Stabilized Vanadium Catalyst for Olefin Polymerization by Site Isolation in a Metal–Organic Framework
- Authors:
-
- Department of ChemistryMassachusetts Institute of Technology 77 Massachusetts Avenue Cambridge MA 02139 USA
- Davidson School of Chemical EngineeringPurdue University 480 Stadium Mall Dr. West Lafayette IN 47907 USA
- Aramco Research Center—Boston, Aramco Services Company 400 Technology Square Cambridge MA 02139 USA
- Department of ChemistryEugene F. Merkert Chemistry CenterBoston College Chestnut Hill MA 02467 USA
- Publication Date:
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1439486
- Grant/Contract Number:
- AC02-06CH11357
- Resource Type:
- Publisher's Accepted Manuscript
- Journal Name:
- Angewandte Chemie (International Edition)
- Additional Journal Information:
- Journal Name: Angewandte Chemie (International Edition) Journal Volume: 57 Journal Issue: 27; Journal ID: ISSN 1433-7851
- Publisher:
- Wiley Blackwell (John Wiley & Sons)
- Country of Publication:
- Germany
- Language:
- English
Citation Formats
Comito, Robert J., Wu, Zhenwei, Zhang, Guanghui, Lawrence, III, John A., Korzyński, Maciej D., Kehl, Jeffrey A., Miller, Jeffrey T., and Dincă, Mircea. Stabilized Vanadium Catalyst for Olefin Polymerization by Site Isolation in a Metal–Organic Framework. Germany: N. p., 2018.
Web. doi:10.1002/anie.201803642.
Comito, Robert J., Wu, Zhenwei, Zhang, Guanghui, Lawrence, III, John A., Korzyński, Maciej D., Kehl, Jeffrey A., Miller, Jeffrey T., & Dincă, Mircea. Stabilized Vanadium Catalyst for Olefin Polymerization by Site Isolation in a Metal–Organic Framework. Germany. doi:https://doi.org/10.1002/anie.201803642
Comito, Robert J., Wu, Zhenwei, Zhang, Guanghui, Lawrence, III, John A., Korzyński, Maciej D., Kehl, Jeffrey A., Miller, Jeffrey T., and Dincă, Mircea. Mon .
"Stabilized Vanadium Catalyst for Olefin Polymerization by Site Isolation in a Metal–Organic Framework". Germany. doi:https://doi.org/10.1002/anie.201803642.
@article{osti_1439486,
title = {Stabilized Vanadium Catalyst for Olefin Polymerization by Site Isolation in a Metal–Organic Framework},
author = {Comito, Robert J. and Wu, Zhenwei and Zhang, Guanghui and Lawrence, III, John A. and Korzyński, Maciej D. and Kehl, Jeffrey A. and Miller, Jeffrey T. and Dincă, Mircea},
abstractNote = {},
doi = {10.1002/anie.201803642},
journal = {Angewandte Chemie (International Edition)},
number = 27,
volume = 57,
place = {Germany},
year = {2018},
month = {7}
}
Free Publicly Available Full Text
Publisher's Version of Record
DOI: https://doi.org/10.1002/anie.201803642
DOI: https://doi.org/10.1002/anie.201803642
Other availability
Cited by: 9 works
Citation information provided by
Web of Science
Web of Science
Save to My Library
You must Sign In or Create an Account in order to save documents to your library.
Works referenced in this record:
Metal–organic frameworks: versatile heterogeneous catalysts for efficient catalytic organic transformations
journal, January 2015
- Chughtai, Adeel H.; Ahmad, Nazir; Younus, Hussein A.
- Chemical Society Reviews, Vol. 44, Issue 19
Modular Chemistry: Secondary Building Units as a Basis for the Design of Highly Porous and Robust Metal−Organic Carboxylate Frameworks
journal, April 2001
- Eddaoudi, Mohamed; Moler, David B.; Li, Hailian
- Accounts of Chemical Research, Vol. 34, Issue 4, p. 319-330
Synthesis, Structures, and Olefin Polymerization Capability of Vanadium(4+) Imido Compounds with f ac -N 3 Donor Ligands
journal, August 2006
- Bigmore, Helen R.; Zuideveld, Martin A.; Kowalczyk, Radoslaw M.
