Capacity fade in high energy silicon-graphite electrodes for lithium-ion batteries

Dose, W. M.; Piernas-Munoz, M. J.; Maroni, V. A.; Trask, S. E.; Bloom, I.; Johnson, C. S.

doi:10.1039/c8cc00456k

Title: Capacity fade in high energy silicon-graphite electrodes for lithium-ion batteries

Abstract

A silicon-graphite blended anode is paired with a high capacity LiFePO₄ reference/counter electrode to track irreversibility and lithium inventory. The LiFePO₄ electrode provides a reliable, flat potential for dQ dV^-1 analysis of Li_xSi and Li_xC electrochemical reactions. We can relate this electrochemistry to the morphological and physical changes taking place.

Authors:

^[1];

^[1]; Maroni, V. A. ^[1];

^[1]; Bloom, I. ^[1];

^[1]

Argonne National Lab. (ANL), Lemont, IL (United States). Chemical Sciences and Engineering Division

Publication Date:: 2018-02-09

Research Org.:: Argonne National Lab. (ANL), Argonne, IL (United States)

Sponsoring Org.:: USDOE Office of Energy Efficiency and Renewable Energy (EERE), Vehicle Technologies Office (EE-3V); USDOE Office of Science (SC), Basic Energy Sciences (BES)

OSTI Identifier:: 1439867

Grant/Contract Number:: AC02-06CH11357

Resource Type:: Accepted Manuscript

Journal Name:: ChemComm

Additional Journal Information:: Journal Volume: 54; Journal Issue: 29; Journal ID: ISSN 1359-7345

Publisher:: Royal Society of Chemistry

Country of Publication:: United States

Language:: English

Subject:: 25 ENERGY STORAGE; 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; 36 MATERIALS SCIENCE

Citation Formats


                    Dose, W. M., Piernas-Munoz, M. J., Maroni, V. A., Trask, S. E., Bloom, I., and Johnson, C. S. Capacity fade in high energy silicon-graphite electrodes for lithium-ion batteries.  United States: N. p., 2018. 
Web.  doi:10.1039/c8cc00456k.

Copy to clipboard


                    Dose, W. M., Piernas-Munoz, M. J., Maroni, V. A., Trask, S. E., Bloom, I., & Johnson, C. S. Capacity fade in high energy silicon-graphite electrodes for lithium-ion batteries.  United States.  https://doi.org/10.1039/c8cc00456k

Copy to clipboard


                    Dose, W. M., Piernas-Munoz, M. J., Maroni, V. A., Trask, S. E., Bloom, I., and Johnson, C. S. Fri .  
"Capacity fade in high energy silicon-graphite electrodes for lithium-ion batteries".  United States.  https://doi.org/10.1039/c8cc00456k.  https://www.osti.gov/servlets/purl/1439867.

Copy to clipboard


                    
@article{osti_1439867,

  title        = {Capacity fade in high energy silicon-graphite electrodes for lithium-ion batteries},

  author       = {Dose, W. M. and Piernas-Munoz, M. J. and Maroni, V. A. and Trask, S. E. and Bloom, I. and Johnson, C. S.},

  abstractNote = {A silicon-graphite blended anode is paired with a high capacity LiFePO4 reference/counter electrode to track irreversibility and lithium inventory. The LiFePO4 electrode provides a reliable, flat potential for dQ dV-1 analysis of LixSi and LixC electrochemical reactions. We can relate this electrochemistry to the morphological and physical changes taking place.},

  doi          = {10.1039/c8cc00456k},

  journal      = {ChemComm},

  number       = 29,

  volume       = 54,

  place        = {United States},

  year         = {2018},

  month        = {2}

}

Copy to clipboard

Journal Article:

Free Publicly Available Full Text

Accepted Manuscript (DOE)

Publisher's Version of Record

https://doi.org/10.1039/c8cc00456k

Other availability

Search WorldCat to find libraries that may hold this journal

Citation Metrics:

