Fe Stabilization by Intermetallic L10-FePt and Pt Catalysis Enhancement in L10-FePt/Pt Nanoparticles for Efficient Oxygen Reduction Reaction in Fuel Cells
- Authors:
-
[1];
[1];
[2];
[4];
[5];
[1];
[1];
[2];
[3];
[1]
- Brown Univ., Providence, RI (United States). Dept. of Chemistry
- Los Alamos National Lab. (LANL), Los Alamos, NM (United States)
- Dalhousie Univ., Halifax, NS (Canada). Dept. of Chemistry
- Brookhaven National Lab. (BNL), Upton, NY (United States). Center for Functional Nanomaterials (CFN)
- Huazhong Univ. of Science and Technology, Hubei (People's Republic of China). School of Materials Science and Engineering
- Publication Date:
- Research Org.:
- Brookhaven National Lab. (BNL), Upton, NY (United States); Argonne National Lab. (ANL), Argonne, IL (United States); Los Alamos National Lab. (LANL), Los Alamos, NM (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22) Scientific User Facilities Division; USDOE Office of Energy Efficiency and Renewable Energy (EERE), Sustainable Transportation Office. Hydrogen Fuel Cell Technologies Office; Canadian Light Sources, Inc., Saskatoon, SK (Canada); National Natural Science Foundation of China (NSFC); Materials Genome Initiative
- OSTI Identifier:
- 1438309
- Alternate Identifier(s):
- OSTI ID: 1461399
- Report Number(s):
- BNL-205665-2018-JAAM; LA-UR-18-20293
Journal ID: ISSN 0002-7863
- Grant/Contract Number:
- SC0012704; AC52-06NA25396; AC02-06CH11357; 21603078; 2016YFB0700600
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Journal of the American Chemical Society
- Additional Journal Information:
- Journal Volume: 140; Journal Issue: 8; Journal ID: ISSN 0002-7863
- Publisher:
- American Chemical Society (ACS)
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 29 ENERGY PLANNING, POLICY AND ECONOMY; L10-FePt; Oxygen Reduction Reaction; MPt alloy nanoparticle; Energy Sciences
Citation Formats
Li, Junrui, Xi, Zheng, Pan, Yung -Tin, Spendelow, Jacob S., Duchesne, Paul N., Su, Dong, Li, Qing, Yu, Chao, Yin, Zhouyang, Shen, Bo, Kim, Yu Seung, Zhang, Peng, and Sun, Shouheng. Fe Stabilization by Intermetallic L10-FePt and Pt Catalysis Enhancement in L10-FePt/Pt Nanoparticles for Efficient Oxygen Reduction Reaction in Fuel Cells. United States: N. p., 2018.
Web. doi:10.1021/jacs.7b12829.
Li, Junrui, Xi, Zheng, Pan, Yung -Tin, Spendelow, Jacob S., Duchesne, Paul N., Su, Dong, Li, Qing, Yu, Chao, Yin, Zhouyang, Shen, Bo, Kim, Yu Seung, Zhang, Peng, & Sun, Shouheng. Fe Stabilization by Intermetallic L10-FePt and Pt Catalysis Enhancement in L10-FePt/Pt Nanoparticles for Efficient Oxygen Reduction Reaction in Fuel Cells. United States. https://doi.org/10.1021/jacs.7b12829
Li, Junrui, Xi, Zheng, Pan, Yung -Tin, Spendelow, Jacob S., Duchesne, Paul N., Su, Dong, Li, Qing, Yu, Chao, Yin, Zhouyang, Shen, Bo, Kim, Yu Seung, Zhang, Peng, and Sun, Shouheng. Wed .
"Fe Stabilization by Intermetallic L10-FePt and Pt Catalysis Enhancement in L10-FePt/Pt Nanoparticles for Efficient Oxygen Reduction Reaction in Fuel Cells". United States. https://doi.org/10.1021/jacs.7b12829. https://www.osti.gov/servlets/purl/1438309.
