Trigonal antiprismatic Co(ii) single molecule magnets with large uniaxial anisotropies: importance of Raman and tunneling mechanisms

Zhang, Yuan -Zhu; Gomez-Coca, Silvia; Brown, Andrew J.; Saber, Mohamed R.; Zhang, Xuan; Dunbar, Kim R.

doi:10.1039/c6sc02035f

Title: Trigonal antiprismatic Co(ii) single molecule magnets with large uniaxial anisotropies: importance of Raman and tunneling mechanisms

Journal Article · 17 June 2016 · Chemical Science

DOI: https://doi.org/10.1039/c6sc02035f · OSTI ID:1439059

Zhang, Yuan -Zhu ^[1];

^[2]; Brown, Andrew J. ^[2]; Saber, Mohamed R. ^[3];

^[2];

^[2]

Texas A & M Univ., College Station, TX (United States); South Univ. of Science and Technology of China, Shenzhen (People's Republic of China); Texas A&M University
Texas A & M Univ., College Station, TX (United States)
Texas A & M Univ., College Station, TX (United States); Fayoum Univ., Fayoum (Egypt)

A trigonal antiprismatic Co(ii) molecule exhibits counterion-dependent relaxation of the magnetization due to the importance of the Raman relaxation process.

View Accepted Manuscript (DOE)

Cite

Export

Save

Research Organization:: Texas A & M Univ., College Station, TX (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22). Materials Sciences & Engineering Division

Grant/Contract Number:: FG02-02ER45999; SC0012582

OSTI ID:: 1439059

Journal Information:: Chemical Science, Journal Name: Chemical Science Journal Issue: 10 Vol. 7; ISSN 2041-6520; ISSN CSHCBM

Publisher:: Royal Society of ChemistryCopyright Statement

Country of Publication:: United States

Language:: English

References (124)

