Time-of-flight electron scattering from molecular hydrogen: Benchmark cross sections for excitation of the transition
Abstract
The electron impact transition in molecular hydrogen is one of the most important dissociation pathways to forming atomic hydrogen atoms, and is of great importance in modeling astrophysical and industrial plasmas where molecular hydrogen is a substantial constituent. Recently, it has been found that the convergent close-coupling (CCC) cross sections of Zammit et al. [Phys. Rev. A 95, 022708 (2017)] are up to a factor of 2 smaller than the currently recommended data. Here, we have determined normalized differential cross sections for excitation of this transition from our experimental ratios of the inelastic to elastic scattering of electrons by molecular hydrogen using a transmission-free time-of-flight electron spectrometer, and find excellent agreement with the CCC calculations. Since there is already excellent agreement for the absolute elastic differential cross sections, we establish benchmark differential and integrated cross sections for the transition, with theory and experiment being essentially in complete agreement.
- Authors:
-
- Gdańsk Univ. of Technology, Gdańsk (Poland)
- California State Univ., Fullerton, CA (United States)
- Curtin Univ., Perth, WA (Australia)
- Los Alamos National Lab. (LANL), Los Alamos, NM (United States)
- Publication Date:
- Research Org.:
- Los Alamos National Lab. (LANL), Los Alamos, NM (United States)
- Sponsoring Org.:
- USDOE National Nuclear Security Administration (NNSA)
- OSTI Identifier:
- 1524401
- Alternate Identifier(s):
- OSTI ID: 1438951
- Report Number(s):
- LA-UR-18-21161
Journal ID: ISSN 2469-9926; PLRAAN
- Grant/Contract Number:
- 89233218CNA000001; AC52-06NA25396
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Physical Review A
- Additional Journal Information:
- Journal Volume: 97; Journal Issue: 5; Journal ID: ISSN 2469-9926
- Publisher:
- American Physical Society (APS)
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 74 ATOMIC AND MOLECULAR PHYSICS
Citation Formats
Zawadzki, Mateusz, Wright, R., Dolmat, G., Martin, M. F., Hargreaves, Leigh, Fursa, Dmitry V., Zammit, Mark Christian, Scarlett, Liam H., Tapley, Jonathan K., Savage, Jeremy S., Bray, Igor, and Khakoo, Murtadha A. Time-of-flight electron scattering from molecular hydrogen: Benchmark cross sections for excitation of the X1Σg+→b3Σu+ transition. United States: N. p., 2018.
Web. doi:10.1103/PhysRevA.97.050702.
Zawadzki, Mateusz, Wright, R., Dolmat, G., Martin, M. F., Hargreaves, Leigh, Fursa, Dmitry V., Zammit, Mark Christian, Scarlett, Liam H., Tapley, Jonathan K., Savage, Jeremy S., Bray, Igor, & Khakoo, Murtadha A. Time-of-flight electron scattering from molecular hydrogen: Benchmark cross sections for excitation of the X1Σg+→b3Σu+ transition. United States. https://doi.org/10.1103/PhysRevA.97.050702
Zawadzki, Mateusz, Wright, R., Dolmat, G., Martin, M. F., Hargreaves, Leigh, Fursa, Dmitry V., Zammit, Mark Christian, Scarlett, Liam H., Tapley, Jonathan K., Savage, Jeremy S., Bray, Igor, and Khakoo, Murtadha A. Thu .
"Time-of-flight electron scattering from molecular hydrogen: Benchmark cross sections for excitation of the X1Σg+→b3Σu+ transition". United States. https://doi.org/10.1103/PhysRevA.97.050702. https://www.osti.gov/servlets/purl/1524401.
