Reaction rates and prediction of thermal instability during aluminum alloy 6061 dissolution

doi:10.1080/01496395.2017.1377245

Title: Reaction rates and prediction of thermal instability during aluminum alloy 6061 dissolution

Abstract

Here, chemical kinetics of dissolution of aluminum alloy 6061 was investigated for the processing of Pu-238 for deep space missions. The rate of dissolution was measured by the heat release and appeared to be controlled by the rate of release of Al(OH) ₄ ^– from the metal surface. Rates of reaction were measured from 273 to 365 K, giving an activation energy of 72 ± 13 kJ•(mol Al) ^–1 and a pre-exponential factor of 5 ± 3 × 10 ⁹ dm ³mol ^–1min ^–1. Minor alloying elements did not appear to affect the reaction kinetics. The average heat of dissolution was –360 ± 70 kJ•(mol NaAlO ₂) ^–1. When extrapolated to an infinitely dilute solution of aluminum, kJ•(mol NaAlO ₂) ^–1.

Authors:

McFarlane, J. ^[1]; DePaoli, D. W. ^[1]; Mattus, C. H. ^[1]

Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

Publication Date:: 2017-11-10

Research Org.:: Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

Sponsoring Org.:: USDOE

OSTI Identifier:: 1440837

Grant/Contract Number:: AC05-00OR22725

Resource Type:: Accepted Manuscript

Journal Name:: Separation Science and Technology

Additional Journal Information:: Journal Volume: 53; Journal Issue: 12; Journal ID: ISSN 0149-6395

Publisher:: Taylor & Francis

Country of Publication:: United States

Language:: English

Subject:: 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; Aluminum alloy 6061 dissolution; kinetics of aluminum dissolution; neptunium target cladding dissolution; plutonium-238 production

Citation Formats


                    McFarlane, J., DePaoli, D. W., and Mattus, C. H. Reaction rates and prediction of thermal instability during aluminum alloy 6061 dissolution.  United States: N. p., 2017. 
        Web.  doi:10.1080/01496395.2017.1377245.

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                    McFarlane, J., DePaoli, D. W., & Mattus, C. H. Reaction rates and prediction of thermal instability during aluminum alloy 6061 dissolution.  United States.  doi:10.1080/01496395.2017.1377245.

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                    McFarlane, J., DePaoli, D. W., and Mattus, C. H. Fri .  
        "Reaction rates and prediction of thermal instability during aluminum alloy 6061 dissolution".  United States.  doi:10.1080/01496395.2017.1377245.  https://www.osti.gov/servlets/purl/1440837.

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@article{osti_1440837,

  title        = {Reaction rates and prediction of thermal instability during aluminum alloy 6061 dissolution},

  author       = {McFarlane, J. and DePaoli, D. W. and Mattus, C. H.},

  abstractNote = {Here, chemical kinetics of dissolution of aluminum alloy 6061 was investigated for the processing of Pu-238 for deep space missions. The rate of dissolution was measured by the heat release and appeared to be controlled by the rate of release of Al(OH)4– from the metal surface. Rates of reaction were measured from 273 to 365 K, giving an activation energy of 72 ± 13 kJ•(mol Al)–1 and a pre-exponential factor of 5 ± 3 × 109 dm3mol–1min–1. Minor alloying elements did not appear to affect the reaction kinetics. The average heat of dissolution was –360 ± 70 kJ•(mol NaAlO2)–1. When extrapolated to an infinitely dilute solution of aluminum, kJ•(mol NaAlO2)–1.},

  doi          = {10.1080/01496395.2017.1377245},

  journal      = {Separation Science and Technology},

  number       = 12,

  volume       = 53,

  place        = {United States},

  year         = {2017},

  month        = {11}

}

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DOI: 10.1080/01496395.2017.1377245

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Title: Reaction rates and prediction of thermal instability during aluminum alloy 6061 dissolution

Abstract

Citation Formats

Transformations of γ-alumina in aqueous suspensions journal, April 2007

Heat capacities of aqueous sodium hydroxide/aluminate mixtures and prediction of the solubility constant of boehmite up to 300°C journal, April 2010

Participation of Aluminum Hydride in the Anodic Dissolution of Aluminum in Alkaline Solutions journal, January 2008

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Surface morphological changes of aluminium alloys in alkaline solution: journal, August 1999

Mechanism of electrochemical reactions at aluminium electrodes in NaOH solutions journal, May 1979

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The Most Probable Mechanism Function and Kinetic Parameters of Gibbsite Dissolution in NaOH journal, August 2010

Pretreatment of Aluminum Alloy 6060 by Selective Removal of Surface Intermetallics journal, July 2004

