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Title: Increasing spin crossover cooperativity in 2D Hofmann-type materials with guest molecule removal

Abstract

Ambient temperature spin crossover with wide hysteresis has been achieved in 2D Hofmann-type materials, where removal of guest molecules optimises ligand–ligand interactions, resulting in increased cooperativity.

Authors:
ORCiD logo [1];  [1];  [2];  [2]; ORCiD logo [3]; ORCiD logo [1];  [1];  [4]
  1. School of Chemistry, The University of Sydney, Sydney, Australia
  2. Univ Rennes, CNRS, IPR (Institut de Physique de Rennes) – UMR 6251, F-35000 Rennes, France
  3. Graduate School of Engineering, Nagasaki University, Nagasaki-shi Nagasaki 852-8521, Japan
  4. School of Chemistry, The University of Sydney, Sydney, Australia, School of Chemistry
Publication Date:
Sponsoring Org.:
USDOE
OSTI Identifier:
1440796
Grant/Contract Number:  
AC02-06CH11357
Resource Type:
Published Article
Journal Name:
Chemical Science
Additional Journal Information:
Journal Name: Chemical Science Journal Volume: 9 Journal Issue: 25; Journal ID: ISSN 2041-6520
Publisher:
Royal Society of Chemistry (RSC)
Country of Publication:
United Kingdom
Language:
English

Citation Formats

Zenere, Katrina A., Duyker, Samuel G., Trzop, Elzbieta, Collet, Eric, Chan, Bun, Doheny, Patrick W., Kepert, Cameron J., and Neville, Suzanne M. Increasing spin crossover cooperativity in 2D Hofmann-type materials with guest molecule removal. United Kingdom: N. p., 2018. Web. doi:10.1039/C8SC01040D.
Zenere, Katrina A., Duyker, Samuel G., Trzop, Elzbieta, Collet, Eric, Chan, Bun, Doheny, Patrick W., Kepert, Cameron J., & Neville, Suzanne M. Increasing spin crossover cooperativity in 2D Hofmann-type materials with guest molecule removal. United Kingdom. doi:10.1039/C8SC01040D.
Zenere, Katrina A., Duyker, Samuel G., Trzop, Elzbieta, Collet, Eric, Chan, Bun, Doheny, Patrick W., Kepert, Cameron J., and Neville, Suzanne M. Mon . "Increasing spin crossover cooperativity in 2D Hofmann-type materials with guest molecule removal". United Kingdom. doi:10.1039/C8SC01040D.
@article{osti_1440796,
title = {Increasing spin crossover cooperativity in 2D Hofmann-type materials with guest molecule removal},
author = {Zenere, Katrina A. and Duyker, Samuel G. and Trzop, Elzbieta and Collet, Eric and Chan, Bun and Doheny, Patrick W. and Kepert, Cameron J. and Neville, Suzanne M.},
abstractNote = {Ambient temperature spin crossover with wide hysteresis has been achieved in 2D Hofmann-type materials, where removal of guest molecules optimises ligand–ligand interactions, resulting in increased cooperativity.},
doi = {10.1039/C8SC01040D},
journal = {Chemical Science},
number = 25,
volume = 9,
place = {United Kingdom},
year = {2018},
month = {1}
}

Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record
DOI: 10.1039/C8SC01040D

Citation Metrics:
Cited by: 7 works
Citation information provided by
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Works referenced in this record:

First Step Towards a Devil's Staircase in Spin-Crossover Materials
journal, May 2016

  • Trzop, Elzbieta; Zhang, Daopeng; Piñeiro-Lopez, Lucia
  • Angewandte Chemie International Edition, Vol. 55, Issue 30
  • DOI: 10.1002/anie.201602441

Elastic Frustration Causing Two-Step and Multistep Transitions in Spin-Crossover Solids: Emergence of Complex Antiferroelastic Structures
journal, February 2016

  • Paez-Espejo, Miguel; Sy, Mouhamadou; Boukheddaden, Kamel
  • Journal of the American Chemical Society, Vol. 138, Issue 9
  • DOI: 10.1021/jacs.6b00049

Triazole-Based One-Dimensional Spin-Crossover Coordination Polymers
journal, November 2012


Spin-crossover Compounds with Wide Thermal Hysteresis
journal, August 2014


Spin state switching in iron coordination compounds
journal, January 2013

  • Gütlich, Philipp; Gaspar, Ana B.; Garcia, Yann
  • Beilstein Journal of Organic Chemistry, Vol. 9
  • DOI: 10.3762/bjoc.9.39