Cited by: 1 work

Citation information provided by
Web of Science

Figures / Tables:

Fig.1 .: Representative electrochemical profile versus capacity with cycle number of (a) high capacity LiFePO₄ cycled against Li metal at C/10, (b) 15% Si graphite cycled against Li metal at C/10, (c) 15% Si graphite cycled against a LiFePO₄ reference electrode at C/10, and (d) 15% Si graphite lithiation capacitymore »

All figures and tables (4 total)

Save / Share:

Export Metadata

Save to My Library

Works referenced in this record:

Solid Electrolyte Interphase Growth and Capacity Loss in Silicon Electrodes
journal, June 2016

Michan, Alison L.; Divitini, Giorgio; Pell, Andrew J.
Journal of the American Chemical Society, Vol. 138, Issue 25
DOI: 10.1021/jacs.6b02882

One-to-One Comparison of Graphite-Blended Negative Electrodes Using Silicon Nanolayer-Embedded Graphite versus Commercial Benchmarking Materials for High-Energy Lithium-Ion Batteries
journal, April 2017

Chae, Sujong; Kim, Namhyung; Ma, Jiyoung
Advanced Energy Materials, Vol. 7, Issue 15
DOI: 10.1002/aenm.201700071

RETRACTED ARTICLE: Theoretical Limits of Energy Density in Silicon-Carbon Composite Anode Based Lithium Ion Batteries
journal, June 2016

Dash, Ranjan; Pannala, Sreekanth
Scientific Reports, Vol. 6, Issue 1
DOI: 10.1038/srep27449

Pair Distribution Function Analysis and Solid State NMR Studies of Silicon Electrodes for Lithium Ion Batteries: Understanding the (De)lithiation Mechanisms
journal, January 2011

Key, Baris; Morcrette, Mathieu; Tarascon, Jean-Marie
Journal of the American Chemical Society, Vol. 133, Issue 3
DOI: 10.1021/ja108085d

Alloy Negative Electrodes for Li-Ion Batteries
journal, October 2014

Obrovac, M. N.; Chevrier, V. L.
Chemical Reviews, Vol. 114, Issue 23
DOI: 10.1021/cr500207g

Failure Mechanism for Fast-Charged Lithium Metal Batteries with Liquid Electrolytes
journal, September 2014

Lu, Dongping; Shao, Yuyan; Lozano, Terence
Advanced Energy Materials, Vol. 5, Issue 3
DOI: 10.1002/aenm.201400993

Differentiating the Degradation Phenomena in Silicon-Graphite Electrodes for Lithium-Ion Batteries
journal, January 2017

Wetjen, Morten; Pritzl, Daniel; Jung, Roland
Journal of The Electrochemical Society, Vol. 164, Issue 12
DOI: 10.1149/2.1921712jes

An In Situ X-Ray Diffraction Study of the Reaction of Li with Crystalline Si
journal, January 2007

Li, Jing; Dahn, J. R.
Journal of The Electrochemical Society, Vol. 154, Issue 3
DOI: 10.1149/1.2409862

Nanosilicon Electrodes for Lithium-Ion Batteries: Interfacial Mechanisms Studied by Hard and Soft X-ray Photoelectron Spectroscopy
journal, February 2012

Philippe, Bertrand; Dedryvère, Rémi; Allouche, Joachim
Chemistry of Materials, Vol. 24, Issue 6
DOI: 10.1021/cm2034195

Nano- and bulk-silicon-based insertion anodes for lithium-ion secondary cells
journal, January 2007

Kasavajjula, Uday; Wang, Chunsheng; Appleby, A. John
Journal of Power Sources, Vol. 163, Issue 2, p. 1003-1039
DOI: 10.1016/j.jpowsour.2006.09.084

A short review of failure mechanisms of lithium metal and lithiated graphite anodes in liquid electrolyte solutions
journal, June 2002

