Amorphous phase state diagrams and viscosity of ternary aqueous organic/organic and inorganic/organic mixtures
Abstract
A Dimer Coagulation, Isolation and Coalescence (DCIC) technique is used to probe the phase behaviour and glass transition temperatures of ternary aerosol mixtures. The DCIC technique is used to perform temperature and relative humidity dependent viscosity measurements at viscosities near 5 ×106 Pa s. Measurements include organic–organic and organic–inorganic mixtures composed of sucrose–citric acid and sucrose–sodium nitrate. The data reported here add additional insight into the wide discrepancies in glass transition temperatures reported for pure sodium nitrate. The phase diagram model used in the work of Rothfuss and Petters (Phys. Chem. Chem. Phys., 2017, 19, 6532–6545) is expanded to include multiple solute components. Data and model predictions of the mixtures are in good agreement with the modified model. These measurements are compared with values from Holographic Optical Tweezer (HOT) measurements taken at room temperature. As a whole, the viscosities determined from the DCIC and HOT techniques are in good agreement.
- Authors:
-
[1];
[2];
[3];
[1];
[1];
[3]
- School of Chemistry, University of Bristol, Bristol, UK
- Department of Atmospheric Science, Colorado State University, Fort Collins, USA
- Department of Marine, Earth, and Atmospheric Sciences, North Carolina State University, Raleigh, USA
- Publication Date:
- Research Org.:
- Univ. of Colorado, Denver, CO (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Biological and Environmental Research (BER)
- OSTI Identifier:
- 1438942
- Alternate Identifier(s):
- OSTI ID: 1501435
- Grant/Contract Number:
- SC 0012043; SC0012043
- Resource Type:
- Published Article
- Journal Name:
- Physical Chemistry Chemical Physics. PCCP
- Additional Journal Information:
- Journal Name: Physical Chemistry Chemical Physics. PCCP Journal Volume: 20 Journal Issue: 22; Journal ID: ISSN 1463-9076
- Publisher:
- Royal Society of Chemistry
- Country of Publication:
- United Kingdom
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Citation Formats
Marsh, Aleksandra, Petters, Sarah Suda, Rothfuss, Nicholas Ernest, Rovelli, Grazia, Song, Young Chul, Reid, Jonathan Philip, and Petters, Markus Dirk. Amorphous phase state diagrams and viscosity of ternary aqueous organic/organic and inorganic/organic mixtures. United Kingdom: N. p., 2018.
Web. doi:10.1039/C8CP00760H.
Marsh, Aleksandra, Petters, Sarah Suda, Rothfuss, Nicholas Ernest, Rovelli, Grazia, Song, Young Chul, Reid, Jonathan Philip, & Petters, Markus Dirk. Amorphous phase state diagrams and viscosity of ternary aqueous organic/organic and inorganic/organic mixtures. United Kingdom. https://doi.org/10.1039/C8CP00760H
Marsh, Aleksandra, Petters, Sarah Suda, Rothfuss, Nicholas Ernest, Rovelli, Grazia, Song, Young Chul, Reid, Jonathan Philip, and Petters, Markus Dirk. Mon .
"Amorphous phase state diagrams and viscosity of ternary aqueous organic/organic and inorganic/organic mixtures". United Kingdom. https://doi.org/10.1039/C8CP00760H.
@article{osti_1438942,
title = {Amorphous phase state diagrams and viscosity of ternary aqueous organic/organic and inorganic/organic mixtures},
author = {Marsh, Aleksandra and Petters, Sarah Suda and Rothfuss, Nicholas Ernest and Rovelli, Grazia and Song, Young Chul and Reid, Jonathan Philip and Petters, Markus Dirk},
abstractNote = {A Dimer Coagulation, Isolation and Coalescence (DCIC) technique is used to probe the phase behaviour and glass transition temperatures of ternary aerosol mixtures. The DCIC technique is used to perform temperature and relative humidity dependent viscosity measurements at viscosities near 5 ×106 Pa s. Measurements include organic–organic and organic–inorganic mixtures composed of sucrose–citric acid and sucrose–sodium nitrate. The data reported here add additional insight into the wide discrepancies in glass transition temperatures reported for pure sodium nitrate. The phase diagram model used in the work of Rothfuss and Petters (Phys. Chem. Chem. Phys., 2017, 19, 6532–6545) is expanded to include multiple solute components. Data and model predictions of the mixtures are in good agreement with the modified model. These measurements are compared with values from Holographic Optical Tweezer (HOT) measurements taken at room temperature. As a whole, the viscosities determined from the DCIC and HOT techniques are in good agreement.},
doi = {10.1039/C8CP00760H},
journal = {Physical Chemistry Chemical Physics. PCCP},
number = 22,
volume = 20,
place = {United Kingdom},
year = {Mon Jan 01 00:00:00 EST 2018},
month = {Mon Jan 01 00:00:00 EST 2018}
}
Free Publicly Available Full Text
Publisher's Version of Record
https://doi.org/10.1039/C8CP00760H
https://doi.org/10.1039/C8CP00760H
Other availability
Search WorldCat to find libraries that may hold this journal
Cited by: 34 works
Citation information provided by
Web of Science
Web of Science
Save to My Library
You must Sign In or Create an Account in order to save documents to your library.