@article{osti_1438309,
title = {Fe Stabilization by Intermetallic L10-FePt and Pt Catalysis Enhancement in L10-FePt/Pt Nanoparticles for Efficient Oxygen Reduction Reaction in Fuel Cells},
author = {Li, Junrui and Xi, Zheng and Pan, Yung -Tin and Spendelow, Jacob S. and Duchesne, Paul N. and Su, Dong and Li, Qing and Yu, Chao and Yin, Zhouyang and Shen, Bo and Kim, Yu Seung and Zhang, Peng and Sun, Shouheng},
abstractNote = {},
doi = {10.1021/jacs.7b12829},
journal = {Journal of the American Chemical Society},
number = 8,
volume = 140,
place = {United States},
year = {2018},
month = {2}
}
Free Publicly Available Full Text
Publisher's Version of Record
Other availability
Search WorldCat to find libraries that may hold this journal
Cited by: 227 works
Citation information provided by
Web of Science
Web of Science
Figures / Tables:
Figure 1: (A) TEM image of C-L10-FePt NPs. (B) 2D EELS elemental mapping image of L10-FePt NPs, where Fe is colored green and Pt is colored red. (C) STEM-EELS line scan of a L10FePt NP. (D) TEM image of C-L10-FePt/Pt NPs. (E) 2D EELS elemental mapping image a L10-FePt/Pt NP,more »
All figures and tables
(6 total)
Save to My Library
You must Sign In or Create an Account in order to save documents to your library.
Works referenced in this record:
Scientific Aspects of Polymer Electrolyte Fuel Cell Durability and Degradation
journal, October 2007
- Borup, Rod; Meyers, Jeremy; Pivovar, Bryan
- Chemical Reviews, Vol. 107, Issue 10
Toward sustainable fuel cells
journal, December 2016
- Stephens, Ifan Erfyl Lester; Rossmeisl, Jan; Chorkendorff, Ib
- Science, Vol. 354, Issue 6318
Trends in electrocatalysis on extended and nanoscale Pt-bimetallic alloy surfaces
journal, February 2007
- Stamenkovic, Vojislav R.; Mun, Bongjin Simon; Arenz, Matthias
- Nature Materials, Vol. 6, Issue 3, p. 241-247
Lattice-strain control of the activity in dealloyed core–shell fuel cell catalysts
journal, April 2010
- Strasser, Peter; Koh, Shirlaine; Anniyev, Toyli
- Nature Chemistry, Vol. 2, Issue 6
Highly Crystalline Multimetallic Nanoframes with Three-Dimensional Electrocatalytic Surfaces
journal, February 2014
- Chen, C.; Kang, Y.; Huo, Z.
- Science, Vol. 343, Issue 6177
High-performance transition metal-doped Pt3Ni octahedra for oxygen reduction reaction
journal, June 2015
- Huang, X.; Zhao, Z.; Cao, L.
- Science, Vol. 348, Issue 6240
Ultrafine jagged platinum nanowires enable ultrahigh mass activity for the oxygen reduction reaction
journal, November 2016
- Li, Mufan; Zhao, Zipeng; Cheng, Tao
- Science, Vol. 354, Issue 6318
Core/Shell Face-Centered Tetragonal FePd/Pd Nanoparticles as an Efficient Non-Pt Catalyst for the Oxygen Reduction Reaction
journal, October 2015
- Jiang, Guangming; Zhu, Huiyuan; Zhang, Xu
- ACS Nano, Vol. 9, Issue 11
Structurally ordered intermetallic platinum–cobalt core–shell nanoparticles with enhanced activity and stability as oxygen reduction electrocatalysts
journal, October 2012
- Wang, Deli; Xin, Huolin L.; Hovden, Robert
- Nature Materials, Vol. 12, Issue 1, p. 81-87
Structure-Induced Enhancement in Electrooxidation of Trimetallic FePtAu Nanoparticles
journal, March 2012
- Zhang, Sen; Guo, Shaojun; Zhu, Huiyuan
- Journal of the American Chemical Society, Vol. 134, Issue 11
New Approach to Fully Ordered fct-FePt Nanoparticles for Much Enhanced Electrocatalysis in Acid
journal, March 2015
- Li, Qing; Wu, Liheng; Wu, Gang
- Nano Letters, Vol. 15, Issue 4
WinXAS a Program for X-ray Absorption Spectroscopy Data Analysis under MS-Windows
journal, March 1998
- Ressler, T.
