In situ identification of cation-exchange-induced reversible transformations of 3D and 2D perovskites
Abstract
In situ XPS analysis shows that reversible transformation of 3D–2D perovskites can occur through post-synthetic introduction of foreign cations.
- Authors:
-
- Radiation Laboratory, University of Notre Dame, Notre Dame, USA, Department of Chemistry and Biochemistry
- Radiation Laboratory, University of Notre Dame, Notre Dame, USA
- Radiation Laboratory, University of Notre Dame, Notre Dame, USA, Department of Physics
- Publication Date:
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1438089
- Grant/Contract Number:
- FC02-04ER15533
- Resource Type:
- Publisher's Accepted Manuscript
- Journal Name:
- ChemComm
- Additional Journal Information:
- Journal Name: ChemComm Journal Volume: 54 Journal Issue: 46; Journal ID: ISSN 1359-7345
- Publisher:
- Royal Society of Chemistry (RSC)
- Country of Publication:
- United Kingdom
- Language:
- English
Citation Formats
Huang, Weixin, Sadhu, Subha, Sapkota, Pitambar, and Ptasinska, Sylwia. In situ identification of cation-exchange-induced reversible transformations of 3D and 2D perovskites. United Kingdom: N. p., 2018.
Web. doi:10.1039/C8CC02801J.
Huang, Weixin, Sadhu, Subha, Sapkota, Pitambar, & Ptasinska, Sylwia. In situ identification of cation-exchange-induced reversible transformations of 3D and 2D perovskites. United Kingdom. https://doi.org/10.1039/C8CC02801J
Huang, Weixin, Sadhu, Subha, Sapkota, Pitambar, and Ptasinska, Sylwia. Mon .
"In situ identification of cation-exchange-induced reversible transformations of 3D and 2D perovskites". United Kingdom. https://doi.org/10.1039/C8CC02801J.
@article{osti_1438089,
title = {In situ identification of cation-exchange-induced reversible transformations of 3D and 2D perovskites},
author = {Huang, Weixin and Sadhu, Subha and Sapkota, Pitambar and Ptasinska, Sylwia},
abstractNote = {In situ XPS analysis shows that reversible transformation of 3D–2D perovskites can occur through post-synthetic introduction of foreign cations.},
doi = {10.1039/C8CC02801J},
journal = {ChemComm},
number = 46,
volume = 54,
place = {United Kingdom},
year = {2018},
month = {1}
}
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https://doi.org/10.1039/C8CC02801J
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Works referenced in this record:
Intriguing Optoelectronic Properties of Metal Halide Perovskites
journal, June 2016
- Manser, Joseph S.; Christians, Jeffrey A.; Kamat, Prashant V.
- Chemical Reviews, Vol. 116, Issue 21
Direct Observation of Reversible Transformation of CH 3 NH 3 PbI 3 and NH 4 PbI 3 Induced by Polar Gaseous Molecules
journal, November 2016
- Huang, Weixin; Manser, Joseph S.; Sadhu, Subha
- The Journal of Physical Chemistry Letters, Vol. 7, Issue 24
Exceptional Morphology-Preserving Evolution of Formamidinium Lead Triiodide Perovskite Thin Films via Organic-Cation Displacement
journal, April 2016
- Zhou, Yuanyuan; Yang, Mengjin; Pang, Shuping
- Journal of the American Chemical Society, Vol. 138, Issue 17
Ion-Exchange-Induced 2D-3D Conversion of HMA 1− x FA x PbI 3 Cl Perovskite into a High-Quality MA 1− x FA x PbI 3 Perovskite
journal, September 2016
- Li, Ge; Zhang, Taiyang; Guo, Nanjie
- Angewandte Chemie International Edition, Vol. 55, Issue 43
Evolution of Chemical Composition, Morphology, and Photovoltaic Efficiency of CH 3 NH 3 PbI 3 Perovskite under Ambient Conditions
journal, December 2015
- Huang, Weixin; Manser, Joseph S.; Kamat, Prashant V.
- Chemistry of Materials, Vol. 28, Issue 1
Bication lead iodide 2D perovskite component to stabilize inorganic α-CsPbI 3 perovskite phase for high-efficiency solar cells
journal, September 2017
- Zhang, Taiyang; Dar, M. Ibrahim; Li, Ge
- Science Advances, Vol. 3, Issue 9
Low-Energy Electron-Induced Transformations in Organolead Halide Perovskite
journal, June 2016
- Milosavljević, Aleksandar R.; Huang, Weixin; Sadhu, Subha
- Angewandte Chemie International Edition, Vol. 55, Issue 34
A Layered Hybrid Perovskite Solar-Cell Absorber with Enhanced Moisture Stability
journal, September 2014
- Smith, Ian C.; Hoke, Eric T.; Solis-Ibarra, Diego
- Angewandte Chemie, Vol. 126, Issue 42
In Situ Fabrication of Highly Luminescent Bifunctional Amino Acid Crosslinked 2D/3D NH 3 C 4 H 9 COO(CH 3 NH 3 PbBr 3 ) n Perovskite Films
journal, October 2016
- Zhang, Taiyang; Xie, Liqiang; Chen, Liang
- Advanced Functional Materials, Vol. 27, Issue 1
Interface engineering of highly efficient perovskite solar cells
journal, July 2014
- Zhou, H.; Chen, Q.; Li, G.
