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Title: Formal Nickelate(−I) Complexes Supported by Group 13 Ions

Authors:
ORCiD logo [1]; ORCiD logo [1];  [1];  [1]; ORCiD logo [2]; ORCiD logo [1]; ORCiD logo [1]
  1. Department of Chemistry and Supercomputing Institute, University of Minnesota, 207 Pleasant St. SE Minneapolis MN 55455 USA
  2. Max-Planck-Institut für chemische Energiekonversion, Stiftstraße 34-36 45470 Mülheim an der Ruhr Germany
Publication Date:
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
OSTI Identifier:
1439265
Grant/Contract Number:  
SC0012702
Resource Type:
Publisher's Accepted Manuscript
Journal Name:
Angewandte Chemie (International Edition)
Additional Journal Information:
Journal Name: Angewandte Chemie (International Edition) Journal Volume: 57 Journal Issue: 26; Journal ID: ISSN 1433-7851
Publisher:
Wiley Blackwell (John Wiley & Sons)
Country of Publication:
Germany
Language:
English

Citation Formats

Vollmer, Matthew V., Xie, Jing, Cammarota, Ryan C., Young, Jr., Victor G., Bill, Eckhard, Gagliardi, Laura, and Lu, Connie C. Formal Nickelate(−I) Complexes Supported by Group 13 Ions. Germany: N. p., 2018. Web. doi:10.1002/anie.201803356.
Vollmer, Matthew V., Xie, Jing, Cammarota, Ryan C., Young, Jr., Victor G., Bill, Eckhard, Gagliardi, Laura, & Lu, Connie C. Formal Nickelate(−I) Complexes Supported by Group 13 Ions. Germany. doi:10.1002/anie.201803356.
Vollmer, Matthew V., Xie, Jing, Cammarota, Ryan C., Young, Jr., Victor G., Bill, Eckhard, Gagliardi, Laura, and Lu, Connie C. Mon . "Formal Nickelate(−I) Complexes Supported by Group 13 Ions". Germany. doi:10.1002/anie.201803356.
@article{osti_1439265,
title = {Formal Nickelate(−I) Complexes Supported by Group 13 Ions},
author = {Vollmer, Matthew V. and Xie, Jing and Cammarota, Ryan C. and Young, Jr., Victor G. and Bill, Eckhard and Gagliardi, Laura and Lu, Connie C.},
abstractNote = {},
doi = {10.1002/anie.201803356},
journal = {Angewandte Chemie (International Edition)},
number = 26,
volume = 57,
place = {Germany},
year = {2018},
month = {5}
}

Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record
DOI: 10.1002/anie.201803356

Citation Metrics:
Cited by: 8 works
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Works referenced in this record:

Generalized Gradient Approximation Made Simple
journal, October 1996

  • Perdew, John P.; Burke, Kieron; Ernzerhof, Matthias
  • Physical Review Letters, Vol. 77, Issue 18, p. 3865-3868
  • DOI: 10.1103/PhysRevLett.77.3865

A Phosphine-Coordinated Boron-Centered Gomberg-Type Radical
journal, June 2015

  • Rosenthal, Amos J.; Devillard, Marc; Miqueu, Karinne
  • Angewandte Chemie, Vol. 127, Issue 32
  • DOI: 10.1002/ange.201504502

Dilithium-Nickel-Olefin Complexes. Novel Bimetal Complexes Containing a Transition Metal and a Main Group Metal
journal, November 1975

  • Jonas, Klaus
  • Angewandte Chemie International Edition in English, Vol. 14, Issue 11
  • DOI: 10.1002/anie.197507521

A Co2N2 Diamond-Core Resting State of Cobalt(I): A Three-Coordinate CoI Synthon Invoking an Unusual Pincer-Type Rearrangement
journal, May 2006

  • Fout, Alison R.; Basuli, Falguni; Fan, Hongjun
  • Angewandte Chemie International Edition, Vol. 45, Issue 20
  • DOI: 10.1002/anie.200504343

