Combinatorial Search for High-Activity Hydrogen Catalysts Based on Transition-Metal-Embedded Graphitic Carbons
Abstract
Transition metal (TM) atoms in porphyrin–like complexes play important roles in many protein and enzymetic systems, where crystal–field effects are used to modify d–orbital levels. Inspired by the tunable electronic structure of these motifs, a high–throughput computational search for synthetic hydrogen catalysts is performed based on a similar motif of TM atoms embedded into the lattice of graphene. Based on an initial list of 300 possible embedding geometries, binders, and host atoms, descriptors for stability and catalytic activity are applied to extract ten promising candidates for hydrogen evolution, two of which are expected to exhibit high activity for hydrogen oxidation. In several instances, the active TM atoms are earth–abundant elements that show no activity in the bulk phase, highlighting the importance of the coordination environment in tuning the d–orbitals. In conclusion, it is found that the most active candidates involve a hitherto unreported surface reaction pathway that involves a Kubas–complex intermediate, which significantly lowers the kinetic barrier associated with hydrogen dissociation and association.
- Authors:
-
- Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States); Samsung Advanced Institute of Technology, Gyeonggi-do (South Korea)
- Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States)
- Publication Date:
- Research Org.:
- Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States)
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1438765
- Report Number(s):
- LLNL-JRNL-737906
Journal ID: ISSN 1614-6832
- Grant/Contract Number:
- AC52-07NA27344
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Advanced Energy Materials
- Additional Journal Information:
- Journal Volume: 5; Journal Issue: 23; Journal ID: ISSN 1614-6832
- Publisher:
- Wiley
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 08 HYDROGEN; 37 INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; computational high-throughput screening; density functional theory calculations; graphene; hydrogen catalysts; transition metals
Citation Formats
Choi, Woon Ih, Wood, Brandon C., Schwegler, Eric, and Ogitsu, Tadashi. Combinatorial Search for High-Activity Hydrogen Catalysts Based on Transition-Metal-Embedded Graphitic Carbons. United States: N. p., 2015.
Web. doi:10.1002/aenm.201501423.
Choi, Woon Ih, Wood, Brandon C., Schwegler, Eric, & Ogitsu, Tadashi. Combinatorial Search for High-Activity Hydrogen Catalysts Based on Transition-Metal-Embedded Graphitic Carbons. United States. https://doi.org/10.1002/aenm.201501423
Choi, Woon Ih, Wood, Brandon C., Schwegler, Eric, and Ogitsu, Tadashi. Tue .
"Combinatorial Search for High-Activity Hydrogen Catalysts Based on Transition-Metal-Embedded Graphitic Carbons". United States. https://doi.org/10.1002/aenm.201501423. https://www.osti.gov/servlets/purl/1438765.
@article{osti_1438765,
title = {Combinatorial Search for High-Activity Hydrogen Catalysts Based on Transition-Metal-Embedded Graphitic Carbons},
author = {Choi, Woon Ih and Wood, Brandon C. and Schwegler, Eric and Ogitsu, Tadashi},
abstractNote = {Transition metal (TM) atoms in porphyrin–like complexes play important roles in many protein and enzymetic systems, where crystal–field effects are used to modify d–orbital levels. Inspired by the tunable electronic structure of these motifs, a high–throughput computational search for synthetic hydrogen catalysts is performed based on a similar motif of TM atoms embedded into the lattice of graphene. Based on an initial list of 300 possible embedding geometries, binders, and host atoms, descriptors for stability and catalytic activity are applied to extract ten promising candidates for hydrogen evolution, two of which are expected to exhibit high activity for hydrogen oxidation. In several instances, the active TM atoms are earth–abundant elements that show no activity in the bulk phase, highlighting the importance of the coordination environment in tuning the d–orbitals. In conclusion, it is found that the most active candidates involve a hitherto unreported surface reaction pathway that involves a Kubas–complex intermediate, which significantly lowers the kinetic barrier associated with hydrogen dissociation and association.},
doi = {10.1002/aenm.201501423},
journal = {Advanced Energy Materials},
number = 23,
volume = 5,
place = {United States},
year = {2015},
month = {9}
}
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Works referenced in this record:
Stellated Ag-Pt bimetallic nanoparticles: An effective platform for catalytic activity tuning
journal, February 2014
- Liu, Hui; Ye, Feng; Yao, Qiaofeng
- Scientific Reports, Vol. 4, Issue 1
Generalized Gradient Approximation Made Simple
journal, October 1996
- Perdew, John P.; Burke, Kieron; Ernzerhof, Matthias
- Physical Review Letters, Vol. 77, Issue 18, p. 3865-3868
Theory, Synthesis, and Oxygen Reduction Catalysis of Fe-Porphyrin-Like Carbon Nanotube
journal, April 2011
- Lee, Duck Hyun; Lee, Won Jun; Lee, Won Jong
- Physical Review Letters, Vol. 106, Issue 17
Computational high-throughput screening of electrocatalytic materials for hydrogen evolution
journal, October 2006
- Greeley, Jeff; Jaramillo, Thomas F.; Bonde, Jacob
- Nature Materials, Vol. 5, Issue 11, p. 909-913
Projector augmented-wave method
journal, December 1994
- Blöchl, P. E.
