Investigation of α-MnO2 Tunneled Structures as Model Cation Hosts for Energy Storage

doi:10.1021/acs.accounts.7b00478

Title: Investigation of α-MnO₂ Tunneled Structures as Model Cation Hosts for Energy Storage

Abstract

Future advances in energy storage systems rely on identification of appropriate target materials and deliberate synthesis of the target materials with control of their physiochemical properties in order to disentangling the contributions of distinct properties to the functional electrochemistry. Furthermore, this goal demands systematic inquiry using model materials that provide the opportunity for significant synthetic versatility and control. Ideally, a material family that enables direct manipulation of characteristics including composition, defects and crystallite size while remaining within the defined structural framework would be necessary. Accomplishing this through direct synthetic methods is desirable to minimize the complicating effects of secondary processing.

Authors:

Housel, Lisa M. ^[1];

^[1]; Abraham, Alyson ^[1]; Huang, Jianping ^[1]; Renderos, Genesis D. ^[1]; Quilty, Calvin D. ^[1]; Brady, Alexander B. ^[1];

^[2];

^[1];

^[2]

Stony Brook Univ., Stony Brook, NY (United States)
Stony Brook Univ., Stony Brook, NY (United States); Brookhaven National Lab. (BNL), Upton, NY (United States)

Publication Date:: 2018-02-19

Research Org.:: Brookhaven National Lab. (BNL), Upton, NY (United States); Energy Frontier Research Centers (EFRC) (United States). Center for Mesoscale Transport Properties (m2M)

Sponsoring Org.:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

OSTI Identifier:: 1438326

Report Number(s):: BNL-205690-2018-JAAM
Journal ID: ISSN 0001-4842

Grant/Contract Number:: SC0012704

Resource Type:: Accepted Manuscript

Journal Name:: Accounts of Chemical Research

Additional Journal Information:: Journal Volume: 51; Journal Issue: 3; Journal ID: ISSN 0001-4842

Publisher:: American Chemical Society

Country of Publication:: United States

Language:: English

Subject:: 25 ENERGY STORAGE

Citation Formats


                    Housel, Lisa M., Wang, Lei, Abraham, Alyson, Huang, Jianping, Renderos, Genesis D., Quilty, Calvin D., Brady, Alexander B., Marschilok, Amy C., Takeuchi, Kenneth J., and Takeuchi, Esther S. Investigation of α-MnO2 Tunneled Structures as Model Cation Hosts for Energy Storage.  United States: N. p., 2018. 
        Web.  doi:10.1021/acs.accounts.7b00478.

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                    Housel, Lisa M., Wang, Lei, Abraham, Alyson, Huang, Jianping, Renderos, Genesis D., Quilty, Calvin D., Brady, Alexander B., Marschilok, Amy C., Takeuchi, Kenneth J., & Takeuchi, Esther S. Investigation of α-MnO2 Tunneled Structures as Model Cation Hosts for Energy Storage.  United States.  doi:10.1021/acs.accounts.7b00478.

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                    Housel, Lisa M., Wang, Lei, Abraham, Alyson, Huang, Jianping, Renderos, Genesis D., Quilty, Calvin D., Brady, Alexander B., Marschilok, Amy C., Takeuchi, Kenneth J., and Takeuchi, Esther S. Mon .  
        "Investigation of α-MnO2 Tunneled Structures as Model Cation Hosts for Energy Storage".  United States.  doi:10.1021/acs.accounts.7b00478.  https://www.osti.gov/servlets/purl/1438326.

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@article{osti_1438326,

  title        = {Investigation of α-MnO2 Tunneled Structures as Model Cation Hosts for Energy Storage},

  author       = {Housel, Lisa M. and Wang, Lei and Abraham, Alyson and Huang, Jianping and Renderos, Genesis D. and Quilty, Calvin D. and Brady, Alexander B. and Marschilok, Amy C. and Takeuchi, Kenneth J. and Takeuchi, Esther S.},

  abstractNote = {Future advances in energy storage systems rely on identification of appropriate target materials and deliberate synthesis of the target materials with control of their physiochemical properties in order to disentangling the contributions of distinct properties to the functional electrochemistry. Furthermore, this goal demands systematic inquiry using model materials that provide the opportunity for significant synthetic versatility and control. Ideally, a material family that enables direct manipulation of characteristics including composition, defects and crystallite size while remaining within the defined structural framework would be necessary. Accomplishing this through direct synthetic methods is desirable to minimize the complicating effects of secondary processing.},

  doi          = {10.1021/acs.accounts.7b00478},

  journal      = {Accounts of Chemical Research},

  number       = 3,

  volume       = 51,

  place        = {United States},

  year         = {2018},

  month        = {2}

}

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Journal Article:

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DOI: 10.1021/acs.accounts.7b00478

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Cited by: 5 works

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Figures / Tables:

Figure 1: General structure of hollandite, with 2 x 2 tunnels and central cation.

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Works referencing / citing this record:

K ⁺ pre-intercalated manganese dioxide with enhanced Zn ²⁺ diffusion for high rate and durable aqueous zinc-ion batteries
journal, January 2019

Liu, Guoxue; Huang, Huawen; Bi, Ran
Journal of Materials Chemistry A, Vol. 7, Issue 36
DOI: 10.1039/c9ta08049j

Tunable nanomechanical performance regimes in ceramic nanowires
journal, September 2019

Maksud, Mahjabin; Barua, Mathius; Shikder, Md Ruhul Amin
Nanotechnology, Vol. 30, Issue 47
DOI: 10.1088/1361-6528/ab3dcf

Solid electrolyte interphases for high-energy aqueous aluminum electrochemical cells
journal, November 2018

Zhao, Qing; Zachman, Michael J.; Al Sadat, Wajdi I.
Science Advances, Vol. 4, Issue 11
DOI: 10.1126/sciadv.aau8131

Silver-Containing α-MnO ₂ Nanorods: Electrochemistry in Rechargeable Aqueous Zn-MnO ₂ Batteries
journal, January 2019

Wang, Lei; Wu, Qiyuan; Abraham, Alyson
Journal of The Electrochemical Society, Vol. 166, Issue 15
DOI: 10.1149/2.0101915jes

Capacity Retention for (De)lithiation of Silver Containing α-MnO ₂ : Impact of Structural Distortion and Transition Metal Dissolution
journal, January 2018

Huang, Jianping; Housel, Lisa M.; Quilty, Calvin D.
Journal of The Electrochemical Society, Vol. 165, Issue 11
DOI: 10.1149/2.0371811jes

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Title: Investigation of α-MnO2 Tunneled Structures as Model Cation Hosts for Energy Storage

Abstract

Citation Formats

Figures / Tables:

K + pre-intercalated manganese dioxide with enhanced Zn 2+ diffusion for high rate and durable aqueous zinc-ion batteries journal, January 2019

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Title: Investigation of α-MnO₂ Tunneled Structures as Model Cation Hosts for Energy Storage

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journal, January 2019

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journal, September 2019

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