Combining CO2 reduction with propane oxidative dehydrogenation over bimetallic catalysts

Gomez, Elaine; Kattel, Shyam; Yan, Binhang; Yao, Siyu; Liu, Ping; Chen, Jingguang G.

doi:10.1038/s41467-018-03793-w

Title: Combining CO₂ reduction with propane oxidative dehydrogenation over bimetallic catalysts

Journal Article · 11 April 2018 · Nature Communications

DOI: https://doi.org/10.1038/s41467-018-03793-w · OSTI ID:1439297

^[1]; Kattel, Shyam ^[2]; Yan, Binhang ^[2]; Yao, Siyu ^[2]; Liu, Ping ^[2];

^[3]

Columbia Univ., New York, NY (United States)
Brookhaven National Lab. (BNL), Upton, NY (United States)
Columbia Univ., New York, NY (United States); Brookhaven National Lab. (BNL), Upton, NY (United States)

In this paper, the inherent variability and insufficiencies in the co-production of propylene from steam crackers has raised concerns regarding the global propylene production gap and has directed industry to develop more on-purpose propylene technologies. The oxidative dehydrogenation of propane by CO₂ (CO₂-ODHP) can potentially fill this gap while consuming a greenhouse gas. Non-precious FeNi and precious NiPt catalysts supported on CeO₂ have been identified as promising catalysts for CO₂-ODHP and dry reforming, respectively, in flow reactor studies conducted at 823 K. In-situ X-ray absorption spectroscopy measurements revealed the oxidation states of metals under reaction conditions and density functional theory calculations were utilized to identify the most favorable reaction pathways over the two types of catalysts.

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Research Organization:: Brookhaven National Laboratory (BNL), Upton, NY (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)

Grant/Contract Number:: SC0012704

OSTI ID:: 1439297

Report Number(s):: BNL--205709-2018-JAAM

Journal Information:: Nature Communications, Journal Name: Nature Communications Journal Issue: 1 Vol. 9; ISSN 2041-1723

Publisher:: Nature Publishing GroupCopyright Statement

Country of Publication:: United States

Language:: English

References (36)