- Physical Review B, Vol. 50, Issue 24, p. 17953-17979
Incorporating Isolated Molybdenum (Mo) Atoms into Bilayer Epitaxial Graphene on 4H-SiC(0001)
journal, December 2013
- Wan, Wen; Li, Hui; Huang, Han
- ACS Nano, Vol. 8, Issue 1
Highly active and durable nanostructured molybdenum carbide electrocatalysts for hydrogen production
journal, January 2013
- Chen, W. -F.; Wang, C. -H.; Sasaki, K.
- Energy & Environmental Science, Vol. 6, Issue 3
Accurate surface and adsorption energies from many-body perturbation theory
journal, July 2010
- Schimka, L.; Harl, J.; Stroppa, A.
- Nature Materials, Vol. 9, Issue 9
Divacancy-nitrogen-assisted transition metal dispersion and hydrogen adsorption in defective graphene: A first-principles study
journal, February 2010
- Choi, Woon Ih; Jhi, Seung-Hoon; Kim, Kwiseon
- Physical Review B, Vol. 81, Issue 8
Elucidating Oxygen Reduction Active Sites in Pyrolyzed Metal–Nitrogen Coordinated Non-Precious-Metal Electrocatalyst Systems
journal, April 2014
- Tylus, Urszula; Jia, Qingying; Strickland, Kara
- The Journal of Physical Chemistry C, Vol. 118, Issue 17
Site-Dependent Free Energy Barrier for Proton Reduction on MoS 2 Edges
journal, October 2013
- Choi, Woon Ih; Wood, Brandon C.; Schwegler, Eric
- The Journal of Physical Chemistry C, Vol. 117, Issue 42
Activity benchmarks and requirements for Pt, Pt-alloy, and non-Pt oxygen reduction catalysts for PEMFCs
journal, March 2005
- Gasteiger, Hubert A.; Kocha, Shyam S.; Sompalli, Bhaskar
- Applied Catalysis B: Environmental, Vol. 56, Issue 1-2, p. 9-35
Earth-abundant inorganic electrocatalysts and their nanostructures for energy conversion applications
journal, January 2014
- Faber, Matthew S.; Jin, Song
- Energy Environ. Sci., Vol. 7, Issue 11
Trends in the Hydrogen Evolution Activity of Metal Carbide Catalysts
journal, March 2014
- Michalsky, Ronald; Zhang, Yin-Jia; Peterson, Andrew A.
- ACS Catalysis, Vol. 4, Issue 5
Recent progress in electrochemical hydrogen production with earth-abundant metal complexes as catalysts
journal, January 2012
- Wang, Mei; Chen, Lin; Sun, Licheng
- Energy & Environmental Science, Vol. 5, Issue 5
Fundamental aspects of electrocatalysis
journal, January 2007
- Santos, E.; Schmickler, W.
- Chemical Physics, Vol. 332, Issue 1
Facile Synthesis of Nitrogen-Doped Graphene via Pyrolysis of Graphene Oxide and Urea, and its Electrocatalytic Activity toward the Oxygen-Reduction Reaction
journal, May 2012
- Lin, Ziyin; Waller, Gordon; Liu, Yan
- Advanced Energy Materials, Vol. 2, Issue 7
Metal–dihydrogen and σ-bond coordination: the consummate extension of the Dewar–Chatt–Duncanson model for metal–olefin π bonding
journal, October 2001
- Kubas, Gregory J.
