Increasing spin crossover cooperativity in 2D Hofmann-type materials with guest molecule removal

Zenere, Katrina A.; Duyker, Samuel G.; Trzop, Elzbieta; Collet, Eric; Chan, Bun; Doheny, Patrick W.; Kepert, Cameron J.; Neville, Suzanne M.

doi:10.1039/C8SC01040D

Title: Increasing spin crossover cooperativity in 2D Hofmann-type materials with guest molecule removal

Abstract

Ambient temperature spin crossover with wide hysteresis has been achieved in 2D Hofmann-type materials, where removal of guest molecules optimises ligand–ligand interactions, resulting in increased cooperativity.

Authors:

^[1]; Duyker, Samuel G. ^[1]; Trzop, Elzbieta ^[2]; Collet, Eric ^[2];

^[3];

^[1]; Kepert, Cameron J. ^[1]; Neville, Suzanne M. ^[4]

School of Chemistry, The University of Sydney, Sydney, Australia
Univ Rennes, CNRS, IPR (Institut de Physique de Rennes) – UMR 6251, F-35000 Rennes, France
Graduate School of Engineering, Nagasaki University, Nagasaki-shi Nagasaki 852-8521, Japan
School of Chemistry, The University of Sydney, Sydney, Australia, School of Chemistry

Publication Date:: Mon Jan 01 00:00:00 EST 2018

Sponsoring Org.:: USDOE

OSTI Identifier:: 1440796

Grant/Contract Number:: AC02-06CH11357

Resource Type:: Published Article

Journal Name:: Chemical Science

Additional Journal Information:: Journal Name: Chemical Science Journal Volume: 9 Journal Issue: 25; Journal ID: ISSN 2041-6520

Publisher:: Royal Society of Chemistry (RSC)

Country of Publication:: United Kingdom

Language:: English

Citation Formats


                    Zenere, Katrina A., Duyker, Samuel G., Trzop, Elzbieta, Collet, Eric, Chan, Bun, Doheny, Patrick W., Kepert, Cameron J., and Neville, Suzanne M. Increasing spin crossover cooperativity in 2D Hofmann-type materials with guest molecule removal.  United Kingdom: N. p., 2018. 
Web.  doi:10.1039/C8SC01040D.

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                    Zenere, Katrina A., Duyker, Samuel G., Trzop, Elzbieta, Collet, Eric, Chan, Bun, Doheny, Patrick W., Kepert, Cameron J., & Neville, Suzanne M. Increasing spin crossover cooperativity in 2D Hofmann-type materials with guest molecule removal.  United Kingdom.  https://doi.org/10.1039/C8SC01040D

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                    Zenere, Katrina A., Duyker, Samuel G., Trzop, Elzbieta, Collet, Eric, Chan, Bun, Doheny, Patrick W., Kepert, Cameron J., and Neville, Suzanne M. Mon .  
"Increasing spin crossover cooperativity in 2D Hofmann-type materials with guest molecule removal".  United Kingdom.  https://doi.org/10.1039/C8SC01040D.

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@article{osti_1440796,

  title        = {Increasing spin crossover cooperativity in 2D Hofmann-type materials with guest molecule removal},

  author       = {Zenere, Katrina A. and Duyker, Samuel G. and Trzop, Elzbieta and Collet, Eric and Chan, Bun and Doheny, Patrick W. and Kepert, Cameron J. and Neville, Suzanne M.},

  abstractNote = {Ambient temperature spin crossover with wide hysteresis has been achieved in 2D Hofmann-type materials, where removal of guest molecules optimises ligand–ligand interactions, resulting in increased cooperativity.},

  doi          = {10.1039/C8SC01040D},

  journal      = {Chemical Science},

  number       = 25,

  volume       = 9,

  place        = {United Kingdom},

  year         = {Mon Jan 01 00:00:00 EST 2018},

  month        = {Mon Jan 01 00:00:00 EST 2018}

}

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Similar Records

Title: Increasing spin crossover cooperativity in 2D Hofmann-type materials with guest molecule removal

Abstract

Citation Formats

First Step Towards a Devil's Staircase in Spin-Crossover Materials journal, May 2016

Neutral Molecular Iron(II) Complexes Showing Tunable Bistability at Above, Below, and Just Room Temperature by a Crystal Engineering Approach: Ligand Mobility into a Three-Dimensional Flexible Supramolecular Network journal, October 2017

Elastic Frustration Causing Two-Step and Multistep Transitions in Spin-Crossover Solids: Emergence of Complex Antiferroelastic Structures journal, February 2016

