A Perovskite Electrolyte That Is Stable in Moist Air for Lithium‐Ion Batteries
Abstract
Abstract Solid‐oxide Li + electrolytes of a rechargeable cell are generally sensitive to moisture in the air as H + exchanges for the mobile Li + of the electrolyte and forms insulating surface phases at the electrolyte interfaces and in the grain boundaries of a polycrystalline membrane. These surface phases dominate the total interfacial resistance of a conventional rechargeable cell with a solid–electrolyte separator. We report a new perovskite Li + solid electrolyte, Li 0.38 Sr 0.44 Ta 0.7 Hf 0.3 O 2.95 F 0.05 , with a lithium‐ion conductivity of σ Li =4.8×10 −4 S cm −1 at 25 °C that does not react with water having 3≤pH≤14. The solid electrolyte with a thin Li + ‐conducting polymer on its surface to prevent reduction of Ta 5+ is wet by metallic lithium and provides low‐impedance dendrite‐free plating/stripping of a lithium anode. It is also stable upon contact with a composite polymer cathode. With this solid electrolyte, we demonstrate excellent cycling performance of an all‐solid‐state Li/LiFePO 4 cell, a Li‐S cell with a polymer‐gel cathode, and a supercapacitor.
- Authors:
-
- Materials Science and Engineering Program and Texas Materials Institute University of Texas at Austin Austin TX 78712 USA
- Department of Chemistry and Biochemistry Florida State University Tallahassee FL 32310 USA
- Department of Chemistry and Biochemistry Florida State University Tallahassee FL 32310 USA, National High Magnetic Field Laboratory 1800 East Paul Dirac Drive Tallahassee FL 32310 USA
- Publication Date:
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1441039
- Grant/Contract Number:
- EE0007762; 7223523
- Resource Type:
- Publisher's Accepted Manuscript
- Journal Name:
- Angewandte Chemie (International Edition)
- Additional Journal Information:
- Journal Name: Angewandte Chemie (International Edition) Journal Volume: 57 Journal Issue: 28; Journal ID: ISSN 1433-7851
- Publisher:
- Wiley Blackwell (John Wiley & Sons)
- Country of Publication:
- Germany
- Language:
- English
Citation Formats
Li, Yutao, Xu, Henghui, Chien, Po‐Hsiu, Wu, Nan, Xin, Sen, Xue, Leigang, Park, Kyusung, Hu, Yan‐Yan, and Goodenough, John B. A Perovskite Electrolyte That Is Stable in Moist Air for Lithium‐Ion Batteries. Germany: N. p., 2018.
Web. doi:10.1002/anie.201804114.
Li, Yutao, Xu, Henghui, Chien, Po‐Hsiu, Wu, Nan, Xin, Sen, Xue, Leigang, Park, Kyusung, Hu, Yan‐Yan, & Goodenough, John B. A Perovskite Electrolyte That Is Stable in Moist Air for Lithium‐Ion Batteries. Germany. https://doi.org/10.1002/anie.201804114
Li, Yutao, Xu, Henghui, Chien, Po‐Hsiu, Wu, Nan, Xin, Sen, Xue, Leigang, Park, Kyusung, Hu, Yan‐Yan, and Goodenough, John B. Thu .
"A Perovskite Electrolyte That Is Stable in Moist Air for Lithium‐Ion Batteries". Germany. https://doi.org/10.1002/anie.201804114.
@article{osti_1441039,
title = {A Perovskite Electrolyte That Is Stable in Moist Air for Lithium‐Ion Batteries},
author = {Li, Yutao and Xu, Henghui and Chien, Po‐Hsiu and Wu, Nan and Xin, Sen and Xue, Leigang and Park, Kyusung and Hu, Yan‐Yan and Goodenough, John B.},
abstractNote = {Abstract Solid‐oxide Li + electrolytes of a rechargeable cell are generally sensitive to moisture in the air as H + exchanges for the mobile Li + of the electrolyte and forms insulating surface phases at the electrolyte interfaces and in the grain boundaries of a polycrystalline membrane. These surface phases dominate the total interfacial resistance of a conventional rechargeable cell with a solid–electrolyte separator. We report a new perovskite Li + solid electrolyte, Li 0.38 Sr 0.44 Ta 0.7 Hf 0.3 O 2.95 F 0.05 , with a lithium‐ion conductivity of σ Li =4.8×10 −4 S cm −1 at 25 °C that does not react with water having 3≤pH≤14. The solid electrolyte with a thin Li + ‐conducting polymer on its surface to prevent reduction of Ta 5+ is wet by metallic lithium and provides low‐impedance dendrite‐free plating/stripping of a lithium anode. It is also stable upon contact with a composite polymer cathode. With this solid electrolyte, we demonstrate excellent cycling performance of an all‐solid‐state Li/LiFePO 4 cell, a Li‐S cell with a polymer‐gel cathode, and a supercapacitor.},
doi = {10.1002/anie.201804114},
journal = {Angewandte Chemie (International Edition)},
number = 28,
volume = 57,
place = {Germany},
year = {Thu Jun 07 00:00:00 EDT 2018},
month = {Thu Jun 07 00:00:00 EDT 2018}
}
https://doi.org/10.1002/anie.201804114
Web of Science
Works referenced in this record:
How we made the Li-ion rechargeable battery
journal, March 2018
- Goodenough, John B.
