High-Performance Transition Metal Phosphide Alloy Catalyst for Oxygen Evolution Reaction
Abstract
Oxygen evolution reaction (OER) is a pivotal process in many energy conversion and storage techniques, such as water splitting, regenerative fuel cells, and rechargeable metal-air batteries. The synthesis of stable, efficient, non-noble metal-based electrocatalysts for OER has been a long-standing challenge. In this work, a facile and scalable method to synthesize hollow and conductive iron–cobalt phosphide (Fe–Co–P) alloy nanostructures using an Fe–Co metal organic complex as a precursor is described. The Fe–Co–P alloy exhibits excellent OER activity with a specific current density of 10 mA/cm2 being achieved at an overpotential as low as 252 mV. The current density at 1.5 V (vs reversible hydrogen electrode) of the Fe–Co–P catalyst is 30.7 mA/cm2, which is more than 3 orders of magnitude greater than that obtained with state-of-the-art Fe–Co oxide catalysts. Our mechanistic experiments and theoretical analysis suggest that the electrochemical-induced high-valent iron stabilizes the cobalt in a low-valent state, leading to the simultaneous enhancement of activity and stability of the OER catalyst.
- Authors:
-
[2];
[1];
[1]
- Univ. of Akron, OH (United States)
- Univ. of Akron, OH (United States); Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Joint Center for Artificial Photosynthesis
- Purdue Univ., West Lafayette, IN (United States). School of Chemical Engineering
- Publication Date:
- Research Org.:
- Argonne National Laboratory (ANL), Argonne, IL (US). Advanced Photon Source (APS)
- Sponsoring Org.:
- USDOE Office of Science (SC)
- OSTI Identifier:
- 1438846
- Grant/Contract Number:
- AC02-06CH11357
- Resource Type:
- Accepted Manuscript
- Journal Name:
- ACS Nano
- Additional Journal Information:
- Journal Volume: 12; Journal Issue: 1; Journal ID: ISSN 1936-0851
- Publisher:
- American Chemical Society (ACS)
- Country of Publication:
- United States
- Language:
- ENGLISH
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; Catalysts; Radiology; Metals; Alloys; Materials; Fe−Co−P alloy; self-assembly; hollow sphere; XANES; EXAFS; oxygen evolution reaction
Citation Formats
Liu, Kewei, Zhang, Changlin, Sun, Yuandong, Zhang, Guanghui, Shen, Xiaochen, Zou, Feng, Zhang, Haichang, Wu, Zhenwei, Wegener, Evan C., Taubert, Clinton J., Miller, Jeffrey T., Peng, Zhenmeng, and Zhu, Yu. High-Performance Transition Metal Phosphide Alloy Catalyst for Oxygen Evolution Reaction. United States: N. p., 2017.
Web. doi:10.1021/acsnano.7b04646.
Liu, Kewei, Zhang, Changlin, Sun, Yuandong, Zhang, Guanghui, Shen, Xiaochen, Zou, Feng, Zhang, Haichang, Wu, Zhenwei, Wegener, Evan C., Taubert, Clinton J., Miller, Jeffrey T., Peng, Zhenmeng, & Zhu, Yu. High-Performance Transition Metal Phosphide Alloy Catalyst for Oxygen Evolution Reaction. United States. doi:10.1021/acsnano.7b04646.
Liu, Kewei, Zhang, Changlin, Sun, Yuandong, Zhang, Guanghui, Shen, Xiaochen, Zou, Feng, Zhang, Haichang, Wu, Zhenwei, Wegener, Evan C., Taubert, Clinton J., Miller, Jeffrey T., Peng, Zhenmeng, and Zhu, Yu. Wed .
"High-Performance Transition Metal Phosphide Alloy Catalyst for Oxygen Evolution Reaction". United States. doi:10.1021/acsnano.7b04646. https://www.osti.gov/servlets/purl/1438846.
