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Title: Stabilized Vanadium Catalyst for Olefin Polymerization by Site Isolation in a Metal–Organic Framework

 [1];  [2];  [2];  [3];  [1];  [4];  [2]; ORCiD logo [1]
  1. Department of ChemistryMassachusetts Institute of Technology 77 Massachusetts Avenue Cambridge MA 02139 USA
  2. Davidson School of Chemical EngineeringPurdue University 480 Stadium Mall Dr. West Lafayette IN 47907 USA
  3. Aramco Research Center—Boston, Aramco Services Company 400 Technology Square Cambridge MA 02139 USA
  4. Department of ChemistryEugene F. Merkert Chemistry CenterBoston College Chestnut Hill MA 02467 USA
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Publisher's Accepted Manuscript
Journal Name:
Angewandte Chemie (International Edition)
Additional Journal Information:
Journal Name: Angewandte Chemie (International Edition) Journal Volume: 57 Journal Issue: 27; Journal ID: ISSN 1433-7851
Wiley Blackwell (John Wiley & Sons)
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Comito, Robert J., Wu, Zhenwei, Zhang, Guanghui, Lawrence, III, John A., Korzyński, Maciej D., Kehl, Jeffrey A., Miller, Jeffrey T., and Dincă, Mircea. Stabilized Vanadium Catalyst for Olefin Polymerization by Site Isolation in a Metal–Organic Framework. Germany: N. p., 2018. Web. doi:10.1002/anie.201803642.
Comito, Robert J., Wu, Zhenwei, Zhang, Guanghui, Lawrence, III, John A., Korzyński, Maciej D., Kehl, Jeffrey A., Miller, Jeffrey T., & Dincă, Mircea. Stabilized Vanadium Catalyst for Olefin Polymerization by Site Isolation in a Metal–Organic Framework. Germany. doi:
Comito, Robert J., Wu, Zhenwei, Zhang, Guanghui, Lawrence, III, John A., Korzyński, Maciej D., Kehl, Jeffrey A., Miller, Jeffrey T., and Dincă, Mircea. Mon . "Stabilized Vanadium Catalyst for Olefin Polymerization by Site Isolation in a Metal–Organic Framework". Germany. doi:
title = {Stabilized Vanadium Catalyst for Olefin Polymerization by Site Isolation in a Metal–Organic Framework},
author = {Comito, Robert J. and Wu, Zhenwei and Zhang, Guanghui and Lawrence, III, John A. and Korzyński, Maciej D. and Kehl, Jeffrey A. and Miller, Jeffrey T. and Dincă, Mircea},
abstractNote = {},
doi = {10.1002/anie.201803642},
journal = {Angewandte Chemie (International Edition)},
number = 27,
volume = 57,
place = {Germany},
year = {2018},
month = {7}

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Works referenced in this record:

Metal–organic frameworks: versatile heterogeneous catalysts for efficient catalytic organic transformations
journal, January 2015

  • Chughtai, Adeel H.; Ahmad, Nazir; Younus, Hussein A.
  • Chemical Society Reviews, Vol. 44, Issue 19
  • DOI: 10.1039/C4CS00395K

Modular Chemistry: Secondary Building Units as a Basis for the Design of Highly Porous and Robust Metal−Organic Carboxylate Frameworks
journal, April 2001

  • Eddaoudi, Mohamed; Moler, David B.; Li, Hailian
  • Accounts of Chemical Research, Vol. 34, Issue 4, p. 319-330
  • DOI: 10.1021/ar000034b

Synthesis, Structures, and Olefin Polymerization Capability of Vanadium(4+) Imido Compounds with f ac -N 3 Donor Ligands
journal, August 2006

  • Bigmore, Helen R.; Zuideveld, Martin A.; Kowalczyk, Radoslaw M.
  • Inorganic Chemistry, Vol. 45, Issue 16
  • DOI: 10.1021/ic060454i

Homogeneous vanadium-based catalysts for the Ziegler–Natta polymerization of α-olefins
journal, January 2002

  • Hagen, Henk; Boersma, Jaap; van Koten, Gerard
  • Chem. Soc. Rev., Vol. 31, Issue 6
  • DOI: 10.1039/B205238E

Elucidating Gating Effects for Hydrogen Sorption in MFU-4-Type Triazolate-Based Metal-Organic Frameworks Featuring Different Pore Sizes
journal, January 2011

  • Denysenko, Dmytro; Grzywa, Maciej; Tonigold, Markus
  • Chemistry - A European Journal, Vol. 17, Issue 6
  • DOI: 10.1002/chem.201001872

Bimodal polyethylene– Interplay of catalyst and process
journal, January 2001

Transformation of Metal–Organic Framework Secondary Building Units into Hexanuclear Zr-Alkyl Catalysts for Ethylene Polymerization
journal, August 2017