- Inorganic Chemistry, Vol. 45, Issue 16
Homogeneous vanadium-based catalysts for the Ziegler–Natta polymerization of α-olefins
journal, January 2002
- Hagen, Henk; Boersma, Jaap; van Koten, Gerard
- Chem. Soc. Rev., Vol. 31, Issue 6
Elucidating Gating Effects for Hydrogen Sorption in MFU-4-Type Triazolate-Based Metal-Organic Frameworks Featuring Different Pore Sizes
journal, January 2011
- Denysenko, Dmytro; Grzywa, Maciej; Tonigold, Markus
- Chemistry - A European Journal, Vol. 17, Issue 6
Bimodal polyethylene– Interplay of catalyst and process
journal, January 2001
- Alt, Frank P.; Böhm, Ludwig L.; Enderle, Hans-Frieder
- Macromolecular Symposia, Vol. 163, Issue 1
Transformation of Metal–Organic Framework Secondary Building Units into Hexanuclear Zr-Alkyl Catalysts for Ethylene Polymerization
journal, August 2017
- Ji, Pengfei; Solomon, Joseph B.; Lin, Zekai
- Journal of the American Chemical Society, Vol. 139, Issue 33
Immobilization and activation of vanadium(III) and titanium(III) single-site catalysts for ethylene polymerization using MgCl2-based supports
journal, January 2005
- Severn, John R.; Duchateau, Robbert; Chadwick, John C.
- Polymer International, Vol. 54, Issue 5
Reversible gas-phase redox processes catalyzed by Co-exchanged MFU-4l(arge)
journal, January 2012
- Denysenko, Dmytro; Werner, Tamas; Grzywa, Maciej
- Chem. Commun., Vol. 48, Issue 9
Heterogenization of Metallocene Catalysts for Alkene Polymerization
journal, April 1999
- Abbenhuis, Hendrikus C. L.
- Angewandte Chemie International Edition, Vol. 38, Issue 8
Polymerization of ethylene at high temperature by vanadium-based heterogeneous Ziegler—Natta catalysts. II. Study of the activation by halocarbons
journal, April 1994
- Adisson, E.; Deffieux, A.; Fontanille, M.
- Journal of Polymer Science Part A: Polymer Chemistry, Vol. 32, Issue 6
-edge absorption spectra of selected vanadium compounds
journal, November 1984
- Wong, J.; Lytle, F. W.; Messmer, R. P.
- Physical Review B, Vol. 30, Issue 10
Metal–Organic Frameworks (MOFs)
journal, January 2014
- Zhou, Hong-Cai “Joe”; Kitagawa, Susumu
- Chem. Soc. Rev., Vol. 43, Issue 16
Oxidation of ethane to ethanol by N2O in a metal–organic framework with coordinatively unsaturated iron(II) sites
journal, May 2014
- Xiao, Dianne J.; Bloch, Eric D.; Mason, Jarad A.
- Nature Chemistry, Vol. 6, Issue 7
Preparation and characterization of (R2N)2VCl2 [R=Cy, i-Pr] and its activity as olefin polymerization catalyst
journal, July 1998
- Desmangles, Natalie; Gambarotta, Sandro; Bensimon, Corinne
- Journal of Organometallic Chemistry, Vol. 562, Issue 1
Highly Active, Thermally Robust V-based New Olefin Polymerization Catalyst System
journal, August 2003
- Nakayama, Yasushi; Bando, Hideki; Sonobe, Yoshiho
- Chemistry Letters, Vol. 32, Issue 8
Organometallic vanadium-based heterogeneous catalysts for ethylene polymerization. Study of the deactivation process
journal, March 1998
- Czaja, Krystyna; Białek, Marzena
- Macromolecular Rapid Communications, Vol. 19, Issue 3
Postsynthetic Metal and Ligand Exchange in MFU-4 l : A Screening Approach toward Functional Metal-Organic Frameworks Comprising Single-Site Active Centers
journal, April 2015
- Denysenko, Dmytro; Jelic, Jelena; Reuter, Karsten
- Chemistry - A European Journal, Vol. 21, Issue 22
Introduction to Metal–Organic Frameworks
journal, September 2011
- Zhou, Hong-Cai; Long, Jeffrey R.; Yaghi, Omar M.
