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Title: Rare Earth Arylsilazido Compounds with Inequivalent Secondary Interactions

Journal Article · · ChemComm
DOI: https://doi.org/10.1039/C8CC03186J · OSTI ID:1441001
 [1];  [2];  [1];  [3];  [1];  [1]
  1. Ames Lab. and Iowa State Univ., Ames, IA (United States)
  2. Beijing Normal Univ., Beijing (People's Republic of China)
  3. Iowa State Univ., Ames, IA (United States)
+ Show Author Affiliations

Here, a new bulky silazido ligand, –N(SiHMe2)Dipp (Dipp = C6H3-2,6-iPr2) supports planar, three-coordinate homoleptic rare earth complexes Ln{N(SiHMe2)Dipp}3 (Ln = Sc, Y, Lu) that each contain three secondary Ln←HSi interactions and one agostic CH bond. Y{N(SiHMe2)Dipp}3 and acetophenone react via hydrosilylation, rather than by insertion into the Y–N bond or enolate formation.

Research Organization:
Ames Laboratory (AMES), Ames, IA (United States)
Sponsoring Organization:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
Grant/Contract Number:
AC02-07CH11358
OSTI ID:
1441001
Alternate ID(s):
OSTI ID: 1454335
Report Number(s):
IS-J-9677; CHCOFS
Journal Information:
ChemComm, Vol. 54; ISSN 1359-7345
Publisher:
Royal Society of ChemistryCopyright Statement
Country of Publication:
United States
Language:
English
Citation Metrics:
Cited by: 4 works
Citation information provided by
Web of Science

References (25)

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Linked Research (4)

Figures / Tables (5)

Figure 1(p. 2)figure Figure 1
Table 1(p. 2)table Table 1
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