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Title: Investigation of α-MnO2 Tunneled Structures as Model Cation Hosts for Energy Storage

Abstract

Future advances in energy storage systems rely on identification of appropriate target materials and deliberate synthesis of the target materials with control of their physiochemical properties in order to disentangling the contributions of distinct properties to the functional electrochemistry. Furthermore, this goal demands systematic inquiry using model materials that provide the opportunity for significant synthetic versatility and control. Ideally, a material family that enables direct manipulation of characteristics including composition, defects and crystallite size while remaining within the defined structural framework would be necessary. Accomplishing this through direct synthetic methods is desirable to minimize the complicating effects of secondary processing.

Authors:
 [1]; ORCiD logo [1];  [1];  [1];  [1];  [1];  [1]; ORCiD logo [2]; ORCiD logo [1]; ORCiD logo [2]
  1. Stony Brook Univ., Stony Brook, NY (United States)
  2. Stony Brook Univ., Stony Brook, NY (United States); Brookhaven National Lab. (BNL), Upton, NY (United States)
Publication Date:
Research Org.:
Brookhaven National Lab. (BNL), Upton, NY (United States); Energy Frontier Research Centers (EFRC) (United States). Center for Mesoscale Transport Properties (m2M)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
OSTI Identifier:
1438326
Report Number(s):
BNL-205690-2018-JAAM
Journal ID: ISSN 0001-4842
Grant/Contract Number:  
SC0012704
Resource Type:
Accepted Manuscript
Journal Name:
Accounts of Chemical Research
Additional Journal Information:
Journal Volume: 51; Journal Issue: 3; Journal ID: ISSN 0001-4842
Publisher:
American Chemical Society
Country of Publication:
United States
Language:
English
Subject:
25 ENERGY STORAGE

Citation Formats

Housel, Lisa M., Wang, Lei, Abraham, Alyson, Huang, Jianping, Renderos, Genesis D., Quilty, Calvin D., Brady, Alexander B., Marschilok, Amy C., Takeuchi, Kenneth J., and Takeuchi, Esther S.. Investigation of α-MnO2 Tunneled Structures as Model Cation Hosts for Energy Storage. United States: N. p., 2018. Web. https://doi.org/10.1021/acs.accounts.7b00478.
Housel, Lisa M., Wang, Lei, Abraham, Alyson, Huang, Jianping, Renderos, Genesis D., Quilty, Calvin D., Brady, Alexander B., Marschilok, Amy C., Takeuchi, Kenneth J., & Takeuchi, Esther S.. Investigation of α-MnO2 Tunneled Structures as Model Cation Hosts for Energy Storage. United States. https://doi.org/10.1021/acs.accounts.7b00478
Housel, Lisa M., Wang, Lei, Abraham, Alyson, Huang, Jianping, Renderos, Genesis D., Quilty, Calvin D., Brady, Alexander B., Marschilok, Amy C., Takeuchi, Kenneth J., and Takeuchi, Esther S.. Mon . "Investigation of α-MnO2 Tunneled Structures as Model Cation Hosts for Energy Storage". United States. https://doi.org/10.1021/acs.accounts.7b00478. https://www.osti.gov/servlets/purl/1438326.
@article{osti_1438326,
title = {Investigation of α-MnO2 Tunneled Structures as Model Cation Hosts for Energy Storage},
author = {Housel, Lisa M. and Wang, Lei and Abraham, Alyson and Huang, Jianping and Renderos, Genesis D. and Quilty, Calvin D. and Brady, Alexander B. and Marschilok, Amy C. and Takeuchi, Kenneth J. and Takeuchi, Esther S.},
abstractNote = {Future advances in energy storage systems rely on identification of appropriate target materials and deliberate synthesis of the target materials with control of their physiochemical properties in order to disentangling the contributions of distinct properties to the functional electrochemistry. Furthermore, this goal demands systematic inquiry using model materials that provide the opportunity for significant synthetic versatility and control. Ideally, a material family that enables direct manipulation of characteristics including composition, defects and crystallite size while remaining within the defined structural framework would be necessary. Accomplishing this through direct synthetic methods is desirable to minimize the complicating effects of secondary processing.},
doi = {10.1021/acs.accounts.7b00478},
journal = {Accounts of Chemical Research},
number = 3,
volume = 51,
place = {United States},
year = {2018},
month = {2}
}

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Cited by: 5 works
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Figures / Tables:

Figure 1 Figure 1: General structure of hollandite, with 2 x 2 tunnels and central cation.

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Works referenced in this record:

Investigating the Complex Chemistry of Functional Energy Storage Systems: The Need for an Integrative, Multiscale (Molecular to Mesoscale) Perspective
journal, April 2016


Structural Defects of Silver Hollandite, Ag x Mn 8 O y , Nanorods: Dramatic Impact on Electrochemistry
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