  • Ji, Pengfei; Solomon, Joseph B.; Lin, Zekai
  • Journal of the American Chemical Society, Vol. 139, Issue 33
  • DOI: 10.1021/jacs.7b05761

Immobilization and activation of vanadium(III) and titanium(III) single-site catalysts for ethylene polymerization using MgCl2-based supports
journal, January 2005

  • Severn, John R.; Duchateau, Robbert; Chadwick, John C.
  • Polymer International, Vol. 54, Issue 5
  • DOI: 10.1002/pi.1779

Reversible gas-phase redox processes catalyzed by Co-exchanged MFU-4l(arge)
journal, January 2012

  • Denysenko, Dmytro; Werner, Tamas; Grzywa, Maciej
  • Chem. Commun., Vol. 48, Issue 9
  • DOI: 10.1039/C2CC16235K

Heterogenization of Metallocene Catalysts for Alkene Polymerization
journal, April 1999

Polymerization of ethylene at high temperature by vanadium-based heterogeneous Ziegler—Natta catalysts. II. Study of the activation by halocarbons
journal, April 1994

  • Adisson, E.; Deffieux, A.; Fontanille, M.
  • Journal of Polymer Science Part A: Polymer Chemistry, Vol. 32, Issue 6
  • DOI: 10.1002/pola.1994.080320604

K -edge absorption spectra of selected vanadium compounds
journal, November 1984

Metal–Organic Frameworks (MOFs)
journal, January 2014

  • Zhou, Hong-Cai “Joe”; Kitagawa, Susumu
  • Chem. Soc. Rev., Vol. 43, Issue 16
  • DOI: 10.1039/C4CS90059F

Oxidation of ethane to ethanol by N2O in a metal–organic framework with coordinatively unsaturated iron(II) sites
journal, May 2014

  • Xiao, Dianne J.; Bloch, Eric D.; Mason, Jarad A.
  • Nature Chemistry, Vol. 6, Issue 7
  • DOI: 10.1038/nchem.1956

Preparation and characterization of (R2N)2VCl2 [R=Cy, i-Pr] and its activity as olefin polymerization catalyst
journal, July 1998

  • Desmangles, Natalie; Gambarotta, Sandro; Bensimon, Corinne
  • Journal of Organometallic Chemistry, Vol. 562, Issue 1
  • DOI: 10.1016/S0022-328X(98)00366-0

Highly Active, Thermally Robust V-based New Olefin Polymerization Catalyst System
journal, August 2003

  • Nakayama, Yasushi; Bando, Hideki; Sonobe, Yoshiho
  • Chemistry Letters, Vol. 32, Issue 8
  • DOI: 10.1246/cl.2003.766

Postsynthetic Metal and Ligand Exchange in MFU-4 l : A Screening Approach toward Functional Metal-Organic Frameworks Comprising Single-Site Active Centers
journal, April 2015

  • Denysenko, Dmytro; Jelic, Jelena; Reuter, Karsten
  • Chemistry - A European Journal, Vol. 21, Issue 22
  • DOI: 10.1002/chem.201406564

Introduction to Metal–Organic Frameworks
journal, September 2011

  • Zhou, Hong-Cai; Long, Jeffrey R.; Yaghi, Omar M.
  • Chemical Reviews, Vol. 112, Issue 2, p. 673-674
  • DOI: 10.1021/cr300014x

Vanadium-based Ziegler–Natta: challenges, promises, problems
journal, February 2003

Highly Stereoselective Heterogeneous Diene Polymerization by Co-MFU-4 l : A Single-Site Catalyst Prepared by Cation Exchange
journal, August 2017

  • Dubey, Romain J. -C.; Comito, Robert J.; Wu, Zhenwei
  • Journal of the American Chemical Society, Vol. 139, Issue 36
  • DOI: 10.1021/jacs.7b06841

Metal Organic Framework Catalysis: Quo vadis ?
journal, December 2013

  • Gascon, Jorge; Corma, Avelino; Kapteijn, Freek
  • ACS Catalysis, Vol. 4, Issue 2, p. 361-378
  • DOI: 10.1021/cs400959k

Solvent-Dependent Cation Exchange in Metal-Organic Frameworks
journal, April 2014

  • Brozek, Carl K.; Bellarosa, Luca; Soejima, Tomohiro
  • Chemistry - A European Journal, Vol. 20, Issue 23
  • DOI: 10.1002/chem.201402682

Single-Site Heterogeneous Catalysts for Olefin Polymerization Enabled by Cation Exchange in a Metal-Organic Framework
journal, August 2016

  • Comito, Robert J.; Fritzsching, Keith J.; Sundell, Benjamin J.
  • Journal of the American Chemical Society, Vol. 138, Issue 32
  • DOI: 10.1021/jacs.6b05200