- Journal of Organometallic Chemistry, Vol. 635, Issue 1-2
3D WS 2 Nanolayers@Heteroatom-Doped Graphene Films as Hydrogen Evolution Catalyst Electrodes
journal, June 2015
- Duan, Jingjing; Chen, Sheng; Chambers, Benjamin A.
- Advanced Materials, Vol. 27, Issue 28
The high-throughput highway to computational materials design
journal, February 2013
- Curtarolo, Stefano; Hart, Gus L. W.; Nardelli, Marco Buongiorno
- Nature Materials, Vol. 12, Issue 3
Advancing the Electrochemistry of the Hydrogen-Evolution Reaction through Combining Experiment and Theory
journal, November 2014
- Zheng, Yao; Jiao, Yan; Jaroniec, Mietek
- Angewandte Chemie International Edition, Vol. 54, Issue 1
Tuning the catalytic property of non-noble metallic impurities in graphene
journal, May 2014
- Tang, Yanan; Dai, Xianqi; Yang, Zongxian
- Carbon, Vol. 71
N-Doped Carbon-Wrapped Cobalt Nanoparticles on N-Doped Graphene Nanosheets for High-Efficiency Hydrogen Production
journal, March 2015
- Zhou, Weijia; Zhou, Jian; Zhou, Yucheng
- Chemistry of Materials, Vol. 27, Issue 6
Artificial photosynthesis for solar water-splitting
journal, July 2012
- Tachibana, Yasuhiro; Vayssieres, Lionel; Durrant, James R.
- Nature Photonics, Vol. 6, Issue 8
CO Catalytic Oxidation on Copper-Embedded Graphene
journal, February 2011
- Song, E. H.; Wen, Z.; Jiang, Q.
- The Journal of Physical Chemistry C, Vol. 115, Issue 9
Trends in the Exchange Current for Hydrogen Evolution
journal, January 2005
- Nørskov, J. K.; Bligaard, T.; Logadottir, A.
- Journal of The Electrochemical Society, Vol. 152, Issue 3
Density functional theory in surface chemistry and catalysis
journal, January 2011
- Norskov, J. K.; Abild-Pedersen, F.; Studt, F.
- Proceedings of the National Academy of Sciences, Vol. 108, Issue 3
The influence of platinum crystallite size on the electrochemical reduction of oxygen in phosphoric acid
journal, June 1978
- Bregoli, L. J.
- Electrochimica Acta, Vol. 23, Issue 6, p. 489-492
Electrochemical CO 2 and CO Reduction on Metal-Functionalized Porphyrin-like Graphene
journal, April 2013
- Tripkovic, Vladimir; Vanin, Marco; Karamad, Mohammedreza
- The Journal of Physical Chemistry C, Vol. 117, Issue 18
Dynamics of Single Fe Atoms in Graphene Vacancies
journal, March 2013
- Robertson, Alex W.; Montanari, Barbara; He, Kuang
- Nano Letters, Vol. 13, Issue 4
Cobalt-Embedded Nitrogen-Rich Carbon Nanotubes Efficiently Catalyze Hydrogen Evolution Reaction at All pH Values
journal, March 2014
- Zou, Xiaoxin; Huang, Xiaoxi; Goswami, Anandarup
- Angewandte Chemie International Edition, Vol. 53, Issue 17
The Impact of Geometric and Surface Electronic Properties of Pt-Catalysts on the Particle Size Effect in Electrocatalysis
journal, August 2005
- Mayrhofer, K. J. J.; Blizanac, B. B.; Arenz, M.
- The Journal of Physical Chemistry B, Vol. 109, Issue 30
Density Functional Theory Study of Ni–N x /C Electrocatalyst for Oxygen Reduction in Alkaline and Acidic Media
journal, August 2012
- Kattel, Shyam; Atanassov, Plamen; Kiefer, Boris
- The Journal of Physical Chemistry C, Vol. 116, Issue 33
Adsorption/Desorption of Hydrogen on Pt Nanoelectrodes: Evidence of Surface Diffusion and Spillover
journal, October 2009
- Zhan, Dongping; Velmurugan, Jeyavel; Mirkin, Michael V.