@article{osti_1524401,
title = {Time-of-flight electron scattering from molecular hydrogen: Benchmark cross sections for excitation of the X1Σg+→b3Σu+ transition},
author = {Zawadzki, Mateusz and Wright, R. and Dolmat, G. and Martin, M. F. and Hargreaves, Leigh and Fursa, Dmitry V. and Zammit, Mark Christian and Scarlett, Liam H. and Tapley, Jonathan K. and Savage, Jeremy S. and Bray, Igor and Khakoo, Murtadha A.},
abstractNote = {The electron impact X1Σg+→b3Σu+ transition in molecular hydrogen is one of the most important dissociation pathways to forming atomic hydrogen atoms, and is of great importance in modeling astrophysical and industrial plasmas where molecular hydrogen is a substantial constituent. Recently, it has been found that the convergent close-coupling (CCC) cross sections of Zammit et al. [Phys. Rev. A 95, 022708 (2017)] are up to a factor of 2 smaller than the currently recommended data. Here, we have determined normalized differential cross sections for excitation of this transition from our experimental ratios of the inelastic to elastic scattering of electrons by molecular hydrogen using a transmission-free time-of-flight electron spectrometer, and find excellent agreement with the CCC calculations. Since there is already excellent agreement for the absolute elastic differential cross sections, we establish benchmark differential and integrated cross sections for the X1Σg+→b3Σu+ transition, with theory and experiment being essentially in complete agreement.},
doi = {10.1103/PhysRevA.97.050702},
journal = {Physical Review A},
number = 5,
volume = 97,
place = {United States},
year = {Thu May 24 00:00:00 EDT 2018},
month = {Thu May 24 00:00:00 EDT 2018}
}
Web of Science
Figures / Tables:
Works referenced in this record:
Calculation of electron-helium scattering
journal, August 1995
- Fursa, Dmitry V.; Bray, Igor
- Physical Review A, Vol. 52, Issue 2
Early Cosmological H ii /He iii Regions and Their Impact on Second‐Generation Star Formation
journal, July 2007
- Yoshida, Naoki; Oh, S. Peng; Kitayama, Tetsu
- The Astrophysical Journal, Vol. 663, Issue 2
Differential cross sections for the electron impact excitation of the b 3 Sigma u + continuum of molecular hydrogen
journal, June 1994
- Khakoo, M. A.; Segura, J.
- Journal of Physics B: Atomic, Molecular and Optical Physics, Vol. 27, Issue 11
Cross Sections for Electron Collisions with Hydrogen Molecules
journal, June 2008
- Yoon, Jung-Sik; Song, Mi-Young; Han, Jeong-Min
- Journal of Physical and Chemical Reference Data, Vol. 37, Issue 2
Low-energy electron-impact excitation of the hydrogen molecule
journal, January 1976
- Rescigno, T. N.; McCurdy, C. W.; McKoy, V.
- Physical Review A, Vol. 13, Issue 1
Stout: Cloudy’S Atomic and Molecular Database
journal, July 2015
- Lykins, M. L.; Ferland, G. J.; Kisielius, R.
- The Astrophysical Journal, Vol. 807, Issue 2
Benchmark experiment and theory for near-threshold excitation of helium by electron impact
journal, October 2006
- Lange, Michael; Matsumoto, Jun; Lower, Julian
- Journal of Physics B: Atomic, Molecular and Optical Physics, Vol. 39, Issue 20
Low energy elastic scattering of electrons from H 2 and N 2
journal, April 2008
- Muse, J.; Silva, H.; Lopes, M. C. A.
- Journal of Physics B: Atomic, Molecular and Optical Physics, Vol. 41, Issue 9
Electron-impact excitation cross sections for the b state of
journal, April 1987
- Khakoo, M. A.; Trajmar, S.; McAdams, R.
- Physical Review A, Vol. 35, Issue 7
Accurate determination of background scattered electrons in crossed electron– and gas–beam experiments using a movable gas beam source
journal, May 2003
- Hughes, M.; James, K. E.; Childers, J. G.
- Measurement Science and Technology, Vol. 14, Issue 6
Cross Sections and Related Data for Electron Collisions with Hydrogen Molecules and Molecular Ions
journal, May 1990
- Tawara, H.; Itikawa, Y.; Nishimura, H.
- Journal of Physical and Chemical Reference Data, Vol. 19, Issue 3
Collisional heating as the origin of filament emission in galaxy clusters
journal, February 2009
- Ferland, G. J.; Fabian, A. C.; Hatch, N. A.
- Monthly Notices of the Royal Astronomical Society, Vol. 392, Issue 4
Angle-resolving time-of-flight electron spectrometer for near-threshold precision measurements of differential cross sections of electron-impact excitation of atoms and molecules
journal, April 2008
- Lange, M.; Matsumoto, J.; Setiawan, A.
- Review of Scientific Instruments, Vol. 79, Issue 4
A time‐of‐flight spectrometer for measuring inelastic to elastic differential cross‐section ratios for electron‐gas scattering
journal, May 1996
- LeClair, L. R.; Trajmar, S.; Khakoo, M. A.