- Journal of Synchrotron Radiation, Vol. 5, Issue 2, p. 118-122
Real-space multiple-scattering calculation and interpretation of x-ray-absorption near-edge structure
journal, September 1998
- Ankudinov, A. L.; Ravel, B.; Rehr, J. J.
- Physical Review B, Vol. 58, Issue 12
Local Structure, Electronic Behavior, and Electrocatalytic Reactivity of CO-Reduced Platinum–Iron Oxide Nanoparticles
journal, November 2013
- Duchesne, Paul N.; Chen, Guangxu; Zheng, Nanfeng
- The Journal of Physical Chemistry C, Vol. 117, Issue 49
Reversibility of Pt-Skin and Pt-Skeleton Nanostructures in Acidic Media
journal, January 2014
- Durst, Julien; Lopez-Haro, Miguel; Dubau, Laetitia
- The Journal of Physical Chemistry Letters, Vol. 5, Issue 3
Role of Crystalline Defects in Electrocatalysis: CO Adsorption and Oxidation on Stepped Platinum Electrodes As Studied by in situ Infrared Spectroscopy
journal, September 2002
- Lebedeva, N. P.; Rodes, A.; Feliu, J. M.
- The Journal of Physical Chemistry B, Vol. 106, Issue 38
Single-atom catalysis of CO oxidation using Pt1/FeOx
journal, July 2011
- Qiao, Botao; Wang, Aiqin; Yang, Xiaofeng
- Nature Chemistry, Vol. 3, Issue 8
Fast Prediction of Adsorption Properties for Platinum Nanocatalysts with Generalized Coordination Numbers
journal, June 2014
- Calle-Vallejo, Federico; Martínez, José I.; García-Lastra, Juan M.
- Angewandte Chemie International Edition, Vol. 53, Issue 32
Atomic-Scale Modeling of Particle Size Effects for the Oxygen Reduction Reaction on Pt
journal, June 2011
- Tritsaris, G. A.; Greeley, J.; Rossmeisl, J.
- Catalysis Letters, Vol. 141, Issue 7
Size-Dependent Chemical and Magnetic Ordering inL10-FePt Nanoparticles
journal, November 2006
- Rong, C. -b.; Li, D.; Nandwana, V.
- Advanced Materials, Vol. 18, Issue 22
Proton exchange membrane fuel cell from low temperature to high temperature: Material challenges
journal, May 2007
- Shao, Yuyan; Yin, Geping; Wang, Zhenbo
- Journal of Power Sources, Vol. 167, Issue 2
Record activity and stability of dealloyed bimetallic catalysts for proton exchange membrane fuel cells
journal, January 2015
- Han, Binghong; Carlton, Christopher E.; Kongkanand, Anusorn
- Energy & Environmental Science, Vol. 8, Issue 1
Highly Durable and Active PtFe Nanocatalyst for Electrochemical Oxygen Reduction Reaction
journal, December 2015
- Chung, Dong Young; Jun, Samuel Woojoo; Yoon, Gabin
- Journal of the American Chemical Society, Vol. 137, Issue 49
Fine-grained and fully ordered intermetallic PtFe catalysts with largely enhanced catalytic activity and durability
journal, January 2016
- Du, Xin Xin; He, Yang; Wang, Xiao Xia
- Energy & Environmental Science, Vol. 9, Issue 8
Highly durable fuel cell electrodes based on ionomers dispersed in glycerol
journal, January 2014
- Kim, Y. S.; Welch, C. F.; Mack, N. H.
