Fast cycling in a non-isothermal monolithic lean NOx trap using H2 as reductant: Experiments and modeling

Ting, Allen Wei-Lun; Li, Mengmeng; Harold, Michael P.; Balakotaiah, Vemuri

doi:10.1016/j.cej.2017.05.002

Title: Fast cycling in a non-isothermal monolithic lean NOx trap using H2 as reductant: Experiments and modeling

Authors:: Ting, Allen Wei-Lun; Li, Mengmeng; Harold, Michael P.; Balakotaiah, Vemuri

Publication Date:: 2017-10-01

Sponsoring Org.:: USDOE Office of Energy Efficiency and Renewable Energy (EERE), Transportation Office. Vehicle Technologies Office

OSTI Identifier:: 1439779

Grant/Contract Number:: EE0000205

Resource Type:: Publisher's Accepted Manuscript

Journal Name:: Chemical Engineering Journal

Additional Journal Information:: Journal Name: Chemical Engineering Journal Journal Volume: 326 Journal Issue: C; Journal ID: ISSN 1385-8947

Publisher:: Elsevier

Country of Publication:: Switzerland

Language:: English

Citation Formats


                    Ting, Allen Wei-Lun, Li, Mengmeng, Harold, Michael P., and Balakotaiah, Vemuri. Fast cycling in a non-isothermal monolithic lean NOx trap using H2 as reductant: Experiments and modeling.  Switzerland: N. p., 2017. 
Web.  doi:10.1016/j.cej.2017.05.002.

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                    Ting, Allen Wei-Lun, Li, Mengmeng, Harold, Michael P., & Balakotaiah, Vemuri. Fast cycling in a non-isothermal monolithic lean NOx trap using H2 as reductant: Experiments and modeling.  Switzerland.  https://doi.org/10.1016/j.cej.2017.05.002

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                    Ting, Allen Wei-Lun, Li, Mengmeng, Harold, Michael P., and Balakotaiah, Vemuri. Sun .  
"Fast cycling in a non-isothermal monolithic lean NOx trap using H2 as reductant: Experiments and modeling".  Switzerland.  https://doi.org/10.1016/j.cej.2017.05.002.

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@article{osti_1439779,

  title        = {Fast cycling in a non-isothermal monolithic lean NOx trap using H2 as reductant: Experiments and modeling},

  author       = {Ting, Allen Wei-Lun and Li, Mengmeng and Harold, Michael P. and Balakotaiah, Vemuri},

  abstractNote = {},

  doi          = {10.1016/j.cej.2017.05.002},

  journal      = {Chemical Engineering Journal},

  number       = C,

  volume       = 326,

  place        = {Switzerland},

  year         = {2017},

  month        = {10}

}

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https://doi.org/10.1016/j.cej.2017.05.002

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Works referenced in this record:

Heat and mass transfer correlations and bifurcation analysis of catalytic monoliths with developing flows
journal, May 2011

Gundlapally, Santhosh R.; Balakotaiah, Vemuri
Chemical Engineering Science, Vol. 66, Issue 9
DOI: 10.1016/j.ces.2011.01.045

Effective Model for Prediction of N2O and NH3 Formation During the Regeneration of NO x Storage Catalyst
journal, March 2013

Kočí, Petr; Bártová, Šárka; Mráček, David
Topics in Catalysis, Vol. 56, Issue 1-8
DOI: 10.1007/s11244-013-9939-y

Analysis of Periodic Storage and Reduction of NOx in Catalytic Monoliths
journal, August 2005

Sharma, Manish; Harold, M. P.; Balakotaiah, V.
Industrial & Engineering Chemistry Research, Vol. 44, Issue 16
DOI: 10.1021/ie0490785

Global kinetic model for the regeneration of NOx storage catalyst with CO, H2 and C3H6 in the presence of CO2 and H2O
journal, September 2009

Kočí, Petr; Plát, František; Štěpánek, Jan
Catalysis Today, Vol. 147
DOI: 10.1016/j.cattod.2009.07.036

Modeling Studies on Lean NO _x Reduction by a Sequence of LNT–SCR Bricks
journal, May 2012

Kota, Arun S.; Luss, Dan; Balakotaiah, Vemuri
Industrial & Engineering Chemistry Research, Vol. 51, Issue 19
DOI: 10.1021/ie300190c

Mass-transfer coefficients in washcoated monoliths
journal, October 2004

Bhattacharya, Madhuchhanda; Harold, Michael P.; Balakotaiah, Vemuri
AIChE Journal, Vol. 50, Issue 11
DOI: 10.1002/aic.10212

Reaction Mechanism Analysis of Di-Air-Contributions of Hydrocarbons and Intermediates
journal, January 2012

Bisaiji, Yuki; Yoshida, Kohei; Inoue, Mikio
SAE International Journal of Fuels and Lubricants, Vol. 5, Issue 3
DOI: 10.4271/2012-01-1744