- Review of Scientific Instruments, Vol. 67, Issue 5
Electron impact excitation of H 2 (D 2 ). Resonance phenomena associated with the X 2 Σ u + and B 2 Σ g + states of H 2 - in the 10 eV region
journal, September 1984
- Hall, R. I.; Andric, L.
- Journal of Physics B: Atomic and Molecular Physics, Vol. 17, Issue 18
Electron-impact dissociation of molecular hydrogen into neutral fragments
journal, February 2018
- Scarlett, Liam H.; Tapley, Jonathan K.; Fursa, Dmitry V.
- The European Physical Journal D, Vol. 72, Issue 2
Differential cross sections for excitation of H 2 by low-energy electron impact
journal, November 2017
- Hargreaves, L. R.; Bhari, S.; Adjari, B.
- Journal of Physics B: Atomic, Molecular and Optical Physics, Vol. 50, Issue 22
Differential Cross Section of Electron Scattering from Molecular Hydrogen. II. b 3 Σ u + Excitation
journal, September 1986
- Nishimura, Hiroyuki; Danjo, Atsunori
- Journal of the Physical Society of Japan, Vol. 55, Issue 9
Plasma assisted combustion: Dynamics and chemistry
journal, June 2015
- Ju, Yiguang; Sun, Wenting
- Progress in Energy and Combustion Science, Vol. 48
Dissociation of Molecular Hydrogen by Electron Impact
journal, December 1965
- Corrigan, S. J. B.
- The Journal of Chemical Physics, Vol. 43, Issue 12
Determination of the ionization and dissociation energies of the hydrogen molecule
journal, May 2009
- Liu, Jinjun; Salumbides, Edcel J.; Hollenstein, Urs
- The Journal of Chemical Physics, Vol. 130, Issue 17
Model of an inductively coupled negative ion source: II. Application to an ITER type source
journal, January 2011
- Boeuf, J. P.; Hagelaar, G. J. M.; Sarrailh, P.
- Plasma Sources Science and Technology, Vol. 20, Issue 1
Electron-impact excitation of molecular hydrogen
journal, February 2017
- Zammit, Mark C.; Savage, Jeremy S.; Fursa, Dmitry V.
- Physical Review A, Vol. 95, Issue 2
Low-energy electron-impact dissociative excitation of molecular hydrogen and its isotopologues
journal, December 2017
- Scarlett, Liam H.; Tapley, Jonathan K.; Fursa, Dmitry V.
- Physical Review A, Vol. 96, Issue 6
Determination of the ionization and dissociation energies of the hydrogen molecule
text, January 2009
- Liu, Jinjun; Salumbides, Edcel J.; Hollenstein, Urs
- ETH Zurich
Collisional heating as the origin of filament emission in galaxy clusters
text, January 2008
- Ferland, G. J.; Fabian, A. C.; Hatch, N. A.
- arXiv
Stout: Cloudy's Atomic and Molecular Database
text, January 2015
- Lykins, M. L.; Ferland, G. J.; Kisielius, R.
- arXiv
Early Cosmological HII/HeIII Regions and Their Impact on Second-Generation Star Formation
text, January 2006
- Yoshida, Naoki; Oh, S. Peng; Kitayama, Tetsu
- arXiv
Works referencing / citing this record:
Roadmap on photonic, electronic and atomic collision physics: II. Electron and antimatter interactions
journal, August 2019
- Schippers, Stefan; Sokell, Emma; Aumayr, Friedrich
- Journal of Physics B: Atomic, Molecular and Optical Physics, Vol. 52, Issue 17
Vibrational excitation of the ${{\rm{H}}}_{2}X{}^{1}{{\rm{\Sigma }}}_{g}^{+}$ state via electron-impact excitation and radiative cascade
journal, February 2019
- Scarlett, Liam H.; Tapley, Jonathan K.; Savage, Jeremy S.
- Plasma Sources Science and Technology, Vol. 28, Issue 2
Low-energy electron scattering from molecular hydrogen: Excitation of the to transition
journal, December 2018
- Zawadzki, M.; Wright, R.; Dolmat, G.
- Physical Review A, Vol. 98, Issue 6
Experimental determination of mass stopping powers for low-energy electrons
journal, April 2019
- Zawadzki, M.; Khakoo, M. A.
- Physical Review A, Vol. 99, Issue 4
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