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Title: On the electrochemical deposition of metal–organic frameworks

Abstract

In this paper we study and compare the anodic and cathodic electrodeposition of Metal–Organic Frameworks (MOFs) and suggest guidelines for the electrodeposition of new MOFs with this technique. KHUST-1 was electrodeposited both anodically and cathodically and a four step mechanism is proposed to explain the anodic synthesis.

Authors:
 [1];  [2];  [3];  [4];  [3];  [2];  [4];  [4];  [4]
  1. KU Leuven, Leuven (Belgium); Massachusetts Inst. of Technology (MIT), Cambridge, MA (United States)
  2. Vrije Univ. Brussel, Brussels (Belgium)
  3. Massachusetts Inst. of Technology (MIT), Cambridge, MA (United States)
  4. KU Leuven, Leuven (Belgium)
Publication Date:
Research Org.:
Katholieke Univ. Leuven, Louvain (Belgium)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
OSTI Identifier:
1437122
Grant/Contract Number:  
SC0006937
Resource Type:
Accepted Manuscript
Journal Name:
Journal of Materials Chemistry. A
Additional Journal Information:
Journal Volume: 4; Journal Issue: 10; Journal ID: ISSN 2050-7488
Publisher:
Royal Society of Chemistry
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Citation Formats

Campagnol, Nicolo, Van Assche, Tom R. C., Li, Minyuan, Stappers, Linda, Dinca, Mircea, Denayer, Joeri F. M., Binnemans, Koen, De Vos, Dirk E., and Fransaer, Jan. On the electrochemical deposition of metal–organic frameworks. United States: N. p., 2016. Web. doi:10.1039/c5ta10782b.
Campagnol, Nicolo, Van Assche, Tom R. C., Li, Minyuan, Stappers, Linda, Dinca, Mircea, Denayer, Joeri F. M., Binnemans, Koen, De Vos, Dirk E., & Fransaer, Jan. On the electrochemical deposition of metal–organic frameworks. United States. doi:10.1039/c5ta10782b.
Campagnol, Nicolo, Van Assche, Tom R. C., Li, Minyuan, Stappers, Linda, Dinca, Mircea, Denayer, Joeri F. M., Binnemans, Koen, De Vos, Dirk E., and Fransaer, Jan. Thu . "On the electrochemical deposition of metal–organic frameworks". United States. doi:10.1039/c5ta10782b. https://www.osti.gov/servlets/purl/1437122.
@article{osti_1437122,
title = {On the electrochemical deposition of metal–organic frameworks},
author = {Campagnol, Nicolo and Van Assche, Tom R. C. and Li, Minyuan and Stappers, Linda and Dinca, Mircea and Denayer, Joeri F. M. and Binnemans, Koen and De Vos, Dirk E. and Fransaer, Jan},
abstractNote = {In this paper we study and compare the anodic and cathodic electrodeposition of Metal–Organic Frameworks (MOFs) and suggest guidelines for the electrodeposition of new MOFs with this technique. KHUST-1 was electrodeposited both anodically and cathodically and a four step mechanism is proposed to explain the anodic synthesis.},
doi = {10.1039/c5ta10782b},
journal = {Journal of Materials Chemistry. A},
number = 10,
volume = 4,
place = {United States},
year = {2016},
month = {2}
}

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Cited by: 18 works
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Works referenced in this record:

A Chemically Functionalizable Nanoporous Material [Cu3(TMA)2(H2O)3]n
journal, February 1999


Metal–Organic Framework Thin Films: From Fundamentals to Applications.
journal, September 2011

  • Bétard, Angélique; Fischer, Roland A.
  • Chemical Reviews, Vol. 112, Issue 2, p. 1055-1083
  • DOI: 10.1021/cr200167v

The Chemistry and Applications of Metal-Organic Frameworks
journal, August 2013

  • Furukawa, H.; Cordova, K. E.; O'Keeffe, M.
  • Science, Vol. 341, Issue 6149, p. 1230444-1230444
  • DOI: 10.1126/science.1230444