- Phys. Chem. Chem. Phys., Vol. 16, Issue 13
Works referencing / citing this record:
Engineering bunched Pt-Ni alloy nanocages for efficient oxygen reduction in practical fuel cells
journal, November 2019
- Tian, Xinlong; Zhao, Xiao; Su, Ya-Qiong
- Science, Vol. 366, Issue 6467
Pt‐Based Nanocrystal for Electrocatalytic Oxygen Reduction
journal, December 2018
- Zhao, Zipeng; Chen, Changli; Liu, Zeyan
- Advanced Materials, Vol. 31, Issue 31
Superior Magnetic Performance in FePt L1 0 Nanomaterials
journal, July 2019
- Son, Kwanghyo; Ryu, Gihun; Jeong, Hyeon‐Ho
- Small, Vol. 15, Issue 34
Leaching- and sintering-resistant hollow or structurally ordered intermetallic PtFe alloy catalysts for oxygen reduction reactions
journal, January 2019
- Zou, Xiao; Chen, Siguo; Wang, Qingmei
- Nanoscale, Vol. 11, Issue 42
Role of Ultrathin Carbon Shell in Enhancing the Performance of PtZn Intermetallic Nanoparticles as an Anode Electrocatalyst for Direct Formic Acid Fuel Cells
journal, April 2019
- Xu, Min; Zhao, Yufei; Chen, Hong
- ChemElectroChem, Vol. 6, Issue 8
All-metallic nanorattles consisting of a Pt core and a mesoporous PtPd shell for enhanced electrocatalysis
journal, September 2019
- Wang, Hongjing; Yin, Shuli; Li, Chunjie
- Nanotechnology, Vol. 30, Issue 47
Highly stable one-dimensional Pt nanowires with modulated structural disorder towards the oxygen reduction reaction
journal, January 2019
- Kong, Fanpeng; Norouzi Banis, Mohammad; Du, Lei
- Journal of Materials Chemistry A, Vol. 7, Issue 43
High‐Performance Platinum‐Perovskite Composite Bifunctional Oxygen Electrocatalyst for Rechargeable Zn–Air Battery
journal, December 2019
- Wang, Xixi; Sunarso, Jaka; Lu, Qian
- Advanced Energy Materials, Vol. 10, Issue 5
Ultralong Ternary PtRuTe Mesoporous Nanotubes Fabricated by Micelle Assembly with a Self‐Sacrificial Template
journal, March 2019
- Yin, Shuli; Wang, Hongjing; Deng, Kai
- Chemistry – A European Journal, Vol. 25, Issue 20
Ligand‐Sharing‐Mediated Synthesis of Intermetallic FeM Clusters Embedded in Ultrathin γ‐Fe 2 O 3 Nanosheets
journal, November 2019
- Liu, Rui; Chen, Yanan; Zhao, Huachao
- Advanced Functional Materials, Vol. 30, Issue 5
High‐Performance Ordered PdCuFe/C Intermetallic Catalyst for Electrochemical Oxygen Reduction in Proton Exchange Membrane Fuel Cells
journal, May 2019
- Ji, Xiangdong; Gao, Peng; Zhang, Libo
- ChemElectroChem, Vol. 6, Issue 12
Monodisperse nanoparticles for catalysis and nanomedicine
journal, January 2019
- Muzzio, Michelle; Li, Junrui; Yin, Zhouyang
- Nanoscale, Vol. 11, Issue 41
Hollow PtFe Alloy Nanoparticles Derived from Pt‐Fe 3 O 4 Dimers through a Silica‐Protection Reduction Strategy as Efficient Oxygen Reduction Electrocatalysts
journal, January 2020
- Yang, Zhaojun; Shang, Lu; Xiong, Xuyang
- Chemistry – A European Journal
Optimizing PtFe intermetallics for oxygen reduction reaction: from DFT screening to in situ XAFS characterization
journal, January 2019
- Gong, Mingxing; Zhu, Jing; Liu, Mingjie
- Nanoscale, Vol. 11, Issue 42
Recent Advances and Prospects of Metal‐Based Catalysts for Oxygen Reduction Reaction
journal, December 2019
- Lang, Peng; Yuan, Nannan; Jiang, Qianqian
- Energy Technology, Vol. 8, Issue 3
Structurally Ordered Low‐Pt Intermetallic Electrocatalysts toward Durably High Oxygen Reduction Reaction Activity
journal, July 2019
- Wang, Zhongxiang; Yao, Xiaozhang; Kang, Yongqiang
- Advanced Functional Materials, Vol. 29, Issue 35
Chemical Synthesis of Magnetically Hard and Strong Rare Earth Metal Based Nanomagnets
journal, December 2018
- Shen, Bo; Yu, Chao; Baker, Alexander A.