@article{osti_1438846,
title = {High-Performance Transition Metal Phosphide Alloy Catalyst for Oxygen Evolution Reaction},
author = {Liu, Kewei and Zhang, Changlin and Sun, Yuandong and Zhang, Guanghui and Shen, Xiaochen and Zou, Feng and Zhang, Haichang and Wu, Zhenwei and Wegener, Evan C. and Taubert, Clinton J. and Miller, Jeffrey T. and Peng, Zhenmeng and Zhu, Yu},
abstractNote = {Oxygen evolution reaction (OER) is a pivotal process in many energy conversion and storage techniques, such as water splitting, regenerative fuel cells, and rechargeable metal-air batteries. The synthesis of stable, efficient, non-noble metal-based electrocatalysts for OER has been a long-standing challenge. In this work, a facile and scalable method to synthesize hollow and conductive iron–cobalt phosphide (Fe–Co–P) alloy nanostructures using an Fe–Co metal organic complex as a precursor is described. The Fe–Co–P alloy exhibits excellent OER activity with a specific current density of 10 mA/cm2 being achieved at an overpotential as low as 252 mV. The current density at 1.5 V (vs reversible hydrogen electrode) of the Fe–Co–P catalyst is 30.7 mA/cm2, which is more than 3 orders of magnitude greater than that obtained with state-of-the-art Fe–Co oxide catalysts. Our mechanistic experiments and theoretical analysis suggest that the electrochemical-induced high-valent iron stabilizes the cobalt in a low-valent state, leading to the simultaneous enhancement of activity and stability of the OER catalyst.},
doi = {10.1021/acsnano.7b04646},
journal = {ACS Nano},
number = 1,
volume = 12,
place = {United States},
year = {2017},
month = {12}
}
Free Publicly Available Full Text
Publisher's Version of Record
Other availability
Search WorldCat to find libraries that may hold this journal
Cited by: 117 works
Citation information provided by
Web of Science
Web of Science
Save to My Library
You must Sign In or Create an Account in order to save documents to your library.
Works referencing / citing this record:
Fused deposition processing polycaprolactone of composites for biomedical applications
journal, January 2019
- Prasad, Arya; Kandasubramanian, Balasubramanian
- Polymer-Plastics Technology and Materials, Vol. 58, Issue 13
Defect‐Rich Nitrogen Doped Co 3 O 4 /C Porous Nanocubes Enable High‐Efficiency Bifunctional Oxygen Electrocatalysis
journal, June 2019
- Wang, Zhichao; Xu, Wenjia; Chen, Xiaokang
- Advanced Functional Materials, Vol. 29, Issue 33
Co 3 O 4 /Fe 0.33 Co 0.66 P Interface Nanowire for Enhancing Water Oxidation Catalysis at High Current Density
journal, September 2018
- Zhang, Xiaoyan; Li, Jing; Yang, Yong
- Advanced Materials, Vol. 30, Issue 45
Morphology‐Controlled Metal Sulfides and Phosphides for Electrochemical Water Splitting
journal, February 2019
- Joo, Jinwhan; Kim, Taekyung; Lee, Jaeyoung
- Advanced Materials, Vol. 31, Issue 14
Ordered Mesoporous Cobalt–Nickel Nitride Prepared by Nanocasting for Oxygen Evolution Reaction Electrocatalysis
journal, August 2019
- Saad, Ali; Cheng, Zhixing; Zhang, Xuyang
- Advanced Materials Interfaces, Vol. 6, Issue 20
Single Atoms and Clusters Based Nanomaterials for Hydrogen Evolution, Oxygen Evolution Reactions, and Full Water Splitting
journal, May 2019
- Sultan, Siraj; Tiwari, Jitendra N.; Singh, Aditya Narayan
- Advanced Energy Materials, Vol. 9, Issue 22
General Method for Synthesis Transition‐Metal Phosphide/Nitrogen and Phosphide Doped Carbon Materials with Yolk‐Shell Structure for Oxygen Reduction Reaction
journal, February 2019
- Yu, Yue; Ma, Jun; Chen, Changli
- ChemCatChem, Vol. 11, Issue 6
Gold Nanocluster‐Decorated Nickel Nitride as Stable Electrocatalyst for Oxygen Evolution Reaction in Alkaline Media
journal, October 2019
- Lv, Mengyao; Zhou, Ying; Rasaki, Sefiu Abolaji
- ChemElectroChem, Vol. 6, Issue 22
An Intriguing Pea-Like Nanostructure of Cobalt Phosphide on Molybdenum Carbide Incorporated Nitrogen-Doped Carbon Nanosheets for Efficient Electrochemical Water Splitting