NOx storage and reduction with H2 on Pt/BaO/Al2O3 monolith: Spatio-temporal resolution of product distribution
journal, December 2008

Clayton, Robert D.; Harold, Michael P.; Balakotaiah, Vemuri
Applied Catalysis B: Environmental, Vol. 84, Issue 3-4
DOI: 10.1016/j.apcatb.2008.05.018

NOx storage and reduction in lean burn vehicle emission control: a catalytic engineer's playground
journal, August 2012

Harold, Michael P.
Current Opinion in Chemical Engineering, Vol. 1, Issue 3
DOI: 10.1016/j.coche.2012.02.002

NOx Release Characteristics of Lean NOx Traps During Rich Purges
conference, March 2003

Theis, Joseph R.; Ura, Justin A.; Li, John J.
SAE 2003 World Congress & Exhibition, SAE Technical Paper Series
DOI: 10.4271/2003-01-1159

A simplified approach to modeling of dual-layer ammonia slip catalysts
journal, June 2012

Colombo, Massimo; Nova, Isabella; Tronconi, Enrico
Chemical Engineering Science, Vol. 75
DOI: 10.1016/j.ces.2012.02.044

Kinetic and bifurcation analysis of the cooxidation of CO and $H_{2}$ in catalytic monolith reactors
journal, April 2009

Bhatia, Divesh; Harold, Michael P.; Balakotaiah, Vemuri
Chemical Engineering Science, Vol. 64, Issue 7
DOI: 10.1016/j.ces.2008.12.012

A simplified model for analyzing catalytic reactions in short monoliths
journal, November 2000

Balakotaiah, Vemuri; Gupta, Nikunj; West, David H.
Chemical Engineering Science, Vol. 55, Issue 22
DOI: 10.1016/S0009-2509(00)00164-0

Fast lean-rich cycling for enhanced NOx conversion on storage and reduction catalysts
journal, August 2014

Perng, Charles C. Y.; Easterling, Vencon G.; Harold, Michael P.
Catalysis Today, Vol. 231
DOI: 10.1016/j.cattod.2014.01.026

Development of NSR and DiAir System to Achieve Clean Emissions under Transient Cycle
conference, October 2014

Yoshida, Kohei; Nozaki, Yusuke; Mori, Toshihiro
SAE 2014 International Powertrain, Fuels & Lubricants Meeting, SAE Technical Paper Series
DOI: 10.4271/2014-01-2809

NOX storage and reduction on a Pt/BaO/alumina monolithic storage catalyst
journal, October 2004

Kabin, Karen S.; Muncrief, Rachel L.; Harold, Michael P.
Catalysis Today, Vol. 96, Issue 1-2
DOI: 10.1016/j.cattod.2004.05.008

Spatio-temporal features of the sequential NOx storage and reduction and selective catalytic reduction reactor system
journal, June 2016

Li, Mengmeng; Easterling, Vencon G.; Harold, Michael P.
Catalysis Today, Vol. 267
DOI: 10.1016/j.cattod.2016.01.020

Enhanced Low-Temperature NOx Conversion by High-Frequency Hydrocarbon Pulsing on a Dual Layer LNT-SCR Catalyst
journal, January 2015

Zheng, Yang; Li, Mengmeng; Harold, Michael
SAE International Journal of Engines, Vol. 8, Issue 3
DOI: 10.4271/2015-01-0984

Analysis of Storage and Reaction Phases of LNT for Diesel Engine Exhaust Treatment
conference, October 2005

Sharma, Manish; Harold, Michael P.; Balakotaiah, Vemuri
Powertrain & Fluid Systems Conference & Exhibition, SAE Technical Paper Series
DOI: 10.4271/2005-01-3882

Selective catalytic reduction of NO by H2 in O2 on Pt/BaO/Al2O3 monolith NOx storage catalysts
journal, June 2008

Clayton, Robert D.; Harold, Michael P.; Balakotaiah, Vemuri
Applied Catalysis B: Environmental, Vol. 81, Issue 3-4
DOI: 10.1016/j.apcatb.2007.11.038

A global kinetic model for NOx storage and reduction on Pt/BaO/Al2O3 monolithic catalysts
journal, September 2009

Bhatia, Divesh; Clayton, Robert D.; Harold, Michael P.
Catalysis Today, Vol. 147
DOI: 10.1016/j.cattod.2009.07.024

Mechanistic and kinetic studies of NOx storage and reduction on Pt/BaO/Al2O3
journal, December 2004

Muncrief, Rachel L.; Khanna, Pranav; Kabin, Karen S.
Catalysis Today, Vol. 98, Issue 3
DOI: 10.1016/j.cattod.2004.08.004

