DOE PAGES title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Gas adsorption in an isostructural series of pillared coordination cages

Abstract

The synthesis and characterization of two novel pillared coordination cages is reported.

Authors:
 [1];  [1]; ORCiD logo [2]; ORCiD logo [3]; ORCiD logo [1]
  1. Department of Chemistry & Biochemistry, University of Delaware, Newark, DE 19716, USA, Center for Neutron Science, Department of Chemical and Biomolecular Engineering, University of Delaware, Newark, DE 19716, USA
  2. Center for Neutron Research, National Institute of Standards and Technology, Gaithersburg, MD 20899, USA
  3. Center for Neutron Research, National Institute of Standards and Technology, Gaithersburg, MD 20899, USA, Department of Chemical and Biomolecular Engineering, University of Delaware, Newark, DE 19716, USA
Publication Date:
Sponsoring Org.:
USDOE
OSTI Identifier:
1440792
Resource Type:
Publisher's Accepted Manuscript
Journal Name:
ChemComm
Additional Journal Information:
Journal Name: ChemComm Journal Volume: 54 Journal Issue: 49; Journal ID: ISSN 1359-7345
Publisher:
Royal Society of Chemistry (RSC)
Country of Publication:
United Kingdom
Language:
English

Citation Formats

Gosselin, Aeri J., Lorzing, Gregory R., Trump, Benjamin A., Brown, Craig M., and Bloch, Eric D. Gas adsorption in an isostructural series of pillared coordination cages. United Kingdom: N. p., 2018. Web. doi:10.1039/C8CC03216E.
Gosselin, Aeri J., Lorzing, Gregory R., Trump, Benjamin A., Brown, Craig M., & Bloch, Eric D. Gas adsorption in an isostructural series of pillared coordination cages. United Kingdom. https://doi.org/10.1039/C8CC03216E
Gosselin, Aeri J., Lorzing, Gregory R., Trump, Benjamin A., Brown, Craig M., and Bloch, Eric D. Thu . "Gas adsorption in an isostructural series of pillared coordination cages". United Kingdom. https://doi.org/10.1039/C8CC03216E.
@article{osti_1440792,
title = {Gas adsorption in an isostructural series of pillared coordination cages},
author = {Gosselin, Aeri J. and Lorzing, Gregory R. and Trump, Benjamin A. and Brown, Craig M. and Bloch, Eric D.},
abstractNote = {The synthesis and characterization of two novel pillared coordination cages is reported.},
doi = {10.1039/C8CC03216E},
journal = {ChemComm},
number = 49,
volume = 54,
place = {United Kingdom},
year = {Thu Jun 14 00:00:00 EDT 2018},
month = {Thu Jun 14 00:00:00 EDT 2018}
}

Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record
https://doi.org/10.1039/C8CC03216E

Citation Metrics:
Cited by: 17 works
Citation information provided by
Web of Science

Save / Share:

Works referenced in this record:

A Chemically Functionalizable Nanoporous Material [Cu3(TMA)2(H2O)3]n
journal, February 1999


Chromium(II) Metal–Organic Polyhedra as Highly Porous Materials
journal, August 2017

  • Park, Jinhee; Perry, Zachary; Chen, Ying-Pin
  • ACS Applied Materials & Interfaces, Vol. 9, Issue 33
  • DOI: 10.1021/acsami.7b09339

Microporous Mixed-Metal Layer-Pillared [Zn1-xCux(bdc)(dabco)0.5] MOFs: Preparation and Characterization
journal, February 2012

  • Kozachuk, Olesia; Khaletskaya, Kira; Halbherr, Markus
  • European Journal of Inorganic Chemistry, Vol. 2012, Issue 10
  • DOI: 10.1002/ejic.201101295

Low-Level Self-Assembly of Open Framework Based on Three Different Polyhedra:  Metal-Organic Analogue of Face-Centered Cubic Dodecaboride
journal, January 2008

  • Chun, Hyungphil
  • Journal of the American Chemical Society, Vol. 130, Issue 3
  • DOI: 10.1021/ja0776778

Methane storage mechanism in the metal-organic framework Cu3(btc)2: An in situ neutron diffraction study
journal, December 2010


Hetero-bimetallic metal–organic polyhedra
journal, January 2016

  • Teo, Jesse M.; Coghlan, Campbell J.; Evans, Jack D.
  • Chemical Communications, Vol. 52, Issue 2
  • DOI: 10.1039/C5CC08336B

Effect of catenation and basicity of pillared ligands on the water stability of MOFs
journal, January 2013

  • Jasuja, Himanshu; Walton, Krista S.
  • Dalton Transactions, Vol. 42, Issue 43
  • DOI: 10.1039/c3dt51819a

