Active Polypyrrole: Toward Polymer-Based Batteries
journal, July 2006

  • Song, H.-K.; Palmore, G. T. R.
  • Advanced Materials, Vol. 18, Issue 13, p. 1764-1768
  • DOI: 10.1002/adma.200600375

On-chip and freestanding elastic carbon films for micro-supercapacitors
journal, February 2016

Catenary shape evolution of spanning structures in direct-write assembly of colloidal gels
journal, March 2012

Origin of Reduced Graphene Oxide Enhancements in Electrochemical Energy Storage
journal, April 2012

  • Radich, James G.; Kamat, Prashant V.
  • ACS Catalysis, Vol. 2, Issue 5
  • DOI: 10.1021/cs3001286

Laser-induced porous graphene films from commercial polymers
journal, December 2014

  • Lin, Jian; Peng, Zhiwei; Liu, Yuanyue
  • Nature Communications, Vol. 5, Issue 1
  • DOI: 10.1038/ncomms6714

Structural Optimization of 3D Porous Electrodes for High-Rate Performance Lithium Ion Batteries
journal, December 2014

  • Ye, Jianchao; Baumgaertel, Andreas C.; Wang, Y. Morris
  • ACS Nano, Vol. 9, Issue 2
  • DOI: 10.1021/nn505490u

Graphene-based in-plane micro-supercapacitors with high power and energy densities
journal, September 2013

  • Wu, Zhong–Shuai; Parvez, Khaled; Feng, Xinliang
  • Nature Communications, Vol. 4, Issue 1
  • DOI: 10.1038/ncomms3487

Highly compressible 3D periodic graphene aerogel microlattices
journal, April 2015

  • Zhu, Cheng; Han, T. Yong-Jin; Duoss, Eric B.
  • Nature Communications, Vol. 6, Issue 1
  • DOI: 10.1038/ncomms7962

Unconventional supercapacitors from nanocarbon-based electrode materials to device configurations
journal, January 2016

  • Liu, Lili; Niu, Zhiqiang; Chen, Jun
  • Chemical Society Reviews, Vol. 45, Issue 15
  • DOI: 10.1039/C6CS00041J

Three-dimensional carbon architectures for electrochemical capacitors
journal, January 2018