journal, October 2018
- Dutta, Soumen; Indra, Arindam; Han, HyukSu
- ChemSusChem, Vol. 11, Issue 22
Preparation of Yolk–Shell‐Structured Co x Fe 1− x P with Enhanced OER Performance
journal, September 2019
- Yue, Song; Wang, Shanshan; Jiao, Qingze
- ChemSusChem, Vol. 12, Issue 19
Metal–Organic Framework‐Derived Fe/Co‐based Bifunctional Electrode for H 2 Production through Water and Urea Electrolysis
journal, October 2019
- Singh, Thangjam Ibomcha; Rajeshkhanna, Gaddam; Singh, Soram Bobby
- ChemSusChem, Vol. 12, Issue 21
A Room-Temperature Postsynthetic Ligand Exchange Strategy to Construct Mesoporous Fe-Doped CoP Hollow Triangle Plate Arrays for Efficient Electrocatalytic Water Splitting
journal, February 2018
- Hu, Enlai; Ning, Jiqiang; Zhao, Dian
- Small, Vol. 14, Issue 14
Electronic Structure Evolution in Tricomponent Metal Phosphides with Reduced Activation Energy for Efficient Electrocatalytic Oxygen Evolution
journal, August 2018
- Wang, Miao; Dong, Chung-Li; Huang, Yu-Cheng
- Small, Vol. 14, Issue 35
Hollow Porous Heterometallic Phosphide Nanocubes for Enhanced Electrochemical Water Splitting
journal, October 2018
- Guo, Yanna; Tang, Jing; Wang, Zhongli
- Small, Vol. 14, Issue 44
Designing Highly Efficient and Long‐Term Durable Electrocatalyst for Oxygen Evolution by Coupling B and P into Amorphous Porous NiFe‐Based Material
journal, May 2019
- Hu, Fei; Wang, Haiyun; Zhang, Yan
- Small, Vol. 15, Issue 28
Bimetallic MOF‐Derived FeCo‐P/C Nanocomposites as Efficient Catalysts for Oxygen Evolution Reaction
journal, August 2018
- Hong, Wei; Kitta, Mitsunori; Xu, Qiang
- Small Methods, Vol. 2, Issue 12
Co-doped SnS2 nanosheet array for efficient oxygen evolution reaction electrocatalyst
journal, August 2019
- Jiang, Meiwen; Huang, Yue; Sun, Wei
- Journal of Materials Science, Vol. 54, Issue 21
Porous NiCoP nanowalls as promising electrode with high-area and mass capacitance for supercapacitors
journal, April 2019
- Zhang, Xiaomeng; Su, Danni; Wu, Aiping
- Science China Materials, Vol. 62, Issue 8
Superb water splitting activity of the electrocatalyst Fe3Co(PO4)4 designed with computation aid
journal, November 2019
- Sultan, Siraj; Ha, Miran; Kim, Dong Yeon
- Nature Communications, Vol. 10, Issue 1
Earthworm-like N, S-Doped carbon tube-encapsulated Co 9 S 8 nanocomposites derived from nanoscaled metal–organic frameworks for highly efficient bifunctional oxygen catalysis
journal, January 2018
- Liu, Tao; Zhang, Limin; Tian, Yang
- Journal of Materials Chemistry A, Vol. 6, Issue 14
Ni-Doped CuS as an efficient electrocatalyst for the oxygen evolution reaction
journal, January 2019
- Kundu, Joyjit; Khilari, Santimoy; Bhunia, Kousik
- Catalysis Science & Technology, Vol. 9, Issue 2
Unveiling dual-linkage 3D hexaiminobenzene metal–organic frameworks towards long-lasting advanced reversible Zn–air batteries
journal, January 2019
- Shinde, Sambhaji S.; Lee, Chi Ho; Jung, Jin-Young
- Energy & Environmental Science, Vol. 12, Issue 2
Accelerating the water splitting kinetics of CoP microcubes anchored on a graphene electrocatalyst by Mn incorporation
journal, January 2019
- Xu, Xun; Liang, Hanfeng; Tang, Guisheng
- Nanoscale Advances, Vol. 1, Issue 1
Engineering a stereo-film of FeNi 3 nanosheet-covered FeOOH arrays for efficient oxygen evolution
journal, January 2018
- Meng, Huiyuan; Ren, Zhiyu; Du, Shichao
- Nanoscale, Vol. 10, Issue 23
3D self-supported Ni(PO 3 ) 2 –MoO 3 nanorods anchored on nickel foam for highly efficient overall water splitting
journal, January 2018
- Li, Kai; Ma, Jingwen; Guan, Xinglong
- Nanoscale, Vol. 10, Issue 47
CoFeP hollow cube as advanced electrocatalyst for water oxidation
journal, January 2019
- Zhang, Xiao; Wu, Yanhua; Sun, Yanfang
- Inorganic Chemistry Frontiers, Vol. 6, Issue 2
Solution-phase phosphorus substitution for enhanced oxygen evolution reaction in Cu 2 WS 4
journal, January 2019
- Novak, Travis G.; Prakash, Om; Tiwari, Anand P.