A pressure-amplifying framework material with negative gas adsorption transitions
journal, April 2016

  • Krause, Simon; Bon, Volodymyr; Senkovska, Irena
  • Nature, Vol. 532, Issue 7599
  • DOI: 10.1038/nature17430

Flexible metal–organic frameworks
journal, January 2014

  • Schneemann, A.; Bon, V.; Schwedler, I.
  • Chem. Soc. Rev., Vol. 43, Issue 16
  • DOI: 10.1039/C4CS00101J

Trends in the Adsorption of Volatile Organic Compounds in a Large-Pore Metal−Organic Framework, IRMOF-1
journal, July 2010

  • Luebbers, Matthew T.; Wu, Tianjiao; Shen, Lingjuan
  • Langmuir, Vol. 26, Issue 13
  • DOI: 10.1021/la100635r

Metal−Organic Frameworks with Functional Pores for Recognition of Small Molecules
journal, August 2010

  • Chen, Banglin; Xiang, Shengchang; Qian, Guodong
  • Accounts of Chemical Research, Vol. 43, Issue 8
  • DOI: 10.1021/ar100023y

Synthesis and Structure of Cuboctahedral and Anticuboctahedral Cages Containing 12 Quadruply Bonded Dimolybdenum Units
journal, June 2005

  • Ke, Yanxiong; Collins, David J.; Zhou, Hong-Cai
  • Inorganic Chemistry, Vol. 44, Issue 12
  • DOI: 10.1021/ic050460z

Metal–organic polyhedra constructed from dinuclear ruthenium paddlewheels
journal, January 2015


Systematic Design of Pore Size and Functionality in Isoreticular MOFs and Their Application in Methane Storage
journal, January 2002

  • Eddaoudi, Mohamed; Kim, Jaheon; Rosi, Nathaniel
  • Science, Vol. 295, Issue 5554, p. 469-472
  • DOI: 10.1126/science.1067208

Design, Synthesis, Structure, and Gas (N2, Ar, CO2, CH4, and H2) Sorption Properties of Porous Metal-Organic Tetrahedral and Heterocuboidal Polyhedra
journal, May 2005

  • Sudik, Andrea C.; Millward, Andrew R.; Ockwig, Nathan W.
  • Journal of the American Chemical Society, Vol. 127, Issue 19, p. 7110-7118
  • DOI: 10.1021/ja042802q

Stepwise assembly of metal–organic framework based on a metal–organic polyhedron precursor for drug delivery
journal, January 2011

  • Wang, Hai-Ning; Meng, Xing; Yang, Guang-Sheng
  • Chemical Communications, Vol. 47, Issue 25
  • DOI: 10.1039/c1cc11932j

Hybrid porous solids past, present, future
journal, January 2008

  • Férey, Gérard
  • Chem. Soc. Rev., Vol. 37, Issue 1, p. 191-214
  • DOI: 10.1039/B618320B

Reconciling the Discrepancies between Crystallographic Porosity and Guest Access As Exemplified by Zn-HKUST-1
journal, November 2011

  • Feldblyum, Jeremy I.; Liu, Ming; Gidley, David W.
  • Journal of the American Chemical Society, Vol. 133, Issue 45
  • DOI: 10.1021/ja2055935

Critical Factors Driving the High Volumetric Uptake of Methane in Cu 3 (btc) 2
journal, August 2015

  • Hulvey, Zeric; Vlaisavljevich, Bess; Mason, Jarad A.
  • Journal of the American Chemical Society, Vol. 137, Issue 33
  • DOI: 10.1021/jacs.5b06657

Direct Measurement of Adsorbed Gas Redistribution in Metal–Organic Frameworks
journal, February 2015

  • Chen, Ying-Pin; Liu, Yangyang; Liu, Dahuan
  • Journal of the American Chemical Society, Vol. 137, Issue 8
  • DOI: 10.1021/ja5103579

Isoreticular Metal-Organic Polyhedral Networks Based on 5-Connecting Paddlewheel Motifs
journal, March 2009

  • Chun, Hyungphil; Jung, Heejin; Seo, Jinwoo
  • Inorganic Chemistry, Vol. 48, Issue 5
  • DOI: 10.1021/ic801784j

A mesoporous metal–organic framework constructed from a nanosized C3-symmetric linker and [Cu24(isophthalate)24] cuboctahedra
journal, January 2011

  • Yan, Yong; Yang, Sihai; Blake, Alexander J.
  • Chemical Communications, Vol. 47, Issue 36
  • DOI: 10.1039/c1cc13170b

Exceptionally High Acetylene Uptake in a Microporous Metal−Organic Framework with Open Metal Sites
journal, September 2009

