Relativistic effects in metallocorroles: comparison of molybdenum and tungsten biscorroles

Alemayehu, Abraham B.; Vazquez-Lima, Hugo; McCormick, Laura J.; Ghosh, Abhik

doi:10.1039/c7cc01549f

Title: Relativistic effects in metallocorroles: comparison of molybdenum and tungsten biscorroles

Journal Article · 12 May 2017 · ChemComm

DOI: https://doi.org/10.1039/c7cc01549f · OSTI ID:1437954

Alemayehu, Abraham B. ^[1]; Vazquez-Lima, Hugo ^[1]; McCormick, Laura J. ^[2];

^[1]

The Arctic University of Norway (Norway). Department of Chemistry and Center for Theoretical and Computational Chemistry, UiT
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Advanced Light Source (ALS)

We present the homoleptic sandwich compounds-Mo and W biscorroles-have afforded a novel platform for experimental studies of relativistic effects. A 200 mV difference in reduction potential and a remarkable 130 nm shift of a near-IR spectral feature have been identified as manifestations of relativistic effects on the properties of these complexes.

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Research Organization:: Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)

Sponsoring Organization:: USDOE Office of Science (SC)

Grant/Contract Number:: AC02-05CH11231

OSTI ID:: 1437954

Journal Information:: ChemComm, Vol. 53, Issue 43; Related Information: © 2017 The Royal Society of Chemistry.; ISSN 1359-7345

Publisher:: Royal Society of ChemistryCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 17 works

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