Aurbach, D.
Solid State Ionics, Vol. 148, Issue 3-4
DOI: 10.1016/S0167-2738(02)00080-2

A 3D porous architecture of Si/graphene nanocomposite as high-performance anode materials for Li-ion batteries
journal, January 2012

Xin, Xing; Zhou, Xufeng; Wang, Feng
Journal of Materials Chemistry, Vol. 22, Issue 16
DOI: 10.1039/c2jm00120a

Failure mechanisms of nano-silicon anodes upon cycling: an electrode porosity evolution model
journal, January 2014

Radvanyi, Etienne; Porcher, Willy; De Vito, Eric
Phys. Chem. Chem. Phys., Vol. 16, Issue 32
DOI: 10.1039/C4CP02324B

Colossal Reversible Volume Changes in Lithium Alloys
journal, January 2001

Beaulieu, L. Y.; Eberman, K. W.; Turner, R. L.
Electrochemical and Solid-State Letters, Vol. 4, Issue 9
DOI: 10.1149/1.1388178

Will advanced lithium-alloy anodes have a chance in lithium-ion batteries?
journal, September 1997

Besenhard, J. O.; Yang, J.; Winter, M.
Journal of Power Sources, Vol. 68, Issue 1
DOI: 10.1016/S0378-7753(96)02547-5

Stabilization of Silicon Anode for Li-Ion Batteries
journal, January 2010

Xiao, Jie; Xu, Wu; Wang, Deyu
Journal of The Electrochemical Society, Vol. 157, Issue 10, p. A1047-A1051
DOI: 10.1149/1.3464767

Layered Oxide, Graphite and Silicon-Graphite Electrodes for Lithium-Ion Cells: Effect of Electrolyte Composition and Cycling Windows
journal, October 2016

Klett, Matilda; Gilbert, James A.; Pupek, Krzysztof Z.
Journal of The Electrochemical Society, Vol. 164, Issue 1
DOI: 10.1149/2.0131701jes

Structural Changes in Silicon Anodes during Lithium Insertion/Extraction
journal, January 2004

Obrovac, M. N.; Christensen, Leif
Electrochemical and Solid-State Letters, Vol. 7, Issue 5
DOI: 10.1149/1.1652421

Phospho-olivines as Positive-Electrode Materials for Rechargeable Lithium Batteries
journal, April 1997

Padhi, A. K.
Journal of The Electrochemical Society, Vol. 144, Issue 4, p. 1188-1194
DOI: 10.1149/1.1837571

The failure mechanism of nano-sized Si-based negative electrodes for lithium ion batteries
journal, January 2011

Oumellal, Y.; Delpuech, N.; Mazouzi, D.
Journal of Materials Chemistry, Vol. 21, Issue 17
DOI: 10.1039/c1jm10213c

Reliable reference electrodes for lithium-ion batteries
journal, June 2013

La Mantia, F.; Wessells, C. D.; Deshazer, H. D.
Electrochemistry Communications, Vol. 31
DOI: 10.1016/j.elecom.2013.03.015

Nano-network electronic conduction in iron and nickel olivine phosphates
journal, February 2004

Herle, P. Subramanya; Ellis, B.; Coombs, N.
Nature Materials, Vol. 3, Issue 3
DOI: 10.1038/nmat1063

The role of anions, solvent molecules and solvated electrons in layer formation processes on anode materials for rechargeable lithium batteries
journal, September 1999

Rahner, D.
Journal of Power Sources, Vol. 81-82
DOI: 10.1016/S0378-7753(98)00218-3

Solid Electrolyte Interphase Growth and Capacity Loss in Silicon Electrodes
text, January 2016

Michan, Alison L.; Divitini, Giorgio; Pell, Andrew J.
Apollo - University of Cambridge Repository
DOI: 10.17863/cam.688

Works referencing / citing this record:

Graphdiyne applied for electrochemical energy storage
journal, January 2019

He, Jianjiang; Li, Xiaodong; Lu, Tiantian
Dalton Transactions, Vol. 48, Issue 39
DOI: 10.1039/c9dt02862e

Assessment of Li-Inventory in Cycled Si-Graphite Anodes Using LiFePO ₄ as a Diagnostic Cathode
journal, January 2018

Dose, Wesley M.; Maroni, Victor A.; Piernas-Muñoz, Maria Jose
Journal of The Electrochemical Society, Vol. 165, Issue 10
DOI: 10.1149/2.1271810jes

Figures / Tables found in this record:

Figures/Tables have been extracted from DOE-funded journal article accepted manuscripts.

Similar Records in DOE PAGES and OSTI.GOV collections:

Improved Capacity Retention of Lithium Ion Batteries under Fast Charge via Metal-Coated Graphite Electrodes

Journal Article Tallman, Killian R. ; Yan, Shan ; Quilty, Calvin D. ; ... - Journal of the Electrochemical Society (Online)

A primary barrier preventing repetitive fast charging of Li-ion batteries is lithium metal plating at the graphite anode. One approach toward mitigating Li metal deposition is the deliberate modification of the graphite anode surface with materials demonstrating high overpotentials unfavorable for Li metal nucleation, such as Ni or Cu nanoscale films. This research explores Ni and Cu surface coatings at different areal loadings (3 or 11 μg cm^-2) on the electrochemistry of graphite/LiNi_0.6Mn_0.2Co_0.2O₂ (NMC622) type Li-ion batteries. Extended galvanostatic cycling of control and metal-coated electrodes in graphite/NMC622 pouch cells are conducted under high rate conditions. Based on the overpotential ofmore »« less
https://doi.org/10.1149/1945-7111/abcaba

Full Text Available
Mitigation of rapid capacity decay in silicon-LiNi_0.6Mn_0.2Co_0.2O₂ full batteries

Journal Article Zhang, Wei ; Son, Seoung-Bum ; Guthrey, Harvey ; ... - Energy Storage Materials

Silicon (Si)-based materials have been considered as the most promising anode materials for high-energy-density lithium-ion batteries because of their higher storage capacity and similar operating voltage, as compared to the commercial graphite (Gr) anode. But the use of Si anodes including silicon-graphite (Si-Gr) blended anodes often leads to rapid capacity decay in Si-Gr/LiNixMnyCo_zO₂ (x+y+z=1) full cells, which has been attributed to surface instability of the Si component. In addition to stabilizing the surface, this work investigates the potential of the Si-Gr blended anodes in a full-cell configuration and its impact on the capacity contribution from active components. Using dQ/dV plotsmore »« less
https://doi.org/10.1016/j.ensm.2022.03.025

Full Text Available
Achieving SEI preformed graphite in flow cell to mitigate initial lithium loss

Journal Article Yu, Yikang ; Yang, Zhenzhen ; Liu, Yuzi ; ... - Carbon

The irreversible lithium loss due to the formation of solid electrolyte interphase (SEI) in the initial cycle on the graphite anode greatly reduces the overall cell energy density of lithium ion batteries, that is, the lost Li ions from forming SEI lead to the decrease of Li ions for the intercalation. The method of cathode prelithiation has been widely explored to compensate this lithium loss. However, these cathode additives with high lithium contents inevitably lower the loading of the cathode active materials. In this work, we report a novel approach to solve this challenge, a facile graphite prelithiation method bymore »« less
https://doi.org/10.1016/j.carbon.2022.05.024
Degradation Mechanisms of High Capacity 18650 Cells Containing Si-Graphite Anode and Nickel-Rich NMC Cathode

Journal Article Li, Xuemin ; Colclasure, Andrew M. ; Finegan, Donal P. ; ... - Electrochimica Acta