Dinitrogen Activation at Iron and Cobalt Metallalumatranes
journal, July 2013

  • Rudd, P. Alex; Planas, Nora; Bill, Eckhard
  • European Journal of Inorganic Chemistry, Vol. 2013, Issue 22-23
  • DOI: 10.1002/ejic.201300272

Sigma Bonded Radical Cation Complexes:  A Theoretical Study
journal, June 2002

  • Maity, Dilip K.
  • The Journal of Physical Chemistry A, Vol. 106, Issue 23
  • DOI: 10.1021/jp025880d

Nitrogen Fixation via a Terminal Fe(IV) Nitride
journal, October 2017

  • Thompson, Niklas B.; Green, Michael T.; Peters, Jonas C.
  • Journal of the American Chemical Society, Vol. 139, Issue 43
  • DOI: 10.1021/jacs.7b09364

Stable GaX2, InX2 and TlX2 radicals
journal, February 2014

  • Protchenko, Andrey V.; Dange, Deepak; Harmer, Jeffrey R.
  • Nature Chemistry, Vol. 6, Issue 4
  • DOI: 10.1038/nchem.1870

Alkali Metal-Transition Metalπ-Complexes
journal, July 1980

  • Jonas, Klaus; Krüger, Carl
  • Angewandte Chemie International Edition in English, Vol. 19, Issue 7
  • DOI: 10.1002/anie.198005201

Reduction of a Tetraaryldigallane to Afford a Radical Anion with GaGa Multiple Bonding Character
journal, May 1993

  • He, Xiaoming; Bartlett, Ruth A.; Olmstead, Marilyn M.
  • Angewandte Chemie International Edition in English, Vol. 32, Issue 5
  • DOI: 10.1002/anie.199307171

Dinuclear Metalloradicals Featuring Unsupported Metal-Metal Bonds
journal, July 2012

  • van der Eide, Edwin F.; Yang, Ping; Walter, Eric D.
  • Angewandte Chemie International Edition, Vol. 51, Issue 33
  • DOI: 10.1002/anie.201203531

Generation of a RuII–Semiquinone–Anilino-Radical Complex through the Deprotonation of a RuIII–Semiquinone–Anilido Complex
journal, July 2007

  • Miyazato, Yuji; Wada, Tohru; Muckerman, James T.
  • Angewandte Chemie, Vol. 119, Issue 30
  • DOI: 10.1002/ange.200701600

Odd-electron .sigma. bonds
journal, March 1988

  • Clark, Timothy.
  • Journal of the American Chemical Society, Vol. 110, Issue 6
  • DOI: 10.1021/ja00214a003

Adventures with Substances Containing Metals in Negative Oxidation States
journal, April 2006


Two-Center/Three-Electron Sigma Half-Bonds in Main Group and Transition Metal Chemistry
journal, January 2016


Aerobic Oxidation of Primary Alcohols (Including Methanol) by Copper(II)− and Zinc(II)−Phenoxyl Radical Catalysts
journal, October 1999

  • Chaudhuri, Phalguni; Hess, Martina; Müller, Jochen
  • Journal of the American Chemical Society, Vol. 121, Issue 41
  • DOI: 10.1021/ja991481t

Isocyano Analogues of [Co(CO) 4 ] n : A Tetraisocyanide of Cobalt Isolated in Three States of Charge
journal, April 2010

  • Margulieux, Grant W.; Weidemann, Nils; Lacy, David C.
  • Journal of the American Chemical Society, Vol. 132, Issue 14
  • DOI: 10.1021/ja1012382

An AlAl One-Electronπ Bond
journal, March 1993

  • Pluta, Christian; Pörschke, Klaus-R.; Krüger, Carl
  • Angewandte Chemie International Edition in English, Vol. 32, Issue 3
  • DOI: 10.1002/anie.199303881