Quantum Tunneling of Magnetization and Related Phenomena in Molecular Materials Gatteschi, Dante; Sessoli, Roberta Angewandte Chemie International Edition, Vol. 42, Issue 3 https://doi.org/10.1002/anie.200390099	journal	January 2003
Influence of the Ligand Field on Slow Magnetization Relaxation versus Spin Crossover in Mononuclear Cobalt Complexes Habib, Fatemah; Luca, Oana R.; Vieru, Veacheslav Angewandte Chemie International Edition, Vol. 52, Issue 43 https://doi.org/10.1002/anie.201303005	journal	September 2013
Syntheses, Structures and Electronic Properties of Zwitterionic Iron(II) and Cobalt(II) Complexes Featuring Ambidentate Tris(pyrazolyl)methanide Ligands Kuzu, Istemi; Krummenacher, Ivo; Hewitt, Ian J. Chemistry - A European Journal, Vol. 15, Issue 17 https://doi.org/10.1002/chem.200802317	journal	April 2009
Triimidosulfonates as Acute Bite-Angle Chelates: Slow Relaxation of the Magnetization in Zero Field and Hysteresis Loop of a Co ^II Complex Carl, Elena; Demeshko, Serhiy; Meyer, Franc Chemistry - A European Journal, Vol. 21, Issue 28 https://doi.org/10.1002/chem.201406083	journal	June 2015
PHI: A powerful new program for the analysis of anisotropic monomeric and exchange-coupled polynuclear d - and f -block complexes Chilton, Nicholas F.; Anderson, Russell P.; Turner, Lincoln D. Journal of Computational Chemistry, Vol. 34, Issue 13 https://doi.org/10.1002/jcc.23234	journal	February 2013
Distortion Pathways of Transition Metal Coordination Polyhedra Induced by Chelating Topology Alvarez, Santiago Chemical Reviews, Vol. 115, Issue 24 https://doi.org/10.1021/acs.chemrev.5b00537	journal	November 2015
A Family of Co ^II Co ^III ₃ Single-Ion Magnets with Zero-Field Slow Magnetic Relaxation: Fine Tuning of Energy Barrier by Remote Substituent and Counter Cation Zhu, Yuan-Yuan; Zhang, Yi-Quan; Yin, Ting-Ting Inorganic Chemistry, Vol. 54, Issue 11 https://doi.org/10.1021/acs.inorgchem.5b00526	journal	May 2015
Structural, Electronic, and Magnetic Properties of {Fe[HC(3,5-Me ₂ pz) ₃ ] ₂ }(BF ₄ ) ₂ (pz = Pyrazolyl): Observation of Unusual Spin-Crossover Behavior Reger, Daniel L.; Little, Christine A.; Rheingold, Arnold L. Inorganic Chemistry, Vol. 39, Issue 21 https://doi.org/10.1021/ic000721z	journal	October 2000
Single-Molecule Magnets Constructed from Cyanometalates: {[Tp*Fe ^III (CN) ₃ M ^II (DMF) ₄ ] ₂ [OTf] ₂ }·2DMF (M ^II = Co, Ni) Li, Dongfeng; Parkin, Sean; Wang, Guangbin Inorganic Chemistry, Vol. 44, Issue 14 https://doi.org/10.1021/ic048367i	journal	July 2005
An S = 2 Cyanide-Bridged Trinuclear Fe ^III ₂ Ni ^II Single-Molecule Magnet Li, Dongfeng; Clérac, Rodolphe; Parkin, Sean Inorganic Chemistry, Vol. 45, Issue 14 https://doi.org/10.1021/ic060379b	journal	July 2006
Synthesis and Coordination Chemistry of a New N ₄ -Polydentate Class of Pyridyl-Functionalized Scorpionate Ligands: Complexes of Fe ^II , Zn ^II , Ni ^II , V ^IV , Pd ^II and Use for Heterobimetallic Systems Wanke, Riccardo; Guedes da Silva, M. Fátima C.; Lancianesi, Stefano Inorganic Chemistry, Vol. 49, Issue 17 https://doi.org/10.1021/ic100966u	journal	September 2010
Detailed Ab Initio First-Principles Study of the Magnetic Anisotropy in a Family of Trigonal Pyramidal Iron(II) Pyrrolide Complexes Atanasov, Mihail; Ganyushin, Dmitry; Pantazis, Dimitrios A. Inorganic Chemistry, Vol. 50, Issue 16 https://doi.org/10.1021/ic200196k	journal	August 2011
Pyrazolylborates and Their Importance in Tuning Single-Molecule Magnet Properties of {Fe ^III ₂ Ni ^II } Complexes Zhang, Yuan-Zhu; Mallik, Uma P.; Rath, Nigam P. Inorganic Chemistry, Vol. 50, Issue 21 https://doi.org/10.1021/ic2017825	journal	November 2011
Tris(5-methylpyrazolyl)methane: Synthesis and Properties of Its Iron(II) Complex Goodman, Margaret A.; Nazarenko, Alexander Y.; Casavant, Barbara J. Inorganic Chemistry, Vol. 51, Issue 2 https://doi.org/10.1021/ic2022038	journal	December 2011
Tuning Transverse Anisotropy in Co ^III –Co ^II –Co ^III Mixed-Valence Complex toward Slow Magnetic Relaxation Wu, Dayu; Zhang, Xingxing; Huang, Ping Inorganic Chemistry, Vol. 52, Issue 19 https://doi.org/10.1021/ic401057f	journal	September 2013
Slow Magnetic Relaxation in Trigonal-Planar Mononuclear Fe(II) and Co(II) Bis(trimethylsilyl)amido Complexes—A Comparative Study Eichhöfer, Andreas; Lan, Yanhua; Mereacre, Valeriu Inorganic Chemistry, Vol. 53, Issue 4 https://doi.org/10.1021/ic401677j	journal	December 2013
Slow Magnetic Relaxation in Octahedral Cobalt(II) Field-Induced Single-Ion Magnet with Positive Axial and Large Rhombic Anisotropy Herchel, Radovan; Váhovská, Lucia; Potočňák, Ivan Inorganic Chemistry, Vol. 53, Issue 12 https://doi.org/10.1021/ic500916u	journal	May 2014
Field-Induced Slow Magnetic Relaxation in Cobalt(II) Compounds with Pentagonal Bipyramid Geometry Huang, Xing-Cai; Zhou, Chun; Shao, Dong Inorganic Chemistry, Vol. 53, Issue 24 https://doi.org/10.1021/ic502006s	journal	November 2014
Cobalt(II) Coordination Polymer Exhibiting Single-Ion-Magnet-Type Field-Induced Slow Relaxation Behavior Zhu, Yuan-Yuan; Zhu, Ming-Sheng; Yin, Ting-Ting Inorganic Chemistry, Vol. 54, Issue 8 https://doi.org/10.1021/ic5029299	journal	March 2015
Molecular Cube of Re ^II and Mn ^II That Exhibits Single-Molecule Magnetism Schelter, Eric J.; Prosvirin, Andrey V.; Dunbar, Kim R. Journal of the American Chemical Society, Vol. 126, Issue 46 https://doi.org/10.1021/ja047088r	journal	November 2004
The Observation of Superparamagnetic Behavior in Molecular Nanowires Wang, Shi; Zuo, Jing-Lin; Gao, Song Journal of the American Chemical Society, Vol. 126, Issue 29 https://doi.org/10.1021/ja0483995	journal	July 2004
An S = 6 Cyanide-Bridged Octanuclear Fe ^III ₄ Ni ^II ₄ Complex that Exhibits Slow Relaxation of the Magnetization Li, Dongfeng; Parkin, Sean; Wang, Guangbin Journal of the American Chemical Society, Vol. 128, Issue 13 https://doi.org/10.1021/ja058626i	journal	April 2006
A Family of Mixed-Metal Cyanide Cubes with Alternating Octahedral and Tetrahedral Corners Exhibiting a Variety of Magnetic Behaviors Including Single Molecule Magnetism Schelter, Eric J.; Karadas, Ferdi; Avendano, Carolina Journal of the American Chemical Society, Vol. 129, Issue 26 https://doi.org/10.1021/ja0683281	journal	July 2007