- Journal of the American Chemical Society, Vol. 131, Issue 41
Lattice-strain control of the activity in dealloyed core–shell fuel cell catalysts
journal, April 2010
- Strasser, Peter; Koh, Shirlaine; Anniyev, Toyli
- Nature Chemistry, Vol. 2, Issue 6
Improved Oxygen Reduction Activity on Pt3Ni(111) via Increased Surface Site Availability
journal, January 2007
- Stamenkovic, V. R.; Fowler, B.; Mun, B. S.
- Science, Vol. 315, Issue 5811, p. 493-497
Biomimetic Hydrogen Evolution: MoS 2 Nanoparticles as Catalyst for Hydrogen Evolution
journal, April 2005
- Hinnemann, Berit; Moses, Poul Georg; Bonde, Jacob
- Journal of the American Chemical Society, Vol. 127, Issue 15
A first-principles investigation of the effect of Pt cluster size on CO and NO oxidation intermediates and energetics
journal, January 2008
- Xu, Ye; Getman, Rachel B.; Shelton, William A.
- Physical Chemistry Chemical Physics, Vol. 10, Issue 39
A Comparison of the Adsorption and Diffusion of Hydrogen on the {111} Surfaces of Ni, Pd, and Pt from Density Functional Theory Calculations
journal, May 2001
- Watson, Graeme W.; Wells, Richard P. K.; Willock, David J.
- The Journal of Physical Chemistry B, Vol. 105, Issue 21
Catalysts made of earth-abundant elements (Co, Ni, Fe) for water splitting: Recent progress and future challenges
journal, January 2012
- Du, Pingwu; Eisenberg, Richard
- Energy & Environmental Science, Vol. 5, Issue 3
CO Catalytic Oxidation on Iron-Embedded Graphene: Computational Quest for Low-Cost Nanocatalysts
journal, February 2010
- Li, Yafei; Zhou, Zhen; Yu, Guangtao
- The Journal of Physical Chemistry C, Vol. 114, Issue 14
Finite-Temperature Hydrogen Adsorption and Desorption Thermodynamics Driven by Soft Vibration Modes
journal, August 2013
- Woo, Sung-Jae; Lee, Eui-Sup; Yoon, Mina
- Physical Review Letters, Vol. 111, Issue 6
Catalytic activity of Co–N x /C electrocatalysts for oxygen reduction reaction: a density functional theory study
journal, January 2013
- Kattel, Shyam; Atanassov, Plamen; Kiefer, Boris
- Phys. Chem. Chem. Phys., Vol. 15, Issue 1
Efficiency of ab-initio total energy calculations for metals and semiconductors using a plane-wave basis set
journal, July 1996
- Kresse, G.; Furthmüller, J.
- Computational Materials Science, Vol. 6, Issue 1, p. 15-50
Model for the electrocatalysis of hydrogen evolution
journal, June 2009
- Santos, E.; Lundin, A.; Pötting, K.
- Physical Review B, Vol. 79, Issue 23
Electrocatalysis of CO tolerance in hydrogen oxidation reaction in PEM fuel cells
journal, May 1999
- Lee, S. J.; Mukerjee, S.; Ticianelli, E. A.
- Electrochimica Acta, Vol. 44, Issue 19
Oxidation Resistance of Reactive Atoms in Graphene
journal, January 2012
- Chisholm, Matthew F.; Duscher, Gerd; Windl, Wolfgang
- Nano Letters, Vol. 12, Issue 9
Design of electrocatalysts for oxygen- and hydrogen-involving energy conversion reactions
journal, January 2015
- Jiao, Yan; Zheng, Yao; Jaroniec, Mietek
- Chemical Society Reviews, Vol. 44, Issue 8
Why gold is the noblest of all the metals
journal, July 1995
- Hammer, B.; Norskov, J. K.
- Nature, Vol. 376, Issue 6537
Metal-Embedded Graphene: A Possible Catalyst with High Activity
journal, October 2009
- Lu, Yun-Hao; Zhou, Miao; Zhang, Chun
- The Journal of Physical Chemistry C, Vol. 113, Issue 47
Aligned carbon nanotubes with built-in FeN 4 active sites for electrocatalytic reduction of oxygen
journal, January 2008
- Yang, Junbing; Liu, Di-Jia; Kariuki, Nancy N.