- Chemical Reviews, Vol. 112, Issue 2, p. 673-674
Vanadium-based Ziegler–Natta: challenges, promises, problems
journal, February 2003
- Gambarotta, S.
- Coordination Chemistry Reviews, Vol. 237, Issue 1-2
Highly Stereoselective Heterogeneous Diene Polymerization by Co-MFU-4 l : A Single-Site Catalyst Prepared by Cation Exchange
journal, August 2017
- Dubey, Romain J. -C.; Comito, Robert J.; Wu, Zhenwei
- Journal of the American Chemical Society, Vol. 139, Issue 36
Metal Organic Framework Catalysis: Quo vadis ?
journal, December 2013
- Gascon, Jorge; Corma, Avelino; Kapteijn, Freek
- ACS Catalysis, Vol. 4, Issue 2, p. 361-378
Solvent-Dependent Cation Exchange in Metal-Organic Frameworks
journal, April 2014
- Brozek, Carl K.; Bellarosa, Luca; Soejima, Tomohiro
- Chemistry - A European Journal, Vol. 20, Issue 23
Single-Site Heterogeneous Catalysts for Olefin Polymerization Enabled by Cation Exchange in a Metal-Organic Framework
journal, August 2016
- Comito, Robert J.; Fritzsching, Keith J.; Sundell, Benjamin J.
- Journal of the American Chemical Society, Vol. 138, Issue 32
Synthesis, Structure, and Olefin Polymerization Activity of Vanadium(V) Catalysts Stabilized by Imido and Hydrotris(pyrazolyl)borato Ligands
journal, June 1995
- Scheuer, Sylvie; Fischer, Jean; Kress, Jacky
- Organometallics, Vol. 14, Issue 6
Selective Dimerization of Propylene with Ni-MFU-4 l
journal, April 2017
- Comito, Robert J.; Metzger, Eric D.; Wu, Zhenwei
- Organometallics, Vol. 36, Issue 9
Well-defined vanadium complexes as the catalysts for olefin polymerization
journal, October 2011
- Wu, Ji-Qian; Li, Yue-Sheng
- Coordination Chemistry Reviews, Vol. 255, Issue 19-20
Die Heterogenisierung von Metallocenkatalysatoren für Alkenpolymerisationen
journal, April 1999
- Abbenhuis, Hendrikus C. L.
- Angewandte Chemie, Vol. 111, Issue 8
MOFs, MILs and more: concepts, properties and applications for porous coordination networks (PCNs)
journal, January 2010
- Janiak, Christoph; Vieth, Jana K.
- New Journal of Chemistry, Vol. 34, Issue 11
Scorpionate-Type Coordination in MFU-4 l Metal-Organic Frameworks: Small-Molecule Binding and Activation upon the Thermally Activated Formation of Open Metal Sites
journal, May 2014
- Denysenko, Dmytro; Grzywa, Maciej; Jelic, Jelena
- Angewandte Chemie International Edition, Vol. 53, Issue 23
Design of Vanadium Complex Catalysts for Precise Olefin Polymerization
journal, March 2011
- Nomura, Kotohiro; Zhang, Shu
- Chemical Reviews, Vol. 111, Issue 3
Ti 3+ -, V 2+/3+ -, Cr 2+/3+ -, Mn 2+ -, and Fe 2+ -Substituted MOF-5 and Redox Reactivity in Cr- and Fe-MOF-5
journal, August 2013
- Brozek, Carl K.; Dincă, Mircea
- Journal of the American Chemical Society, Vol. 135, Issue 34
Regulation of morphology and mechanical properties of polypropylene/poly(ethylene-co-propylene) in-reactor alloys by multi-stage sequential polymerization
journal, September 2007
- Dong, Qi; Wang, Xiaofeng; Fu, Zhisheng
- Polymer, Vol. 48, Issue 20
A cubic coordination framework constructed from benzobistriazolate ligands and zinc ions having selective gas sorption properties
journal, January 2009
- Biswas, Shyam; Grzywa, Maciej; Nayek, Hari Pada
- Dalton Transactions, Issue 33
Destruction of chemical warfare agents using metal–organic frameworks
journal, March 2015
- Mondloch, Joseph E.; Katz, Michael J.; Isley III, William C.
