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Title: Chemical and valence reconstruction at the surface of SmB 6 revealed by means of resonant soft x-ray reflectometry

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Publisher's Accepted Manuscript
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Physical Review B
Additional Journal Information:
Journal Name: Physical Review B Journal Volume: 97 Journal Issue: 20; Journal ID: ISSN 2469-9950
American Physical Society
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United States

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Zabolotnyy, V. B., Fürsich, K., Green, R. J., Lutz, P., Treiber, K., Min, Chul-Hee, Dukhnenko, A. V., Shitsevalova, N. Y., Filipov, V. B., Kang, B. Y., Cho, B. K., Sutarto, R., He, Feizhou, Reinert, F., Inosov, D. S., and Hinkov, V. Chemical and valence reconstruction at the surface of SmB 6 revealed by means of resonant soft x-ray reflectometry. United States: N. p., 2018. Web. doi:10.1103/PhysRevB.97.205416.
Zabolotnyy, V. B., Fürsich, K., Green, R. J., Lutz, P., Treiber, K., Min, Chul-Hee, Dukhnenko, A. V., Shitsevalova, N. Y., Filipov, V. B., Kang, B. Y., Cho, B. K., Sutarto, R., He, Feizhou, Reinert, F., Inosov, D. S., & Hinkov, V. Chemical and valence reconstruction at the surface of SmB 6 revealed by means of resonant soft x-ray reflectometry. United States. doi:10.1103/PhysRevB.97.205416.
Zabolotnyy, V. B., Fürsich, K., Green, R. J., Lutz, P., Treiber, K., Min, Chul-Hee, Dukhnenko, A. V., Shitsevalova, N. Y., Filipov, V. B., Kang, B. Y., Cho, B. K., Sutarto, R., He, Feizhou, Reinert, F., Inosov, D. S., and Hinkov, V. Mon . "Chemical and valence reconstruction at the surface of SmB 6 revealed by means of resonant soft x-ray reflectometry". United States. doi:10.1103/PhysRevB.97.205416.
title = {Chemical and valence reconstruction at the surface of SmB 6 revealed by means of resonant soft x-ray reflectometry},
author = {Zabolotnyy, V. B. and Fürsich, K. and Green, R. J. and Lutz, P. and Treiber, K. and Min, Chul-Hee and Dukhnenko, A. V. and Shitsevalova, N. Y. and Filipov, V. B. and Kang, B. Y. and Cho, B. K. and Sutarto, R. and He, Feizhou and Reinert, F. and Inosov, D. S. and Hinkov, V.},
abstractNote = {},
doi = {10.1103/PhysRevB.97.205416},
journal = {Physical Review B},
number = 20,
volume = 97,
place = {United States},
year = {2018},
month = {5}

Journal Article:
Free Publicly Available Full Text
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DOI: 10.1103/PhysRevB.97.205416

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Works referenced in this record:

Density-functional calculation of effective Coulomb interactions in metals
journal, April 1991

Magnetic and nonmagnetic doping dependence of the conducting surface states in Sm B 6
journal, October 2016

X-ray photoreduction of U(VI)-bearing compounds
journal, March 2011

  • Mercier-Bion, F.; Drot, R.; Ehrhardt, J. J.
  • Surface and Interface Analysis, Vol. 43, Issue 4
  • DOI: 10.1002/sia.3617

Surface state reconstruction in ion-damaged SmB 6
journal, February 2015

What determines the probing depth of electron yield XAS?
journal, February 1995

Efficient real-frequency solver for dynamical mean-field theory
journal, August 2014

Bulk and surface electronic properties of SmB 6 : A hard x-ray photoelectron spectroscopy study
journal, October 2017

Surface Studies of Solids by Total Reflection of X-Rays
journal, July 1954

Electron-yield saturation effects in L -edge x-ray magnetic circular dichroism spectra of Fe, Co, and Ni
journal, March 1999