Single-Molecule Magnet Behavior with a Single Metal Center Enhanced through Peripheral Ligand Modifications Jurca, Titel; Farghal, Ahmed; Lin, Po-Heng Journal of the American Chemical Society, Vol. 133, Issue 40 https://doi.org/10.1021/ja204562m	journal	October 2011
Field-Induced Slow Magnetic Relaxation in a Six-Coordinate Mononuclear Cobalt(II) Complex with a Positive Anisotropy Vallejo, Julia; Castro, Isabel; Ruiz-García, Rafael Journal of the American Chemical Society, Vol. 134, Issue 38 https://doi.org/10.1021/ja3075314	journal	September 2012
Mononuclear Single-Molecule Magnets: Tailoring the Magnetic Anisotropy of First-Row Transition-Metal Complexes Gomez-Coca, Silvia; Cremades, Eduard; Aliaga-Alcalde, Núria Journal of the American Chemical Society, Vol. 135, Issue 18 https://doi.org/10.1021/ja4015138	journal	April 2013
A four-coordinate cobalt(II) single-ion magnet with coercivity and a very high energy barrier Rechkemmer, Yvonne; Breitgoff, Frauke D.; van der Meer, Margarethe Nature Communications, Vol. 7, Issue 1 https://doi.org/10.1038/ncomms10467	journal	February 2016
Origin of slow magnetic relaxation in Kramers ions with non-uniaxial anisotropy Gómez-Coca, Silvia; Urtizberea, Ainhoa; Cremades, Eduard Nature Communications, Vol. 5, Issue 1 https://doi.org/10.1038/ncomms5300	journal	July 2014
Accurate Coulomb-fitting basis sets for H to Rn Weigend, Florian Physical Chemistry Chemical Physics, Vol. 8, Issue 9 https://doi.org/10.1039/b515623h	journal	January 2006
Spin crossover in di-, tri- and tetranuclear, mixed-ligand tris(pyrazolyl)methane iron(ii) complexes Schneider, Caspar J.; Moubaraki, Boujemaa; Cashion, John D. Dalton Transactions, Vol. 40, Issue 26 https://doi.org/10.1039/c0dt01725f	journal	January 2011
A density functional study of the spin state energetics of polypyrazolylborato complexes of first-row transition metals Gruden-Pavlović, M.; Stepanović, S.; Perić, M. Physical Chemistry Chemical Physics, Vol. 16, Issue 28 https://doi.org/10.1039/c3cp55488k	journal	January 2014
3d single-ion magnets Craig, Gavin A.; Murrie, Mark Chemical Society Reviews, Vol. 44, Issue 8 https://doi.org/10.1039/c4cs00439f	journal	January 2015
Slow magnetic relaxation in mononuclear seven-coordinate cobalt( ii ) complexes with easy plane anisotropy Chen, Lei; Chen, Shu-Yang; Sun, Yi-Chen Dalton Transactions, Vol. 44, Issue 25 https://doi.org/10.1039/c5dt00785b	journal	January 2015
A mononuclear Ni( ii ) complex: a field induced single-molecule magnet showing two slow relaxation processes Miklovič, Jozef; Valigura, Dušan; Boča, Roman Dalton Transactions, Vol. 44, Issue 28 https://doi.org/10.1039/c5dt01213a	journal	January 2015
Quantum Tunneling of Magnetization in Lanthanide Single-Molecule Magnets: Bis(phthalocyaninato)terbium and Bis(phthalocyaninato)dysprosium Anions Ishikawa, Naoto; Sugita, Miki; Wernsdorfer, Wolfgang Angewandte Chemie, Vol. 117, Issue 19 https://doi.org/10.1002/ange.200462638	journal	May 2005
Influence of the Ligand Field on Slow Magnetization Relaxation versus Spin Crossover in Mononuclear Cobalt Complexes Habib, Fatemah; Luca, Oana R.; Vieru, Veacheslav Angewandte Chemie, Vol. 125, Issue 43 https://doi.org/10.1002/ange.201303005	journal	September 2013
Slow Magnetic Relaxation in a Co ^II –Y ^III Single‐Ion Magnet with Positive Axial Zero‐Field Splitting Colacio, Enrique; Ruiz, José; Ruiz, Eliseo Angewandte Chemie, Vol. 125, Issue 35 https://doi.org/10.1002/ange.201304386	journal	July 2013
Quantum Tunneling of Magnetization and Related Phenomena in Molecular Materials Gatteschi, Dante; Sessoli, Roberta Angewandte Chemie International Edition, Vol. 42, Issue 3 https://doi.org/10.1002/anie.200390099	journal	January 2003
Quantum Tunneling of Magnetization in Lanthanide Single-Molecule Magnets: Bis(phthalocyaninato)terbium and Bis(phthalocyaninato)dysprosium Anions Ishikawa, Naoto; Sugita, Miki; Wernsdorfer, Wolfgang Angewandte Chemie International Edition, Vol. 44, Issue 19 https://doi.org/10.1002/anie.200462638	journal	May 2005
Influence of the Ligand Field on Slow Magnetization Relaxation versus Spin Crossover in Mononuclear Cobalt Complexes Habib, Fatemah; Luca, Oana R.; Vieru, Veacheslav Angewandte Chemie International Edition, Vol. 52, Issue 43 https://doi.org/10.1002/anie.201303005	journal	September 2013
Slow Magnetic Relaxation in a Co ^II -Y ^III Single-Ion Magnet with Positive Axial Zero-Field Splitting Colacio, Enrique; Ruiz, José; Ruiz, Eliseo Angewandte Chemie International Edition, Vol. 52, Issue 35 https://doi.org/10.1002/anie.201304386	journal	July 2013
Syntheses, Structures and Electronic Properties of Zwitterionic Iron(II) and Cobalt(II) Complexes Featuring Ambidentate Tris(pyrazolyl)methanide Ligands Kuzu, Istemi; Krummenacher, Ivo; Hewitt, Ian J. Chemistry - A European Journal, Vol. 15, Issue 17 https://doi.org/10.1002/chem.200802317	journal	April 2009
Triimidosulfonates as Acute Bite-Angle Chelates: Slow Relaxation of the Magnetization in Zero Field and Hysteresis Loop of a Co ^II Complex Carl, Elena; Demeshko, Serhiy; Meyer, Franc Chemistry - A European Journal, Vol. 21, Issue 28 https://doi.org/10.1002/chem.201406083	journal	June 2015
Quantum Tunneling of Magnetization and Related Phenomena in Molecular Materials Gatteschi, Dante; Sessoli, Roberta ChemInform, Vol. 34, Issue 16 https://doi.org/10.1002/chin.200316300	journal	April 2003
A Study of the Electronic Spin-State Crossover in {Fe[HC(3,4,5-Me3pz)3]2}(BF4)2 Reger, Daniel L.; Elgin, J. Derek; Smith, Mark D. European Journal of Inorganic Chemistry, Vol. 2004, Issue 16 https://doi.org/10.1002/ejic.200300973	journal	August 2004
A Click-Functionalized Single-Molecule Magnet Based on Cobalt(II) and Its Analogous Manganese(II) and Zinc(II) Compounds: A Click-Functionalized Single-Molecule Magnet Plenk, Christian; Krause, Jasmin; Rentschler, Eva European Journal of Inorganic Chemistry, Vol. 2015, Issue 3 https://doi.org/10.1002/ejic.201402955	journal	December 2014
PHI: A powerful new program for the analysis of anisotropic monomeric and exchange-coupled polynuclear d - and f -block complexes Chilton, Nicholas F.; Anderson, Russell P.; Turner, Lincoln D. Journal of Computational Chemistry, Vol. 34, Issue 13 https://doi.org/10.1002/jcc.23234	journal	February 2013
The ORCA program system: The ORCA program system Neese, Frank Wiley Interdisciplinary Reviews: Computational Molecular Science, Vol. 2, Issue 1 https://doi.org/10.1002/wcms.81	journal	June 2011