Works referenced in this record:
Effect of varying experimental conditions on the viscosity of α -pinene derived secondary organic material
journal, January 2016
- Grayson, James W.; Zhang, Yue; Mutzel, Anke
- Atmospheric Chemistry and Physics, Vol. 16, Issue 10
Direct imaging of changes in aerosol particle viscosity upon hydration and chemical aging
journal, January 2016
- Hosny, N. A.; Fitzgerald, C.; Vyšniauskas, A.
- Chemical Science, Vol. 7, Issue 2
The influence of physical state on shikimic acid ozonolysis: a case for in situ microspectroscopy
journal, January 2014
- Steimer, S. S.; Lampimäki, M.; Coz, E.
- Atmospheric Chemistry and Physics, Vol. 14, Issue 19
Effect of crystallization kinetics on the properties of spray dried microparticles
journal, April 2016
- Baldelli, Alberto; Power, Rory M.; Miles, Rachael E. H.
- Aerosol Science and Technology, Vol. 50, Issue 7
Coalescence Sampling and Analysis of Aerosols using Aerosol Optical Tweezers
journal, January 2017
- Haddrell, Allen E.; Miles, Rachael E. H.; Bzdek, Bryan R.
- Analytical Chemistry, Vol. 89, Issue 4
Competition between water uptake and ice nucleation by glassy organic aerosol particles
journal, January 2014
- Berkemeier, T.; Shiraiwa, M.; Pöschl, U.
- Atmospheric Chemistry and Physics, Vol. 14, Issue 22
Fast and Slow Components in the Crystallization of a Model Multicomponent System, NaKCa(NO 3 ): The Role of Composition Fluctuations
journal, June 2011
- Wen, Ping; Harrowell, Peter; Angell, C. Austen
- The Journal of Physical Chemistry A, Vol. 115, Issue 23
Review of the vapour pressures of ice and supercooled water for atmospheric applications
journal, April 2005
- Murphy, D. M.; Koop, T.
- Quarterly Journal of the Royal Meteorological Society, Vol. 131, Issue 608
Relative humidity-dependent viscosity of secondary organic material from
toluene photo-oxidation and possible implications for organic particulate
matter over megacities
journal, January 2016
- Song, Mijung; Liu, Pengfei F.; Hanna, Sarah J.
- Atmospheric Chemistry and Physics, Vol. 16, Issue 14
Coalescence-based assessment of aerosol phase state using dimers prepared through a dual-differential mobility analyzer technique
journal, August 2016
- Rothfuss, Nicholas E.; Petters, Markus D.
- Aerosol Science and Technology, Vol. 50, Issue 12
Hygroscopic behavior of wet dispersed and dry deposited NaNO3 particles
journal, December 2012
- Kim, HyeKyeong; Lee, Mi-Jung; Jung, Hae-Jin
- Atmospheric Environment, Vol. 60
Reactions between water-soluble organic acids and nitrates in atmospheric aerosols: Recycling of nitric acid and formation of organic salts: Organics and Nitrates in Aerosols
journal, March 2014
- Wang, Bingbing; Laskin, Alexander
- Journal of Geophysical Research: Atmospheres, Vol. 119, Issue 6
Experimental determination of chemical diffusion within secondary organic aerosol particles
journal, January 2013
- Abramson, Evan; Imre, Dan; Beránek, Josef
- Physical Chemistry Chemical Physics, Vol. 15, Issue 8
Non-Isothermal and Isothermal Crystallization of Sucrose from the Amorphous State
journal, August 1994
- Saleki‐Gerhardt, Azita; Zografi, George
- Pharmaceutical Research, Vol. 11, Issue 8, p. 1166-1173
The transition from liquid to solid-like behaviour in ultrahigh viscosity aerosol particles
journal, January 2013
- Power, R. M.; Simpson, S. H.; Reid, J. P.