Surface electronic structure of the topological Kondo-insulator candidate correlated electron system SmB6
journal, December 2013

  • Neupane, M.; Alidoust, N.; Xu, S-Y.
  • Nature Communications, Vol. 4, Issue 1
  • DOI: 10.1038/ncomms3991

Mixed-Valence State in SmB 6
journal, May 1994

Termination-dependent surface in-gap states in a potential mixed-valent topological insulator: SmB 6
journal, August 2014

Quantitative analysis by X-ray induced total electron yield (TEY) compared to XRFA
journal, March 2004

3d x-ray-absorption lines and the 3 d 9 4 f n + 1 multiplets of the lanthanides
journal, October 1985

Tuning Bulk and Surface Conduction in the Proposed Topological Kondo Insulator SmB 6
journal, March 2015

Two-component analysis of the 4f multiplet of samarium hexaboride
journal, February 2015

LaB6 and SmB6 (001) surfaces studied by angle-resolved XPS, LEED and ISS
journal, July 1979

The nature of spatiotemporal changes in cerebral hemodynamics as manifested in functional magnetic resonance imaging
journal, April 1997

  • Mitra, Partha P.; Ogawa, Seiji; Hu, Xiaoping
  • Magnetic Resonance in Medicine, Vol. 37, Issue 4
  • DOI: 10.1002/mrm.1910370407

Lack of proportionality of total electron yield and soft x-ray absorption coefficient
journal, January 2000

  • Henneken, H.; Scholze, F.; Ulm, G.
  • Journal of Applied Physics, Vol. 87, Issue 1
  • DOI: 10.1063/1.371854

Orbital reflectometry of oxide heterostructures
journal, February 2011

  • Benckiser, Eva; Haverkort, Maurits W.; Brück, Sebastian
  • Nature Materials, Vol. 10, Issue 3
  • DOI: 10.1038/nmat2958

Fe 2p absorption in magnetic oxides: Quantifying angular-dependent saturation effects
journal, August 2000

  • Gota, Susana; Gautier-Soyer, Martine; Sacchi, Maurizio
  • Physical Review B, Vol. 62, Issue 7
  • DOI: 10.1103/PhysRevB.62.4187

Magnetic excitation spectrum of mixed-valence SmB 6 studied by neutron scattering on a single crystal
journal, January 1995

  • Alekseev, P. A.; Mignot, J. M.; Rossat-Mignod, J.
  • Journal of Physics: Condensed Matter, Vol. 7, Issue 2
  • DOI: 10.1088/0953-8984/7/2/007

Suppression of magnetic excitations near the surface of the topological Kondo insulator SmB 6
journal, January 2017

Hybridization, Inter-Ion Correlation, and Surface States in the Kondo Insulator SmB 6
journal, February 2013

Imperfection of the Sm sublattice and valence instability in compounds based on SmB6
journal, March 1999

  • Nefedova, E. V.; Alekseev, P. A.; Klement’ev, E. S.
  • Journal of Experimental and Theoretical Physics, Vol. 88, Issue 3
  • DOI: 10.1134/1.558830

Elastic scattering effects in the electron mean free path in a graphite overlayer studied by photoelectron spectroscopy and LEED
journal, January 2005

Photon-stimulated desorption from rare earth oxides
journal, September 1983

Intrinsic deviations in fluorescence yield detected x-ray absorption spectroscopy: the case of the transition metal L 2,3 edges
journal, October 2012

An in-vacuum diffractometer for resonant elastic soft x-ray scattering
journal, July 2011

  • Hawthorn, D. G.; He, F.; Venema, L.
  • Review of Scientific Instruments, Vol. 82, Issue 7
  • DOI: 10.1063/1.3607438

Surface and electronic structure of SmB through scanning tunneling microscopy
journal, April 2016

A Study of the Electronic Structure of Rare Earth Hexaborides
journal, April 1985

