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Title: Investigating subtle 4f vs. 5f coordination differences using kinetically inert Eu( iii ), Tb( iii ), and Cm( iii ) complexes of a coumarin-appended 1,4,7,10-tetraazacyclododecane-1,4,7-triacetate (DO3A) ligand

Coumarin appended DO3A complexes of Cm( iii ), Eu( iii ), and Tb( iii ) show that more than ionic radius determines the coordination chemistry of the f-elements.
Authors:
 [1] ; ORCiD logo [2] ; ORCiD logo [3] ; ORCiD logo [1]
  1. Nano-Science Center & Department of Chemistry, University of Copenhagen, 2100 København Ø, Denmark
  2. Chemical Sciences Division, Lawrence Berkeley National Laboratory, Berkeley, USA
  3. Chemical Sciences Division, Lawrence Berkeley National Laboratory, Berkeley, USA, Department of Nuclear Engineering
Publication Date:
Grant/Contract Number:
AC02-05CH11231
Type:
Publisher's Accepted Manuscript
Journal Name:
Dalton Transactions
Additional Journal Information:
Journal Name: Dalton Transactions Journal Volume: 47 Journal Issue: 21; Journal ID: ISSN 1477-9226
Publisher:
Royal Society of Chemistry
Sponsoring Org:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
Country of Publication:
United Kingdom
Language:
English
OSTI Identifier:
1437673

Junker, Anne Kathrine R., Deblonde, Gauthier J. -P., Abergel, Rebecca J., and Sørensen, Thomas Just. Investigating subtle 4f vs. 5f coordination differences using kinetically inert Eu( iii ), Tb( iii ), and Cm( iii ) complexes of a coumarin-appended 1,4,7,10-tetraazacyclododecane-1,4,7-triacetate (DO3A) ligand. United Kingdom: N. p., Web. doi:10.1039/C8DT01547C.
Junker, Anne Kathrine R., Deblonde, Gauthier J. -P., Abergel, Rebecca J., & Sørensen, Thomas Just. Investigating subtle 4f vs. 5f coordination differences using kinetically inert Eu( iii ), Tb( iii ), and Cm( iii ) complexes of a coumarin-appended 1,4,7,10-tetraazacyclododecane-1,4,7-triacetate (DO3A) ligand. United Kingdom. doi:10.1039/C8DT01547C.
Junker, Anne Kathrine R., Deblonde, Gauthier J. -P., Abergel, Rebecca J., and Sørensen, Thomas Just. 2018. "Investigating subtle 4f vs. 5f coordination differences using kinetically inert Eu( iii ), Tb( iii ), and Cm( iii ) complexes of a coumarin-appended 1,4,7,10-tetraazacyclododecane-1,4,7-triacetate (DO3A) ligand". United Kingdom. doi:10.1039/C8DT01547C.
@article{osti_1437673,
title = {Investigating subtle 4f vs. 5f coordination differences using kinetically inert Eu( iii ), Tb( iii ), and Cm( iii ) complexes of a coumarin-appended 1,4,7,10-tetraazacyclododecane-1,4,7-triacetate (DO3A) ligand},
author = {Junker, Anne Kathrine R. and Deblonde, Gauthier J. -P. and Abergel, Rebecca J. and Sørensen, Thomas Just},
abstractNote = {Coumarin appended DO3A complexes of Cm( iii ), Eu( iii ), and Tb( iii ) show that more than ionic radius determines the coordination chemistry of the f-elements.},
doi = {10.1039/C8DT01547C},
journal = {Dalton Transactions},
number = 21,
volume = 47,
place = {United Kingdom},
year = {2018},
month = {1}
}

Works referenced in this record:

Europium as a label in time-resolved immunofluorometric assays
journal, March 1984
  • Hemmilä, Ilkka; Dakubu, Salifu; Mukkala, Veli-Matti
  • Analytical Biochemistry, Vol. 137, Issue 2, p. 335-343
  • DOI: 10.1016/0003-2697(84)90095-2