- Chemical Science, Vol. 4, Issue 6
Characterization of the temperature and humidity-dependent phase diagram of amorphous nanoscale organic aerosols
journal, January 2017
- Rothfuss, Nicholas E.; Petters, Markus D.
- Physical Chemistry Chemical Physics, Vol. 19, Issue 9
Atmospheric Size Distributions Measured by Differential Mobility Optical Particle Size Spectrometry
journal, January 1998
- Stolzenburg, Mark; Kreisberg, Nathan; Hering, Susanne
- Aerosol Science and Technology, Vol. 29, Issue 5
Surface tensions of multi-component mixed inorganic/organic aqueous systems of atmospheric significance: measurements, model predictions and importance for cloud activation predictions
journal, January 2007
- Topping, D. O.; McFiggans, G. B.; Kiss, G.
- Atmospheric Chemistry and Physics, Vol. 7, Issue 9
Modification of Frenkel's model for sintering
journal, December 1997
- Pokluda, Ondřej; Bellehumeur, Céline T.; Vlachopoulos, John
- AIChE Journal, Vol. 43, Issue 12
Glass Formation Processes in Mixed Inorganic/Organic Aerosol Particles
journal, November 2014
- Dette, Hans P.; Koop, Thomas
- The Journal of Physical Chemistry A, Vol. 119, Issue 19
Surface Tensions of Inorganic Multicomponent Aqueous Electrolyte Solutions and Melts
journal, November 2010
- Dutcher, Cari S.; Wexler, Anthony S.; Clegg, Simon L.
- The Journal of Physical Chemistry A, Vol. 114, Issue 46
Water activities, densities, and refractive indices of aqueous sulfates and sodium nitrate droplets of atmospheric importance
journal, January 1994
- Tang, I. N.; Munkelwitz, H. R.
- Journal of Geophysical Research, Vol. 99, Issue D9
Alkali metal nitrate glass transition temperatures from vapor deposited films
journal, October 1972
- Smyrl, Norman; Devlin, J. Paul
- The Journal of Physical Chemistry, Vol. 76, Issue 21
Dynamic viscosity mapping of the oxidation of squalene aerosol particles
journal, January 2016
- Athanasiadis, Athanasios; Fitzgerald, Clare; Davidson, Nicholas M.
- Physical Chemistry Chemical Physics, Vol. 18, Issue 44
Formation of Low-Volatility Organic Compounds in the Atmosphere: Recent Advancements and Insights
journal, March 2017
- Barsanti, Kelley C.; Kroll, Jesse H.; Thornton, Joel A.
- The Journal of Physical Chemistry Letters, Vol. 8, Issue 7
Estimating the Viscosity Range of SOA Particles Based on Their Coalescence Time
journal, December 2013
- Pajunoja, Aki; Malila, Jussi; Hao, Liqing
- Aerosol Science and Technology, Vol. 48, Issue 2
Validation of the poke-flow technique combined with simulations of fluid flow for determining viscosities in samples with small volumes and high viscosities
journal, January 2015
- Grayson, J. W.; Song, M.; Sellier, M.
- Atmospheric Measurement Techniques, Vol. 8, Issue 6
Observation of viscosity transition in α -pinene secondary organic aerosol
journal, January 2016
- Järvinen, Emma; Ignatius, Karoliina; Nichman, Leonid
- Atmospheric Chemistry and Physics, Vol. 16, Issue 7
Probing the micro-rheological properties of aerosol particles using optical tweezers
journal, July 2014
- Power, Rory M.; Reid, Jonathan P.
- Reports on Progress in Physics, Vol. 77, Issue 7
Gas uptake and chemical aging of semisolid organic aerosol particles
journal, June 2011
- Shiraiwa, M.; Ammann, M.; Koop, T.
- Proceedings of the National Academy of Sciences, Vol. 108, Issue 27
Fluorescent lifetime imaging of atmospheric aerosols: a direct probe of aerosol viscosity
journal, January 2013
- Hosny, Neveen A.; Fitzgerald, Clare; Tong, Changlun
- Faraday Discussions, Vol. 165
Influence of Functional Groups on the Viscosity of Organic Aerosol
journal, December 2016
- Rothfuss, Nicholas E.; Petters, Markus D.