A Fractional Bond Order of 1/2 in Pd 2 5+ −Formamidinate Species; The Value of Very High-Field EPR Spectra
journal, February 2007

  • Berry, John F.; Bill, Eckhard; Bothe, Eberhard
  • Journal of the American Chemical Society, Vol. 129, Issue 5
  • DOI: 10.1021/ja067328y

Leveraging molecular metal–support interactions for H2 and N2 activation
journal, March 2017

  • Cammarota, Ryan C.; Clouston, Laura J.; Lu, Connie C.
  • Coordination Chemistry Reviews, Vol. 334
  • DOI: 10.1016/j.ccr.2016.06.014

An Intramolecular Boron−Boron One-Electron σ-Bond
journal, September 2000

  • Hoefelmeyer, James D.; Gabbaï, François P.
  • Journal of the American Chemical Society, Vol. 122, Issue 37
  • DOI: 10.1021/ja001739b

A consistent and accurate ab initio parametrization of density functional dispersion correction (DFT-D) for the 94 elements H-Pu
journal, April 2010

  • Grimme, Stefan; Antony, Jens; Ehrlich, Stephan
  • The Journal of Chemical Physics, Vol. 132, Issue 15
  • DOI: 10.1063/1.3382344

Reduction of a tetraaryldialane to generate aluminum-aluminum .pi.-bonding
journal, July 1993

  • Wehmschulte, Rudolf J.; Ruhlandt-Senge, Karin; Olmstead, Marilyn M.
  • Inorganic Chemistry, Vol. 32, Issue 14
  • DOI: 10.1021/ic00066a002

Covalent radii revisited
journal, January 2008

  • Cordero, Beatriz; Gómez, Verónica; Platero-Prats, Ana E.
  • Dalton Transactions, Issue 21
  • DOI: 10.1039/b801115j

Alkalimetall-Übergangsmetall-π-Komplexe
journal, July 1980


Redox-active ligands in catalysis
journal, January 2013

  • Luca, Oana R.; Crabtree, Robert H.
  • Chem. Soc. Rev., Vol. 42, Issue 4
  • DOI: 10.1039/C2CS35228A

Electronic Structure of Ni 2 E 2 Complexes (E = S, Se, Te) and a Global Analysis of M 2 E 2 Compounds: A Case for Quantized E 2 n Oxidation Levels with n = 2, 3, or 4
journal, April 2015

  • Yao, Shu A.; Martin-Diaconescu, Vlad; Infante, Ivan
  • Journal of the American Chemical Society, Vol. 137, Issue 15
  • DOI: 10.1021/ja511607j

Tuning Nickel with Lewis Acidic Group 13 Metalloligands for Catalytic Olefin Hydrogenation
journal, September 2015

  • Cammarota, Ryan C.; Lu, Connie C.
  • Journal of the American Chemical Society, Vol. 137, Issue 39
  • DOI: 10.1021/jacs.5b08313

Production of carbonyl anions by the vacuum ultraviolet photolysis of matrix isolated metal carbonyls
journal, January 1973

  • Burdett, Jeremy K.
  • Journal of the Chemical Society, Chemical Communications, Issue 19
  • DOI: 10.1039/c39730000763

Dinuclear Metalloradicals Featuring Unsupported Metal-Metal Bonds
journal, July 2012

  • van der Eide, Edwin F.; Yang, Ping; Walter, Eric D.
  • Angewandte Chemie, Vol. 124, Issue 33
  • DOI: 10.1002/ange.201203531

A complete active space SCF method (CASSCF) using a density matrix formulated super-CI approach
journal, May 1980


Tris(tri-tert-butylsilyl)digallanyl(tBu3Si)3Ga2: A New Type of Compound for a Heavy Group 13 Element
journal, June 1997

