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Title: Trigonal antiprismatic Co(ii) single molecule magnets with large uniaxial anisotropies: importance of Raman and tunneling mechanisms

Abstract

A trigonal antiprismatic Co(ii) molecule exhibits counterion-dependent relaxation of the magnetization due to the importance of the Raman relaxation process.

Authors:
 [1]; ORCiD logo [2];  [2];  [3]; ORCiD logo [2]; ORCiD logo [2]
  1. Texas A & M Univ., College Station, TX (United States); South Univ. of Science and Technology of China, Shenzhen (People's Republic of China)
  2. Texas A & M Univ., College Station, TX (United States)
  3. Texas A & M Univ., College Station, TX (United States); Fayoum Univ., Fayoum (Egypt)
Publication Date:
Research Org.:
Texas A & M Univ., College Station, TX (United States)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22). Materials Sciences & Engineering Division
OSTI Identifier:
1439059
Grant/Contract Number:  
FG02-02ER45999; SC0012582
Resource Type:
Accepted Manuscript
Journal Name:
Chemical Science
Additional Journal Information:
Journal Volume: 7; Journal Issue: 10; Journal ID: ISSN 2041-6520
Publisher:
Royal Society of Chemistry
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Citation Formats

Zhang, Yuan -Zhu, Gomez-Coca, Silvia, Brown, Andrew J., Saber, Mohamed R., Zhang, Xuan, and Dunbar, Kim R. Trigonal antiprismatic Co(ii) single molecule magnets with large uniaxial anisotropies: importance of Raman and tunneling mechanisms. United States: N. p., 2016. Web. doi:10.1039/c6sc02035f.
Zhang, Yuan -Zhu, Gomez-Coca, Silvia, Brown, Andrew J., Saber, Mohamed R., Zhang, Xuan, & Dunbar, Kim R. Trigonal antiprismatic Co(ii) single molecule magnets with large uniaxial anisotropies: importance of Raman and tunneling mechanisms. United States. doi:10.1039/c6sc02035f.
Zhang, Yuan -Zhu, Gomez-Coca, Silvia, Brown, Andrew J., Saber, Mohamed R., Zhang, Xuan, and Dunbar, Kim R. Fri . "Trigonal antiprismatic Co(ii) single molecule magnets with large uniaxial anisotropies: importance of Raman and tunneling mechanisms". United States. doi:10.1039/c6sc02035f. https://www.osti.gov/servlets/purl/1439059.
@article{osti_1439059,
title = {Trigonal antiprismatic Co(ii) single molecule magnets with large uniaxial anisotropies: importance of Raman and tunneling mechanisms},
author = {Zhang, Yuan -Zhu and Gomez-Coca, Silvia and Brown, Andrew J. and Saber, Mohamed R. and Zhang, Xuan and Dunbar, Kim R.},
abstractNote = {A trigonal antiprismatic Co(ii) molecule exhibits counterion-dependent relaxation of the magnetization due to the importance of the Raman relaxation process.},
doi = {10.1039/c6sc02035f},
journal = {Chemical Science},
number = 10,
volume = 7,
place = {United States},
year = {2016},
month = {6}
}

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Cited by: 53 works
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    • Habib, Fatemah; Luca, Oana R.; Vieru, Veacheslav
    • Angewandte Chemie International Edition, Vol. 52, Issue 43
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    • Dalton Transactions, Vol. 46, Issue 36
    • DOI: 10.1039/c7dt02556d

    A new series of tetrahedral Co( ii ) complexes [CoLX 2 ] (X = NCS, Cl, Br, I) manifesting single-ion magnet features
    journal, January 2018

    • Mondal, Amit Kumar; Sundararajan, Mahesh; Konar, Sanjit
    • Dalton Transactions, Vol. 47, Issue 11
    • DOI: 10.1039/c7dt04007e