- Environmental Science & Technology, Vol. 51, Issue 1
Simple amorphous salts: Spectra and glass transition temperatures
journal, May 1981
- Consani, Keith; Devlin, J. Paul; Ray, Alex
- The Journal of Chemical Physics, Vol. 74, Issue 9
Glass transition and phase state of organic compounds: dependency on molecular properties and implications for secondary organic aerosols in the atmosphere
journal, January 2011
- Koop, Thomas; Bookhold, Johannes; Shiraiwa, Manabu
- Physical Chemistry Chemical Physics, Vol. 13, Issue 43
Viscosity controls humidity dependence of N 2 O 5 uptake to citric acid aerosol
journal, January 2015
- Gržinić, G.; Bartels-Rausch, T.; Berkemeier, T.
- Atmospheric Chemistry and Physics, Vol. 15, Issue 23
Evolution of Organic Aerosols in the Atmosphere
journal, December 2009
- Jimenez, J. L.; Canagaratna, M. R.; Donahue, N. M.
- Science, Vol. 326, Issue 5959
Fluorescence lifetime imaging of optically levitated aerosol: a technique to quantitatively map the viscosity of suspended aerosol particles
journal, January 2016
- Fitzgerald, C.; Hosny, N. A.; Tong, H.
- Physical Chemistry Chemical Physics, Vol. 18, Issue 31
In Situ Observation on the Dynamic Process of Evaporation and Crystallization of Sodium Nitrate Droplets on a ZnSe Substrate by FTIR-ATR
journal, April 2014
- Zhang, Qing-Nuan; Zhang, Yun; Cai, Chen
- The Journal of Physical Chemistry A, Vol. 118, Issue 15
Factors controlling the evaporation of secondary organic aerosol from α‐pinene ozonolysis
journal, March 2017
- Yli‐Juuti, Taina; Pajunoja, Aki; Tikkanen, Olli‐Pekka
- Geophysical Research Letters, Vol. 44, Issue 5
Radial Differential Mobility Analyzer
journal, January 1995
- Zhang, Shou-Hua; Akutsu, Yoshiaki; Russell, Lynn M.
- Aerosol Science and Technology, Vol. 23, Issue 3
Infrared and Raman spectra of group I nitrate aggregates in carbon dioxide matrixes and glassy thin films
journal, June 1972
- Pollard, Gary; Smyrl, Norman; Devlin, J. Paul
- The Journal of Physical Chemistry, Vol. 76, Issue 13
Corresponding states and the glass transition for alkali metal nitrates
journal, July 1971
- Angell, C. A.; Helphrey, D. B.
- The Journal of Physical Chemistry, Vol. 75, Issue 15
Mixing times of organic molecules within secondary organic aerosol particles: a global planetary boundary layer perspective
journal, January 2017
- Maclean, Adrian M.; Butenhoff, Christopher L.; Grayson, James W.
- Atmospheric Chemistry and Physics, Vol. 17, Issue 21
Global distribution of particle phase state in atmospheric secondary organic aerosols
journal, April 2017
- Shiraiwa, Manabu; Li, Ying; Tsimpidi, Alexandra P.
- Nature Communications, Vol. 8, Issue 1
Changing shapes and implied viscosities of suspended submicron particles
journal, January 2015
- Zhang, Y.; Sanchez, M. S.; Douet, C.
- Atmospheric Chemistry and Physics, Vol. 15, Issue 14
Surfactant effect on cloud condensation nuclei for two-component internally mixed aerosols: CCN ACTIVITY OF SURFACTANTS
journal, February 2016
- Petters, Sarah Suda; Petters, Markus Dirk
- Journal of Geophysical Research: Atmospheres, Vol. 121, Issue 4
Surface Tension of Liquid Nitrate Systems
journal, October 1964
- Bertozzi, G.; Sternheim, G.
- The Journal of Physical Chemistry, Vol. 68, Issue 10
A single parameter representation of hygroscopic growth and cloud condensation nucleus activity
journal, January 2007
- Petters, M. D.; Kreidenweis, S. M.