Syntheses of tris(pyrazolyl)methane ligands and {[tris(pyrazolyl)methane]Mn(CO)3}SO3CF3 complexes: comparison of ligand donor properties Reger, Daniel L.; Grattan, T. Christian; Brown, Kenneth J. Journal of Organometallic Chemistry, Vol. 607, Issue 1-2 https://doi.org/10.1016/S0022-328X(00)00290-4	journal	August 2000
Shape maps and polyhedral interconversion paths in transition metal chemistry Alvarez, S.; Alemany, P.; Casanova, D. Coordination Chemistry Reviews, Vol. 249, Issue 17-18 https://doi.org/10.1016/j.ccr.2005.03.031	journal	September 2005
Strategies towards single-chain magnets Sun, Hao-Ling; Wang, Zhe-Ming; Gao, Song Coordination Chemistry Reviews, Vol. 254, Issue 9-10 https://doi.org/10.1016/j.ccr.2010.02.010	journal	May 2010
First principles approach to the electronic structure, magnetic anisotropy and spin relaxation in mononuclear 3d-transition metal single molecule magnets Atanasov, Mihail; Aravena, Daniel; Suturina, Elizaveta Coordination Chemistry Reviews, Vol. 289-290 https://doi.org/10.1016/j.ccr.2014.10.015	journal	April 2015
Large magnetic anisotropy in mononuclear metal complexes Gómez-Coca, Silvia; Aravena, Daniel; Morales, Roser Coordination Chemistry Reviews, Vol. 289-290 https://doi.org/10.1016/j.ccr.2015.01.021	journal	April 2015
Magnetic anisotropy in two- to eight-coordinated transition–metal complexes: Recent developments in molecular magnetism Bar, Arun Kumar; Pichon, Céline; Sutter, Jean-Pascal Coordination Chemistry Reviews, Vol. 308 https://doi.org/10.1016/j.ccr.2015.06.013	journal	February 2016
Slow magnetic relaxation in mononuclear tetrahedral cobalt(II) complexes with 2-(1H-imidazol-2-yl)phenol based ligands Buchholz, Axel; Eseola, Abiodun O.; Plass, Winfried Comptes Rendus Chimie, Vol. 15, Issue 10 https://doi.org/10.1016/j.crci.2012.07.005	journal	October 2012
Slow magnetic relaxation in the tetrahedral cobalt(II) complexes [Co(EPh)4]2− (EO, S, Se) Zadrozny, Joseph M.; Telser, Joshua; Long, Jeffrey R. Polyhedron, Vol. 64 https://doi.org/10.1016/j.poly.2013.04.008	journal	November 2013
Reprint of “EPR studies of a cyano-bridged {Fe2IIINiII} coordination complex and its corresponding FeIII mononuclear building-block” Beedle, Christopher C.; Zhang, Yuan-Zhu; Holmes, Stephen M. Polyhedron, Vol. 66 https://doi.org/10.1016/j.poly.2013.08.002	journal	December 2013
Distortion Pathways of Transition Metal Coordination Polyhedra Induced by Chelating Topology Alvarez, Santiago Chemical Reviews, Vol. 115, Issue 24 https://doi.org/10.1021/acs.chemrev.5b00537	journal	November 2015
A Family of Co ^II Co ^III ₃ Single-Ion Magnets with Zero-Field Slow Magnetic Relaxation: Fine Tuning of Energy Barrier by Remote Substituent and Counter Cation Zhu, Yuan-Yuan; Zhang, Yi-Quan; Yin, Ting-Ting Inorganic Chemistry, Vol. 54, Issue 11 https://doi.org/10.1021/acs.inorgchem.5b00526	journal	May 2015
Structural, Electronic, and Magnetic Properties of {Fe[HC(3,5-Me ₂ pz) ₃ ] ₂ }(BF ₄ ) ₂ (pz = Pyrazolyl): Observation of Unusual Spin-Crossover Behavior Reger, Daniel L.; Little, Christine A.; Rheingold, Arnold L. Inorganic Chemistry, Vol. 39, Issue 21 https://doi.org/10.1021/ic000721z	journal	October 2000
Single-Molecule Magnets Constructed from Cyanometalates: {[Tp*Fe ^III (CN) ₃ M ^II (DMF) ₄ ] ₂ [OTf] ₂ }·2DMF (M ^II = Co, Ni) Li, Dongfeng; Parkin, Sean; Wang, Guangbin Inorganic Chemistry, Vol. 44, Issue 14 https://doi.org/10.1021/ic048367i	journal	July 2005
An S = 2 Cyanide-Bridged Trinuclear Fe ^III ₂ Ni ^II Single-Molecule Magnet Li, Dongfeng; Clérac, Rodolphe; Parkin, Sean Inorganic Chemistry, Vol. 45, Issue 14 https://doi.org/10.1021/ic060379b	journal	July 2006
Synthesis and Coordination Chemistry of a New N ₄ -Polydentate Class of Pyridyl-Functionalized Scorpionate Ligands: Complexes of Fe ^II , Zn ^II , Ni ^II , V ^IV , Pd ^II and Use for Heterobimetallic Systems Wanke, Riccardo; Guedes da Silva, M. Fátima C.; Lancianesi, Stefano Inorganic Chemistry, Vol. 49, Issue 17 https://doi.org/10.1021/ic100966u	journal	September 2010
Detailed Ab Initio First-Principles Study of the Magnetic Anisotropy in a Family of Trigonal Pyramidal Iron(II) Pyrrolide Complexes Atanasov, Mihail; Ganyushin, Dmitry; Pantazis, Dimitrios A. Inorganic Chemistry, Vol. 50, Issue 16 https://doi.org/10.1021/ic200196k	journal	August 2011
Pyrazolylborates and Their Importance in Tuning Single-Molecule Magnet Properties of {Fe ^III ₂ Ni ^II } Complexes Zhang, Yuan-Zhu; Mallik, Uma P.; Rath, Nigam P. Inorganic Chemistry, Vol. 50, Issue 21 https://doi.org/10.1021/ic2017825	journal	November 2011
Tris(5-methylpyrazolyl)methane: Synthesis and Properties of Its Iron(II) Complex Goodman, Margaret A.; Nazarenko, Alexander Y.; Casavant, Barbara J. Inorganic Chemistry, Vol. 51, Issue 2 https://doi.org/10.1021/ic2022038	journal	December 2011
Slow Magnetic Relaxation in Co(III)–Co(II) Mixed-Valence Dinuclear Complexes with a Co ^II O ₅ X (X = Cl, Br, NO ₃ ) Distorted-Octahedral Coordination Sphere Chandrasekhar, Vadapalli; Dey, Atanu; Mota, Antonio J. Inorganic Chemistry, Vol. 52, Issue 8 https://doi.org/10.1021/ic400073y	journal	March 2013
Zero-Field Splitting in Pseudotetrahedral Co(II) Complexes: a Magnetic, High-Frequency and -Field EPR, and Computational Study Idešicová, Monika; Titiš, Ján; Krzystek, J. Inorganic Chemistry, Vol. 52, Issue 16 https://doi.org/10.1021/ic400980b	journal	August 2013
Tuning Transverse Anisotropy in Co ^III –Co ^II –Co ^III Mixed-Valence Complex toward Slow Magnetic Relaxation Wu, Dayu; Zhang, Xingxing; Huang, Ping Inorganic Chemistry, Vol. 52, Issue 19 https://doi.org/10.1021/ic401057f	journal	September 2013
Slow Magnetic Relaxation in Trigonal-Planar Mononuclear Fe(II) and Co(II) Bis(trimethylsilyl)amido Complexes—A Comparative Study Eichhöfer, Andreas; Lan, Yanhua; Mereacre, Valeriu Inorganic Chemistry, Vol. 53, Issue 4 https://doi.org/10.1021/ic401677j	journal	December 2013
Simple Mononuclear Cobalt(II) Complex: A Single-Molecule Magnet Showing Two Slow Relaxation Processes Boča, Roman; Miklovič, Jozef; Titiš, Ján Inorganic Chemistry, Vol. 53, Issue 5 https://doi.org/10.1021/ic5000638	journal	February 2014