  • Xiang, Shengchang; Zhou, Wei; Gallegos, Jose M.
  • Journal of the American Chemical Society, Vol. 131, Issue 34
  • DOI: 10.1021/ja904782h

Designing Higher Surface Area Metal–Organic Frameworks: Are Triple Bonds Better Than Phenyls?
journal, June 2012

  • Farha, Omar K.; Wilmer, Christopher E.; Eryazici, Ibrahim
  • Journal of the American Chemical Society, Vol. 134, Issue 24
  • DOI: 10.1021/ja302623w

Iron and Porphyrin Metal–Organic Frameworks: Insight into Structural Diversity, Stability, and Porosity
journal, March 2015

  • Fateeva, Alexandra; Clarisse, Jade; Pilet, Guillaume
  • Crystal Growth & Design, Vol. 15, Issue 4
  • DOI: 10.1021/cg501855k

Freeze Drying Significantly Increases Permanent Porosity and Hydrogen Uptake in 4,4-Connected Metal–Organic Frameworks
journal, December 2009

  • Ma, Liqing; Jin, Athena; Xie, Zhigang
  • Angewandte Chemie International Edition, Vol. 48, Issue 52
  • DOI: 10.1002/anie.200904983

Rhodium–Organic Cuboctahedra as Porous Solids with Strong Binding Sites
journal, October 2016


Porous Metal–Organic Polyhedral Frameworks with Optimal Molecular Dynamics and Pore Geometry for Methane Storage
journal, September 2017

  • Yan, Yong; Kolokolov, Daniil I.; da Silva, Ivan
  • Journal of the American Chemical Society, Vol. 139, Issue 38
  • DOI: 10.1021/jacs.7b05453

Porous Metal−Organic Polyhedra:  25 Å Cuboctahedron Constructed from 12 Cu2(CO2)4 Paddle-Wheel Building Blocks
journal, May 2001

  • Eddaoudi, M.; Kim, Jaheon; Wachter, J. B.
  • Journal of the American Chemical Society, Vol. 123, Issue 18, p. 4368-4369
  • DOI: 10.1021/ja0104352

Three neutral metal–organic frameworks with micro- and meso-pores for adsorption and separation of dyes
journal, January 2013

  • Wang, Hai-Ning; Liu, Fu-Hong; Wang, Xin-Long
  • Journal of Materials Chemistry A, Vol. 1, Issue 42
  • DOI: 10.1039/c3ta13242k

Interaction of Small Gases with the Unsaturated Metal Centers of the HKUST-1 Metal Organic Framework
journal, July 2013

  • Supronowicz, Barbara; Mavrandonakis, Andreas; Heine, Thomas
  • The Journal of Physical Chemistry C, Vol. 117, Issue 28
  • DOI: 10.1021/jp4018037

Synthesis and properties of the metal-organic framework Mo3(BTC)2 (TUDMOF-1)
journal, January 2006

  • Kramer, Markus; Schwarz, Ulrich; Kaskel, Stefan
  • Journal of Materials Chemistry, Vol. 16, Issue 23
  • DOI: 10.1039/b601811d

Pressure-Responsive Curvature Change of a “Rigid” Geodesic Ligand in a (3,24)-Connected Mesoporous Metal–Organic Framework
journal, November 2011

  • Yuan, Daqiang; Zhao, Dan; Zhou, Hong-Cai
  • Inorganic Chemistry, Vol. 50, Issue 21
  • DOI: 10.1021/ic201744n

Functional Porous Coordination Polymers
journal, April 2004

  • Kitagawa, Susumu; Kitaura, Ryo; Noro, Shin-ichiro
  • Angewandte Chemie International Edition, Vol. 43, Issue 18, p. 2334-2375
  • DOI: 10.1002/anie.200300610

Bridging-ligand-substitution strategy for the preparation of metal–organic polyhedra
journal, August 2010

  • Li, Jian-Rong; Zhou, Hong-Cai
  • Nature Chemistry, Vol. 2, Issue 10
  • DOI: 10.1038/nchem.803

Ligand Bridging-Angle-Driven Assembly of Molecular Architectures Based on Quadruply Bonded Mo−Mo Dimers
journal, December 2010

  • Li, Jian-Rong; Yakovenko, Andrey A.; Lu, Weigang
  • Journal of the American Chemical Society, Vol. 132, Issue 49
  • DOI: 10.1021/ja1080794

Selective Gas Adsorption in Highly Porous Chromium(II)-Based Metal–Organic Polyhedra
journal, October 2017


Metal-Organic Frameworks with Exceptionally High Methane Uptake: Where and How is Methane Stored?
journal, March 2010

  • Wu, Hui; Simmons, Jason M.; Liu, Yun
  • Chemistry - A European Journal, Vol. 16, Issue 17
  • DOI: 10.1002/chem.200902719