  • Wiberg, Nils; Amelunxen, Kerstin; Nöth, Heinrich
  • Angewandte Chemie International Edition in English, Vol. 36, Issue 11
  • DOI: 10.1002/anie.199712131

Charged carbonyls in matrices. Infrared structural characterization of tricarbonylnickel(1-), pentacarbonylchromium(1-), and tetracarbonyliron(1-)
journal, October 1981

  • Breeze, Paul A.; Burdett, Jeremy K.; Turner, James J.
  • Inorganic Chemistry, Vol. 20, Issue 10
  • DOI: 10.1021/ic50224a044

An e.s.r. study of the gallane radical anion
journal, January 1984

  • Brand, John C.; Roberts, Brian P.
  • Journal of the Chemical Society, Chemical Communications, Issue 2
  • DOI: 10.1039/c39840000109

Generalized Gradient Approximation Made Simple [Phys. Rev. Lett. 77, 3865 (1996)]
journal, February 1997


Stable Mononuclear Radical Anions of Heavier Group 13 Elements:  [( t Bu 2 MeSi) 3 E •- ]·[K + (2.2.2-Cryptand)] (E = Al, Ga)
journal, May 2005

  • Nakamoto, Masaaki; Yamasaki, Tomoki; Sekiguchi, Akira
  • Journal of the American Chemical Society, Vol. 127, Issue 19
  • DOI: 10.1021/ja051814o

Reduktion eines Digallans zu einem Radikalanion mit Ga-Ga-Mehrfachbindungscharakter
journal, May 1993

  • He, Xiaoming; Bartlett, Ruth A.; Olmstead, Marilyn M.
  • Angewandte Chemie, Vol. 105, Issue 5
  • DOI: 10.1002/ange.19931050523

Terminal Iron Carbyne Complexes Derived from Arrested CO 2 Reductive Disproportionation
journal, July 2017

  • Mokhtarzadeh, Charles C.; Moore, Curtis E.; Rheingold, Arnold L.
  • Angewandte Chemie, Vol. 129, Issue 36
  • DOI: 10.1002/ange.201705877

Are One-Electron Bonds Any Different from Standard Two-Electron Covalent Bonds?
journal, August 2017

  • Sousa, David Wilian Oliveira de; Nascimento, Marco Antonio Chaer
  • Accounts of Chemical Research, Vol. 50, Issue 9
  • DOI: 10.1021/acs.accounts.7b00260

A new local density functional for main-group thermochemistry, transition metal bonding, thermochemical kinetics, and noncovalent interactions
journal, November 2006

  • Zhao, Yan; Truhlar, Donald G.
  • The Journal of Chemical Physics, Vol. 125, Issue 19, Article No. 194101
  • DOI: 10.1063/1.2370993

Characterization of Intermediary Redox States of the Water Oxidation Catalyst, [Ru(bpy) 2 (OH 2 )] 2 O 4+
journal, May 2009

  • Cape, Jonathan L.; Lymar, Sergei V.; Lightbody, Travis
  • Inorganic Chemistry, Vol. 48, Issue 10
  • DOI: 10.1021/ic9001219

Alkene Metalates as Hydrogenation Catalysts
journal, February 2017

  • Büschelberger, Philipp; Gärtner, Dominik; Reyes-Rodriguez, Efrain
  • Chemistry - A European Journal, Vol. 23, Issue 13
  • DOI: 10.1002/chem.201605222

Zwitterionic Stabilization of a Reactive Cobalt Tris-Isocyanide Monoanion by Cation Coordination
journal, August 2012

  • Carpenter, Alex E.; Margulieux, Grant W.; Millard, Matthew D.
  • Angewandte Chemie International Edition, Vol. 51, Issue 37
  • DOI: 10.1002/anie.201205058

A Phosphine-Coordinated Boron-Centered Gomberg-Type Radical
journal, June 2015

  • Rosenthal, Amos J.; Devillard, Marc; Miqueu, Karinne
  • Angewandte Chemie International Edition, Vol. 54, Issue 32
  • DOI: 10.1002/anie.201504502

