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Title: Controlled vapor crystal growth of N a 4 I r 3 O 8 : A three-dimensional quantum spin liquid candidate

Abstract

We report the successful bulk single-crystal growth of the hyperkagome lattice iridate Na4Ir3O8 (Na438) by vapor transport using a sealed aluminum oxide tube as a container. Crystals were characterized by magnetization, x-ray diffraction, and energy-dispersive x-ray measurements, confirming their identity and properties. Single-crystal x-ray diffraction experiments revealed superlattice peaks indexed on a propagation vector q = (1/3, 1/3, 1/3) based on the cubic substructure with cell parameter a = 8.986(1) angstrom. This superlattice is three-dimensional and fully coherent. Polarization analysis rules out spin and/or orbital order as the underlying origin of the modulation and points to long-range ordering of Na ions at the notionally disordered Na sites as a plausible origin for the observed superlattice.

Authors:
; ; ; ; ; ; ; ;
Publication Date:
Research Org.:
Argonne National Lab. (ANL), Argonne, IL (United States)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
OSTI Identifier:
1437371
Alternate Identifier(s):
OSTI ID: 1434390
Grant/Contract Number:  
AC02-06CH11357; AC05-00OR22725
Resource Type:
Accepted Manuscript
Journal Name:
Physical Review Materials
Additional Journal Information:
Journal Volume: 2; Journal Issue: 4; Journal ID: ISSN 2475-9953
Publisher:
American Physical Society (APS)
Country of Publication:
United States
Language:
English

Citation Formats

Zheng, Hong, Zhang, Junjie, Stoumpos, Constantinos C., Ren, Yang, Chen, Yu-Sheng, Dally, Rebecca, Wilson, Stephen D., Islam, Zahirul, and Mitchell, J. F. Controlled vapor crystal growth of Na4Ir3O8 : A three-dimensional quantum spin liquid candidate. United States: N. p., 2018. Web. doi:10.1103/PhysRevMaterials.2.043403.
Zheng, Hong, Zhang, Junjie, Stoumpos, Constantinos C., Ren, Yang, Chen, Yu-Sheng, Dally, Rebecca, Wilson, Stephen D., Islam, Zahirul, & Mitchell, J. F. Controlled vapor crystal growth of Na4Ir3O8 : A three-dimensional quantum spin liquid candidate. United States. doi:10.1103/PhysRevMaterials.2.043403.
Zheng, Hong, Zhang, Junjie, Stoumpos, Constantinos C., Ren, Yang, Chen, Yu-Sheng, Dally, Rebecca, Wilson, Stephen D., Islam, Zahirul, and Mitchell, J. F. Sun . "Controlled vapor crystal growth of Na4Ir3O8 : A three-dimensional quantum spin liquid candidate". United States. doi:10.1103/PhysRevMaterials.2.043403. https://www.osti.gov/servlets/purl/1437371.
@article{osti_1437371,
title = {Controlled vapor crystal growth of Na4Ir3O8 : A three-dimensional quantum spin liquid candidate},
author = {Zheng, Hong and Zhang, Junjie and Stoumpos, Constantinos C. and Ren, Yang and Chen, Yu-Sheng and Dally, Rebecca and Wilson, Stephen D. and Islam, Zahirul and Mitchell, J. F.},
abstractNote = {We report the successful bulk single-crystal growth of the hyperkagome lattice iridate Na4Ir3O8 (Na438) by vapor transport using a sealed aluminum oxide tube as a container. Crystals were characterized by magnetization, x-ray diffraction, and energy-dispersive x-ray measurements, confirming their identity and properties. Single-crystal x-ray diffraction experiments revealed superlattice peaks indexed on a propagation vector q = (1/3, 1/3, 1/3) based on the cubic substructure with cell parameter a = 8.986(1) angstrom. This superlattice is three-dimensional and fully coherent. Polarization analysis rules out spin and/or orbital order as the underlying origin of the modulation and points to long-range ordering of Na ions at the notionally disordered Na sites as a plausible origin for the observed superlattice.},
doi = {10.1103/PhysRevMaterials.2.043403},
journal = {Physical Review Materials},
number = 4,
volume = 2,
place = {United States},
year = {2018},
month = {4}
}

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Works referenced in this record:

Anomalous enhancement of the Wilson ratio in a quantum spin liquid: The case of Na 4 Ir 3 O 8
journal, April 2013


Proximate Kitaev quantum spin liquid behaviour in a honeycomb magnet
journal, April 2016

  • Banerjee, A.; Bridges, C. A.; Yan, J. -Q.
  • Nature Materials, Vol. 15, Issue 7
  • DOI: 10.1038/nmat4604

Spin-Orbit Physics Giving Rise to Novel Phases in Correlated Systems: Iridates and Related Materials
journal, March 2016


Synthesis and crystal structure of Na4Sn3O8
journal, March 2002

  • Iwasaki, Masato; Takizawa, Hirotsugu; Uheda, Kyota
  • Journal of Materials Chemistry, Vol. 12, Issue 4
  • DOI: 10.1039/b107364h

Neutron scattering in the proximate quantum spin liquid α-RuCl 3
journal, June 2017