Triazole-Based One-Dimensional Spin-Crossover Coordination Polymers journal, November 2012

Spin-crossover Compounds with Wide Thermal Hysteresis journal, August 2014

Spin state switching in iron coordination compounds journal, January 2013

Non-isothermal kinetics of spin crossover journal, January 2017

Heterometallic Fe III /K Coordination Polymer with a Wide Thermal Hysteretic Spin Transition at Room Temperature journal, November 2015

Iron( ii ) spin crossover complexes with diaminonaphthalene-based Schiff base-like ligands: 1D coordination polymers journal, January 2016

Dynamic molecular crystals with switchable physical properties journal, June 2016

Influence of Hydrogen Bonding on the Hysteresis Width in Iron(II) Spin-Crossover Complexes journal, June 2011

Thermal spin-crossover with a large hysteresis spanning room temperature in a mononuclear complex journal, January 2017

Guest Tunable Structure and Spin Crossover Properties in a Nanoporous Coordination Framework Material journal, September 2009

Dynamic Interplay between Spin-Crossover and Host−Guest Function in a Nanoporous Metal−Organic Framework Material journal, August 2009

Spin Transition Molecular Materials for displays and data recording journal, November 1992

Four-step iron( ii ) spin state cascade driven by antagonistic solid state interactions journal, January 2017

Spin crossover with thermal hysteresis: practicalities and lessons learnt journal, January 2015

Solvent modified spin crossover in an iron( iii ) complex: phase changes and an exceptionally wide hysteresis journal, January 2017

Elastic Frustration Triggering Photoinduced Hidden Hysteresis and Multistability in a Two-Dimensional Photoswitchable Hofmann-Like Spin-Crossover Metal–Organic Framework journal, July 2016

An iron( ii ) complex exhibiting five anhydrous phases, two of which interconvert by spin-crossover with wide hysteresis journal, January 2012

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Symmetry Breaking in Iron(II) Spin-Crossover Molecular Crystals journal, March 2016

Controlling charge separation in a novel donor–acceptor metal–organic framework via redox modulation journal, January 2014

Molecular spin crossover phenomenon: recent achievements and prospects journal, January 2011

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Large Thermal Hysteresis for Iron(II) Spin Crossover Complexes with N -(Pyrid-4-yl)isonicotinamide journal, October 2014

Recent advances in guest effects on spin-crossover behavior in Hofmann-type metal-organic frameworks journal, March 2017

Guest Programmable Multistep Spin Crossover in a Porous 2-D Hofmann-Type Material journal, January 2017

Ordering phenomena of high-spin/low-spin states in stepwise spin-crossover materials described by the ANNNI model journal, January 2016

The 1-D polymeric structure of the [Fe(NH2trz)3](NO3)2·nH2O (with n = 2) spin crossover compound proven by single crystal investigations journal, January 2011

Spin-Crossover Iron(II) Coordination Polymer with Fluorescent Properties: Correlation between Emission Properties and Spin State journal, January 2018

Symmetry-breaking structural phase transitions in spin crossover complexes journal, April 2015

An Iron(II) Spin-Crossover Complex with a 70 K Wide Thermal Hysteresis Loop journal, December 2008

Fe II Spin Transition Materials Including an Amino–Ester 1,2,4-Triazole Derivative, Operating at, below, and above Room Temperature journal, April 2016

Hysteretic Four-Step Spin Crossover within a Three-Dimensional Porous Hofmann-like Material journal, October 2016

Pressure and Temperature Spin Crossover Sensors with Optical Detection journal, April 2012

Strong Cooperative Spin Crossover in 2D and 3D Fe II –M I,II Hofmann-Like Coordination Polymers Based on 2-Fluoropyrazine journal, September 2016

Exploiting Pressure To Induce a “Guest-Blocked” Spin Transition in a Framework Material journal, September 2016

Synergetic Effect of Host-Guest Chemistry and Spin Crossover in 3D Hofmann-like Metal-Organic Frameworks [Fe(bpac)M(CN)4] (M=Pt, Pd, Ni) journal, December 2011

Emerging properties and applications of spin crossover nanomaterials journal, January 2014

First Step Towards a Devil's Staircase in Spin-Crossover Materials
journal, May 2016

Neutral Molecular Iron(II) Complexes Showing Tunable Bistability at Above, Below, and Just Room Temperature by a Crystal Engineering Approach: Ligand Mobility into a Three-Dimensional Flexible Supramolecular Network
journal, October 2017