Slow Magnetic Relaxation in Octahedral Cobalt(II) Field-Induced Single-Ion Magnet with Positive Axial and Large Rhombic Anisotropy Herchel, Radovan; Váhovská, Lucia; Potočňák, Ivan Inorganic Chemistry, Vol. 53, Issue 12 https://doi.org/10.1021/ic500916u	journal	May 2014
A Mononuclear Transition Metal Single-Molecule Magnet in a Nuclear Spin-Free Ligand Environment Fataftah, Majed S.; Zadrozny, Joseph M.; Rogers, Dylan M. Inorganic Chemistry, Vol. 53, Issue 19 https://doi.org/10.1021/ic501906z	journal	September 2014
Field-Induced Slow Magnetic Relaxation in Cobalt(II) Compounds with Pentagonal Bipyramid Geometry Huang, Xing-Cai; Zhou, Chun; Shao, Dong Inorganic Chemistry, Vol. 53, Issue 24 https://doi.org/10.1021/ic502006s	journal	November 2014
Cobalt(II) Coordination Polymer Exhibiting Single-Ion-Magnet-Type Field-Induced Slow Relaxation Behavior Zhu, Yuan-Yuan; Zhu, Ming-Sheng; Yin, Ting-Ting Inorganic Chemistry, Vol. 54, Issue 8 https://doi.org/10.1021/ic5029299	journal	March 2015
Structural, Magnetic, and Mössbauer Spectral Study of the Electronic Spin-State Transition in [Fe{HC(3-Mepz) ₂ (5-Mepz)} ₂ ](BF ₄ ) ₂ Reger, Daniel L.; Elgin, J. Derek; Foley, Elizabeth A. Inorganic Chemistry, Vol. 48, Issue 19 https://doi.org/10.1021/ic901259e	journal	October 2009
Molecular Cube of Re ^II and Mn ^II That Exhibits Single-Molecule Magnetism Schelter, Eric J.; Prosvirin, Andrey V.; Dunbar, Kim R. Journal of the American Chemical Society, Vol. 126, Issue 46 https://doi.org/10.1021/ja047088r	journal	November 2004
The Observation of Superparamagnetic Behavior in Molecular Nanowires Wang, Shi; Zuo, Jing-Lin; Gao, Song Journal of the American Chemical Society, Vol. 126, Issue 29 https://doi.org/10.1021/ja0483995	journal	July 2004
An S = 6 Cyanide-Bridged Octanuclear Fe ^III ₄ Ni ^II ₄ Complex that Exhibits Slow Relaxation of the Magnetization Li, Dongfeng; Parkin, Sean; Wang, Guangbin Journal of the American Chemical Society, Vol. 128, Issue 13 https://doi.org/10.1021/ja058626i	journal	April 2006
Symmetry-Based Magnetic Anisotropy in the Trigonal Bipyramidal Cluster [Tp₂(Me₃tacn)₃Cu₃Fe₂(CN)₆]⁴⁺ Wang, Cai-Feng; Zuo, Jing-Lin; Bartlett, Bart M. Journal of the American Chemical Society, Vol. 128, Issue 22 https://doi.org/10.1021/ja061788+	journal	May 2006
A Family of Mixed-Metal Cyanide Cubes with Alternating Octahedral and Tetrahedral Corners Exhibiting a Variety of Magnetic Behaviors Including Single Molecule Magnetism Schelter, Eric J.; Karadas, Ferdi; Avendano, Carolina Journal of the American Chemical Society, Vol. 129, Issue 26 https://doi.org/10.1021/ja0683281	journal	July 2007
Single-Molecule Magnet Behavior with a Single Metal Center Enhanced through Peripheral Ligand Modifications Jurca, Titel; Farghal, Ahmed; Lin, Po-Heng Journal of the American Chemical Society, Vol. 133, Issue 40 https://doi.org/10.1021/ja204562m	journal	October 2011
Slow Magnetic Relaxation at Zero Field in the Tetrahedral Complex [Co(SPh) ₄ ] ^2– Zadrozny, Joseph M.; Long, Jeffrey R. Journal of the American Chemical Society, Vol. 133, Issue 51 https://doi.org/10.1021/ja2100142	journal	December 2011
Field-Induced Slow Magnetic Relaxation in a Six-Coordinate Mononuclear Cobalt(II) Complex with a Positive Anisotropy Vallejo, Julia; Castro, Isabel; Ruiz-García, Rafael Journal of the American Chemical Society, Vol. 134, Issue 38 https://doi.org/10.1021/ja3075314	journal	September 2012
Mononuclear Single-Molecule Magnets: Tailoring the Magnetic Anisotropy of First-Row Transition-Metal Complexes Gomez-Coca, Silvia; Cremades, Eduard; Aliaga-Alcalde, Núria Journal of the American Chemical Society, Vol. 135, Issue 18 https://doi.org/10.1021/ja4015138	journal	April 2013
Slow Magnetic Relaxation in a Mononuclear Eight-Coordinate Cobalt(II) Complex Chen, Lei; Wang, Jing; Wei, Jin-Mei Journal of the American Chemical Society, Vol. 136, Issue 35 https://doi.org/10.1021/ja5051605	journal	August 2014
Slow Magnetic Relaxation in a High-Spin Iron(II) Complex Freedman, Danna E.; Harman, W. Hill; Harris, T. David Journal of the American Chemical Society, Vol. 132, Issue 4 https://doi.org/10.1021/ja909560d	journal	February 2010
A Trigonal Prismatic Mononuclear Cobalt(II) Complex Showing Single-Molecule Magnet Behavior Novikov, Valentin V.; Pavlov, Alexander A.; Nelyubina, Yulia V. Journal of the American Chemical Society, Vol. 137, Issue 31 https://doi.org/10.1021/jacs.5b05739	journal	July 2015
Transition Ion Strikes Back: Large Magnetic Susceptibility Anisotropy in Cobalt(II) Clathrochelates Novikov, Valentin V.; Pavlov, Alexander A.; Belov, Alexander S. The Journal of Physical Chemistry Letters, Vol. 5, Issue 21 https://doi.org/10.1021/jz502011z	journal	October 2014
Magnetic blocking in a linear iron(I) complex Zadrozny, Joseph M.; Xiao, Dianne J.; Atanasov, Mihail Nature Chemistry, Vol. 5, Issue 7 https://doi.org/10.1038/nchem.1630	journal	May 2013
A four-coordinate cobalt(II) single-ion magnet with coercivity and a very high energy barrier Rechkemmer, Yvonne; Breitgoff, Frauke D.; van der Meer, Margarethe Nature Communications, Vol. 7, Issue 1 https://doi.org/10.1038/ncomms10467	journal	February 2016
Origin of slow magnetic relaxation in Kramers ions with non-uniaxial anisotropy Gómez-Coca, Silvia; Urtizberea, Ainhoa; Cremades, Eduard Nature Communications, Vol. 5, Issue 1 https://doi.org/10.1038/ncomms5300	journal	July 2014
Slow magnetization dynamics in a series of two-coordinate iron( ii ) complexes Zadrozny, Joseph M.; Atanasov, Mihail; Bryan, Aimee M. Chem. Sci., Vol. 4, Issue 1 https://doi.org/10.1039/C2SC20801F	journal	January 2013
Trigonal bipyramidal 5d–4f molecules with SMM behavior Saber, Mohamed R.; Dunbar, Kim R. Chem. Commun., Vol. 50, Issue 17 https://doi.org/10.1039/C3CC49124B	journal	January 2014
Ligands effects on the magnetic anisotropy of tetrahedral cobalt complexes Saber, Mohamed R.; Dunbar, Kim R. Chem. Commun., Vol. 50, Issue 82 https://doi.org/10.1039/C4CC05724D	journal	January 2014
A synthetic strategy for switching the single ion anisotropy in tetrahedral Co( ii ) complexes Vaidya, Shefali; Upadhyay, Apoorva; Singh, Saurabh Kumar Chemical Communications, Vol. 51, Issue 18 https://doi.org/10.1039/C4CC08305A	journal	January 2015
3d single-ion magnets Craig, Gavin A.; Murrie, Mark Chemical Society Reviews, Vol. 44, Issue 8 https://doi.org/10.1039/C4CS00439F	journal	January 2015