Fundamentals of Industrial Catalytic Processes Bartholomew, Calvin H.; Farrauto, Robert J. John Wiley & Sons, Inc. https://doi.org/10.1002/9780471730071	book	January 2005
Kinetics of the reverse-Boudouard reaction over supported nickel catalysts Osaki, Toshihiko; Mori, Toshiaki Reaction Kinetics and Catalysis Letters, Vol. 89, Issue 2 https://doi.org/10.1007/s11144-006-0145-9	journal	August 2006
Efficiency of ab-initio total energy calculations for metals and semiconductors using a plane-wave basis set Kresse, G.; Furthmüller, J. Computational Materials Science, Vol. 6, Issue 1, p. 15-50 https://doi.org/10.1016/0927-0256(96)00008-0	journal	July 1996
CO 2 reforming of propane over supported Rh Solymosi, F.; Tolmacsov, P.; Kedves, K. Journal of Catalysis, Vol. 216, Issue 1-2 https://doi.org/10.1016/S0021-9517(02)00071-4	journal	May 2003
Selective oxidehydrogenation of ethane with CO2 over CeO2-based catalysts Valenzuela, Rita X.; Bueno, Gema; Cortés Corberán, Vicente Catalysis Today, Vol. 61, Issue 1-4 https://doi.org/10.1016/S0920-5861(00)00366-7	journal	August 2000
Promoting effects of CO2 on dehydrogenation of propane over a SiO2-supported Cr2O3 catalyst Takahara, I.; Chang, W. -C; Mimura, N. Catalysis Today, Vol. 45, Issue 1-4 https://doi.org/10.1016/S0920-5861(98)00245-4	journal	October 1998
Oxidative dehydrogenation of ethane to ethylene by carbon dioxide over Cr/TiO 2 –ZrO 2 nanocatalyst: Effect of active phase and support composition on catalytic properties and performance Talati, Azadeh; Haghighi, Mohammad; Rahmani, Farhad Advanced Powder Technology, Vol. 27, Issue 4 https://doi.org/10.1016/j.apt.2016.04.003	journal	July 2016
Light alkanes CO2 reforming to synthesis gas over Ni based catalysts Olafsen, A.; Daniel, C.; Schuurman, Y. Catalysis Today, Vol. 115, Issue 1-4 https://doi.org/10.1016/j.cattod.2006.02.053	journal	June 2006
Opportunities and prospects in the chemical recycling of carbon dioxide to fuels Centi, Gabriele; Perathoner, Siglinda Catalysis Today, Vol. 148, Issue 3-4 https://doi.org/10.1016/j.cattod.2009.07.075	journal	November 2009
The role of the Boudouard and water–gas shift reactions in the methanation of CO or CO2 over Ni/γ-Al2O3 catalyst Lim, Jin Yang; McGregor, James; Sederman, Andrew J. Chemical Engineering Science, Vol. 152 https://doi.org/10.1016/j.ces.2016.06.042	journal	October 2016
Dry reforming of propane over supported Re catalyst Solymosi, F.; Tolmacsov, P.; Zakar, T. Journal of Catalysis, Vol. 233, Issue 1 https://doi.org/10.1016/j.jcat.2005.04.013	journal	July 2005
Propane dry reforming to synthesis gas over Ni-based catalysts: Influence of support and operating parameters on catalyst activity and stability Raberg, L.; Jensen, M.; Olsbye, U. Journal of Catalysis, Vol. 249, Issue 2 https://doi.org/10.1016/j.jcat.2007.04.004	journal	July 2007
CO2Oxidative Dehydrogenation of Ethane to Ethylene over Cr/MCM-41 Nanocatalyst Synthesized via Hydrothermal/Impregnation Methods: Influence of Chromium Content on Catalytic Properties and Performance Asghari, Elmira; Haghighi, Mohammad; Rahmani, Farhad Journal of Molecular Catalysis A: Chemical, Vol. 418-419 https://doi.org/10.1016/j.molcata.2016.03.033	journal	July 2016
Enhanced Carbon-Resistant Dry Reforming Fe-Ni Catalyst: Role of Fe Theofanidis, Stavros Alexandros; Galvita, Vladimir V.; Poelman, Hilde ACS Catalysis, Vol. 5, Issue 5 https://doi.org/10.1021/acscatal.5b00357	journal	March 2015
Dry Reforming of Ethane and Butane with CO ₂ over PtNi/CeO ₂ Bimetallic Catalysts Yan, Binhang; Yang, Xiaofang; Yao, Siyu ACS Catalysis, Vol. 6, Issue 11 https://doi.org/10.1021/acscatal.6b02176	journal	September 2016
Preparation of Highly Dispersed Chromium Oxide Catalysts Supported on Mesoporous Silica for the Oxidative Dehydrogenation of Propane Using CO ₂ : Insight into the Nature of Catalytically Active Chromium Sites Baek, Jayeon; Yun, Hyeong Jin; Yun, Danim ACS Catalysis, Vol. 2, Issue 9 https://doi.org/10.1021/cs300198u	journal	August 2012
Catalytic Conversion of Alkanes to Olefins by Carbon Dioxide Oxidative DehydrogenationA Review Wang, Shaobin; Zhu, Z. H. Energy & Fuels, Vol. 18, Issue 4 https://doi.org/10.1021/ef0340716	journal	July 2004
Kinetic Study of Propane CO ₂ Reforming over Bimetallic Mo–Ni/Al ₂ O ₃ Catalyst Siahvashi, Arman; Adesina, Adesoji A. Industrial & Engineering Chemistry Research, Vol. 52, Issue 44 https://doi.org/10.1021/ie400637w	journal	June 2013
Cooperativity and Dynamics Increase the Performance of NiFe Dry Reforming Catalysts Kim, Sung Min; Abdala, Paula Macarena; Margossian, Tigran Journal of the American Chemical Society, Vol. 139, Issue 5 https://doi.org/10.1021/jacs.6b11487	journal	January 2017