The mechanism of aluminium corrosion in alkaline solutions journal, September 1996

Volumetric Analysis of Sodium Aluminate Solutions journal, June 1953

Aluminum speciation and equilibria in aqueous solution: I. The solubility of gibbsite in the system Na-K-Cl-OH-Al(OH)4 from 0 to 100°C journal, March 1992

The Dissolution of Aluminum in Sodium Hydroxide Solutions journal, January 1948

Formation of Aluminum Hydride during Alkaline Dissolution of Aluminum journal, January 2008

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Corrosion behaviour of aluminium in NaOH solutions journal, December 1979

Modeling the Heat Capacities of Aqueous 1−1 Electrolyte Solutions with Pitzer's Equations journal, January 1996

Application of the Radiotracer Technique for the Study of the Specific Anion Adsorption on Al2O3 in Acidic Medium journal, November 2000

In situ generation of hydrogen from water by aluminum corrosion in solutions of sodium aluminate journal, July 2009

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Thermodynamic model for equilibrium solubility of gibbsite in concentrated NaOH solutions journal, February 2012

Adsorption of sulfate and chloride ions on aluminum journal, June 1998

Experimental data on aluminum dissolution in KOH electrolytes journal, January 1991

Precipitation and Dissolution Reactions in a 6061 Aluminum Alloy journal, January 2000

Chemistry of soil minerals. Part VII. Synthesis, properties, and crystal structures of salt-filled cancrinites journal, January 1970

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Origins of pitting corrosion journal, March 2004

Thermal Explosion of Explosives and Propellants. A review journal, October 1981

Hydrogen Production from Waste Aluminum at Different Temperatures, with LCA journal, January 2005

Transformations of γ-alumina in aqueous suspensions
journal, April 2007

Heat capacities of aqueous sodium hydroxide/aluminate mixtures and prediction of the solubility constant of boehmite up to 300°C
journal, April 2010

Participation of Aluminum Hydride in the Anodic Dissolution of Aluminum in Alkaline Solutions
journal, January 2008

Inhibition of aluminium corrosion in alkaline solutions using natural compound
journal, June 2008

Corrosion of aluminium in perchloric acid in presence of various inorganic additives
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The Dissolution of Aluminum in Sodium Hydroxide Solutions. II
journal, January 1949

Surface morphological changes of aluminium alloys in alkaline solution:
journal, August 1999

Mechanism of electrochemical reactions at aluminium electrodes in NaOH solutions
journal, May 1979

Kinetics and mechanism of the heterogeneous reactions of γ-, χ-, and α- aluminas with aqueous sodium hydroxide solutions
journal, January 1970

The Most Probable Mechanism Function and Kinetic Parameters of Gibbsite Dissolution in NaOH
journal, August 2010

Pretreatment of Aluminum Alloy 6060 by Selective Removal of Surface Intermetallics
journal, July 2004

The mechanism of aluminium corrosion in alkaline solutions
journal, September 1996

Volumetric Analysis of Sodium Aluminate Solutions
journal, June 1953

Aluminum speciation and equilibria in aqueous solution: I. The solubility of gibbsite in the system Na-K-Cl-OH-Al(OH)4 from 0 to 100°C
journal, March 1992

The Dissolution of Aluminum in Sodium Hydroxide Solutions
journal, January 1948

Formation of Aluminum Hydride during Alkaline Dissolution of Aluminum
journal, January 2008

Hydrogen in aluminum during alkaline corrosion
journal, July 2010

Corrosion behaviour of aluminium in NaOH solutions
journal, December 1979

Modeling the Heat Capacities of Aqueous 1−1 Electrolyte Solutions with Pitzer's Equations
journal, January 1996

Application of the Radiotracer Technique for the Study of the Specific Anion Adsorption on Al2O3 in Acidic Medium
journal, November 2000

In situ generation of hydrogen from water by aluminum corrosion in solutions of sodium aluminate
journal, July 2009

Heat capacities of aqueous solutions of sodium hydroxide and water ionization up to 300°C at 10MPa
journal, July 2008

Thermodynamic model for equilibrium solubility of gibbsite in concentrated NaOH solutions
journal, February 2012

Adsorption of sulfate and chloride ions on aluminum
journal, June 1998

Experimental data on aluminum dissolution in KOH electrolytes
journal, January 1991

Precipitation and Dissolution Reactions in a 6061 Aluminum Alloy
journal, January 2000

Chemistry of soil minerals. Part VII. Synthesis, properties, and crystal structures of salt-filled cancrinites
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journal, March 2004

Thermal Explosion of Explosives and Propellants. A review
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Hydrogen Production from Waste Aluminum at Different Temperatures, with LCA
journal, January 2005