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This content will become publicly available on June 5, 2019

Title: Rare Earth Arylsilazido Compounds with Inequivalent Secondary Interactions

Here, a new bulky silazido ligand, –N(SiHMe 2)Dipp (Dipp = C 6H 3-2,6- iPr 2) supports planar, three-coordinate homoleptic rare earth complexes Ln{N(SiHMe 2)Dipp} 3 (Ln = Sc, Y, Lu) that each contain three secondary Ln←HSi interactions and one agostic CH bond. Y{N(SiHMe 2)Dipp} 3 and acetophenone react via hydrosilylation, rather than by insertion into the Y–N bond or enolate formation.
Authors:
 [1] ;  [2] ;  [1] ;  [3] ;  [1] ;  [1]
  1. Ames Lab. and Iowa State Univ., Ames, IA (United States)
  2. Beijing Normal Univ., Beijing (People's Republic of China)
  3. Iowa State Univ., Ames, IA (United States)
Publication Date:
Report Number(s):
IS-J-9677
Journal ID: ISSN 1359-7345; CHCOFS
Grant/Contract Number:
AC02-07CH11358
Type:
Accepted Manuscript
Journal Name:
ChemComm
Additional Journal Information:
Journal Name: ChemComm; Journal ID: ISSN 1359-7345
Publisher:
Royal Society of Chemistry
Research Org:
Ames Laboratory (AMES), Ames, IA (United States)
Sponsoring Org:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
OSTI Identifier:
1441001
Alternate Identifier(s):
OSTI ID: 1454335