In Situ Analysis of Solvent and Additive Effects on Film Morphology Evolution in Spin-Cast Small-Molecule and Polymer Photovoltaic Materials
Abstract
Abstract To elucidate the details of film morphology/order evolution during spin‐coating, solvent and additive effects are systematically investigated for three representative organic solar cell (OSC) active layer materials using combined in situ grazing incidence wide angle x‐ray scattering (GIWAXS) and optical reflectance. Two archetypical semiconducting donor (p‐type) polymers, P3HT and PTB7, and semiconducting donor small‐molecule, p ‐DTS(FBTTh 2 ) 2 are studied using three neat solvents (chloroform, chlorobenzene, 1,2‐dichlorobenzene) and four processing additives (1‐chloronaphthalene, diphenyl ether, 1,8‐diiodooctane, and 1,6‐diiodohexane). In situ GIWAXS identifies several trends: 1) for neat solvents, rapid crystallization occurs that risks kinetically locking the material into multiple crystal structures or crystalline orientations; and 2) for solvent + additive processed films, morphology evolution involves sequential transformations on timescales ranging from seconds to hours, with key divergences dependent on additive/semiconductor molecular interactions. When π‐planes dominate the additive/semiconductor interactions, both polymers and small molecule films follow similar evolutions, completing in 1–5 min. When side chains dominate the additive/semiconductor interactions, polymer film maturation times are up to 9 h, while initial crystallization times <10 s are observed for small‐molecule films. This study offers guiding information on OSC donor intermediate morphologies, evolution timescales, and divergent evolutions that can inform OSC manufacture.
- Authors:
-
- Northwestern Univ., Evanston, IL (United States). Dept. of Chemistry and the Argonne-Northwestern Solar Energy Research (ANSER) Center; Argonne National Lab. (ANL), Argonne, IL (United States). Chemical Sciences and Engineering Division
- Argonne National Lab. (ANL), Argonne, IL (United States). X-Ray Science Division
- Northwestern Univ., Evanston, IL (United States). Dept. of Chemistry and the Argonne-Northwestern Solar Energy Research (ANSER) Center
- Publication Date:
- Research Org.:
- Energy Frontier Research Centers (EFRC) (United States). Center for Light Energy Activated Redox Processes (LEAP); Argonne National Laboratory (ANL), Argonne, IL (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES); National Science Foundation (NSF); Qatar NPRP
- OSTI Identifier:
- 1471497
- Alternate Identifier(s):
- OSTI ID: 1439115
- Grant/Contract Number:
- AC02-06CH11357; SC0001059; FG02-08ER46536; 7-286-1-046; 0960140; DE‐SC0001059; DE‐FG02‐08ER46536; DE‐AC02‐06CH11357
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Advanced Energy Materials
- Additional Journal Information:
- Journal Volume: 8; Journal Issue: 23; Journal ID: ISSN 1614-6832
- Publisher:
- Wiley
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 25 ENERGY STORAGE; 36 MATERIALS SCIENCE; additives; in situ GIWAXS; organic solar cells; polymer; spin-coating
Citation Formats
Manley, Eric F., Strzalka, Joseph, Fauvell, Thomas J., Marks, Tobin J., and Chen, Lin X. In Situ Analysis of Solvent and Additive Effects on Film Morphology Evolution in Spin-Cast Small-Molecule and Polymer Photovoltaic Materials. United States: N. p., 2018.
Web. doi:10.1002/aenm.201800611.
Manley, Eric F., Strzalka, Joseph, Fauvell, Thomas J., Marks, Tobin J., & Chen, Lin X. In Situ Analysis of Solvent and Additive Effects on Film Morphology Evolution in Spin-Cast Small-Molecule and Polymer Photovoltaic Materials. United States. https://doi.org/10.1002/aenm.201800611
Manley, Eric F., Strzalka, Joseph, Fauvell, Thomas J., Marks, Tobin J., and Chen, Lin X. Fri .
"In Situ Analysis of Solvent and Additive Effects on Film Morphology Evolution in Spin-Cast Small-Molecule and Polymer Photovoltaic Materials". United States. https://doi.org/10.1002/aenm.201800611. https://www.osti.gov/servlets/purl/1471497.
@article{osti_1471497,
title = {In Situ Analysis of Solvent and Additive Effects on Film Morphology Evolution in Spin-Cast Small-Molecule and Polymer Photovoltaic Materials},
author = {Manley, Eric F. and Strzalka, Joseph and Fauvell, Thomas J. and Marks, Tobin J. and Chen, Lin X.},
abstractNote = {Abstract To elucidate the details of film morphology/order evolution during spin‐coating, solvent and additive effects are systematically investigated for three representative organic solar cell (OSC) active layer materials using combined in situ grazing incidence wide angle x‐ray scattering (GIWAXS) and optical reflectance. Two archetypical semiconducting donor (p‐type) polymers, P3HT and PTB7, and semiconducting donor small‐molecule, p ‐DTS(FBTTh 2 ) 2 are studied using three neat solvents (chloroform, chlorobenzene, 1,2‐dichlorobenzene) and four processing additives (1‐chloronaphthalene, diphenyl ether, 1,8‐diiodooctane, and 1,6‐diiodohexane). In situ GIWAXS identifies several trends: 1) for neat solvents, rapid crystallization occurs that risks kinetically locking the material into multiple crystal structures or crystalline orientations; and 2) for solvent + additive processed films, morphology evolution involves sequential transformations on timescales ranging from seconds to hours, with key divergences dependent on additive/semiconductor molecular interactions. When π‐planes dominate the additive/semiconductor interactions, both polymers and small molecule films follow similar evolutions, completing in 1–5 min. When side chains dominate the additive/semiconductor interactions, polymer film maturation times are up to 9 h, while initial crystallization times <10 s are observed for small‐molecule films. This study offers guiding information on OSC donor intermediate morphologies, evolution timescales, and divergent evolutions that can inform OSC manufacture.},
doi = {10.1002/aenm.201800611},
journal = {Advanced Energy Materials},
number = 23,
volume = 8,
place = {United States},
year = {Fri May 25 00:00:00 EDT 2018},
month = {Fri May 25 00:00:00 EDT 2018}
}
Web of Science
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