Spin-orbit coupling induced semi-metallic state in the 1/3 hole-doped hyper-kagome Na3Ir3O8
journal, October 2014

  • Takayama, Tomohiro; Yaresko, Alexander; Matsumoto, Akiyo
  • Scientific Reports, Vol. 4, Issue 1
  • DOI: 10.1038/srep06818

Quantum spin liquids: a review
journal, November 2016


Evidence for a spinon Fermi surface in a triangular-lattice quantum-spin-liquid candidate
journal, December 2016


Topological Spin Liquid on the Hyperkagome Lattice of Na 4 Ir 3 O 8
journal, June 2008


Short-Range Correlations in the Magnetic Ground State of Na 4 Ir 3 O 8
journal, December 2014


Spin Hamiltonian of hyper-kagome Na 4 Ir 3 O 8
journal, May 2010


Quantum spin liquid states
journal, April 2017


Spin liquid like Raman signatures in the hyperkagome iridate Na 4 Ir 3 O 8
journal, October 2016

  • Gupta, Satyendra Nath; Sriluckshmy, P. V.; Balodhi, Ashiwini
  • Physical Review B, Vol. 94, Issue 15
  • DOI: 10.1103/PhysRevB.94.155153

Frozen State and Spin Liquid Physics in Na 4 Ir 3 O 8 : An NMR Study
journal, July 2015


Evidence for a Field-Induced Quantum Spin Liquid in α - RuCl 3
journal, July 2017


Gapless spin liquid of an organic triangular compound evidenced by thermodynamic measurements
journal, April 2011

  • Yamashita, Satoshi; Yamamoto, Takashi; Nakazawa, Yasuhiro
  • Nature Communications, Vol. 2, Issue 1
  • DOI: 10.1038/ncomms1274

Continuous excitations of the triangular-lattice quantum spin liquid YbMgGaO4
journal, December 2016

  • Paddison, Joseph A. M.; Daum, Marcus; Dun, Zhiling
  • Nature Physics, Vol. 13, Issue 2
  • DOI: 10.1038/nphys3971

Rare-Earth Triangular Lattice Spin Liquid: A Single-Crystal Study of YbMgGaO 4
journal, October 2015


Electronic structure of hyper-kagome Na 4 Ir 3 O 8
journal, January 2010


Spin liquid close to a quantum critical point in Na 4 Ir 3 O 8
journal, December 2013


Gapless Spin Excitations in the Field-Induced Quantum Spin Liquid Phase of α RuCl 3
journal, December 2017


A Structurally Perfect S = 1 / 2 Kagomé Antiferromagnet
journal, October 2005

  • Shores, Matthew P.; Nytko, Emily A.; Bartlett, Bart M.
  • Journal of the American Chemical Society, Vol. 127, Issue 39
  • DOI: 10.1021/ja053891p

Fractionalized excitations in the spin-liquid state of a kagome-lattice antiferromagnet
journal, December 2012

  • Han, Tian-Heng; Helton, Joel S.; Chu, Shaoyan
  • Nature, Vol. 492, Issue 7429
  • DOI: 10.1038/nature11659

Colloquium : Herbertsmithite and the search for the quantum spin liquid
journal, December 2016


Evidence for a gapped spin-liquid ground state in a kagome Heisenberg antiferromagnet
journal, November 2015


Mott Transition between a Spin-Liquid Insulator and a Metal in Three Dimensions
journal, May 2009


Evolution of magnetic, transport, and thermal properties in Na 4 x Ir 3 O 8
journal, June 2015


Phase relations in the systems Na2OIrO2 and Na2OPtO2 in air
journal, February 1974


Interplay of nonsymmorphic symmetry and spin-orbit coupling in hyperkagome spin liquids: Applications to Na 4 Ir 3 O 8
journal, February 2017


Spin-orbit coupling in the metallic and spin-liquid phases of Na 4 Ir 3 O 8
journal, February 2011


Spin-Liquid State in the S = 1 / 2 Hyperkagome Antiferromagnet Na 4 Ir 3 O 8
journal, September 2007


Na 4 Ir 3 O 8 as a 3D Spin Liquid with Fermionic Spinons
journal, November 2008


Gapless Spin Liquids on the Three-Dimensional Hyperkagome Lattice of Na 4 Ir 3 O 8
journal, November 2008


Direct evidence for dominant bond-directional interactions in a honeycomb lattice iridate Na2IrO3
journal, May 2015

  • Hwan Chun, Sae; Kim, Jong-Woo; Kim, Jungho
  • Nature Physics, Vol. 11, Issue 6
  • DOI: 10.1038/nphys3322

Symmetry Breaking on the Three-Dimensional Hyperkagome Lattice of Na 4 Ir 3 O 8
journal, December 2010


Spin Liquid State in an Organic Mott Insulator with a Triangular Lattice
journal, September 2003


Generic model for the hyperkagome iridate Na 4 Ir 3 O 8 in the local-moment regime
journal, August 2016


Spin-orbit effects in Na 4 Ir 3 O 8 : A hyper-kagome lattice antiferromagnet
journal, September 2008