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Title: Volume collapse phase transitions in cerium-praseodymium alloys under high pressure

Abstract

Cerium-12at%Praseodymium(Ce 0.88Pr 0.12) and Ce-50at%Praseodymium(Ce 0.50Pr 0.50) alloy samples that contain a random solid-solution of Ce (4f1 (J=5/2)) and Pr (4f2 (J=4)) localized f-states have been studied by angle dispersive x-ray diffraction in a diamond anvil cell to a pressure of 65 GPa and 150 GPa respectively using a synchrotron source. Ce 0.88Pr 0.12 alloy crystallizes in a face-centered cubic (γ-phase) structure at ambient conditions, while Ce 0.50Pr 0.50 alloy crystallizes in the double hexagonal close packed (dhcp) structure at ambient conditions. Two distinct volume collapse transitions are observed in Ce 0.88Pr 0.12 alloy at 1.5 GPa and 18 GPa with volume change of 8.5% and 3% respectively. In contrast, Ce 0.50Pr 0.50 alloy shows only a single volume collapse of 5.6% at 20 GPa on phase transformation to α-Uranium structure under high pressure. Electrical transport measurements under high pressure show anomalies in electrical resistance at phase transitions for both compositions of this alloy.

Authors:
 [1];  [2];  [1];  [1];  [1]
  1. Univ. of Alabama, Birmingham, AL (United States)
  2. Los Alamos National Lab. (LANL), Los Alamos, NM (United States)
Publication Date:
Research Org.:
Univ. of Alabama, Birmingham, AL (United States)
Sponsoring Org.:
USDOE National Nuclear Security Administration (NNSA)
OSTI Identifier:
1440764
Grant/Contract Number:  
NA0002928
Resource Type:
Accepted Manuscript
Journal Name:
High Pressure Research
Additional Journal Information:
Journal Volume: 38; Journal Issue: 3; Journal ID: ISSN 0895-7959
Publisher:
Taylor & Francis
Country of Publication:
United States
Language:
English
Subject:
36 MATERIALS SCIENCE; High Pressure; Rare Earth Metals and Alloys; Equation of State; Phase Transformations

Citation Formats

Perreault, Christopher S., Velisavljevic, Nenad, Samudrala, Gopi K., Kalai Selvan, G., and Vohra, Yogesh K. Volume collapse phase transitions in cerium-praseodymium alloys under high pressure. United States: N. p., 2018. Web. doi:10.1080/08957959.2018.1484917.
Perreault, Christopher S., Velisavljevic, Nenad, Samudrala, Gopi K., Kalai Selvan, G., & Vohra, Yogesh K. Volume collapse phase transitions in cerium-praseodymium alloys under high pressure. United States. doi:10.1080/08957959.2018.1484917.
Perreault, Christopher S., Velisavljevic, Nenad, Samudrala, Gopi K., Kalai Selvan, G., and Vohra, Yogesh K. Fri . "Volume collapse phase transitions in cerium-praseodymium alloys under high pressure". United States. doi:10.1080/08957959.2018.1484917. https://www.osti.gov/servlets/purl/1440764.
@article{osti_1440764,
title = {Volume collapse phase transitions in cerium-praseodymium alloys under high pressure},
author = {Perreault, Christopher S. and Velisavljevic, Nenad and Samudrala, Gopi K. and Kalai Selvan, G. and Vohra, Yogesh K.},
abstractNote = {Cerium-12at%Praseodymium(Ce0.88Pr0.12) and Ce-50at%Praseodymium(Ce0.50Pr0.50) alloy samples that contain a random solid-solution of Ce (4f1 (J=5/2)) and Pr (4f2 (J=4)) localized f-states have been studied by angle dispersive x-ray diffraction in a diamond anvil cell to a pressure of 65 GPa and 150 GPa respectively using a synchrotron source. Ce0.88Pr0.12 alloy crystallizes in a face-centered cubic (γ-phase) structure at ambient conditions, while Ce0.50Pr0.50 alloy crystallizes in the double hexagonal close packed (dhcp) structure at ambient conditions. Two distinct volume collapse transitions are observed in Ce0.88Pr0.12 alloy at 1.5 GPa and 18 GPa with volume change of 8.5% and 3% respectively. In contrast, Ce0.50Pr0.50 alloy shows only a single volume collapse of 5.6% at 20 GPa on phase transformation to α-Uranium structure under high pressure. Electrical transport measurements under high pressure show anomalies in electrical resistance at phase transitions for both compositions of this alloy.},
doi = {10.1080/08957959.2018.1484917},
journal = {High Pressure Research},
number = 3,
volume = 38,
place = {United States},
year = {2018},
month = {6}
}

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