Experimental and kinetic modeling study of NH3-SCR of NOx on Fe-ZSM-5, Cu-chabazite and combined Fe- and Cu-zeolite monolithic catalysts
journal, January 2013

Metkar, Pranit S.; Harold, Michael P.; Balakotaiah, Vemuri
Chemical Engineering Science, Vol. 87
DOI: 10.1016/j.ces.2012.09.008

Rapid propylene pulsing for enhanced low temperature NO conversion on combined LNT-SCR catalysts
journal, June 2016

Zheng, Yang; Li, Mengmeng; Wang, Di
Catalysis Today, Vol. 267
DOI: 10.1016/j.cattod.2015.10.029

Mean field modelling of NOx storage on Pt/BaO/Al2O3
journal, April 2002

Olsson, Louise; Fridell, Erik; Skoglundh, Magnus
Catalysis Today, Vol. 73, Issue 3-4
DOI: 10.1016/S0920-5861(02)00009-3

Spatio-temporal dynamics of oxygen storage and release in a three-way catalytic converter
journal, May 2014

Kumar, Pankaj; Gu, Tian; Grigoriadis, Karolos
Chemical Engineering Science, Vol. 111
DOI: 10.1016/j.ces.2014.02.014

Development of Di-Air - A New Diesel deNOx System by Adsorbed Intermediate Reductants
journal, August 2011

Bisaiji, Yuki; Yoshida, Kohei; Inoue, Mikio
SAE International Journal of Fuels and Lubricants, Vol. 5, Issue 1
DOI: 10.4271/2011-01-2089

Modeling and analysis of dual-layer NOx storage and reduction and selective catalytic reduction monolithic catalyst
journal, February 2014

Shakya, Bijesh M.; Harold, Michael P.; Balakotaiah, Vemuri
Chemical Engineering Journal, Vol. 237
DOI: 10.1016/j.cej.2013.10.008

Experimental and kinetic study of NO oxidation on model Pt catalysts
journal, August 2009

Bhatia, Divesh; McCabe, Robert W.; Harold, Michael P.
Journal of Catalysis, Vol. 266, Issue 1
DOI: 10.1016/j.jcat.2009.05.020

On the use of internal mass transfer coefficients in modeling of diffusion and reaction in catalytic monoliths
journal, December 2009

Joshi, Saurabh Y.; Harold, Michael P.; Balakotaiah, Vemuri
Chemical Engineering Science, Vol. 64, Issue 23
DOI: 10.1016/j.ces.2009.08.008

Pt dispersion effects during NOx storage and reduction on Pt/BaO/Al2O3 catalysts
journal, August 2009

Clayton, Robert D.; Harold, Michael P.; Balakotaiah, Vemuri
Applied Catalysis B: Environmental, Vol. 90, Issue 3-4
DOI: 10.1016/j.apcatb.2009.04.029

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Similar Records

Title: Fast cycling in a non-isothermal monolithic lean NOx trap using H2 as reductant: Experiments and modeling

Citation Formats

Heat and mass transfer correlations and bifurcation analysis of catalytic monoliths with developing flows journal, May 2011

Effective Model for Prediction of N2O and NH3 Formation During the Regeneration of NO x Storage Catalyst journal, March 2013

Analysis of Periodic Storage and Reduction of NOx in Catalytic Monoliths journal, August 2005

Global kinetic model for the regeneration of NOx storage catalyst with CO, H2 and C3H6 in the presence of CO2 and H2O journal, September 2009

Modeling Studies on Lean NO x Reduction by a Sequence of LNT–SCR Bricks journal, May 2012

Mass-transfer coefficients in washcoated monoliths journal, October 2004

Reaction Mechanism Analysis of Di-Air-Contributions of Hydrocarbons and Intermediates journal, January 2012

NOx storage and reduction with H2 on Pt/BaO/Al2O3 monolith: Spatio-temporal resolution of product distribution journal, December 2008

NOx storage and reduction in lean burn vehicle emission control: a catalytic engineer's playground journal, August 2012

NOx Release Characteristics of Lean NOx Traps During Rich Purges conference, March 2003

A simplified approach to modeling of dual-layer ammonia slip catalysts journal, June 2012

Kinetic and bifurcation analysis of the cooxidation of CO and H 2 in catalytic monolith reactors journal, April 2009

A simplified model for analyzing catalytic reactions in short monoliths journal, November 2000

Fast lean-rich cycling for enhanced NOx conversion on storage and reduction catalysts journal, August 2014

Development of NSR and DiAir System to Achieve Clean Emissions under Transient Cycle conference, October 2014

NOX storage and reduction on a Pt/BaO/alumina monolithic storage catalyst journal, October 2004

Spatio-temporal features of the sequential NOx storage and reduction and selective catalytic reduction reactor system journal, June 2016

Enhanced Low-Temperature NOx Conversion by High-Frequency Hydrocarbon Pulsing on a Dual Layer LNT-SCR Catalyst journal, January 2015