  • Grushko, Yu. S.; Paderno, Yu. B.; Ya. Mishin, K.
  • physica status solidi (b), Vol. 128, Issue 2
  • DOI: 10.1002/pssb.2221280225

Multipolar phases and magnetically hidden order: review of the heavy-fermion compound Ce 1− x La x B 6
journal, May 2016

Surface Kondo effect and non-trivial metallic state of the Kondo insulator YbB12
journal, August 2016

  • Hagiwara, Kenta; Ohtsubo, Yoshiyuki; Matsunami, Masaharu
  • Nature Communications, Vol. 7, Issue 1
  • DOI: 10.1038/ncomms12690

Topological surface state in the Kondo insulator samarium hexaboride
journal, March 2014

  • Kim, D. J.; Xia, J.; Fisk, Z.
  • Nature Materials, Vol. 13, Issue 5
  • DOI: 10.1038/nmat3913

X-ray initiated molecular photochemistry of Cl-containing adsorbates on a Si(100) surface using synchrotron radiation
journal, September 2006

Is samarium metal in an intermediate valence state?
journal, April 1977

X-ray-absorption near-edge structure study in mixed-valent samarium systems
journal, April 1990

Carrier-Density Control of the SrTiO 3 (001) Surface 2D Electron Gas studied by ARPES
journal, May 2015

  • Walker, Siobhan McKeown; Bruno, Flavio Yair; Wang, Zhiming
  • Advanced Materials, Vol. 27, Issue 26
  • DOI: 10.1002/adma.201501556

The accumulation of disorder, subject to saturation and sputter limitation, in ion irradiated solids
journal, January 1978

Chemical selective microstructural analysis of thin film using resonant x-ray reflectivity
journal, July 2013

  • Nayak, Maheswar; Lodha, G. S.
  • Journal of Applied Physics, Vol. 114, Issue 2
  • DOI: 10.1063/1.4812245

Distribution of Eigenvalues for some sets of Random Matrices
journal, April 1967

Theoretical foundation of X-ray and neutron reflectometry
journal, June 1995

In Situ Control of Separate Electronic Phases on SrTiO 3 Surfaces by Oxygen Dosing
journal, June 2016

  • Dudy, Lenart; Sing, Michael; Scheiderer, Philipp
  • Advanced Materials, Vol. 28, Issue 34
  • DOI: 10.1002/adma.201600046

Valence characterisation of the subsurface region in
journal, May 2016

Electronic and Magnetic Structure of Sm B 6
journal, February 1970

Electron Tunneling into Intermediate-Valence Materials
journal, October 1982

Surface properties of SmB 6 from x-ray photoelectron spectroscopy
journal, November 2014

Magnetic excitations in CeB6
journal, October 1985

  • Loewenhaupt, M.; Carpenter, J. M.; Loong, C. -K.
  • Journal of Magnetism and Magnetic Materials, Vol. 52, Issue 1-4
  • DOI: 10.1016/0304-8853(85)90270-7

Valence-state reflectometry of complex oxide heterointerfaces
journal, September 2016

Branching ratio in x-ray absorption spectroscopy
journal, August 1988

Topological Kondo Insulators
journal, March 2010

Model-independent decomposition of two-state data
journal, December 2013

Low-temperature thermal expansion of SmB 6 : Evidence for a single energy scale in the thermodynamics of Kondo insulators
journal, June 1994

Sm B 6 : Kondo Insulator or Exotic Metal?
journal, February 1995

Additional energy scale in SmB6 at low-temperature
journal, December 2016

  • Jiao, L.; Rößler, S.; Kim, D. J.
  • Nature Communications, Vol. 7, Issue 1
  • DOI: 10.1038/ncomms13762

Investigation of the structure of thin HfO 2 films by soft x-ray reflectometry techniques
journal, March 2009