- Angewandte Chemie, Vol. 131, Issue 2
PDA-assisted formation of ordered intermetallic CoPt 3 catalysts with enhanced oxygen reduction activity and stability
journal, January 2018
- Zhao, Yige; Wang, Chen; Liu, Jingjun
- Nanoscale, Vol. 10, Issue 19
Ternary CoPtAu Nanoparticles as a General Catalyst for Highly Efficient Electro-oxidation of Liquid Fuels
journal, July 2019
- Li, Junrui; Jilani, Safia Z.; Lin, Honghong
- Angewandte Chemie International Edition, Vol. 58, Issue 33
Structurally Ordered Fe 3 Pt Nanoparticles on Robust Nitride Support as a High Performance Catalyst for the Oxygen Reduction Reaction
journal, December 2018
- Liu, Quanbing; Du, Li; Fu, Gengtao
- Advanced Energy Materials, Vol. 9, Issue 3
Tungsten‐Doped L1 0 ‐PtCo Ultrasmall Nanoparticles as a High‐Performance Fuel Cell Cathode
journal, September 2019
- Liang, Jiashun; Li, Na; Zhao, Zhonglong
- Angewandte Chemie, Vol. 131, Issue 43
Facile synthesis of PdFe alloy tetrahedrons for boosting electrocatalytic properties towards formic acid oxidation
journal, January 2019
- Cai, Bingfeng; Ma, Yanrong; Wang, Shangzhi
- Nanoscale, Vol. 11, Issue 39
Spherical α-MnO2 Supported on N-KB as Efficient Electrocatalyst for Oxygen Reduction in Al–Air Battery
journal, April 2018
- Chen, Kui; Wang, Mei; Li, Guangli
- Materials, Vol. 11, Issue 4
Invigorating the catalytic performance of CoP through interfacial engineering by Ni 2 P precipitation
journal, January 2019
- Zhang, Junyu; Wei, Sufeng; Liu, Yan
- Journal of Materials Chemistry A, Vol. 7, Issue 45
Chemical Synthesis of Magnetic Nanoparticles for Permanent Magnet Applications
journal, October 2019
- Shen, Bo; Sun, Shouheng
- Chemistry – A European Journal, Vol. 26, Issue 30
Fabrication of Superior Single‐Atom Catalysts toward Diverse Electrochemical Reactions
journal, February 2019
- Zhang, Bin‐Wei; Wang, Yun‐Xiao; Chou, Shu‐Lei
- Small Methods, Vol. 3, Issue 9
Sub‐6 nm Fully Ordered L 1 0 ‐Pt–Ni–Co Nanoparticles Enhance Oxygen Reduction via Co Doping Induced Ferromagnetism Enhancement and Optimized Surface Strain
journal, March 2019
- Wang, Tanyuan; Liang, Jiashun; Zhao, Zhonglong
- Advanced Energy Materials, Vol. 9, Issue 17
Highly active zigzag-like Pt-Zn alloy nanowires with high-index facets for alcohol electrooxidation
journal, April 2019
- Xu, Yanchao; Cui, Xiaoqiang; Wei, Shuting
- Nano Research, Vol. 12, Issue 5
Regulating locations of active sites: a novel strategy to greatly improve the stability of PtAu electrocatalysts
journal, January 2019
- Xu, Suying; Hou, Wenjie; Jiang, Rui
