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Title: Red persistent luminescence in rare earth-free AlN:Mn 2+ phosphor

Here, we investigated the persistent luminescence (PersL) properties of a rare earth-free Mn 2+ doped AlN (AlN:Mn) red phosphor together with a commercial SrAl 2O 4:Eu 2+, Dy 3+ green persistent phosphor as a reference. Similar to its photoluminescence (PL) spectrum, the PersL spectrum of the AlN:Mn phosphor exhibited a red emission band centered at 600 nm due to the Mn 2+: 4T 1( 4G) → 6A 1( 6S) transition with a relatively narrow full width at half maximum (FWHM) of 43 nm. The luminance of AlN:Mn powders was 0.65 mcd/m 2 at 60 min after ceasing ultraviolet (UV) illumination, and its duration upon 0.32 mcd/m 2 could reach over 110 min. An extremely broad thermoluminescence (TL) glow curve was observed ranging from 100 K to 600 K and peaked at around 310 K, indicating a wide trap distribution in this material.
Authors:
ORCiD logo [1] ;  [2] ;  [1] ;  [1]
  1. Kyoto Univ., Kyoto (Japan)
  2. Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States)
Publication Date:
Report Number(s):
LLNL-JRNL-731409
Journal ID: ISSN 0167-577X
Grant/Contract Number:
AC52-07NA27344
Type:
Accepted Manuscript
Journal Name:
Materials Letters
Additional Journal Information:
Journal Volume: 206; Journal Issue: C; Journal ID: ISSN 0167-577X
Publisher:
Elsevier
Research Org:
Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States)
Sponsoring Org:
USDOE
Country of Publication:
United States
Language:
English
Subject:
36 MATERIALS SCIENCE; Optical materials and properties; Phosphors; Luminescence
OSTI Identifier:
1438705

Xu, Jian, Cherepy, Nerine J., Ueda, Jumpei, and Tanabe, Setsuhisa. Red persistent luminescence in rare earth-free AlN:Mn2+ phosphor. United States: N. p., Web. doi:10.1016/j.matlet.2017.07.015.
Xu, Jian, Cherepy, Nerine J., Ueda, Jumpei, & Tanabe, Setsuhisa. Red persistent luminescence in rare earth-free AlN:Mn2+ phosphor. United States. doi:10.1016/j.matlet.2017.07.015.
Xu, Jian, Cherepy, Nerine J., Ueda, Jumpei, and Tanabe, Setsuhisa. 2017. "Red persistent luminescence in rare earth-free AlN:Mn2+ phosphor". United States. doi:10.1016/j.matlet.2017.07.015. https://www.osti.gov/servlets/purl/1438705.
@article{osti_1438705,
title = {Red persistent luminescence in rare earth-free AlN:Mn2+ phosphor},
author = {Xu, Jian and Cherepy, Nerine J. and Ueda, Jumpei and Tanabe, Setsuhisa},
abstractNote = {Here, we investigated the persistent luminescence (PersL) properties of a rare earth-free Mn2+ doped AlN (AlN:Mn) red phosphor together with a commercial SrAl2O4:Eu2+, Dy3+ green persistent phosphor as a reference. Similar to its photoluminescence (PL) spectrum, the PersL spectrum of the AlN:Mn phosphor exhibited a red emission band centered at 600 nm due to the Mn2+: 4T1(4G) → 6A1(6S) transition with a relatively narrow full width at half maximum (FWHM) of 43 nm. The luminance of AlN:Mn powders was 0.65 mcd/m2 at 60 min after ceasing ultraviolet (UV) illumination, and its duration upon 0.32 mcd/m2 could reach over 110 min. An extremely broad thermoluminescence (TL) glow curve was observed ranging from 100 K to 600 K and peaked at around 310 K, indicating a wide trap distribution in this material.},
doi = {10.1016/j.matlet.2017.07.015},
journal = {Materials Letters},
number = C,
volume = 206,
place = {United States},
year = {2017},
month = {7}
}