- RSC Advances, Vol. 9, Issue 1
Supramolecular bimetallogels: a nanofiber network for bimetal/nitrogen co-doped carbon electrocatalysts
journal, January 2018
- Tan, Minli; He, Ting; Liu, Jian
- Journal of Materials Chemistry A, Vol. 6, Issue 18
Recent developments of transition metal phosphides as catalysts in the energy conversion field
journal, January 2018
- Pei, Yu; Cheng, Yu; Chen, Jiyi
- Journal of Materials Chemistry A, Vol. 6, Issue 46
Construction of a hollow porous carbon spheres@CoP/nitrogen-doped carbon supported platinum catalyst for high performance methanol oxidation
journal, January 2019
- Zhang, Huanhuan; Ma, Li; Gan, Mengyu
- New Journal of Chemistry, Vol. 43, Issue 27
Electrodeposition of sulfur-engineered amorphous nickel hydroxides on MIL-53(Fe) nanosheets to accelerate the oxygen evolution reaction
journal, January 2019
- Wu, Fang; Guo, Xiaoxue; Hao, Gazi
- Nanoscale, Vol. 11, Issue 31
Scalable synthesis of self-assembled bimetallic phosphide/N-doped graphene nanoflakes as an efficient electrocatalyst for overall water splitting
journal, January 2019
- Yang, Dongxu; Hou, Wenqiang; Lu, Yingjiong
- Nanoscale, Vol. 11, Issue 27
Ultrathin trimetallic metal–organic framework nanosheets for highly efficient oxygen evolution reaction
journal, January 2019
- Ding, Mengmeng; Chen, Jing; Jiang, Meiwen
- Journal of Materials Chemistry A, Vol. 7, Issue 23
High-performance hierarchical ultrathin sheet-based CoOOH hollow nanospheres with rich oxygen vacancies for the oxygen evolution reaction
journal, January 2019
- Wang, Huan; Feng, Er-ming; Liu, Yan-ming
- Journal of Materials Chemistry A, Vol. 7, Issue 13
NiFe (sulfur)oxyhydroxide porous nanoclusters/Ni foam composite electrode drives a large-current-density oxygen evolution reaction with an ultra-low overpotential
journal, January 2019
- Wang, Yanqing; Li, Yuemeng; Ding, Liping
- Journal of Materials Chemistry A, Vol. 7, Issue 32
Facile fabrication of a hierarchical NiCoFeP hollow nanoprism for efficient oxygen evolution in the Zn–air battery
journal, January 2019
- He, Bin; Xu, Chunyu; Tang, Yawen
- Journal of Materials Chemistry A, Vol. 7, Issue 43
Pressure-promoted irregular CoMoP 2 nanoparticles activated by surface reconstruction for oxygen evolution reaction electrocatalysts
journal, January 2020
- Xu, Shishuai; Gao, Xiang; Deshmukh, Amol
- Journal of Materials Chemistry A, Vol. 8, Issue 4
Highly crystalline Ni-doped FeP/carbon hollow nanorods as all-pH efficient and durable hydrogen evolving electrocatalysts
journal, February 2019
- Lu, Xue Feng; Yu, Le; Lou, Xiong Wen (David)
- Science Advances, Vol. 5, Issue 2
Bimetallic Iron–Cobalt Catalysts and Their Applications in Energy-Related Electrochemical Reactions
journal, September 2019
- Li, Kai; Li, Yang; Peng, Wenchao
- Catalysts, Vol. 9, Issue 9