Ising-type magnetic anisotropy and single molecule magnet behaviour in mononuclear trigonal bipyramidal Co( ii ) complexes Ruamps, Renaud; Batchelor, Luke J.; Guillot, Régis Chemical Science, Vol. 5, Issue 9 https://doi.org/10.1039/C4SC00984C	journal	January 2014
Slow magnetic relaxation in mononuclear seven-coordinate cobalt( ii ) complexes with easy plane anisotropy Chen, Lei; Chen, Shu-Yang; Sun, Yi-Chen Dalton Transactions, Vol. 44, Issue 25 https://doi.org/10.1039/C5DT00785B	journal	January 2015
A mononuclear Ni( ii ) complex: a field induced single-molecule magnet showing two slow relaxation processes Miklovič, Jozef; Valigura, Dušan; Boča, Roman Dalton Transactions, Vol. 44, Issue 28 https://doi.org/10.1039/C5DT01213A	journal	January 2015
Observation of the single-ion magnet behavior of d ⁸ ions on two-coordinate Co( i )–NHC complexes Meng, Yin-Shan; Mo, Zhenbo; Wang, Bing-Wu Chemical Science, Vol. 6, Issue 12 https://doi.org/10.1039/C5SC02611C	journal	January 2015
Pushing the limits of magnetic anisotropy in trigonal bipyramidal Ni( ii ) Marriott, Katie E. R.; Bhaskaran, Lakshmi; Wilson, Claire Chemical Science, Vol. 6, Issue 12 https://doi.org/10.1039/C5SC02854J	journal	January 2015
Multiscale study of mononuclear Co ^II SMMs based on curcuminoid ligands Díaz-Torres, Raúl; Menelaou, Melita; Roubeau, Olivier Chemical Science, Vol. 7, Issue 4 https://doi.org/10.1039/C5SC03298A	journal	January 2016
Guest-dependent single-ion magnet behaviour in a cobalt( ii ) metal–organic framework Vallejo, Julia; Fortea-Pérez, Francisco R.; Pardo, Emilio Chemical Science, Vol. 7, Issue 3 https://doi.org/10.1039/C5SC04461H	journal	January 2016
Structures and spectra of bis-tripodal iron(II) chelates, [FeL2]2+, where L = tris(pyrazol-1-yl)methane, tris(pyridin-2-yl)methane, bis(pyrazol-1-yl)(pyridin-2-yl)methane and tris(pyridin-2-yl)phosphine oxide. Magnetism and spin crossover in the (pz)3CH case Anderson, Peter A.; Astley, Timothy; Hitchman, Michael A. Journal of the Chemical Society, Dalton Transactions, Issue 20 https://doi.org/10.1039/b003299i	journal	January 2000
Accurate Coulomb-fitting basis sets for H to Rn Weigend, Florian Physical Chemistry Chemical Physics, Vol. 8, Issue 9 https://doi.org/10.1039/b515623h	journal	January 2006
Structure, magnetism and photomagnetism of mixed-ligand tris(pyrazolyl)methane iron(ii) spin crossover compounds Moubaraki, Boujemaa; Leita, Ben A.; Halder, Gregory J. Dalton Transactions, Issue 39 https://doi.org/10.1039/b708773j	journal	January 2007
Cobalt(ii) single-molecule magnets Murrie, Mark Chemical Society Reviews, Vol. 39, Issue 6 https://doi.org/10.1039/b913279c	journal	January 2010
Single chain magnet of a cyanide bridged FeII/FeIII complex Mitsumoto, Kiyotaka; Ui, Mayumi; Nihei, Masayuki CrystEngComm, Vol. 12, Issue 10 https://doi.org/10.1039/c004351f	journal	January 2010
Achiral single molecule magnet and chiral single chain magnet Hoshino, Norihisa; Sekine, Yoshihiro; Nihei, Masayuki Chemical Communications, Vol. 46, Issue 33 https://doi.org/10.1039/c0cc00184h	journal	January 2010
A cyano-based octanuclear {FeIII4NiII4} single-molecule magnet Zhang, Yuanzhu; Mallik, Uma Prasad; Rath, Nigam Chemical Communications, Vol. 46, Issue 27 https://doi.org/10.1039/c0cc00317d	journal	January 2010
Spin crossover in di-, tri- and tetranuclear, mixed-ligand tris(pyrazolyl)methane iron(ii) complexes Schneider, Caspar J.; Moubaraki, Boujemaa; Cashion, John D. Dalton Transactions, Vol. 40, Issue 26 https://doi.org/10.1039/c0dt01725f	journal	January 2011
Irreversible solvent-driven conversion in cyanometalate {Fe2Ni}n (n = 2, 3) single-molecule magnets Zhang, Yuan-Zhu; Mallik, Uma P.; Clérac, Rodolphe Chemical Communications, Vol. 47, Issue 25 https://doi.org/10.1039/c1cc10679a	journal	January 2011
Slow magnetic relaxation in a pseudotetrahedral cobalt(ii) complex with easy-plane anisotropy Zadrozny, Joseph M.; Liu, Junjie; Piro, Nicholas A. Chemical Communications, Vol. 48, Issue 33 https://doi.org/10.1039/c2cc16430b	journal	January 2012
Single-chain magnets: beyond the Glauber model Zhang, Wei-Xiong; Ishikawa, Ryuta; Breedlove, Brian RSC Advances, Vol. 3, Issue 12 https://doi.org/10.1039/c2ra22675h	journal	January 2013
Inspiration from old molecules: field-induced slow magnetic relaxation in three air-stable tetrahedral cobalt(ii) compounds Yang, Fen; Zhou, Qi; Zhang, Yiquan Chemical Communications, Vol. 49, Issue 46 https://doi.org/10.1039/c3cc00277b	journal	January 2013
A density functional study of the spin state energetics of polypyrazolylborato complexes of first-row transition metals Gruden-Pavlović, M.; Stepanović, S.; Perić, M. Physical Chemistry Chemical Physics, Vol. 16, Issue 28 https://doi.org/10.1039/c3cp55488k	journal	January 2014
Field-induced slow relaxation of magnetization in a tetrahedral Co(ii) complex with easy plane anisotropy Huang, Wei; Liu, Tao; Wu, Dayu Dalton Transactions, Vol. 42, Issue 43 https://doi.org/10.1039/c3dt51801a	journal	January 2013
Zero-field slow magnetic relaxation from single Co(ii) ion: a transition metal single-molecule magnet with high anisotropy barrier Zhu, Yuan-Yuan; Cui, Chang; Zhang, Yi-Quan Chemical Science, Vol. 4, Issue 4 https://doi.org/10.1039/c3sc21893g	journal	January 2013
Optical and Paramagnetic Resonance Spectra of Some Trigonal Co(II) Chelates Jesson, J. P. The Journal of Chemical Physics, Vol. 45, Issue 3 https://doi.org/10.1063/1.1727656	journal	August 1966
Fully optimized contracted Gaussian basis sets of triple zeta valence quality for atoms Li to Kr Schäfer, Ansgar; Huber, Christian; Ahlrichs, Reinhart The Journal of Chemical Physics, Vol. 100, Issue 8 https://doi.org/10.1063/1.467146	journal	April 1994
Spin-lattice relaxation in rare-earth salts Orbach, R. Proceedings of the Royal Society of London. Series A. Mathematical and Physical Sciences, Vol. 264, Issue 1319, p. 458-484 https://doi.org/10.1098/rspa.1961.0211	journal	December 1961
Paramagnetic Relaxation Times for Titanium and Chrome Alum Van Vleck, J. H. Physical Review, Vol. 57, Issue 5 https://doi.org/10.1103/PhysRev.57.426	journal	March 1940
A four-coordinate cobalt(II) single-ion magnet with coercivity and a very high energy barrier Rechkemmer, Yvonne; Breitgoff, Frauke D.; Van Der Meer, Margarethe ETH Zurich https://doi.org/10.3929/ethz-b-000113730	text	January 2016