Application of advanced anode and cathode materials in commercial lithium-ion batteries is attracting attention due to their high capacity. Silicon (Si)/graphite anodes and nickel (Ni)-rich lithium nickel manganese cobalt oxide with layered structures have been paired in commercial 18650 high energy density cells (~270 Wh/kg). It is crucial to investigate the cell performance and the aging behavior of this commercial cell. In this study, we present commercial cell degradation mechanisms by comparing fresh and aged electrodes, including changes of crystal structure, morphology, elemental composition, and electrochemical properties. The quantitative analysis was done based on dV/dQ incremental capacity analysis of 18650more »« less
Cited by 15
https://doi.org/10.1016/j.electacta.2018.11.194

Full Text Available
Understanding Conversion-Type Electrodes for Lithium Rechargeable Batteries

Journal Article Yu, Seung-Ho ; Feng, Xinran ; Zhang, Na ; ... - Accounts of Chemical Research

The need/desire to lower the consumption of fossil fuels and its environmental consequences has reached unprecedented levels in recent years. A global effort has been undertaken to develop advanced renewable energy generation and especially energy storage technologies, as they would enable a dramatic increase in the effective and efficient use of renewable (and often intermittent) energy sources. The development of electrical energy storage (EES) technologies with high energy and power densities, long life, low cost, and safe use represents a challenge from both the fundamental science and technological application points of view. While the advent and broad deployment of lithium-ionmore »« less
Cited by 92
https://doi.org/10.1021/acs.accounts.7b00487

Full Text Available

Similar Records

Title: Capacity fade in high energy silicon-graphite electrodes for lithium-ion batteries

Abstract

Citation Formats

Figures / Tables:

Solid Electrolyte Interphase Growth and Capacity Loss in Silicon Electrodes journal, June 2016

One-to-One Comparison of Graphite-Blended Negative Electrodes Using Silicon Nanolayer-Embedded Graphite versus Commercial Benchmarking Materials for High-Energy Lithium-Ion Batteries journal, April 2017

RETRACTED ARTICLE: Theoretical Limits of Energy Density in Silicon-Carbon Composite Anode Based Lithium Ion Batteries journal, June 2016

Pair Distribution Function Analysis and Solid State NMR Studies of Silicon Electrodes for Lithium Ion Batteries: Understanding the (De)lithiation Mechanisms journal, January 2011

Alloy Negative Electrodes for Li-Ion Batteries journal, October 2014

Failure Mechanism for Fast-Charged Lithium Metal Batteries with Liquid Electrolytes journal, September 2014

Differentiating the Degradation Phenomena in Silicon-Graphite Electrodes for Lithium-Ion Batteries journal, January 2017

An In Situ X-Ray Diffraction Study of the Reaction of Li with Crystalline Si journal, January 2007

Nanosilicon Electrodes for Lithium-Ion Batteries: Interfacial Mechanisms Studied by Hard and Soft X-ray Photoelectron Spectroscopy journal, February 2012

Nano- and bulk-silicon-based insertion anodes for lithium-ion secondary cells journal, January 2007

A short review of failure mechanisms of lithium metal and lithiated graphite anodes in liquid electrolyte solutions journal, June 2002

A 3D porous architecture of Si/graphene nanocomposite as high-performance anode materials for Li-ion batteries journal, January 2012

Failure mechanisms of nano-silicon anodes upon cycling: an electrode porosity evolution model journal, January 2014

Colossal Reversible Volume Changes in Lithium Alloys journal, January 2001

Will advanced lithium-alloy anodes have a chance in lithium-ion batteries? journal, September 1997

Stabilization of Silicon Anode for Li-Ion Batteries journal, January 2010

Layered Oxide, Graphite and Silicon-Graphite Electrodes for Lithium-Ion Cells: Effect of Electrolyte Composition and Cycling Windows journal, October 2016

Structural Changes in Silicon Anodes during Lithium Insertion/Extraction journal, January 2004