Non-isothermal kinetics of spin crossover
journal, January 2017

  • Bushuev, Mark B.; Nikolaenkova, Elena B.; Krivopalov, Viktor P.
  • Physical Chemistry Chemical Physics, Vol. 19, Issue 26
  • DOI: 10.1039/C7CP03442C

Heterometallic Fe III /K Coordination Polymer with a Wide Thermal Hysteretic Spin Transition at Room Temperature
journal, November 2015

  • Kang, Soonchul; Shiota, Yoshihito; Kariyazaki, Akira
  • Chemistry - A European Journal, Vol. 22, Issue 2
  • DOI: 10.1002/chem.201503392

Iron( ii ) spin crossover complexes with diaminonaphthalene-based Schiff base-like ligands: 1D coordination polymers
journal, January 2016

  • Lochenie, Charles; Gebauer, Andreas; Klimm, Ottokar
  • New Journal of Chemistry, Vol. 40, Issue 5
  • DOI: 10.1039/C5NJ02470F

Dynamic molecular crystals with switchable physical properties
journal, June 2016


Influence of Hydrogen Bonding on the Hysteresis Width in Iron(II) Spin-Crossover Complexes
journal, June 2011

  • Weber, Birgit; Bauer, Wolfgang; Pfaffeneder, Toni
  • European Journal of Inorganic Chemistry, Vol. 2011, Issue 21
  • DOI: 10.1002/ejic.201100394

Thermal spin-crossover with a large hysteresis spanning room temperature in a mononuclear complex
journal, January 2017

  • Tailleur, E.; Marchivie, M.; Daro, N.
  • Chemical Communications, Vol. 53, Issue 35
  • DOI: 10.1039/C7CC01806A

Guest Tunable Structure and Spin Crossover Properties in a Nanoporous Coordination Framework Material
journal, September 2009

  • Neville, Suzanne M.; Halder, Gregory J.; Chapman, Karena W.
  • Journal of the American Chemical Society, Vol. 131, Issue 34
  • DOI: 10.1021/ja905360g

Dynamic Interplay between Spin-Crossover and Host−Guest Function in a Nanoporous Metal−Organic Framework Material
journal, August 2009

  • Southon, Peter D.; Liu, Lang; Fellows, Elizabeth A.
  • Journal of the American Chemical Society, Vol. 131, Issue 31
  • DOI: 10.1021/ja902187d

Spin Transition Molecular Materials for displays and data recording
journal, November 1992


Four-step iron( ii ) spin state cascade driven by antagonistic solid state interactions
journal, January 2017

  • Sciortino, Natasha F.; Zenere, Katrina A.; Corrigan, Maggie E.
  • Chemical Science, Vol. 8, Issue 1
  • DOI: 10.1039/C6SC03114E

Spin crossover with thermal hysteresis: practicalities and lessons learnt
journal, January 2015


Solvent modified spin crossover in an iron( iii ) complex: phase changes and an exceptionally wide hysteresis
journal, January 2017

  • Phonsri, Wasinee; Harding, Phimphaka; Liu, Lujia
  • Chemical Science, Vol. 8, Issue 5
  • DOI: 10.1039/C6SC05317C

An iron( ii ) complex exhibiting five anhydrous phases, two of which interconvert by spin-crossover with wide hysteresis
journal, January 2012

  • Roberts, Thomas D.; Tuna, Floriana; Malkin, Tamsin L.
  • Chem. Sci., Vol. 3, Issue 2
  • DOI: 10.1039/C1SC00584G

Enhanced bistability by guest inclusion in Fe(ii) spin crossover porous coordination polymers
journal, January 2012

  • Muñoz Lara, Francisco J.; Gaspar, Ana B.; Aravena, Daniel
  • Chemical Communications, Vol. 48, Issue 39
  • DOI: 10.1039/c2cc31048a

Symmetry Breaking in Iron(II) Spin-Crossover Molecular Crystals
journal, March 2016


Controlling charge separation in a novel donor–acceptor metal–organic framework via redox modulation
journal, January 2014

  • Leong, C. F.; Chan, B.; Faust, T. B.
  • Chem. Sci., Vol. 5, Issue 12
  • DOI: 10.1039/C4SC01551G

Molecular spin crossover phenomenon: recent achievements and prospects
journal, January 2011