Analysis of Storage and Reaction Phases of LNT for Diesel Engine Exhaust Treatment conference, October 2005

Selective catalytic reduction of NO by H2 in O2 on Pt/BaO/Al2O3 monolith NOx storage catalysts journal, June 2008

A global kinetic model for NOx storage and reduction on Pt/BaO/Al2O3 monolithic catalysts journal, September 2009

Mechanistic and kinetic studies of NOx storage and reduction on Pt/BaO/Al2O3 journal, December 2004

Experimental and kinetic modeling study of NH3-SCR of NOx on Fe-ZSM-5, Cu-chabazite and combined Fe- and Cu-zeolite monolithic catalysts journal, January 2013

Rapid propylene pulsing for enhanced low temperature NO conversion on combined LNT-SCR catalysts journal, June 2016

Mean field modelling of NOx storage on Pt/BaO/Al2O3 journal, April 2002

Spatio-temporal dynamics of oxygen storage and release in a three-way catalytic converter journal, May 2014

Development of Di-Air - A New Diesel deNOx System by Adsorbed Intermediate Reductants journal, August 2011

Modeling and analysis of dual-layer NOx storage and reduction and selective catalytic reduction monolithic catalyst journal, February 2014

Experimental and kinetic study of NO oxidation on model Pt catalysts journal, August 2009

On the use of internal mass transfer coefficients in modeling of diffusion and reaction in catalytic monoliths journal, December 2009

Pt dispersion effects during NOx storage and reduction on Pt/BaO/Al2O3 catalysts journal, August 2009

Heat and mass transfer correlations and bifurcation analysis of catalytic monoliths with developing flows
journal, May 2011

Effective Model for Prediction of N2O and NH3 Formation During the Regeneration of NO x Storage Catalyst
journal, March 2013

Analysis of Periodic Storage and Reduction of NOx in Catalytic Monoliths
journal, August 2005

Global kinetic model for the regeneration of NOx storage catalyst with CO, H2 and C3H6 in the presence of CO2 and H2O
journal, September 2009

Modeling Studies on Lean NO _x Reduction by a Sequence of LNT–SCR Bricks
journal, May 2012

Mass-transfer coefficients in washcoated monoliths
journal, October 2004

Reaction Mechanism Analysis of Di-Air-Contributions of Hydrocarbons and Intermediates
journal, January 2012

NOx storage and reduction with H2 on Pt/BaO/Al2O3 monolith: Spatio-temporal resolution of product distribution
journal, December 2008

NOx storage and reduction in lean burn vehicle emission control: a catalytic engineer's playground
journal, August 2012

NOx Release Characteristics of Lean NOx Traps During Rich Purges
conference, March 2003

A simplified approach to modeling of dual-layer ammonia slip catalysts
journal, June 2012

Kinetic and bifurcation analysis of the cooxidation of CO and $H_{2}$ in catalytic monolith reactors
journal, April 2009

A simplified model for analyzing catalytic reactions in short monoliths
journal, November 2000

Fast lean-rich cycling for enhanced NOx conversion on storage and reduction catalysts
journal, August 2014

Development of NSR and DiAir System to Achieve Clean Emissions under Transient Cycle
conference, October 2014

NOX storage and reduction on a Pt/BaO/alumina monolithic storage catalyst
journal, October 2004

Spatio-temporal features of the sequential NOx storage and reduction and selective catalytic reduction reactor system
journal, June 2016

Enhanced Low-Temperature NOx Conversion by High-Frequency Hydrocarbon Pulsing on a Dual Layer LNT-SCR Catalyst
journal, January 2015

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conference, October 2005

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journal, June 2008

A global kinetic model for NOx storage and reduction on Pt/BaO/Al2O3 monolithic catalysts
journal, September 2009

Mechanistic and kinetic studies of NOx storage and reduction on Pt/BaO/Al2O3
journal, December 2004

Experimental and kinetic modeling study of NH3-SCR of NOx on Fe-ZSM-5, Cu-chabazite and combined Fe- and Cu-zeolite monolithic catalysts
journal, January 2013

Rapid propylene pulsing for enhanced low temperature NO conversion on combined LNT-SCR catalysts
journal, June 2016

Mean field modelling of NOx storage on Pt/BaO/Al2O3
journal, April 2002

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journal, May 2014

Development of Di-Air - A New Diesel deNOx System by Adsorbed Intermediate Reductants
journal, August 2011

Modeling and analysis of dual-layer NOx storage and reduction and selective catalytic reduction monolithic catalyst
journal, February 2014

Experimental and kinetic study of NO oxidation on model Pt catalysts
journal, August 2009

On the use of internal mass transfer coefficients in modeling of diffusion and reaction in catalytic monoliths
journal, December 2009

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journal, August 2009