Phospho-olivines as Positive-Electrode Materials for Rechargeable Lithium Batteries journal, April 1997

The failure mechanism of nano-sized Si-based negative electrodes for lithium ion batteries journal, January 2011

Reliable reference electrodes for lithium-ion batteries journal, June 2013

Nano-network electronic conduction in iron and nickel olivine phosphates journal, February 2004

The role of anions, solvent molecules and solvated electrons in layer formation processes on anode materials for rechargeable lithium batteries journal, September 1999

Solid Electrolyte Interphase Growth and Capacity Loss in Silicon Electrodes text, January 2016

Graphdiyne applied for electrochemical energy storage journal, January 2019

Assessment of Li-Inventory in Cycled Si-Graphite Anodes Using LiFePO 4 as a Diagnostic Cathode journal, January 2018

Solid Electrolyte Interphase Growth and Capacity Loss in Silicon Electrodes
journal, June 2016

One-to-One Comparison of Graphite-Blended Negative Electrodes Using Silicon Nanolayer-Embedded Graphite versus Commercial Benchmarking Materials for High-Energy Lithium-Ion Batteries
journal, April 2017

RETRACTED ARTICLE: Theoretical Limits of Energy Density in Silicon-Carbon Composite Anode Based Lithium Ion Batteries
journal, June 2016

Pair Distribution Function Analysis and Solid State NMR Studies of Silicon Electrodes for Lithium Ion Batteries: Understanding the (De)lithiation Mechanisms
journal, January 2011

Alloy Negative Electrodes for Li-Ion Batteries
journal, October 2014

Failure Mechanism for Fast-Charged Lithium Metal Batteries with Liquid Electrolytes
journal, September 2014

Differentiating the Degradation Phenomena in Silicon-Graphite Electrodes for Lithium-Ion Batteries
journal, January 2017

An In Situ X-Ray Diffraction Study of the Reaction of Li with Crystalline Si
journal, January 2007

Nanosilicon Electrodes for Lithium-Ion Batteries: Interfacial Mechanisms Studied by Hard and Soft X-ray Photoelectron Spectroscopy
journal, February 2012

Nano- and bulk-silicon-based insertion anodes for lithium-ion secondary cells
journal, January 2007

A short review of failure mechanisms of lithium metal and lithiated graphite anodes in liquid electrolyte solutions
journal, June 2002

A 3D porous architecture of Si/graphene nanocomposite as high-performance anode materials for Li-ion batteries
journal, January 2012

Failure mechanisms of nano-silicon anodes upon cycling: an electrode porosity evolution model
journal, January 2014

Colossal Reversible Volume Changes in Lithium Alloys
journal, January 2001

Will advanced lithium-alloy anodes have a chance in lithium-ion batteries?
journal, September 1997

Stabilization of Silicon Anode for Li-Ion Batteries
journal, January 2010

Layered Oxide, Graphite and Silicon-Graphite Electrodes for Lithium-Ion Cells: Effect of Electrolyte Composition and Cycling Windows
journal, October 2016

Structural Changes in Silicon Anodes during Lithium Insertion/Extraction
journal, January 2004

Phospho-olivines as Positive-Electrode Materials for Rechargeable Lithium Batteries
journal, April 1997

The failure mechanism of nano-sized Si-based negative electrodes for lithium ion batteries
journal, January 2011

Reliable reference electrodes for lithium-ion batteries
journal, June 2013

Nano-network electronic conduction in iron and nickel olivine phosphates
journal, February 2004

The role of anions, solvent molecules and solvated electrons in layer formation processes on anode materials for rechargeable lithium batteries
journal, September 1999

Solid Electrolyte Interphase Growth and Capacity Loss in Silicon Electrodes
text, January 2016

Graphdiyne applied for electrochemical energy storage
journal, January 2019

Assessment of Li-Inventory in Cycled Si-Graphite Anodes Using LiFePO ₄ as a Diagnostic Cathode
journal, January 2018