  • Bousseksou, Azzedine; Molnár, Gábor; Salmon, Lionel
  • Chemical Society Reviews, Vol. 40, Issue 6
  • DOI: 10.1039/c1cs15042a

Structure:function relationships in molecular spin-crossover complexes
journal, January 2011


Large Thermal Hysteresis for Iron(II) Spin Crossover Complexes with N -(Pyrid-4-yl)isonicotinamide
journal, October 2014

  • Lochenie, Charles; Bauer, Wolfgang; Railliet, Antoine P.
  • Inorganic Chemistry, Vol. 53, Issue 21
  • DOI: 10.1021/ic501624b

Recent advances in guest effects on spin-crossover behavior in Hofmann-type metal-organic frameworks
journal, March 2017


Guest Programmable Multistep Spin Crossover in a Porous 2-D Hofmann-Type Material
journal, January 2017

  • Murphy, Michael J.; Zenere, Katrina A.; Ragon, Florence
  • Journal of the American Chemical Society, Vol. 139, Issue 3
  • DOI: 10.1021/jacs.6b12465

Ordering phenomena of high-spin/low-spin states in stepwise spin-crossover materials described by the ANNNI model
journal, January 2016


The 1-D polymeric structure of the [Fe(NH2trz)3](NO3)2·nH2O (with n = 2) spin crossover compound proven by single crystal investigations
journal, January 2011

  • Grosjean, Arnaud; Daro, Nathalie; Kauffmann, Brice
  • Chemical Communications, Vol. 47, Issue 45
  • DOI: 10.1039/c1cc14220h

Spin-Crossover Iron(II) Coordination Polymer with Fluorescent Properties: Correlation between Emission Properties and Spin State
journal, January 2018

  • Lochenie, Charles; Schötz, Konstantin; Panzer, Fabian
  • Journal of the American Chemical Society, Vol. 140, Issue 2
  • DOI: 10.1021/jacs.7b10571

Symmetry-breaking structural phase transitions in spin crossover complexes
journal, April 2015

  • Shatruk, Michael; Phan, Hoa; Chrisostomo, Bruno A.
  • Coordination Chemistry Reviews, Vol. 289-290
  • DOI: 10.1016/j.ccr.2014.09.018

An Iron(II) Spin-Crossover Complex with a 70 K Wide Thermal Hysteresis Loop
journal, December 2008

  • Weber, Birgit; Bauer, Wolfgang; Obel, Jaroslava
  • Angewandte Chemie International Edition, Vol. 47, Issue 52
  • DOI: 10.1002/anie.200802806

Fe II Spin Transition Materials Including an Amino–Ester 1,2,4-Triazole Derivative, Operating at, below, and above Room Temperature
journal, April 2016


Hysteretic Four-Step Spin Crossover within a Three-Dimensional Porous Hofmann-like Material
journal, October 2016

  • Clements, John E.; Price, Jason R.; Neville, Suzanne M.
  • Angewandte Chemie International Edition, Vol. 55, Issue 48
  • DOI: 10.1002/anie.201605418

Pressure and Temperature Spin Crossover Sensors with Optical Detection
journal, April 2012

  • Linares, Jorge; Codjovi, Epiphane; Garcia, Yann
  • Sensors, Vol. 12, Issue 4
  • DOI: 10.3390/s120404479

Strong Cooperative Spin Crossover in 2D and 3D Fe II –M I,II Hofmann-Like Coordination Polymers Based on 2-Fluoropyrazine
journal, September 2016

  • Valverde-Muñoz, Francisco Javier; Seredyuk, Maksym; Muñoz, M. Carmen
  • Inorganic Chemistry, Vol. 55, Issue 20
  • DOI: 10.1021/acs.inorgchem.6b01901

Exploiting Pressure To Induce a “Guest-Blocked” Spin Transition in a Framework Material
journal, September 2016


Synergetic Effect of Host-Guest Chemistry and Spin Crossover in 3D Hofmann-like Metal-Organic Frameworks [Fe(bpac)M(CN)4] (M=Pt, Pd, Ni)
journal, December 2011

  • Bartual-Murgui, Carlos; Salmon, Lionel; Akou, Amal
  • Chemistry - A European Journal, Vol. 18, Issue 2
  • DOI: 10.1002/chem.201102357

Emerging properties and applications of spin crossover nanomaterials
journal, January 2014

  • Molnár, Gábor; Salmon, Lionel; Nicolazzi, William
  • J. Mater. Chem. C, Vol. 2, Issue 8
  • DOI: 10.1039/C3TC31750A