    Transition metal complexes of a versatile polyalkoxy oxazolidine-based ligand derived from in situ cyclization
    journal, January 2018

    • Saleem, Ayaan; Kobielska, Paulina A.; Harms, Klaus
    • Dalton Transactions, Vol. 47, Issue 17
    • DOI: 10.1039/c7dt04634k

    Enforcing Ising-like magnetic anisotropy via trigonal distortion in the design of a W( v )–Co( ii ) cyanide single-chain magnet
    journal, January 2018

    • Zhang, Yuan-Zhu; Dolinar, Brian S.; Liu, Shihao
    • Chemical Science, Vol. 9, Issue 1
    • DOI: 10.1039/c7sc02925j

    Switching single chain magnet behavior via photoinduced bidirectional metal-to-metal charge transfer
    journal, January 2018

    • Jiang, Wenjing; Jiao, Chengqi; Meng, Yinshan
    • Chemical Science, Vol. 9, Issue 3
    • DOI: 10.1039/c7sc03401f

    Field-induced single-molecule magnet behavior in ideal trigonal antiprismatic cobalt( ii ) complexes: precise geometrical control by a hydrogen-bonded rigid metalloligand
    journal, January 2018

    • Mitsuhashi, Ryoji; Pedersen, Kasper S.; Ueda, Takaaki
    • Chemical Communications, Vol. 54, Issue 64
    • DOI: 10.1039/c8cc04756a

    Slow magnetic relaxation in a {Co II CoIII2} complex containing a high magnetic anisotropy trigonal bipyramidal Co II centre
    journal, January 2018

    • Collet, Alexandra; Craig, Gavin A.; Heras Ojea, María José
    • Dalton Transactions, Vol. 47, Issue 28
    • DOI: 10.1039/c8dt01997e

    Single-ion magnetic anisotropy in a vacant octahedral Co( ii ) complex
    journal, January 2019

    • Mondal, Amit Kumar; Jover, Jesús; Ruiz, Eliseo
    • Dalton Transactions, Vol. 48, Issue 1
    • DOI: 10.1039/c8dt03862g

    Field-induced slow magnetic relaxation in pseudooctahedral cobalt( ii ) complexes with positive axial and large rhombic anisotropy
    journal, January 2019

    • Świtlicka, Anna; Palion-Gazda, Joanna; Machura, Barbara
    • Dalton Transactions, Vol. 48, Issue 4
    • DOI: 10.1039/c8dt03965h

    Slow magnetization dynamics in Co( ii )/Co( iii ) triethanolamine/pivalate complexes
    journal, January 2018

    • Sarto, Carolina; Rouzières, Mathieu; Liu, Jun-Liang
    • Dalton Transactions, Vol. 47, Issue 47
    • DOI: 10.1039/c8dt04041a

    Diazine based ligand supported CoII3 and CoII4 coordination complexes: role of anions
    journal, January 2018

    • Sikdar, Yeasin; Goswami, Ranadip; Modak, Ritwik
    • New Journal of Chemistry, Vol. 42, Issue 21
    • DOI: 10.1039/c8nj02955e

    Field-induced slow magnetic relaxation of two 1-D compounds containing six-coordinated cobalt( ii ) ions: influence of the coordination geometry
    journal, January 2018

    • Chen, Zhiwei; Yin, Lei; Mi, Xiuna
    • Inorganic Chemistry Frontiers, Vol. 5, Issue 9
    • DOI: 10.1039/c8qi00388b

    Anionic guest-dependent slow magnetic relaxation in Co( ii ) tripodal iminopyridine complexes
    journal, January 2019

    • Klug, Christina M.; Ozumerzifon, Tarik J.; Bhowmick, Indrani
    • Dalton Transactions, Vol. 48, Issue 25
    • DOI: 10.1039/c9dt00739c

    Effects of ligand substituents on the single-molecule magnetic behavior of quinonoid-bridged dicobalt compounds
    journal, January 2020