- Chemical Communications, Vol. 55, Issue 90
Tunable synthesis of multiply twinned intermetallic Pd 3 Pb nanowire networks toward efficient N 2 to NH 3 conversion
journal, January 2019
- Guo, Jingchun; Wang, Hui; Xue, Fei
- Journal of Materials Chemistry A, Vol. 7, Issue 35
Atomically ordered non-precious Co3Ta intermetallic nanoparticles as high-performance catalysts for hydrazine electrooxidation
journal, October 2019
- Feng, Guang; An, Li; Li, Biao
- Nature Communications, Vol. 10, Issue 1
Pt-rare earth metal alloy/metal oxide catalysts for oxygen reduction and alcohol oxidation reactions: an overview
journal, January 2019
- Peera, Shaik Gouse; Lee, Tae Gwan; Sahu, Akhila Kumar
- Sustainable Energy & Fuels, Vol. 3, Issue 8
Sub‐3 nm Intermetallic Ordered Pt 3 In Clusters for Oxygen Reduction Reaction
journal, November 2019
- Wang, Qi; Zhao, Zhi Liang; Zhang, Zhe
- Advanced Science, Vol. 7, Issue 2
High temperature self-assembly one-step synthesis of a structurally ordered PtFe catalyst for the oxygen reduction reaction
journal, January 2019
- Gao, Xiaoyan; Chen, Siguo; Deng, Jianghai
- Chemical Communications, Vol. 55, Issue 80
The application of CeO 2 -based materials in electrocatalysis
journal, January 2019
- Wang, Jianda; Xiao, Xiao; Liu, Yong
- Journal of Materials Chemistry A, Vol. 7, Issue 30
Chemical Synthesis of Magnetically Hard and Strong Rare Earth Metal Based Nanomagnets
journal, December 2018
- Shen, Bo; Yu, Chao; Baker, Alexander A.
- Angewandte Chemie International Edition, Vol. 58, Issue 2
Core-Shell Polydopamine@Zr-Hemin MOFs Derived Fe-N-Doped Porous Carbon Nanospheres Electrocatalysts for the Oxygen Reduction
journal, January 2018
- Wang, Yinling; Wang, Juan; Zhang, Youliang
- Journal of The Electrochemical Society, Vol. 165, Issue 10
Tungsten‐Doped L1 0 ‐PtCo Ultrasmall Nanoparticles as a High‐Performance Fuel Cell Cathode
journal, October 2019
- Liang, Jiashun; Li, Na; Zhao, Zhonglong
- Angewandte Chemie International Edition, Vol. 58, Issue 43
Direct fabrication of bimetallic AuPt nanobrick spherical nanoarchitectonics for the oxygen reduction reaction
journal, January 2019
- Narendra Kumar, Alam Venugopal; Yin, Shuli; Wang, Ziqiang
- New Journal of Chemistry, Vol. 43, Issue 24
Ternary CoPtAu Nanoparticles as a General Catalyst for Highly Efficient Electro‐oxidation of Liquid Fuels
journal, July 2019
- Li, Junrui; Jilani, Safia Z.; Lin, Honghong
- Angewandte Chemie, Vol. 131, Issue 33
Figures / Tables found in this record:
Figures/Tables have been extracted from DOE-funded journal article accepted manuscripts.