E.s.r. spectra and reactivity of alane radical anions in solution
journal, January 1981

  • Giles, Jeremy R. M.; Roberts, Brian P.
  • Journal of the Chemical Society, Chemical Communications, Issue 22
  • DOI: 10.1039/c39810001167

A Co2N2 Diamond-Core Resting State of Cobalt(I): A Three-Coordinate CoI Synthon Invoking an Unusual Pincer-Type Rearrangement
journal, May 2006

  • Fout, Alison R.; Basuli, Falguni; Fan, Hongjun
  • Angewandte Chemie, Vol. 118, Issue 20
  • DOI: 10.1002/ange.200504343

Configuring Bonds between First-Row Transition Metals
journal, October 2015


Disodium tetracarbonylferrate, a transition metal analog of a Grignard reagent
journal, October 1975


Isolation of Neutral Mononuclear Copper Complexes Stabilized by Two Cyclic (Alkyl)(amino)carbenes
journal, April 2014

  • Weinberger, David S.; Amin SK, Nurul; Mondal, Kartik Chandra
  • Journal of the American Chemical Society, Vol. 136, Issue 17
  • DOI: 10.1021/ja502521b

Metal Carbonyl Anions:  from [Fe(CO) 4 ] 2 - to [Hf(CO) 6 ] 2 - and Beyond
journal, August 2003


Tris(tri-tert-butylsilyl)digallanyl (tBu3Si)3Ga2 - ein neuer Verbindungstyp eines schweren Borgruppenelements
journal, June 1997


Terminal Iron Carbyne Complexes Derived from Arrested CO 2 Reductive Disproportionation
journal, July 2017

  • Mokhtarzadeh, Charles C.; Moore, Curtis E.; Rheingold, Arnold L.
  • Angewandte Chemie International Edition, Vol. 56, Issue 36
  • DOI: 10.1002/anie.201705877

Metal–Alane Adducts with Zero-Valent Nickel, Cobalt, and Iron
journal, December 2011

  • Rudd, P. Alex; Liu, Shengsi; Gagliardi, Laura
  • Journal of the American Chemical Society, Vol. 133, Issue 51
  • DOI: 10.1021/ja2099744

Eine Al-Al-Einelektronen-π-Bindung
journal, March 1993

  • Pluta, Clirisiian; Porschke, Klaus-R.; Krüger, Carl
  • Angewandte Chemie, Vol. 105, Issue 3
  • DOI: 10.1002/ange.19931050330

Generation of a RuII–Semiquinone–Anilino-Radical Complex through the Deprotonation of a RuIII–Semiquinone–Anilido Complex
journal, July 2007

  • Miyazato, Yuji; Wada, Tohru; Muckerman, James T.
  • Angewandte Chemie International Edition, Vol. 46, Issue 30
  • DOI: 10.1002/anie.200701600

Bindungen mit ungerader Elektronenzahl und Biradikale in der Chemie der Hauptgruppenelemente
journal, November 2002


Zwitterionic Stabilization of a Reactive Cobalt Tris-Isocyanide Monoanion by Cation Coordination
journal, August 2012

  • Carpenter, Alex E.; Margulieux, Grant W.; Millard, Matthew D.
  • Angewandte Chemie, Vol. 124, Issue 37
  • DOI: 10.1002/ange.201205058

A Polar Copper–Boron One-Electron σ-Bond
journal, March 2013

  • Moret, Marc-Etienne; Zhang, Limei; Peters, Jonas C.
  • Journal of the American Chemical Society, Vol. 135, Issue 10
  • DOI: 10.1021/ja4006578

Odd-Electron Bonds and Biradicals in Main Group Element Chemistry
journal, November 2002


Persistent and Stable Radicals of the Heavier Main Group Elements and Related Species
journal, March 2003