Synthesis, Structure, and Olefin Polymerization Activity of Vanadium(V) Catalysts Stabilized by Imido and Hydrotris(pyrazolyl)borato Ligands
journal, June 1995

  • Scheuer, Sylvie; Fischer, Jean; Kress, Jacky
  • Organometallics, Vol. 14, Issue 6
  • DOI: 10.1021/om00006a006

Selective Dimerization of Propylene with Ni-MFU-4 l
journal, April 2017

Well-defined vanadium complexes as the catalysts for olefin polymerization
journal, October 2011

MOFs, MILs and more: concepts, properties and applications for porous coordination networks (PCNs)
journal, January 2010

  • Janiak, Christoph; Vieth, Jana K.
  • New Journal of Chemistry, Vol. 34, Issue 11
  • DOI: 10.1039/c0nj00275e

Scorpionate-Type Coordination in MFU-4 l Metal-Organic Frameworks: Small-Molecule Binding and Activation upon the Thermally Activated Formation of Open Metal Sites
journal, May 2014

  • Denysenko, Dmytro; Grzywa, Maciej; Jelic, Jelena
  • Angewandte Chemie International Edition, Vol. 53, Issue 23
  • DOI: 10.1002/anie.201310004

Design of Vanadium Complex Catalysts for Precise Olefin Polymerization
journal, March 2011

  • Nomura, Kotohiro; Zhang, Shu
  • Chemical Reviews, Vol. 111, Issue 3
  • DOI: 10.1021/cr100207h

Ti 3+ -, V 2+/3+ -, Cr 2+/3+ -, Mn 2+ -, and Fe 2+ -Substituted MOF-5 and Redox Reactivity in Cr- and Fe-MOF-5
journal, August 2013

  • Brozek, Carl K.; Dincă, Mircea
  • Journal of the American Chemical Society, Vol. 135, Issue 34
  • DOI: 10.1021/ja4064475

A cubic coordination framework constructed from benzobistriazolate ligands and zinc ions having selective gas sorption properties
journal, January 2009

  • Biswas, Shyam; Grzywa, Maciej; Nayek, Hari Pada
  • Dalton Transactions, Issue 33
  • DOI: 10.1039/b904280f

Destruction of chemical warfare agents using metal–organic frameworks
journal, March 2015

  • Mondloch, Joseph E.; Katz, Michael J.; Isley III, William C.
  • Nature Materials, Vol. 14, Issue 5
  • DOI: 10.1038/nmat4238

“Bound but Not Gagged”Immobilizing Single-Site α-Olefin Polymerization Catalysts
journal, November 2005

  • Severn, John R.; Chadwick, John C.; Duchateau, Robbert
  • Chemical Reviews, Vol. 105, Issue 11
  • DOI: 10.1021/cr040670d

Vanadium-based Ziegler-Natta catalyst supported on MgCl2(THF)2 for ethylene polymerization
journal, April 1996

Covalent Chemistry beyond Molecules
journal, February 2016

  • Jiang, Juncong; Zhao, Yingbo; Yaghi, Omar M.
  • Journal of the American Chemical Society, Vol. 138, Issue 10
  • DOI: 10.1021/jacs.5b10666

Single-Site Cobalt Catalysts at New Zr 82 -O) 82 -OH) 4 Metal-Organic Framework Nodes for Highly Active Hydrogenation of Alkenes, Imines, Carbonyls, and Heterocycles
journal, September 2016

  • Ji, Pengfei; Manna, Kuntal; Lin, Zekai
  • Journal of the American Chemical Society, Vol. 138, Issue 37
  • DOI: 10.1021/jacs.6b06759

The Chemistry and Applications of Metal-Organic Frameworks
journal, August 2013

  • Furukawa, H.; Cordova, K. E.; O'Keeffe, M.
  • Science, Vol. 341, Issue 6149, p. 1230444-1230444
  • DOI: 10.1126/science.1230444

Heterogeneous Single-Site Catalysts for Olefin Polymerization
journal, April 2000

Cation exchange at the secondary building units of metal–organic frameworks
journal, January 2014

Metal–Organic Frameworks of Vanadium as Catalysts for Conversion of Methane to Acetic Acid
journal, August 2011

  • Phan, Anh; Czaja, Alexander U.; Gándara, Felipe
  • Inorganic Chemistry, Vol. 50, Issue 16, p. 7388-7390
  • DOI: 10.1021/ic201396m

Single-Site Organozirconium Catalyst Embedded in a Metal–Organic Framework
journal, December 2015

  • Klet, Rachel C.; Tussupbayev, Samat; Borycz, Joshua
  • Journal of the American Chemical Society, Vol. 137, Issue 50
  • DOI: 10.1021/jacs.5b11350

Stabilizing reactive intermediates through site isolation
journal, January 2009