Cited By (41)

Tuning Magnetic Anisotropy in a Class of Co(II) Bis(hexafluoroacetylacetonate) Complexes Huang, Xing‐Cai; Li, Jia‐Xin; Chen, Yong‐Zhi Chemistry – An Asian Journal, Vol. 15, Issue 9 https://doi.org/10.1002/asia.201901625	journal	April 2020
Pentagonal Bipyramid Fe ^II Complexes: Robust Ising-Spin Units towards Heteropolynuclear Nanomagnets Bar, Arun Kumar; Gogoi, Nayanmoni; Pichon, Céline Chemistry - A European Journal, Vol. 23, Issue 18 https://doi.org/10.1002/chem.201605549	journal	March 2017
Role of Halide Ions in the Nature of the Magnetic Anisotropy in Tetrahedral Co ^II Complexes Vaidya, Shefali; Singh, Saurabh Kumar; Shukla, Pragya Chemistry - A European Journal, Vol. 23, Issue 40 https://doi.org/10.1002/chem.201606031	journal	June 2017
Analysis of Magnetic Anisotropy and the Role of Magnetic Dilution in Triggering Single-Molecule Magnet (SMM) Behavior in a Family of Co ^II Y ^III Dinuclear Complexes with Easy-Plane Anisotropy Palacios, María A.; Nehrkorn, Joscha; Suturina, Elizaveta A. Chemistry - A European Journal, Vol. 23, Issue 48 https://doi.org/10.1002/chem.201702099	journal	July 2017
Quantitative Estimation of Ising-Type Magnetic Anisotropy in a Family of C ₃ -Symmetric Co ^II Complexes Mondal, Amit Kumar; Jover, Jesús; Ruiz, Eliseo Chemistry - A European Journal, Vol. 23, Issue 51 https://doi.org/10.1002/chem.201702108	journal	August 2017
Heterometallic Zn ₃ Ln ₃ Ensembles Containing (μ ₆ -CO ₃ ) Ligand and Triangular Disposition of Ln ³⁺ ions: Analysis of Single-Molecule Toroic (SMT) and Single-Molecule Magnet (SMM) Behavior Goura, Joydeb; Colacio, Enrique; Herrera, Juan Manuel Chemistry - A European Journal, Vol. 23, Issue 65 https://doi.org/10.1002/chem.201703842	journal	October 2017
A Pseudo-Octahedral Cobalt(II) Complex with Bispyrazolylpyridine Ligands Acting as a Zero-Field Single-Molecule Magnet with Easy Axis Anisotropy Rigamonti, Luca; Bridonneau, Nathalie; Poneti, Giordano Chemistry - A European Journal, Vol. 24, Issue 35 https://doi.org/10.1002/chem.201801026	journal	May 2018
Field-Supported Single-Molecule Magnets of Type [Co(bzimpy)X ₂ ] : Field-Supported Single-Molecule Magnets of Type [Co(bzimpy)X Rajnák, Cyril; Varga, Filip; Titiš, Ján European Journal of Inorganic Chemistry, Vol. 2017, Issue 13 https://doi.org/10.1002/ejic.201601279	journal	April 2017
Mononuclear and One-Dimensional Cobalt(II) Complexes with the 3,6-Bis(picolylamino)-1,2,4,5-tetrazine Ligand: Mononuclear and One-Dimensional Cobalt(II) Complexes with the 3,6-Bis(picolylamino)-1,2,4,5-tetrazine Ligand Stetsiuk, Oleh; El-Ghayoury, Abdelkrim; Lloret, Francesc European Journal of Inorganic Chemistry, Vol. 2018, Issue 3-4 https://doi.org/10.1002/ejic.201701224	journal	December 2017
New Cobalt(II) Field-Induced Single-Molecule Magnet and the First Example of a Cobalt(III) Complex with Tridentate Binding of a Deprotonated 4-Amino-3,5-bis(pyridin-2-yl)-1,2,4-Triazole Ligand: New Cobalt(II) Field-Induced Single-Molecule Magnet and the First Example of a Cobalt(III) Complex with Tridentate Binding of a Deprotonated 4-Amino-3 Váhovská, Lucia; Bukrynov, Oleksandr; Potočňák, Ivan European Journal of Inorganic Chemistry, Vol. 2019, Issue 2 https://doi.org/10.1002/ejic.201801225	journal	December 2018
Toward steric control of guest binding modality: a cationic Co( ii ) complex exhibiting cation binding and zero-field relaxation Ozumerzifon, Tarik J.; Bhowmick, Indrani; Spaller, William C. Chemical Communications, Vol. 53, Issue 30 https://doi.org/10.1039/c7cc01172e	journal	January 2017
Phthalocyanine supported dinuclear Ln ^III complexes: the solvent-induced change of magnetic properties in dysprosium( iii ) analogues Ge, Jing-Yuan; Wang, Hai-Ying; Li, Jing Dalton Transactions, Vol. 46, Issue 10 https://doi.org/10.1039/c7dt00298j	journal	January 2017
A mononuclear Co( ii ) complex formed from pyridinedimethanol with manifold slow relaxation channels Valigura, Dušan; Rajnák, Cyril; Moncol, Ján Dalton Transactions, Vol. 46, Issue 33 https://doi.org/10.1039/c7dt02131c	journal	January 2017
Syntheses, crystal structures and magnetic properties of two mixed-valence Co( iii )Co( ii ) compounds derived from Schiff base ligands: field-supported single-ion-magnet behavior with easy-plane anisotropy Mandal, Shuvankar; Mondal, Suraj; Rajnák, Cyril Dalton Trans., Vol. 46, Issue 38 https://doi.org/10.1039/c7dt02455j	journal	January 2017
Synthesis and characterisation of new tripodal lanthanide complexes and investigation of their optical and magnetic properties Craze, Alexander R.; Huang, Xin-Da; Etchells, Isaac Dalton Transactions, Vol. 46, Issue 36 https://doi.org/10.1039/c7dt02556d	journal	January 2017
A new series of tetrahedral Co( ii ) complexes [CoLX ₂ ] (X = NCS, Cl, Br, I) manifesting single-ion magnet features Mondal, Amit Kumar; Sundararajan, Mahesh; Konar, Sanjit Dalton Transactions, Vol. 47, Issue 11 https://doi.org/10.1039/c7dt04007e	journal	January 2018
Transition metal complexes of a versatile polyalkoxy oxazolidine-based ligand derived from in situ cyclization Saleem, Ayaan; Kobielska, Paulina A.; Harms, Klaus Dalton Transactions, Vol. 47, Issue 17 https://doi.org/10.1039/c7dt04634k	journal	January 2018
Slow magnetic relaxation influenced by change of symmetry from ideal C _i to D _3d in cobalt( ii )-based single-ion magnets Chen, Lei; Zhou, Jianjun; Cui, Hui-Hui Dalton Transactions, Vol. 47, Issue 8 https://doi.org/10.1039/c7dt04651k	journal	January 2018
Probing the influence of molecular symmetry on the magnetic anisotropy of octahedral cobalt( ii ) complexes Ding, Zhong-Yu; Meng, Yin-Shan; Xiao, Yi Inorganic Chemistry Frontiers, Vol. 4, Issue 11 https://doi.org/10.1039/c7qi00547d	journal	January 2017
Enforcing Ising-like magnetic anisotropy via trigonal distortion in the design of a W( v )–Co( ii ) cyanide single-chain magnet Zhang, Yuan-Zhu; Dolinar, Brian S.; Liu, Shihao Chemical Science, Vol. 9, Issue 1 https://doi.org/10.1039/c7sc02925j	journal	January 2018
Switching single chain magnet behavior via photoinduced bidirectional metal-to-metal charge transfer Jiang, Wenjing; Jiao, Chengqi; Meng, Yinshan Chemical Science, Vol. 9, Issue 3 https://doi.org/10.1039/c7sc03401f	journal	January 2018
Field-induced single-molecule magnet behavior in ideal trigonal antiprismatic cobalt( ii ) complexes: precise geometrical control by a hydrogen-bonded rigid metalloligand Mitsuhashi, Ryoji; Pedersen, Kasper S.; Ueda, Takaaki Chemical Communications, Vol. 54, Issue 64 https://doi.org/10.1039/c8cc04756a	journal	January 2018
Magnetic anisotropy and relaxation behavior of six-coordinate tris(pivalato)-Co( ii ) and -Ni( ii ) complexes Chen, Shu-Yang; Cui, Hui-Hui; Zhang, Yi-Quan Dalton Transactions, Vol. 47, Issue 30 https://doi.org/10.1039/c8dt01554f	journal	January 2018
Slow magnetic relaxation in a {Co ^II CoIII2} complex containing a high magnetic anisotropy trigonal bipyramidal Co ^II centre Collet, Alexandra; Craig, Gavin A.; Heras Ojea, María José Dalton Transactions, Vol. 47, Issue 28 https://doi.org/10.1039/c8dt01997e	journal	January 2018
Single-ion magnetic anisotropy in a vacant octahedral Co( ii ) complex Mondal, Amit Kumar; Jover, Jesús; Ruiz, Eliseo Dalton Transactions, Vol. 48, Issue 1 https://doi.org/10.1039/c8dt03862g	journal	January 2019
Field-induced slow magnetic relaxation in pseudooctahedral cobalt( ii ) complexes with positive axial and large rhombic anisotropy Świtlicka, Anna; Palion-Gazda, Joanna; Machura, Barbara Dalton Transactions, Vol. 48, Issue 4 https://doi.org/10.1039/c8dt03965h	journal	January 2019
Slow magnetization dynamics in Co( ii )/Co( iii ) triethanolamine/pivalate complexes Sarto, Carolina; Rouzières, Mathieu; Liu, Jun-Liang Dalton Transactions, Vol. 47, Issue 47 https://doi.org/10.1039/c8dt04041a	journal	January 2018
Diazine based ligand supported CoII3 and CoII4 coordination complexes: role of anions Sikdar, Yeasin; Goswami, Ranadip; Modak, Ritwik New Journal of Chemistry, Vol. 42, Issue 21 https://doi.org/10.1039/c8nj02955e	journal	January 2018
Field-induced slow magnetic relaxation of two 1-D compounds containing six-coordinated cobalt( ii ) ions: influence of the coordination geometry Chen, Zhiwei; Yin, Lei; Mi, Xiuna Inorganic Chemistry Frontiers, Vol. 5, Issue 9 https://doi.org/10.1039/c8qi00388b	journal	January 2018
Charge transfer and slow magnetic relaxation in a series of cyano-bridged FeIII4MII2 (M = Fe ^II , Co ^II , Ni ^II ) molecules Wang, Jin-Hua; Vignesh, Kuduva R.; Zhao, Jia Inorganic Chemistry Frontiers, Vol. 6, Issue 2 https://doi.org/10.1039/c8qi01245h	journal	January 2019
Syntheses, structures, and magnetic properties of three two-dimensional cobalt( ii ) single-ion magnets with a Co ^II N ₄ X ₂ octahedral geometry Shi, Le; Shen, Fu-Xing; Shao, Dong CrystEngComm, Vol. 21, Issue 20 https://doi.org/10.1039/c9ce00030e	journal	January 2019
Switching on single-molecule magnet properties of homoleptic sandwich tris(pyrazolyl)borate dysprosium( iii ) cations via intermolecular dipolar coupling Alexandropoulos, Dimitris I.; Vignesh, Kuduva R.; Xie, Haomiao Dalton Transactions, Vol. 48, Issue 28 https://doi.org/10.1039/c9dt00597h	journal	January 2019
Anionic guest-dependent slow magnetic relaxation in Co( ii ) tripodal iminopyridine complexes Klug, Christina M.; Ozumerzifon, Tarik J.; Bhowmick, Indrani Dalton Transactions, Vol. 48, Issue 25 https://doi.org/10.1039/c9dt00739c	journal	January 2019
Stereochemistry of coordination polyhedra vs. single ion magnetism in penta- and hexacoordinated Co( ii ) complexes with tridentate rigid ligands Brachňaková, Barbora; Matejová, Simona; Moncol, Ján Dalton Transactions, Vol. 49, Issue 4 https://doi.org/10.1039/c9dt04592a	journal	January 2020
Synthesis, crystal structures, HF-EPR, and magnetic properties of six-coordinate transition metal (Co, Ni, and Cu) compounds with a 4-amino-1,2,4-triazole Schiff-base ligand Zhang, Ya-Jie; Yin, Lei; Li, Jing RSC Advances, Vol. 10, Issue 22 https://doi.org/10.1039/c9ra10851c	journal	January 2020
How to link theory and experiment for single-chain magnets beyond the Ising model: magnetic properties modeled from ab initio calculations of molecular fragments Böhme, Michael; Plass, Winfried Chemical Science, Vol. 10, Issue 40 https://doi.org/10.1039/c9sc02735a	journal	January 2019
Effects of ligand substituents on the single-molecule magnetic behavior of quinonoid-bridged dicobalt compounds Zhu, Xiao-Quan; Cao, Wen-Hai; Su, Shao-Dong Dalton Transactions https://doi.org/10.1039/d0dt00033g	journal	January 2020
Field-induced slow magnetic relaxation in mixed valence di- and tri-nuclear Co ^II –Co ^III complexes Paul, Aparup; Viciano-Chumillas, Marta; Puschmann, Horst Dalton Transactions, Vol. 49, Issue 27 https://doi.org/10.1039/d0dt00588f	journal	January 2020
Two azido-bridged [2×2] cobalt( ii ) grids featuring single-molecule magnet behaviour Guo, Zhilin; Deng, Yi-Fei; Zhang, Yipei Dalton Transactions, Vol. 49, Issue 27 https://doi.org/10.1039/d0dt01461c	journal	January 2020
A Series of Field-Induced Single-Ion Magnets Based on the Seven-Coordinate Co(II) Complexes with the Pentadentate (N3O2) H2dapsc Ligand Kopotkov, Vyacheslav A.; Korchagin, Denis V.; Sasnovskaya, Valentina D. Magnetochemistry, Vol. 5, Issue 4, p. 58 https://doi.org/10.3390/magnetochemistry5040058	journal	October 2019
A series of field-induced single-ion magnets based on the seven-coordinate Co(II) complexes with the pentadentate (N3O2) H2dapsc ligand Kopotkov, Vyacheslav A.; Korchagin, Denis V.; Sasnovskaya, Valentina D. Zenodo https://doi.org/10.5281/zenodo.3475419	text	January 2019