An extreme event of sea-level rise along the Northeast coast of North America in 2009–2010 Goddard, Paul B.; Yin, Jianjun; Griffies, Stephen M. Nature Communications, Vol. 6, Issue 1 https://doi.org/10.1038/ncomms7346	journal	February 2015
Reducing Dzyaloshinskii-Moriya interaction and field-free spin-orbit torque switching in synthetic antiferromagnets Chen, Ruyi; Cui, Qirui; Liao, Liyang Nature Communications, Vol. 12, Issue 1 https://doi.org/10.1038/s41467-021-23414-3	journal	May 2021
High-resolution X-ray luminescence extension imaging Ou, Xiangyu; Qin, Xian; Huang, Bolong Nature, Vol. 590, Issue 7846 https://doi.org/10.1038/s41586-021-03251-6	journal	February 2021
Electronic structure of AlFeN films exhibiting crystallographic orientation change from c- to a-axis with Fe concentrations and annealing effect Tatemizo, Nobuyuki; Imada, Saki; Okahara, Kizuna Scientific Reports, Vol. 10, Issue 1 https://doi.org/10.1038/s41598-020-58835-5	journal	February 2020
A review of dry (CO ₂ ) reforming of methane over noble metal catalysts Pakhare, Devendra; Spivey, James Chem. Soc. Rev., Vol. 43, Issue 22 https://doi.org/10.1039/C3CS60395D	journal	January 2014
Methane activation: the past and future Tang, Pei; Zhu, Qingjun; Wu, Zhaoxuan Energy Environ. Sci., Vol. 7, Issue 8 https://doi.org/10.1039/C4EE00604F	journal	January 2014
Carbon dioxide utilization as a soft oxidant and promoter in catalysis Ansari, Mohd Bismillah; Park, Sang-Eon Energy & Environmental Science, Vol. 5, Issue 11 https://doi.org/10.1039/c2ee22409g	journal	January 2012
A climbing image nudged elastic band method for finding saddle points and minimum energy paths Henkelman, Graeme; Uberuaga, Blas P.; Jónsson, Hannes The Journal of Chemical Physics, Vol. 113, Issue 22, p. 9901-9904 https://doi.org/10.1063/1.1329672	journal	December 2000
Inhomogeneous Electron Gas Hohenberg, P.; Kohn, W. Physical Review, Vol. 136, Issue 3B, p. B864-B871 https://doi.org/10.1103/PhysRev.136.B864	journal	November 1964
Self-Consistent Equations Including Exchange and Correlation Effects Kohn, W.; Sham, L. J. Physical Review, Vol. 140, Issue 4A, p. A1133-A1138 https://doi.org/10.1103/PhysRev.140.A1133	journal	November 1965
Special points for Brillouin-zone integrations Monkhorst, Hendrik J.; Pack, James D. Physical Review B, Vol. 13, Issue 12, p. 5188-5192 https://doi.org/10.1103/PhysRevB.13.5188	journal	June 1976
Accurate and simple analytic representation of the electron-gas correlation energy Perdew, John P.; Wang, Yue Physical Review B, Vol. 45, Issue 23, p. 13244-13249 https://doi.org/10.1103/PhysRevB.45.13244	journal	June 1992
Ab initio molecular dynamics for open-shell transition metals Kresse, G.; Hafner, J. Physical Review B, Vol. 48, Issue 17 https://doi.org/10.1103/PhysRevB.48.13115	journal	November 1993
Projector augmented-wave method Blöchl, P. E. Physical Review B, Vol. 50, Issue 24, p. 17953-17979 https://doi.org/10.1103/PhysRevB.50.17953	journal	December 1994
From ultrasoft pseudopotentials to the projector augmented-wave method Kresse, G.; Joubert, D. Physical Review B, Vol. 59, Issue 3, p. 1758-1775 https://doi.org/10.1103/PhysRevB.59.1758	journal	January 1999
Inhomogeneous Electron Gas Rajagopal, A. K.; Callaway, J. Physical Review B, Vol. 7, Issue 5 https://doi.org/10.1103/physrevb.7.1912	journal	March 1973
The role of the Boudouard and water–gas shift reactions in the methanation of CO or CO$_2$ over Ni/γ-Al$_2$O$_3$ catalyst Lim, Jin Yang; McGregor, James; Sederman, Andy Apollo - University of Cambridge Repository https://doi.org/10.17863/cam.802	text	January 2016

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Enhancing Activity and Reducing Cost for Electrochemical Reduction of CO ₂ by Supporting Palladium on Metal Carbides Wang, Jiajun; Kattel, Shyam; Hawxhurst, Christopher J. Angewandte Chemie International Edition, Vol. 58, Issue 19 https://doi.org/10.1002/anie.201900781	journal	April 2019
Vibrational Spectroscopic Characterization of Glycerol Reaction Pathways over Metal‐Modified Molybdenum Carbide Surfaces Wan, Weiming; Lin, Zhexi; Chen, Jingguang G. ChemCatChem, Vol. 12, Issue 1 https://doi.org/10.1002/cctc.201901629	journal	October 2019
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Insights into the role of nanoalloy surface compositions toward catalytic acetone hydrogenation Yang, Zhao; Zhu, Huaze; Zhu, Huijuan Chemical Communications, Vol. 54, Issue 60 https://doi.org/10.1039/c8cc04293d	journal	January 2018
Escaping undesired gas-phase chemistry: Microwave-driven selectivity enhancement in heterogeneous catalytic reactors Ramirez, A.; Hueso, J. L.; Abian, M. Science Advances, Vol. 5, Issue 3 https://doi.org/10.1126/sciadv.aau9000	journal	March 2019

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