Elastic Frustration Causing Two-Step and Multistep Transitions in Spin-Crossover Solids: Emergence of Complex Antiferroelastic Structures
journal, February 2016

Triazole-Based One-Dimensional Spin-Crossover Coordination Polymers
journal, November 2012

Spin-crossover Compounds with Wide Thermal Hysteresis
journal, August 2014

Spin state switching in iron coordination compounds
journal, January 2013

Non-isothermal kinetics of spin crossover
journal, January 2017

Heterometallic Fe ^III /K Coordination Polymer with a Wide Thermal Hysteretic Spin Transition at Room Temperature
journal, November 2015

Iron( ii ) spin crossover complexes with diaminonaphthalene-based Schiff base-like ligands: 1D coordination polymers
journal, January 2016

Dynamic molecular crystals with switchable physical properties
journal, June 2016

Influence of Hydrogen Bonding on the Hysteresis Width in Iron(II) Spin-Crossover Complexes
journal, June 2011

Thermal spin-crossover with a large hysteresis spanning room temperature in a mononuclear complex
journal, January 2017

Guest Tunable Structure and Spin Crossover Properties in a Nanoporous Coordination Framework Material
journal, September 2009

Dynamic Interplay between Spin-Crossover and Host−Guest Function in a Nanoporous Metal−Organic Framework Material
journal, August 2009

Spin Transition Molecular Materials for displays and data recording
journal, November 1992

Four-step iron( ii ) spin state cascade driven by antagonistic solid state interactions
journal, January 2017

Spin crossover with thermal hysteresis: practicalities and lessons learnt
journal, January 2015

Solvent modified spin crossover in an iron( iii ) complex: phase changes and an exceptionally wide hysteresis
journal, January 2017

Elastic Frustration Triggering Photoinduced Hidden Hysteresis and Multistability in a Two-Dimensional Photoswitchable Hofmann-Like Spin-Crossover Metal–Organic Framework
journal, July 2016

An iron( ii ) complex exhibiting five anhydrous phases, two of which interconvert by spin-crossover with wide hysteresis
journal, January 2012

Enhanced bistability by guest inclusion in Fe(ii) spin crossover porous coordination polymers
journal, January 2012

Symmetry Breaking in Iron(II) Spin-Crossover Molecular Crystals
journal, March 2016

Controlling charge separation in a novel donor–acceptor metal–organic framework via redox modulation
journal, January 2014

Molecular spin crossover phenomenon: recent achievements and prospects
journal, January 2011

Structure:function relationships in molecular spin-crossover complexes
journal, January 2011

Large Thermal Hysteresis for Iron(II) Spin Crossover Complexes with N -(Pyrid-4-yl)isonicotinamide
journal, October 2014

Recent advances in guest effects on spin-crossover behavior in Hofmann-type metal-organic frameworks
journal, March 2017

Guest Programmable Multistep Spin Crossover in a Porous 2-D Hofmann-Type Material
journal, January 2017

Ordering phenomena of high-spin/low-spin states in stepwise spin-crossover materials described by the ANNNI model
journal, January 2016

The 1-D polymeric structure of the [Fe(NH2trz)3](NO3)2·nH2O (with n = 2) spin crossover compound proven by single crystal investigations
journal, January 2011

Spin-Crossover Iron(II) Coordination Polymer with Fluorescent Properties: Correlation between Emission Properties and Spin State
journal, January 2018

Symmetry-breaking structural phase transitions in spin crossover complexes
journal, April 2015

An Iron(II) Spin-Crossover Complex with a 70 K Wide Thermal Hysteresis Loop
journal, December 2008

Fe ^II Spin Transition Materials Including an Amino–Ester 1,2,4-Triazole Derivative, Operating at, below, and above Room Temperature
journal, April 2016

Hysteretic Four-Step Spin Crossover within a Three-Dimensional Porous Hofmann-like Material
journal, October 2016

Pressure and Temperature Spin Crossover Sensors with Optical Detection
journal, April 2012

Strong Cooperative Spin Crossover in 2D and 3D Fe ^II –M ^I,II Hofmann-Like Coordination Polymers Based on 2-Fluoropyrazine
journal, September 2016

Exploiting Pressure To Induce a “Guest-Blocked” Spin Transition in a Framework Material
journal, September 2016

Synergetic Effect of Host-Guest Chemistry and Spin Crossover in 3D Hofmann-like Metal-Organic Frameworks [Fe(bpac)M(CN)4] (M=Pt, Pd, Ni)
journal, December 2011

Emerging properties and applications of spin crossover nanomaterials
journal, January 2014