- Nature Materials, Vol. 14, Issue 5
“Bound but Not Gagged”Immobilizing Single-Site α-Olefin Polymerization Catalysts
journal, November 2005
- Severn, John R.; Chadwick, John C.; Duchateau, Robbert
- Chemical Reviews, Vol. 105, Issue 11
Vanadium-based Ziegler-Natta catalyst supported on MgCl2(THF)2 for ethylene polymerization
journal, April 1996
- Czaja, Krystyna; Białek, Marzena
- Macromolecular Rapid Communications, Vol. 17, Issue 4
Covalent Chemistry beyond Molecules
journal, February 2016
- Jiang, Juncong; Zhao, Yingbo; Yaghi, Omar M.
- Journal of the American Chemical Society, Vol. 138, Issue 10
Single-Site Cobalt Catalysts at New Zr 8 (μ 2 -O) 8 (μ 2 -OH) 4 Metal-Organic Framework Nodes for Highly Active Hydrogenation of Alkenes, Imines, Carbonyls, and Heterocycles
journal, September 2016
- Ji, Pengfei; Manna, Kuntal; Lin, Zekai
- Journal of the American Chemical Society, Vol. 138, Issue 37
Scorpionate-Type Coordination in MFU-4 l Metal-Organic Frameworks: Small-Molecule Binding and Activation upon the Thermally Activated Formation of Open Metal Sites
journal, May 2014
- Denysenko, Dmytro; Grzywa, Maciej; Jelic, Jelena
- Angewandte Chemie, Vol. 126, Issue 23
The Chemistry and Applications of Metal-Organic Frameworks
journal, August 2013
- Furukawa, H.; Cordova, K. E.; O'Keeffe, M.
- Science, Vol. 341, Issue 6149, p. 1230444-1230444
Heterogeneous Single-Site Catalysts for Olefin Polymerization
journal, April 2000
- Hlatky, Gregory G.
- Chemical Reviews, Vol. 100, Issue 4
Cation exchange at the secondary building units of metal–organic frameworks
journal, January 2014
- Brozek, C. K.; Dincă, M.
- Chem. Soc. Rev., Vol. 43, Issue 16
Metal–Organic Frameworks of Vanadium as Catalysts for Conversion of Methane to Acetic Acid
journal, August 2011
- Phan, Anh; Czaja, Alexander U.; Gándara, Felipe
- Inorganic Chemistry, Vol. 50, Issue 16, p. 7388-7390
Single-Site Organozirconium Catalyst Embedded in a Metal–Organic Framework
journal, December 2015
- Klet, Rachel C.; Tussupbayev, Samat; Borycz, Joshua
- Journal of the American Chemical Society, Vol. 137, Issue 50
Stabilizing reactive intermediates through site isolation
journal, January 2009
- Copéret, Christophe
- Pure and Applied Chemistry, Vol. 81, Issue 4
Novel vanadium(II) amine complexes: a facile entry in the chemistry of divalent vanadium. Synthesis and characterization of mononuclear L4VCl2 [L = amine, pyridine]: x-ray structures of trans-(TMEDA)2VCl2 [TMEDA = N,N,N',N'-tetramethylethylenediamine] and trans-Mz2V(py)2 [Mz = o-C6H4CH2N(CH3)2, py = pyridine]
journal, April 1990
- Edema, Jilles J. H.; Stauthamer, Walter; Van Bolhuis, Fre
- Inorganic Chemistry, Vol. 29, Issue 7