- Chem. Commun., Issue 3
Work function, electronegativity, and electrochemical behaviour of metals
journal, September 1972
- Trasatti, Sergio
- Journal of Electroanalytical Chemistry and Interfacial Electrochemistry, Vol. 39, Issue 1
Noble-Metal-Free NiS/C 3 N 4 for Efficient Photocatalytic Hydrogen Evolution from Water
journal, October 2013
- Hong, Jindui; Wang, Yongsheng; Wang, Yabo
- ChemSusChem, Vol. 6, Issue 12
Hydrogen evolution by a metal-free electrocatalyst
journal, April 2014
- Zheng, Yao; Jiao, Yan; Zhu, Yihan
- Nature Communications, Vol. 5, Issue 1
Density functional theory calculations of XPS binding energy shift for nitrogen-containing graphene-like structures
journal, January 2013
- Artyushkova, K.; Kiefer, B.; Halevi, B.
- Chemical Communications, Vol. 49, Issue 25
A model for the Heyrovsky reaction as the second step in hydrogen evolution
journal, January 2011
- Santos, E.; Hindelang, P.; Quaino, P.
- Physical Chemistry Chemical Physics, Vol. 13, Issue 15
Atomic Structure and Dynamics of Metal Dopant Pairs in Graphene
journal, June 2014
- He, Zhengyu; He, Kuang; Robertson, Alex W.
- Nano Letters, Vol. 14, Issue 7
Electrochemical Evaluation of Porous Non-Platinum Oxygen Reduction Catalysts for Polymer Electrolyte Fuel Cells
journal, October 2009
- Olson, T. S.; Blizanac, B.; Piela, B.
- Fuel Cells, Vol. 9, Issue 5
Activity Descriptor Identification for Oxygen Reduction on Nonprecious Electrocatalysts: Linking Surface Science to Coordination Chemistry
journal, October 2013
- Ramaswamy, Nagappan; Tylus, Urszula; Jia, Qingying
- Journal of the American Chemical Society, Vol. 135, Issue 41
The surface structure of Pt crystallites supported on carbon black
journal, January 1986
- Sattler, M. L.; Ross, P. N.
- Ultramicroscopy, Vol. 20, Issue 1-2
Porous C 3 N 4 Nanolayers@N-Graphene Films as Catalyst Electrodes for Highly Efficient Hydrogen Evolution
journal, January 2015
- Duan, Jingjing; Chen, Sheng; Jaroniec, Mietek
- ACS Nano, Vol. 9, Issue 1
The Effect of Size on the Oxygen Electroreduction Activity of Mass-Selected Platinum Nanoparticles
journal, March 2012
- Perez-Alonso, Francisco J.; McCarthy, David N.; Nierhoff, Anders
- Angewandte Chemie International Edition, Vol. 51, Issue 19
Trends in electrocatalysis on extended and nanoscale Pt-bimetallic alloy surfaces
journal, February 2007
- Stamenkovic, Vojislav R.; Mun, Bongjin Simon; Arenz, Matthias
- Nature Materials, Vol. 6, Issue 3, p. 241-247
Clustering of Ti on a C 60 Surface and Its Effect on Hydrogen Storage
journal, October 2005
- Sun, Qiang; Wang, Qian; Jena, Puru
- Journal of the American Chemical Society, Vol. 127, Issue 42
A Monolithic Photovoltaic-Photoelectrochemical Device for Hydrogen Production via Water Splitting
journal, April 1998
- Khaselev, O.
- Science, Vol. 280, Issue 5362
Non-platinum oxygen reduction electrocatalysts based on pyrolyzed transition metal macrocycles
journal, November 2008
- Pylypenko, Svitlana; Mukherjee, Sanjoy; Olson, Tim S.
- Electrochimica Acta, Vol. 53, Issue 27
Preparation and characterization TiOx–Pt/C catalyst for hydrogen oxidation reaction
journal, January 2009
- Elezović, N. R.; Babić, B. M.; Vračar, Lj. M.
