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Title: Increasing spin crossover cooperativity in 2D Hofmann-type materials with guest molecule removal

Ambient temperature spin crossover with wide hysteresis has been achieved in 2D Hofmann-type materials, where removal of guest molecules optimises ligand–ligand interactions, resulting in increased cooperativity.
Authors:
ORCiD logo [1] ;  [1] ;  [2] ;  [2] ; ORCiD logo [3] ; ORCiD logo [1] ;  [1] ;  [4]
  1. School of Chemistry, The University of Sydney, Sydney, Australia
  2. Univ Rennes, CNRS, IPR (Institut de Physique de Rennes) – UMR 6251, F-35000 Rennes, France
  3. Graduate School of Engineering, Nagasaki University, Nagasaki-shi Nagasaki 852-8521, Japan
  4. School of Chemistry, The University of Sydney, Sydney, Australia, School of Chemistry
Publication Date:
Grant/Contract Number:
AC02-06CH11357
Type:
Published Article
Journal Name:
Chemical Science
Additional Journal Information:
Journal Name: Chemical Science Journal Volume: 9 Journal Issue: 25; Journal ID: ISSN 2041-6520
Publisher:
Royal Society of Chemistry (RSC)
Sponsoring Org:
USDOE
Country of Publication:
United Kingdom
Language:
English
OSTI Identifier:
1440796

Zenere, Katrina A., Duyker, Samuel G., Trzop, Elzbieta, Collet, Eric, Chan, Bun, Doheny, Patrick W., Kepert, Cameron J., and Neville, Suzanne M.. Increasing spin crossover cooperativity in 2D Hofmann-type materials with guest molecule removal. United Kingdom: N. p., Web. doi:10.1039/C8SC01040D.
Zenere, Katrina A., Duyker, Samuel G., Trzop, Elzbieta, Collet, Eric, Chan, Bun, Doheny, Patrick W., Kepert, Cameron J., & Neville, Suzanne M.. Increasing spin crossover cooperativity in 2D Hofmann-type materials with guest molecule removal. United Kingdom. doi:10.1039/C8SC01040D.
Zenere, Katrina A., Duyker, Samuel G., Trzop, Elzbieta, Collet, Eric, Chan, Bun, Doheny, Patrick W., Kepert, Cameron J., and Neville, Suzanne M.. 2018. "Increasing spin crossover cooperativity in 2D Hofmann-type materials with guest molecule removal". United Kingdom. doi:10.1039/C8SC01040D.
@article{osti_1440796,
title = {Increasing spin crossover cooperativity in 2D Hofmann-type materials with guest molecule removal},
author = {Zenere, Katrina A. and Duyker, Samuel G. and Trzop, Elzbieta and Collet, Eric and Chan, Bun and Doheny, Patrick W. and Kepert, Cameron J. and Neville, Suzanne M.},
abstractNote = {Ambient temperature spin crossover with wide hysteresis has been achieved in 2D Hofmann-type materials, where removal of guest molecules optimises ligand–ligand interactions, resulting in increased cooperativity.},
doi = {10.1039/C8SC01040D},
journal = {Chemical Science},
number = 25,
volume = 9,
place = {United Kingdom},
year = {2018},
month = {1}
}