Element Specific Monolayer Depth Profiling
journal, August 2014

  • Macke, Sebastian; Radi, Abdullah; Hamann-Borrero, Jorge E.
  • Advanced Materials, Vol. 26, Issue 38
  • DOI: 10.1002/adma.201402028

Valence fluctuation phenomena
journal, January 1981

  • Lawrence, J. M.; Riseborough, P. S.; Parks, R. D.
  • Reports on Progress in Physics, Vol. 44, Issue 1
  • DOI: 10.1088/0034-4885/44/1/001

Sputtering—a review of some recent experimental and theoretical aspects
journal, November 1975

Surface science studies of metal hexaborides
journal, April 2012

Racah materials: role of atomic multiplets in intermediate valence systems
journal, October 2015

  • Shick, A. B.; Havela, L.; Lichtenstein, A. I.
  • Scientific Reports, Vol. 5, Issue 1
  • DOI: 10.1038/srep15429

Evidence for in-gap surface states on the single phase SmB6(001) surface
journal, October 2017

Screening effects in the core-level spectra of mixed-valence compounds
journal, August 1982

Interpretation of the Shirley background in x-ray photoelectron spectroscopy analysis
journal, July 2001

  • Castle, J. E.; Salvi, A. M.
  • Journal of Vacuum Science & Technology A: Vacuum, Surfaces, and Films, Vol. 19, Issue 4
  • DOI: 10.1116/1.1378074

Multiplet ligand-field theory using Wannier orbitals
journal, April 2012

NEXAFS microscopy and resonant scattering: Composition and orientation probed in real and reciprocal space
journal, February 2008

4 f Crystal Field Ground State of the Strongly Correlated Topological Insulator SmB 6
journal, January 2018

Bands, resonances, edge singularities and excitons in core level spectroscopy investigated within the dynamical mean-field theory
journal, December 2014

Correlated Topological Insulators with Mixed Valence
journal, February 2013

Intermediate-valent Sm B 6 and the hybridization model: An optical study
journal, January 1984

Irreversible proliferation of magnetic moments at cleaved surfaces of the topological Kondo insulator SmB 6
journal, May 2017

Polarity-Driven Surface Metallicity in SmB 6
journal, November 2013

Resonant elastic soft x-ray scattering
journal, April 2013

Emergence of a Coherent In-Gap State in the SmB 6 Kondo Insulator Revealed by Scanning Tunneling Spectroscopy
journal, March 2014

Hybridization gap and Fano resonance in SmB 6
journal, March 2014

  • Rößler, Sahana; Jang, Tae-Hwan; Kim, Dae-Jeong
  • Proceedings of the National Academy of Sciences, Vol. 111, Issue 13
  • DOI: 10.1073/pnas.1402643111

Samarium hexaboride is a trivial surface conductor
journal, February 2018

Scattering of X-rays and neutrons at interfaces
journal, September 1995

Physical Properties of Sm B 6
journal, March 1971

Direct observation of the spin texture in SmB6 as evidence of the topological Kondo insulator
journal, July 2014

  • Xu, N.; Biswas, P. K.; Dil, J. H.
  • Nature Communications, Vol. 5, Issue 1
  • DOI: 10.1038/ncomms5566

Ion Desorption by Core-Hole Auger Decay
journal, April 1978

Neutron Scattering Study of the Intermediate-Valent Ground State in SmB 6
journal, August 1993

Multiplet effects in the electronic structure of intermediate-valence compounds
journal, April 2009

Near‐surface disorder studied with slow positrons
journal, July 1987

  • Vehanen, A.; Huttunen, P.; Mäkinen, J.
  • Journal of Vacuum Science & Technology A: Vacuum, Surfaces, and Films, Vol. 5, Issue 4
  • DOI: 10.1116/1.574818

Surface mixed valence in Sm and Sm B 6
journal, February 1980

Element-specific structural analysis of Si/B 4 C using resonant X-ray reflectivity
journal, May 2015