- Nature Electronics, Vol. 1, Issue 3
Negating interfacial impedance in garnet-based solid-state Li metal batteries
journal, December 2016
- Han, Xiaogang; Gong, Yunhui; Fu, Kun (Kelvin)
- Nature Materials, Vol. 16, Issue 5
Li-Ion Conduction and Stability of Perovskite Li 3/8 Sr 7/16 Hf 1/4 Ta 3/4 O 3
journal, June 2016
- Huang, Bing; Xu, Biyi; Li, Yutao
- ACS Applied Materials & Interfaces, Vol. 8, Issue 23
Fluorine-Doped Antiperovskite Electrolyte for All-Solid-State Lithium-Ion Batteries
journal, June 2016
- Li, Yutao; Zhou, Weidong; Xin, Sen
- Angewandte Chemie International Edition, Vol. 55, Issue 34
Challenges for Rechargeable Li Batteries
journal, February 2010
- Goodenough, John B.; Kim, Youngsik
- Chemistry of Materials, Vol. 22, Issue 3, p. 587-603
High-power all-solid-state batteries using sulfide superionic conductors
journal, March 2016
- Kato, Yuki; Hori, Satoshi; Saito, Toshiya
- Nature Energy, Vol. 1, Issue 4
Hybrid Polymer/Garnet Electrolyte with a Small Interfacial Resistance for Lithium-Ion Batteries
journal, December 2016
- Li, Yutao; Xu, Biyi; Xu, Henghui
- Angewandte Chemie International Edition, Vol. 56, Issue 3
Transition from Superlithiophobicity to Superlithiophilicity of Garnet Solid-State Electrolyte
journal, September 2016
- Luo, Wei; Gong, Yunhui; Zhu, Yizhou
- Journal of the American Chemical Society, Vol. 138, Issue 37
Hybrid Polymer/Garnet Electrolyte with a Small Interfacial Resistance for Lithium-Ion Batteries
journal, December 2016
- Li, Yutao; Xu, Biyi; Xu, Henghui
- Angewandte Chemie, Vol. 129, Issue 3
Fluorine-Doped Antiperovskite Electrolyte for All-Solid-State Lithium-Ion Batteries
journal, June 2016
- Li, Yutao; Zhou, Weidong; Xin, Sen
- Angewandte Chemie, Vol. 128, Issue 34
The origin of high electrolyte–electrode interfacial resistances in lithium cells containing garnet type solid electrolytes
journal, January 2014
- Cheng, Lei; Crumlin, Ethan J.; Chen, Wei
- Phys. Chem. Chem. Phys., Vol. 16, Issue 34
A chemistry and material perspective on lithium redox flow batteries towards high-density electrical energy storage
journal, January 2015
- Zhao, Yu; Ding, Yu; Li, Yutao
- Chemical Society Reviews, Vol. 44, Issue 22
Surface Chemistry Mechanism of Ultra-Low Interfacial Resistance in the Solid-State Electrolyte Li 7 La 3 Zr 2 O 12
journal, September 2017
- Sharafi, Asma; Kazyak, Eric; Davis, Andrew L.
- Chemistry of Materials, Vol. 29, Issue 18
An In Vivo Formed Solid Electrolyte Surface Layer Enables Stable Plating of Li Metal
journal, December 2017
- Pang, Quan; Liang, Xiao; Shyamsunder, Abhinandan
- Joule, Vol. 1, Issue 4
Synergistic Coupling between Li 6.75 La 3 Zr 1.75 Ta 0.25 O 12 and Poly(vinylidene fluoride) Induces High Ionic Conductivity, Mechanical Strength, and Thermal Stability of Solid Composite Electrolytes
journal, September 2017
- Zhang, Xue; Liu, Ting; Zhang, Shuofeng
- Journal of the American Chemical Society, Vol. 139, Issue 39
Polysulfide-Shuttle Control in Lithium-Sulfur Batteries with a Chemically/Electrochemically Compatible NaSICON-Type Solid Electrolyte
journal, August 2016
- Yu, Xingwen; Bi, Zhonghe; Zhao, Feng
- Advanced Energy Materials, Vol. 6, Issue 24
Stability of NaSICON-type Li1.3Al0.3Ti1.7P3O12 in aqueous solutions
journal, May 2013
- Jackman, Spencer D.; Cutler, Raymond A.
- Journal of Power Sources, Vol. 230
Facile proton conduction in H+/Li+ ion-exchanged garnet-type fast Li-ion conducting Li5La3Nb2O12
journal, January 2013
- Truong, Lina; Howard, Matthew; Clemens, Oliver
- Journal of Materials Chemistry A, Vol. 1, Issue 43
Mastering the interface for advanced all-solid-state lithium rechargeable batteries
journal, November 2016
- Li, Yutao; Zhou, Weidong; Chen, Xi
- Proceedings of the National Academy of Sciences, Vol. 113, Issue 47
Dendrite-Free Li-Metal Battery Enabled by a Thin Asymmetric Solid Electrolyte with Engineered Layers
journal, December 2017
- Duan, Hui; Yin, Ya-Xia; Shi, Yang
- Journal of the American Chemical Society, Vol. 140, Issue 1
Lithium battery chemistries enabled by solid-state electrolytes
journal, February 2017
- Manthiram, Arumugam; Yu, Xingwen; Wang, Shaofei
- Nature Reviews Materials, Vol. 2, Issue 4
Toward garnet electrolyte–based Li metal batteries: An ultrathin, highly effective, artificial solid-state electrolyte/metallic Li interface
journal, April 2017
- Fu, Kun (Kelvin); Gong, Yunhui; Liu, Boyang
- Science Advances, Vol. 3, Issue 4
Plating a Dendrite-Free Lithium Anode with a Polymer/Ceramic/Polymer Sandwich Electrolyte
journal, July 2016
- Zhou, Weidong; Wang, Shaofei; Li, Yutao
- Journal of the American Chemical Society, Vol. 138, Issue 30
Stability of the solid electrolyte Li3OBr to common battery solvents
journal, January 2014
- Schroeder, D. J.; Hubaud, A. A.; Vaughey, J. T.
- Materials Research Bulletin, Vol. 49