Linked Research (2)

Similar Records

Enforcing Ising-like magnetic anisotropy via trigonal distortion in the design of a W( v )–Co( ii ) cyanide single-chain magnet

Journal Article · 2018 · Chemical Science · OSTI ID:1410835

Zhang, Yuan-Zhu; Dolinar, Brian S.; Liu, Shihao; +4 more

Origin of the anomalously low Raman exponents in single molecule magnets

Journal Article · 2021 · Physical Review. B · OSTI ID:1853286

Gu, Lei; Wu, Ruqian

Fluorescent H-aggregates of an asymmetrically substituted mono-amino Zn( ii ) phthalocyanine

Journal Article · 2017 · Dalton Transactions · OSTI ID:1535132

Bayda, Malgorzata; Dumoulin, Fabienne; Hug, Gordon L.; +3 more

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

CCDC 1422285: Experimental Crystal Structure Determination: IRIWUD : bis(1,1',1''-methanetriyltris-1H-pyrazole)-cobalt(ii) diperchlorate Zhang, Yuan-Zhu; Gómez-Coca, Silvia; Brown, Andrew https://doi.org/10.5517/ccdc.csd.cc1jr05g The current record is supplemented by this dataset	dataset	September 2015
CCDC 1422286: Experimental Crystal Structure Determination: IRIXAK : bis(1,1',1''-methanetriyltris-1H-pyrazole)-cobalt(ii) bis(tetraphenylborate) acetonitrile solvate Zhang, Yuan-Zhu; Gómez-Coca, Silvia; Brown, Andrew https://doi.org/10.5517/ccdc.csd.cc1jr06h The current record is supplemented by this dataset	dataset	September 2015