  • Nayak, Maheswar; Pradhan, P. C.; Lodha, G. S.
  • Journal of Applied Crystallography, Vol. 48, Issue 3
  • DOI: 10.1107/S1600576715005877

A Fourier series method for numerical Kramers-Kronig analysis
journal, April 1975

Crystal-field excitations in CeB 6 studied by Raman and neutron spectroscopy
journal, October 1984

GenX : an extensible X-ray reflectivity refinement program utilizing differential evolution
journal, November 2007

Quanty for core level spectroscopy - excitons, resonances and band excitations in time and frequency domain
journal, May 2016

Temperature dependence of the samarium oxidation state in SmB6 and Sm1-xLaxB6
journal, January 1980

Momentum microscopy of single crystals with detailed surface characterisation
journal, May 2016

Intermediate valence in rare earth systems
journal, March 1986

  • Sampathkumaran, E. V.
  • Hyperfine Interactions, Vol. 27, Issue 1-4
  • DOI: 10.1007/BF02354754

Singular-value decomposition and embedding dimension
journal, July 1987

Theoretical Form Factor, Attenuation, and Scattering Tabulation for Z =1–92 from E =1–10 eV to E =0.4–1.0 MeV
journal, January 1995

  • Chantler, C. T.
  • Journal of Physical and Chemical Reference Data, Vol. 24, Issue 1
  • DOI: 10.1063/1.555974

Sputtering-induced reemergence of the topological surface state in Bi 2 Se 3
journal, April 2016

Lattice Dynamics of Intermediate Valence Semiconductor SmB 6
journal, November 1989

Magnetic and Semiconducting Properties of Sm B 6
journal, February 1969

Ion damage overrides structural disorder in silicon surface nanopatterning by low-energy ion beam sputtering
journal, February 2015

Effect of photoelectron mean free path on the photoemission cross-section of Cu(111) and Ag(111) Shockley states
journal, December 2011

  • Lobo-Checa, Jorge; Ortega, J. Enrique; Mascaraque, Arantzazu
  • Physical Review B, Vol. 84, Issue 24
  • DOI: 10.1103/PhysRevB.84.245419

Surface valence transition in trivalent Eu insulating compounds observed by photoelectron spectroscopy
journal, June 1999

Surface and bulk electronic structure of the unconventional superconductor Sr 2 RuO 4 : unusual splitting of the β band
journal, June 2012

Study of valence mixing in SmB 6 by x-ray photoelectron spectroscopy
journal, November 1976

Correlation between Bulk Thermodynamic Measurements and the Low-Temperature-Resistance Plateau in SmB 6
journal, July 2014

Heavy fermion semiconductors
journal, May 2000

Photoemission experiments on YbInCu 4 : Surface effects and temperature dependence
journal, November 1998

The effect of sputtering-induced disorder on the surface dielectric tensor of Cu(110)
journal, August 1999

Resonant magnetic exciton mode in the heavy-fermion antiferromagnet CeB6
journal, January 2012

  • Friemel, G.; Li, Yuan; Dukhnenko, A. V.
  • Nature Communications, Vol. 3, Issue 1
  • DOI: 10.1038/ncomms1821

Momentum-dependent hybridization gap and dispersive in-gap state of the Kondo semiconductor SmB 6
journal, August 2012

The probing depth of total electron yield in the sub-keV range: TEY-XAS and X-PEEM
journal, July 2003

Kondo Hybridization and the Origin of Metallic States at the (001) Surface of SmB 6
journal, December 2013

Electronic structure of mixed-valence semiconductors in the LSDA + U approximation. II.  SmB 6 and YbB 12
journal, October 2002

Observation of possible topological in-gap surface states in the Kondo insulator SmB6 by photoemission
journal, December 2013

  • Jiang, J.; Li, S.; Zhang, T.
  • Nature Communications, Vol. 4, Issue 1
  • DOI: 10.1038/ncomms4010