DOE PAGES title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: The nanoscale structure of the electrolyte–metal oxide interface

Journal Article · · Energy & Environmental Science
DOI: https://doi.org/10.1039/c7ee02724a · OSTI ID:1439106

Combined experimental and theoretical insights into electrolyte–electrode interfaces relevant to lithium ion batteries.

Research Organization:
SLAC National Accelerator Laboratory (SLAC), Menlo Park, CA (United States)
Sponsoring Organization:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
Grant/Contract Number:
AC02-76SF00515; FOA-0000559
OSTI ID:
1439106
Journal Information:
Energy & Environmental Science, Vol. 11, Issue 3; ISSN 1754-5692
Publisher:
Royal Society of ChemistryCopyright Statement
Country of Publication:
United States
Language:
English

References (66)

Ramifications of Water-in-Salt Interfacial Structure at Charged Electrodes for Electrolyte Electrochemical Stability journal August 2017
Atomic-Scale Structure of a Liquid Metal−Insulator Interface journal March 2010
“Charge-Transfer” Process at Graphite/Electrolyte Interface and the Solvation Sheath Structure of Li[sup +] in Nonaqueous Electrolytes journal January 2007
A New Lipid Anchor for Sparsely Tethered Bilayer Lipid Membranes journal April 2009
Modeling Insight into Battery Electrolyte Electrochemical Stability and Interfacial Structure journal November 2017
In Situ Potentiodynamic Analysis of the Electrolyte/Silicon Electrodes Interface Reactions - A Sum Frequency Generation Vibrational Spectroscopy Study journal January 2016
Solid-liquid interfaces of ionic liquid solutions—Interfacial layering and bulk correlations journal April 2015
Liquid Surfaces and Interfaces: Synchrotron X-ray Methods book September 2012
Ion Distributions near a Liquid-Liquid Interface journal January 2006
Layering of a liquid metal in contact with a hard wall journal November 1997
Structural Investigations of Self-Assembled Monolayers for Organic Electronics: Results from X-ray Reflectivity journal June 2015
Complementary Molecular Dynamics and X-ray Reflectivity Study of an Imidazolium-Based Ionic Liquid at a Neutral Sapphire Interface journal January 2015
Surface Tension Measurements of Surface Freezing in Liquid Normal Alkanes journal August 1993
Model Approach in Heterogeneous Catalysis: Kinetics and Thermodynamics of Surface Reactions journal September 2015
X-Ray Reflectivity Measurements of Surface Layering in Liquid Mercury journal May 1995
Electrode/Electrolyte Interface in Sulfolane-Based Electrolytes for Li Ion Batteries: A Molecular Dynamics Simulation Study journal November 2012
Atomistic Modeling of the Electrode–Electrolyte Interface in Li-Ion Energy Storage Systems: Electrolyte Structuring journal February 2013
Checkerboard Self-Patterning of an Ionic Liquid Film on Mercury journal May 2011
Melting and freezing at surfaces journal August 1999
Nonaqueous Liquid Electrolytes for Lithium-Based Rechargeable Batteries journal October 2004
Electrolytes and Interphases in Li-Ion Batteries and Beyond journal October 2014
PDFgetX2: a GUI-driven program to obtain the pair distribution function from X-ray powder diffraction data journal July 2004
Untersuchungen zur Totalreflexion von Röntgenstrahlen journal January 1931
Influence of surface topology and electrostatic potential on water/electrode systems journal January 1995
Development of novel lithium borate additives for designed surface modification of high voltage LiNi 0.5 Mn 1.5 O 4 cathodes journal January 2016
Electrochemical interface between an ionic liquid and a model metallic electrode journal February 2007
A review of molecular modelling of electric double layer capacitors journal January 2014
A Gouy–Chapman–Stern model of the double layer at a (metal)/(ionic liquid) interface journal February 2008
Surface Layering at the Mercury-Electrolyte Interface journal March 2010
Solvated Li-Ion Transfer at Interface Between Graphite and Electrolyte journal January 2004
Nanoscale Structure of the Oil-Water Interface journal December 2016
Molecular Layering of Fluorinated Ionic Liquids at a Charged Sapphire (0001) Surface journal October 2008
Observation of Surface Layering in a Nonmetallic Liquid journal March 2006
Electrical double layers. 4. Limitations of the Gouy-Chapman theory journal August 1982
Anion Solvation in Carbonate-Based Electrolytes journal November 2015
In Situ Study of Silicon Electrode Lithiation with X-ray Reflectivity journal November 2016
Studies of the Electrochemical Double Layer at (100) Au in Perchloric Acid Solutions by In Situ Infrared Spectroscopy journal January 1996
Order and Melting in Self-Assembled Alkanol Monolayers on Amorphous SiO 2 journal July 2015
Unifying Interfacial Self-Assembly and Surface Freezing journal March 2011
Structure of Water Adsorbed on a Mica Surface journal August 2002
Pseudorotational Epitaxy of Self-Assembled Octadecyltrichlorosilane Monolayers on Sapphire (0001) journal October 2014
Origin of Interface Magnetism in BiMnO 3 / SrTiO 3 and LaAlO 3 / SrTiO 3 Heterostructures journal August 2013
Surface Layering in Liquid Gallium: An X-Ray Reflectivity Study journal September 1995
Particle mesh Ewald method for three-dimensional systems with two-dimensional periodicity journal May 2001
The Lotus Effect:  Superhydrophobicity and Metastability journal April 2004
Solvation Sheath of Li + in Nonaqueous Electrolytes and Its Implication of Graphite/Electrolyte Interface Chemistry journal May 2007
Atomic-Scale Quantification of Grain Boundary Segregation in Nanocrystalline Material journal March 2014
Decay of interfacial fluid ordering probed by X-ray reflectivity journal January 2012
Molecular Structure of Canonical Liquid Crystal Interfaces journal March 2017
Differentiating Contributions to “Ion Transfer” Barrier from Interphasial Resistance and Li + Desolvation at Electrolyte/Graphite Interface journal July 2010
Low-Voltage Self-Assembled Monolayer Field-Effect Transistors on Flexible Substrates journal June 2013
Molecular-Scale Density Oscillations in Water Adjacent to a Mica Surface journal September 2001
Troika II: a versatile beamline for the study of liquid and solid interfaces journal April 2005
Observation of Molecular Layering in Thin Liquid Films Using X-Ray Reflectivity journal March 1999
Voltage-Controlled Interfacial Layering in an Ionic Liquid on SrTiO 3 journal March 2016
Polarizable Force Field Development and Molecular Dynamics Simulations of Ionic Liquids journal August 2009
Molecular Dynamics Simulation Studies of the Structure of a Mixed Carbonate/LiPF 6 Electrolyte near Graphite Surface as a Function of Electrode Potential journal December 2011
Voltage-dependent ordering of water molecules at an electrode–electrolyte interface journal March 1994
Avogadro: an advanced semantic chemical editor, visualization, and analysis platform journal August 2012
A smooth particle mesh Ewald method journal November 1995
Critical Drying of Liquids journal October 2016
Preferential Adsorption of Solvents on the Cathode Surface of Lithium Ion Batteries journal April 2013
Preferential Adsorption of Solvents on the Cathode Surface of Lithium Ion Batteries journal April 2013
Nonaqueous Liquid Electrolytes for Lithium-Based Rechargeable Batteries journal December 2004
Molecular-Scale Density Oscillations in Water Adjacent to a Mica Surface text January 2001
Voltage Controlled Interfacial Layering in an Ionic Liquid on SrTiO$_3$ text January 2016

Cited By (3)


Figures / Tables (7)