- Science, Vol. 345, Issue 6196
Blue-luminescent organic lead bromide perovskites: highly dispersible and photostable materials
journal, January 2015
- Gonzalez-Carrero, Soranyel; Espallargas, Guillermo Mínguez; Galian, Raquel E.
- Journal of Materials Chemistry A, Vol. 3, Issue 26
Tuning the Optical Properties of Cesium Lead Halide Perovskite Nanocrystals by Anion Exchange Reactions
journal, August 2015
- Akkerman, Quinten A.; D’Innocenzo, Valerio; Accornero, Sara
- Journal of the American Chemical Society, Vol. 137, Issue 32
Capturing the Sun: A Review of the Challenges and Perspectives of Perovskite Solar Cells
journal, June 2017
- Petrus, Michiel L.; Schlipf, Johannes; Li, Cheng
- Advanced Energy Materials, Vol. 7, Issue 16
Quantum Size Effect in Organometal Halide Perovskite Nanoplatelets
journal, September 2015
- Sichert, Jasmina A.; Tong, Yu; Mutz, Niklas
- Nano Letters, Vol. 15, Issue 10
Making and Breaking of Lead Halide Perovskites
journal, January 2016
- Manser, Joseph S.; Saidaminov, Makhsud I.; Christians, Jeffrey A.
- Accounts of Chemical Research, Vol. 49, Issue 2
Cation exchange for thin film lead iodide perovskite interconversion
journal, January 2016
- Eperon, Giles E.; Beck, Clara E.; Snaith, Henry J.
- Materials Horizons, Vol. 3, Issue 1
An amorphous precursor route to the conformable oriented crystallization of CH 3 NH 3 PbBr 3 in mesoporous scaffolds: toward efficient and thermally stable carbon-based perovskite solar cells
journal, January 2016
- Chen, Haining; Zheng, Xiaoli; Li, Qiang
- Journal of Materials Chemistry A, Vol. 4, Issue 33
pH-responsive octylamine coupling modification of carboxylated aluminium oxide surfaces
journal, January 2015
- Alexander, Shirin; Morrow, Lauren; Lord, Alex M.
- Journal of Materials Chemistry A, Vol. 3, Issue 18
Device stability of perovskite solar cells – A review
journal, September 2017
- Asghar, M. I.; Zhang, J.; Wang, H.
- Renewable and Sustainable Energy Reviews, Vol. 77
Colloidal Synthesis of CH 3 NH 3 PbBr 3 Nanoplatelets with Polarized Emission through Self-Organization
journal, January 2017
- Liu, Lige; Huang, Sheng; Pan, Longfei
- Angewandte Chemie International Edition, Vol. 56, Issue 7
A perovskite cell with a record-high-V oc of 1.61 V based on solvent annealed CH 3 NH 3 PbBr 3 /ICBA active layer
journal, January 2016
- Wu, Chun-Guey; Chiang, Chien-Hung; Chang, Sheng Hsiung
- Nanoscale, Vol. 8, Issue 7
A mixed-cation lead mixed-halide perovskite absorber for tandem solar cells
journal, January 2016
- McMeekin, D. P.; Sadoughi, G.; Rehman, W.
- Science, Vol. 351, Issue 6269
Heat- and Gas-Induced Transformation in CH 3 NH 3 PbI 3 Perovskites and Its Effect on the Efficiency of Solar Cells
journal, September 2017
- Huang, Weixin; Sadhu, Subha; Ptasinska, Sylwia
- Chemistry of Materials, Vol. 29, Issue 19
Between the Sheets: Postsynthetic Transformations in Hybrid Perovskites
journal, February 2017
- Smith, Ian C.; Smith, Matthew D.; Jaffe, Adam
- Chemistry of Materials, Vol. 29, Issue 5
High-efficiency two-dimensional Ruddlesden–Popper perovskite solar cells
journal, July 2016
- Tsai, Hsinhan; Nie, Wanyi; Blancon, Jean-Christophe
- Nature, Vol. 536, Issue 7616
Organic–inorganic hybrid lead halide perovskites for optoelectronic and electronic applications
journal, January 2016
- Zhao, Yixin; Zhu, Kai
- Chemical Society Reviews, Vol. 45, Issue 3
Transformation of the Excited State and Photovoltaic Efficiency of CH 3 NH 3 PbI 3 Perovskite upon Controlled Exposure to Humidified Air
journal, January 2015
- Christians, Jeffrey A.; Miranda Herrera, Pierre A.; Kamat, Prashant V.
- Journal of the American Chemical Society, Vol. 137, Issue 4
2D Homologous Perovskites as Light-Absorbing Materials for Solar Cell Applications
journal, June 2015
- Cao, Duyen H.; Stoumpos, Constantinos C.; Farha, Omar K.
- Journal of the American Chemical Society, Vol. 137, Issue 24