- Atmospheric Chemistry and Physics, Vol. 7, Issue 8
Global long-range transport and lung cancer risk from polycyclic aromatic hydrocarbons shielded by coatings of organic aerosol
journal, January 2017
- Shrivastava, Manish; Lou, Silja; Zelenyuk, Alla
- Proceedings of the National Academy of Sciences, Vol. 114, Issue 6
Trends in particle-phase liquid water during the Southern Oxidant and Aerosol Study
journal, January 2014
- Nguyen, T. K. V.; Petters, M. D.; Suda, S. R.
- Atmospheric Chemistry and Physics, Vol. 14, Issue 20
Nitrate Ion Photolysis in Thin Water Films in the Presence of Bromide Ions
journal, June 2011
- Richards, Nicole K.; Wingen, Lisa M.; Callahan, Karen M.
- The Journal of Physical Chemistry A, Vol. 115, Issue 23
Interactions in Aqueous Nonelectrolyte Solutions. I. Solute-Solvent Equilibria
journal, July 1966
- Stokes, R. H.; Robinson, R. A.
- The Journal of Physical Chemistry, Vol. 70, Issue 7
Diffusivity measurements of volatile organics in levitated viscous aerosol particles
journal, January 2017
- Bastelberger, Sandra; Krieger, Ulrich K.; Luo, Beiping
- Atmospheric Chemistry and Physics, Vol. 17, Issue 13
Do atmospheric aerosols form glasses?
journal, January 2008
- Zobrist, B.; Marcolli, C.; Pedernera, D. A.
- Atmospheric Chemistry and Physics, Vol. 8, Issue 17
An amorphous solid state of biogenic secondary organic aerosol particles
journal, October 2010
- Virtanen, Annele; Joutsensaari, Jorma; Koop, Thomas
- Nature, Vol. 467, Issue 7317
Effect of viscosity on photodegradation rates in complex secondary organic aerosol materials
journal, January 2016
- Hinks, Mallory L.; Brady, Monica V.; Lignell, Hanna
- Physical Chemistry Chemical Physics, Vol. 18, Issue 13
Ozone uptake on glassy, semi-solid and liquid organic matter and the role of reactive oxygen intermediates in atmospheric aerosol chemistry
journal, January 2016
- Berkemeier, Thomas; Steimer, Sarah S.; Krieger, Ulrich K.
- Physical Chemistry Chemical Physics, Vol. 18, Issue 18
Nanoscale interfacial gradients formed by the reactive uptake of OH radicals onto viscous aerosol surfaces
journal, January 2015
- Davies, James F.; Wilson, Kevin R.
- Chemical Science, Vol. 6, Issue 12
Exploring the complexity of aerosol particle properties and processes using single particle techniques
journal, January 2012
- Krieger, Ulrich K.; Marcolli, Claudia; Reid, Jonathan P.
- Chemical Society Reviews, Vol. 41, Issue 19
Diffusion and reactivity in ultraviscous aerosol and the correlation with particle viscosity
journal, January 2016
- Marshall, Frances H.; Miles, Rachael E. H.; Song, Young-Chul
- Chemical Science, Vol. 7, Issue 2
Sucrose diffusion in aqueous solution
journal, January 2016
- Price, Hannah C.; Mattsson, Johan; Murray, Benjamin J.
- Physical Chemistry Chemical Physics, Vol. 18, Issue 28
Measurements and Predictions of Binary Component Aerosol Particle Viscosity
journal, October 2016
- Song, Young Chul; Haddrell, Allen E.; Bzdek, Bryan R.
- The Journal of Physical Chemistry A, Vol. 120, Issue 41
Synergy between Secondary Organic Aerosols and Long-Range Transport of Polycyclic Aromatic Hydrocarbons
journal, November 2012
- Zelenyuk, Alla; Imre, Dan; Beránek, Josef
- Environmental Science & Technology, Vol. 46, Issue 22
Viscosity of -pinene secondary organic material and implications for particle growth and reactivity
journal, April 2013
- Renbaum-Wolff, L.; Grayson, J. W.; Bateman, A. P.
- Proceedings of the National Academy of Sciences, Vol. 110, Issue 20
Scanning Electrical Mobility Spectrometer
journal, January 1990
- Wang, Shih Chen; Flagan, Richard C.
- Aerosol Science and Technology, Vol. 13, Issue 2
Amorphous and crystalline aerosol particles interacting with water vapor: conceptual framework and experimental evidence for restructuring, phase transitions and kinetic limitations
journal, January 2009
- Mikhailov, E.; Vlasenko, S.; Martin, S. T.
- Atmospheric Chemistry and Physics, Vol. 9, Issue 24