- Physical Chemistry Chemical Physics, Vol. 11, Issue 25
Highly active and durable non-precious-metal catalysts encapsulated in carbon nanotubes for hydrogen evolution reaction
journal, January 2014
- Deng, Jiao; Ren, Pengju; Deng, Dehui
- Energy Environ. Sci., Vol. 7, Issue 6
Towards the computational design of solid catalysts
journal, April 2009
- Nørskov, J.; Bligaard, T.; Rossmeisl, J.
- Nature Chemistry, Vol. 1, Issue 1, p. 37-46
Embedding Transition-Metal Atoms in Graphene: Structure, Bonding, and Magnetism
journal, March 2009
- Krasheninnikov, A. V.; Lehtinen, P. O.; Foster, A. S.
- Physical Review Letters, Vol. 102, Issue 12
Iron-Based Catalysts with Improved Oxygen Reduction Activity in Polymer Electrolyte Fuel Cells
journal, April 2009
- Lefèvre, Michel; Proietti, Eric; Jaouen, Frédéric
- Science, Vol. 324, Issue 5923, p. 71-74
The Particle Size Effect on the Oxygen Reduction Reaction Activity of Pt Catalysts: Influence of Electrolyte and Relation to Single Crystal Models
journal, November 2011
- Nesselberger, Markus; Ashton, Sean; Meier, Josef C.
- Journal of the American Chemical Society, Vol. 133, Issue 43
Adsorption of gas molecules on transition metal embedded graphene: a search for high-performance graphene-based catalysts and gas sensors
journal, August 2011
- Zhou, Miao; Lu, Yun-Hao; Cai, Yong-Qing
- Nanotechnology, Vol. 22, Issue 38
Design criteria for stable Pt/C fuel cell catalysts
journal, January 2014
- Meier, Josef C.; Galeano, Carolina; Katsounaros, Ioannis
- Beilstein Journal of Nanotechnology, Vol. 5
Works referencing / citing this record:
Molybdenum Carbide-Based Electrocatalysts for Hydrogen Evolution Reaction
journal, July 2017
- Miao, Mao; Pan, Jing; He, Ting
- Chemistry - A European Journal, Vol. 23, Issue 46
Single vs double atom catalyst for N 2 activation in nitrogen reduction reaction: A DFT perspective
journal, January 2020
- Qian, Yumin; Liu, Yuanyue; Zhao, Yu
- EcoMat, Vol. 2, Issue 1
A General Two‐Step Strategy–Based High‐Throughput Screening of Single Atom Catalysts for Nitrogen Fixation
journal, December 2018
- Ling, Chongyi; Ouyang, Yixin; Li, Qiang
- Small Methods, Vol. 3, Issue 9
Ruthenium atomically dispersed in carbon outperforms platinum toward hydrogen evolution in alkaline media
journal, February 2019
- Lu, Bingzhang; Guo, Lin; Wu, Feng
- Nature Communications, Vol. 10, Issue 1
Cobalt-porphine catalyzed CO 2 electro-reduction: a novel protonation mechanism
journal, January 2017
- Yao, Cang Lang; Li, Jian Chen; Gao, Wang
- Physical Chemistry Chemical Physics, Vol. 19, Issue 23
Two-dimensional π-conjugated metal–organic nanosheets as single-atom catalysts for the hydrogen evolution reaction
journal, January 2019
- Ji, Yujin; Dong, Huilong; Liu, Cheng
- Nanoscale, Vol. 11, Issue 2
Transition metal embedded C 3 N monolayers as promising catalysts for the hydrogen evolution reaction
journal, January 2019
- Zhao, Yameng; Ma, Dongwei; Zhang, Jing
- Physical Chemistry Chemical Physics, Vol. 21, Issue 36
Single atom electrocatalysts supported on graphene or graphene-like carbons
journal, January 2019
- Fei, Huilong; Dong, Juncai; Chen, Dongliang
- Chemical Society Reviews, Vol. 48, Issue 20
Recent advances in tuning the electronic structures of atomically dispersed M–N–C materials for efficient gas-involving electrocatalysis
journal, January 2020
- Huang, Dekang; Luo, Yanzhu; Li, Shu
- Materials Horizons, Vol. 7, Issue 4